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DOI: 10.1039/D5CY00766F

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DOI: 10.3390/molecules29245952

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DOI: 10.1002/anie.202520739

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DOI: 10.1002/ange.202514794

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DOI: 10.1002/cctc.202400756

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DOI: 10.1038/s41467-024-53021-x

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DOI: 10.1021/acscatal.5c04020

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DOI: 10.1021/acscatal.4c03153

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DOI: 10.1016/j.mcat.2024.114645

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DOI: 10.1002/cctc.202401398

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DOI: 10.1021/acs.orglett.4c04722

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DOI: 10.1002/aoc.70221

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DOI: 10.1002/ajoc.202400762

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DOI: 10.1021/jacs.5c18484