Issue 41, 2021
From the journal:

CrystEngComm

Mass spectrometry guided surface modification of a tellurate ion templated 36-nucleus silver alkynyl nanocluster†

Lin-Lin Hou, ORCID logo a   Hong-Jing Li,a   Dong-Nan Yu,a   Xun Cheng,a   Zi-Xuan Yao,a   Kuan-Guan Liu ORCID logo *a  and  Xiao-Wei Yan*b  

* Corresponding authors

a State Key Laboratory of High-efficiency Coal Utilization and Green Chemical Engineering, and Ningxia Key Laboratory of Photovoltaic Materials, Ningxia University, Yin-Chuan 750021, China
E-mail: liukuanguan@nxu.edu.cn

b College of Food and Bioengineering, Research Institute of Food Science and Engineering Technology, Hezhou University, Hezhou 542899, China
E-mail: yanxiaoweizb@163.com

Abstract

Under the guidance of the ESI-MS result for [TeO6@Ag36(C[triple bond, length as m-dash]CtBu)18(tfa)12] (1, tfa = trifluoroacetate), a new 36-nucleus silver-alkynyl cluster substituted by four pentafluorobenzoates, named as [TeO6@Ag36(C[triple bond, length as m-dash]CtBu)18(tfa)8(F5PhCO2)4] (2), has been fabricated. After shell ligand substitution, cluster 2 emits green yellow light in the solid state and shows a remarkable change in the near-infrared luminescence emission compared to cluster 1.

Graphical abstract: Mass spectrometry guided surface modification of a tellurate ion templated 36-nucleus silver alkynyl nanocluster

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Article information

DOI
https://doi.org/10.1039/D1CE01061A
Article type
Communication
Submitted
10 Aug 2021
Accepted
15 Sep 2021
First published
16 Sep 2021

CrystEngComm, 2021,23, 7202-7205

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Mass spectrometry guided surface modification of a tellurate ion templated 36-nucleus silver alkynyl nanocluster

L. Hou, H. Li, D. Yu, X. Cheng, Z. Yao, K. Liu and X. Yan, CrystEngComm, 2021, 23, 7202 DOI: 10.1039/D1CE01061A

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