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The first palladium-catalyzed Suzuki cross-coupling of N′-tosyl arylhydrazines with various organoboron reagents has been developed for the preparation of biaryl compounds in high yields. N′-Tosyl arylhydrazine as a readily available and stable electrophile also demonstrated its generality in a number of coupling reactions.

Graphical abstract: Palladium-catalyzed Suzuki cross-coupling of N′-tosyl arylhydrazines

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