Issue 6, 2010

Rhodium-catalyzed dehydrogenative borylation of cyclic alkenes

Abstract

A rhodium-catalyzed dehydrogenative borylation of cyclic alkenes is described. This reaction provides direct access to cyclic 1-alkenylboronic acid pinacol esters, useful intermediates in organic synthesis. Suzuki–Miyaura cross-coupling applications are also presented.

Graphical abstract: Rhodium-catalyzed dehydrogenative borylation of cyclic alkenes

Supplementary files

Article information

Article type
Communication
Submitted
14 10 2009
Accepted
10 12 2009
First published
05 1 2010

Chem. Commun., 2010,46, 907-909

Rhodium-catalyzed dehydrogenative borylation of cyclic alkenes

A. Kondoh and T. F. Jamison, Chem. Commun., 2010, 46, 907 DOI: 10.1039/B921387B

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