Issue 35, 2009

Synthesis of highly enantiomerically enriched planar chiral ruthenium complexes viaPd-catalysed asymmetric hydrogenolysis

Abstract

Key elements in this communication are a very efficient microwave synthesis of [RuCp(naphthalene)][PF6], the precursor of [RuCp(CH3CN)3][PF6], and a Pd-catalysed asymmetric hydrogenolysis to afford planar chiral ruthenium complexes with high levels of enantioselectivity using a bulky chiral phosphoramidite ligand.

Graphical abstract: Synthesis of highly enantiomerically enriched planar chiral ruthenium complexes viaPd-catalysed asymmetric hydrogenolysis

Supplementary files

Article information

Article type
Communication
Submitted
04 6 2009
Accepted
21 7 2009
First published
05 8 2009

Chem. Commun., 2009, 5227-5229

Synthesis of highly enantiomerically enriched planar chiral ruthenium complexes viaPd-catalysed asymmetric hydrogenolysis

A. Mercier, W. C. Yeo, J. Chou, P. D. Chaudhuri, G. Bernardinelli and E. P. Kündig, Chem. Commun., 2009, 5227 DOI: 10.1039/B910977C

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