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A novel structurally simple calix[4]arene appended 8-amidoquinoline linked conjugate was synthesized and has been used as a turn-on fluorescence probe for Zn2+ and turn off fluorescence probe for F. Moreover, this probe has been applied for Zn2+ detection in blood serum upto 8.7 μM and fluoride detection upto 22 nM in waste water samples, using emission spectra.

Graphical abstract: An ICT based “turn on/off” quinoline armed calix[4]arene fluoroionophore: its sensing efficiency towards fluoride from waste water and Zn2+ from blood serum

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