Plasma-driven redox mechanism in the reverse water–gas shift reaction over Ni–In intermetallic catalysts

Abstract

The reverse water–gas shift (RWGS) reaction has been recognized as a promising strategy for CO2 valorization. However, it faces limitations due to low activity and poor CO selectivity at low temperatures. In this study, we report that plasma can effectively promote the low-temperature RWGS reaction over Ni–In intermetallic catalysts. The formation of the Ni–In intermetallic phases completely suppresses CH4 formation and achieves 100% CO selectivity. Through in situ transmission infrared spectroscopy (TIR) and in situ X-ray absorption fine-structure (XAFS) analysis, we monitored the changes occurring on the catalyst surface during the plasma reaction. The interaction between redox-active sites present in the Ni–In intermetallic catalysts and plasma-activated species lowers the activation energy, thereby facilitating the RWGS reaction at low temperatures. This study offers fundamental insights into how plasma-activated species enhance catalysis and the underlying mechanisms of low-temperature activation in plasma catalysis.

Graphical abstract: Plasma-driven redox mechanism in the reverse water–gas shift reaction over Ni–In intermetallic catalysts

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Article information

Article type
Paper
Submitted
07 apr 2025
Accepted
09 lug 2025
First published
17 lug 2025
This article is Open Access
Creative Commons BY-NC license

EES Catal., 2025, Advance Article

Plasma-driven redox mechanism in the reverse water–gas shift reaction over Ni–In intermetallic catalysts

D. Kim, Z. Wenjun, K. Dong, B. Lu, D. Li, S. Takakusagi, S. Furukawa and T. Nozaki, EES Catal., 2025, Advance Article , DOI: 10.1039/D5EY00101C

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