Issue 55, 2023

On the competition between six-membered and five-membered NHC towards alane centered ring expansion

Abstract

The combination of 6-SIDippĀ·AlH3 (1) and 5-IDipp resulted in the ring expansion of 6-NHC, while the five-membered NHC remained unchanged, which was subsequently explained by DFT studies. Besides, the substitution chemistry of 1 was also studied with TMSOTf and I2, which gave rise to the substitution of a hydride by triflate or iodide ligands.

Graphical abstract: On the competition between six-membered and five-membered NHC towards alane centered ring expansion

Supplementary files

Article information

Article type
Communication
Submitted
27 4 2023
Accepted
12 6 2023
First published
13 6 2023

Chem. Commun., 2023,59, 8540-8543

On the competition between six-membered and five-membered NHC towards alane centered ring expansion

K. Balayan, H. Sharma, K. Vanka, S. Ravindranathan, R. G. Gonnade and S. S. Sen, Chem. Commun., 2023, 59, 8540 DOI: 10.1039/D3CC02063K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements