We shed light on the influence of the catalyst structure and reaction conditions on the spontaneity of the dimerization process for popular chiral organocatalysts derived from phosphoric acids using high-level quantum mechanical calculations.
Four organocatalytic approaches for the synthesis of axially chiral tetrasubstituted allenes are described with new critical insights into reaction scope and mechanisms.
This review article presents an in-depth analysis of the strategies and methodologies for using chiral phosphoric acids as organocatalysts in asymmetric syntheses from recent literature.
A cyclic-anion dopant (Li-CYCLIC) with high doping performance and intrinsic stability was used for efficient and stable perovskite solar cells.
Alternation of flexible and rigid substituents improved the hole mobility and morphology of composite films in copolymers of phenothiazine and ethylenedioxythiophene, boosting the performance of perovskite solar cells.