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Diameter dependent electron donor behavior of (6,5)- and (7,6)-enriched semiconducting SWCNT is proved by constructing supramolecular nanohybrids with pyrene functionalized electron acceptor, fullerene, and the subsequent photocatalytic/ photoelectrochemical processes.

Graphical abstract: Diameter dependent electron transfer in supramolecular nanohybrids of (6,5)- or (7,6)-enriched semiconducting SWCNT as donors and fullerene as acceptor

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