Issue 8, 2022

Highly efficient catalytic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid using bimetallic Pt–Cu alloy nanoparticles as catalysts

Abstract

Bimetallic platinumcopper alloy nanoparticles are highly active catalysts for the oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA) under base-free conditions, with a high turnover frequency of up to 135 h−1 in aqueous solution. The Pt–Cu1.5/AC alloyed catalyst promoted the rate-determining step in the tandem oxidation compared with the monometallic Pt/AC catalyst, thus improving the catalytic performance.

Graphical abstract: Highly efficient catalytic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid using bimetallic Pt–Cu alloy nanoparticles as catalysts

Supplementary files

Article information

Article type
Communication
Submitted
12 10 2021
Accepted
17 12 2021
First published
20 12 2021

Chem. Commun., 2022,58, 1183-1186

Highly efficient catalytic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid using bimetallic Pt–Cu alloy nanoparticles as catalysts

X. Cheng, S. Li, S. Liu, Y. Xin, J. Yang, B. Chen and H. Liu, Chem. Commun., 2022, 58, 1183 DOI: 10.1039/D1CC05757J

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