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Abstract | Cited by

The atomic structure of an electrodeposited Ni catalyst film is dominated by extensive di-μ-oxido bridging between NiIII/IV ions, as revealed by X-ray absorption spectroscopy. The structure is surprisingly similar to that of an analogous Co-based film and colloidal Mn-based catalysts. Structural requirements for water oxidation are discussed.

Graphical abstract: Nickel-oxido structure of a water-oxidizing catalyst film

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