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Abstract | Cited by

A regio- and stereoselective synthesis of highly substituted α-haloenamides was described via the zinc halide mediated direct addition of benzhydryl halides to ynamides under mild conditions. The products α-haloenamides were further transformed into multisubstituted enamides via Suzuki and Sonogashira cross-coupling reactions.

Graphical abstract: Synthesis of α-haloenamides via zinc halide mediated direct addition of benzhydryl halides to ynamides

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