A series of six isomeric Re(I) tricarbonyl complexes bearing benzo[d]oxazole ligands exhibit tunable photocatalytic and electrochemical CO2 reduction activity. Ligand design offers key insights into optimizing catalysts for solar-to-fuel conversion.
This review article highlights the use of Betti base derivatives in transformation reactions for synthesizing organic compounds, particularly heterocyclic molecules, and investigation into their pharmacological properties.
Silver catalysed reactions have become an indispensable tool in organic synthesis due to their high efficiency, selectivity, and environmental friendliness.
Annulation of 2-nitrophenols and N,N-dialkyl-3-nitroanilines with styrenes in the presence of elemental sulfur and the base DABCO successfully yielded 2-benzyl benzoxazoles and 2-benzyl benzothiazoles, respectively.
The PD reaction mechanism of t-2FSBO and the AIE properties of the two resultant isomers, t-2FPCBO and c-2FPCBO, in both different environments are theoretically investigated using PCM and QM/MM models coupled with the TVCF-based rate theory.