Issue 38, 2009

Metal-catalyzed rearrangement of enantiomerically pure alkylidenecyclopropane derivatives as a new access to cyclobutenes possessing quaternary stereocenters

Abstract

Pd(II)- and Pt(II)-catalyzed ring-expansion of enantiomerically pure alkylidenecyclopropane derivatives leads to the formation of cyclobutene species with a complete preservation of the stereogenic center.

Graphical abstract: Metal-catalyzed rearrangement of enantiomerically pure alkylidenecyclopropane derivatives as a new access to cyclobutenes possessing quaternary stereocenters

Supplementary files

Article information

Article type
Communication
Submitted
28 5 2009
Accepted
07 8 2009
First published
02 9 2009

Chem. Commun., 2009, 5760-5762

Metal-catalyzed rearrangement of enantiomerically pure alkylidenecyclopropane derivatives as a new access to cyclobutenes possessing quaternary stereocenters

A. Masarwa, A. Fürstner and I. Marek, Chem. Commun., 2009, 5760 DOI: 10.1039/B910465H

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