Issue 52, 2012

Targeted functionalisation of a hierarchically-structured porous coordination polymer crystal enhances its entire function

Abstract

Spatiospecific functionalisation of a shell crystal was performed in a core–shell crystal of a porous coordination polymer (PCP) via post-synthetic modification (PSM). The shell crystal allowed the core crystal to selectively accumulate N,N-dimethylaniline (DMA) and afford the intense exciplex fluorescence.

Graphical abstract: Targeted functionalisation of a hierarchically-structured porous coordination polymer crystal enhances its entire function

Supplementary files

Article information

Article type
Communication
Submitted
26 feb 2012
Accepted
30 mar 2012
First published
02 apr 2012

Chem. Commun., 2012,48, 6472-6474

Targeted functionalisation of a hierarchically-structured porous coordination polymer crystal enhances its entire function

K. Hirai, S. Furukawa, M. Kondo, M. Meilikhov, Y. Sakata, O. Sakata and S. Kitagawa, Chem. Commun., 2012, 48, 6472 DOI: 10.1039/C2CC31421E

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