Issue 10, 2016

Postsynthetic bromination of UiO-66 analogues: altering linker flexibility and mechanical compliance

Abstract

A new member of the UiO-66 series of zirconium metal–organic frameworks (MOFs) is reported, and the postsynthetic bromination of its integral alkene moeities in a single-crystal to single-crystal manner is fully characterised. Nanoindentation is used to probe the bromination of unsaturated carbon–carbon bonds, in it and an analogous Zr MOF, which leads to more compliant materials with lower elastic moduli.

Graphical abstract: Postsynthetic bromination of UiO-66 analogues: altering linker flexibility and mechanical compliance

Supplementary files

Article information

Article type
Communication
Submitted
17 ago 2015
Accepted
11 nov 2015
First published
11 nov 2015
This article is Open Access
Creative Commons BY license

Dalton Trans., 2016,45, 4132-4135

Author version available

Postsynthetic bromination of UiO-66 analogues: altering linker flexibility and mechanical compliance

R. J. Marshall, T. Richards, C. L. Hobday, C. F. Murphie, C. Wilson, S. A. Moggach, T. D. Bennett and R. S. Forgan, Dalton Trans., 2016, 45, 4132 DOI: 10.1039/C5DT03178H

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