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Visible-light-derived O2 production was yielded by conjugating water oxidation catalysis by [(OH2)(terpy)Mn(μ-O)2Mn(terpy)(OH2)]3+ as an oxygen evolving center model and photo-sensitization of [Ru(bpy)3]2+ as a photoexcitation center model at an interlayer of mica.

Graphical abstract: An artificial model of photosynthetic photosystem II: visible-light-derived O2 production from water by a di-μ-oxo-bridged manganese dimer as an oxygen evolving center

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