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The diarylaminobiphenyl-functionalized bimesityls 1 and 2 exhibit amorphous nature, high thermal stability and excellent blue emission in the solid state. They serve as both hole-transporting and emissive materials in OLEDs for blue emission with high external quantum efficiencies.

Graphical abstract: Blue light-emitting and hole-transporting amorphous molecular materials based on diarylaminobiphenyl-functionalized bimesitylenes

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