Issue 47, 2012

An inorganic propellane with central B–B bond

Abstract

9,10-Dihydroanthracene-9,10-diyl-bridged B2(NMe2)2 readily adds [H2NMe2]+, HCl and F3CCOOH across its partial B[double bond, length as m-dash]N double bond(s), thereby forming mono- or diadducts; treatment with 1-iso-propyl-2-mercaptoimidazole leads to a triply B–B-bridged propellane-like structure.

Graphical abstract: An inorganic propellane with central B–B bond

Supplementary files

Article information

Article type
Communication
Submitted
28 mar 2012
Accepted
23 apr 2012
First published
24 apr 2012

Chem. Commun., 2012,48, 5886-5888

An inorganic propellane with central B–B bond

S. Pospiech, S. Brough, M. Bolte, H. Lerner, H. F. Bettinger and M. Wagner, Chem. Commun., 2012, 48, 5886 DOI: 10.1039/C2CC32256K

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