Issue 40, 2013

Mechanical properties of a metal–organic framework containing hydrogen-bonded bifluoride linkers

Abstract

We report the mechanical properties of a framework structure, [Cu2F(HF)(HF2)(pyz)4][(SbF6)2]n (pyz = pyrazine), in which [Cu(pyz)2]2+ layers are pillared by HF2 anions containing the exceptionally strong F–H⋯F hydrogen bonds. Nanoindentation studies on single-crystals clearly demonstrate that such bonds are extremely robust and mechanically comparable with coordination bonds in this system.

Graphical abstract: Mechanical properties of a metal–organic framework containing hydrogen-bonded bifluoride linkers

Supplementary files

Article information

Article type
Communication
Submitted
21 feb 2013
Accepted
27 mar 2013
First published
28 mar 2013

Chem. Commun., 2013,49, 4471-4473

Mechanical properties of a metal–organic framework containing hydrogen-bonded bifluoride linkers

W. Li, M. S. R. N. Kiran, J. L. Manson, J. A. Schlueter, A. Thirumurugan, U. Ramamurty and A. K. Cheetham, Chem. Commun., 2013, 49, 4471 DOI: 10.1039/C3CC41357H

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