This website uses cookies to give you the best user experience. If you continue without changing your settings we'll assume you are happy to receive all RSC cookies. You can change your cookie settings by navigating to our Privacy and Cookies page and following the instructions. These instructions are also obtainable from the privacy link at the bottom of any RSC page.
Lite Version|Standard version
Home > Organic & Biomolecular ... >
To gain access to this content please
Log in via your home Institution.
Log in with your member or subscriber username and password.
Download


Buy PDF Add PDF to Basket (£42,50*)
*Exclusive of taxes
This article contains 5 page(s)
Abstract | Cited by

To reconcile the urgent need to access well defined β-configured 2,6-di-deoxypyranose analogues for chemical biology, with the intrinsic α-selectivity of the native system, the directing role of fluorine at C2 has been explored. Localised partial charge inversion (C–Hδ+ → C–Fδ−) elicits a reversal of the substrate-based α-stereoselectivity, irrespective of the protecting group electronics.

Graphical abstract: Fluorine-directed 1,2-trans glycosylation of rare sugars

Page: ^ Top


Enter Keywords, author, title,reference, or DOI
Log in | Register