Issue 36, 2010
From the journal:

Chemical Communications

Design and synthesis of tetranuclear clustermonophosphine-cyclopalladated ferrocenylpyrimidinone complexes from the palladium-catalyzed hydroxylation of chloropyrimidine†

Chen Xu,*a   Ya-Peng Zhang,b   Zhi-Qiang Wang,a   Wei-Jun Fu,a   Xin-Qi Hao,b   Yan Xub  and  Bao-Ming Ji*a  

* Corresponding authors

a College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, Henan 471022, China
E-mail: xubohan@163.com

b Department of Chemistry, Zhengzhou University, Zhengzhou, Henan 450052, China

Abstract

Hydroxylation of a monomeric triphenylphosphine-cyclopalladated ferrocenylchloropyrimidine [PdCl{[(η5-C5H5)]Fe[(η5-C5H3)-N2C4H2-Cl]}(PPh3)] with KOH gave the first example of a tetranuclear cluster monophosphine-palladacycle [Pd{[(η5-C5H5)]Fe[(η5-C5H3)-N2C4H2O]}(PPh3)]4. Additionally, the analogous tricyclohexylphosphine tetranuclear cluster palladacycle has also been successfully synthesized by the same method.

Graphical abstract: Design and synthesis of tetranuclear cluster monophosphine-cyclopalladated ferrocenylpyrimidinone complexes from the palladium-catalyzed hydroxylation of chloropyrimidine

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Article information

DOI
https://doi.org/10.1039/C0CC01870H
Article type
Communication
Submitted
13 giu 2010
Accepted
14 lug 2010
First published
23 ago 2010

Chem. Commun., 2010,46, 6852-6854

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Design and synthesis of tetranuclear cluster monophosphine-cyclopalladated ferrocenylpyrimidinone complexes from the palladium-catalyzed hydroxylation of chloropyrimidine

C. Xu, Y. Zhang, Z. Wang, W. Fu, X. Hao, Y. Xu and B. Ji, Chem. Commun., 2010, 46, 6852 DOI: 10.1039/C0CC01870H

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