Issue 44, 2013

Catalytic hydrogen production by a Ni–Ru mimic of NiFe hydrogenases involves a proton-coupled electron transfer step

Abstract

A combined electrochemical and theoretical study suggests that hydrogen evolution from weak acids catalyzed by a structural mimic of the active site of NiFe hydrogenases [Ni(xbsms)Ru(C6Me6)Cl]+ proceeds through proton-coupled electron transfer steps.

Graphical abstract: Catalytic hydrogen production by a Ni–Ru mimic of NiFe hydrogenases involves a proton-coupled electron transfer step

Supplementary files

Article information

Article type
Communication
Submitted
05 feb 2013
Accepted
05 apr 2013
First published
23 apr 2013

Chem. Commun., 2013,49, 5004-5006

Catalytic hydrogen production by a Ni–Ru mimic of NiFe hydrogenases involves a proton-coupled electron transfer step

S. Canaguier, V. Fourmond, C. U. Perotto, J. Fize, J. Pécaut, M. Fontecave, M. J. Field and V. Artero, Chem. Commun., 2013, 49, 5004 DOI: 10.1039/C3CC40987B

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