Issue 32, 2009

Electronic and steric tuning of chiral diene ligands for rhodium-catalyzed asymmetric arylation of imines

Abstract

Rhodium-catalyzed asymmetric arylation of imines using electronically and sterically-modified chiral diene ligands gave the corresponding diarylmethylamines in high yield and with high enantioselectivity using just 0.3 mol% of catalyst.

Graphical abstract: Electronic and steric tuning of chiral diene ligands for rhodium-catalyzed asymmetric arylation of imines

Supplementary files

Article information

Article type
Communication
Submitted
06 3 2009
Accepted
24 4 2009
First published
19 5 2009

Chem. Commun., 2009, 4815-4817

Electronic and steric tuning of chiral diene ligands for rhodium-catalyzed asymmetric arylation of imines

K. Okamoto, T. Hayashi and V. H. Rawal, Chem. Commun., 2009, 4815 DOI: 10.1039/B904624K

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