Issue 7, 2022

Electrophilic and nucleophilic displacement reactions at the bridgehead borons of tris(pyridyl)borate scorpionate complexes

Abstract

Although a wide variety of boron-based “scorpionate” ligands have been implemented, a modular route that offers facile access to different substitution patterns at boron has yet to be developed. Here, we demonstrate new reactivity patterns at the bridgehead positions of a ruthenium tris(pyrid-2-yl)borate complex that allow for facile tuning of steric and electronic properties.

Graphical abstract: Electrophilic and nucleophilic displacement reactions at the bridgehead borons of tris(pyridyl)borate scorpionate complexes

Supplementary files

Article information

Article type
Communication
Submitted
02 11 2021
Accepted
24 12 2021
First published
24 12 2021

Chem. Commun., 2022,58, 977-980

Author version available

Electrophilic and nucleophilic displacement reactions at the bridgehead borons of tris(pyridyl)borate scorpionate complexes

J. Goura, J. McQuade, D. Shimoyama, R. A. Lalancette, J. B. Sheridan and F. Jäkle, Chem. Commun., 2022, 58, 977 DOI: 10.1039/D1CC06181J

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