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DOI: 10.1039/A906009J (Paper) Reference Section for: J. Mater. Chem., 1999, 9, 3087-3092

Syntheses and structures of the open-framework phases (CH3NH3)3·Zn4O(AsO4)3 and (CH3NH3)3·Zn4O(PO4)3 related to the M3Zn4O(XO4)3·nH2O family

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William T. A. Harrison, Mark L. F. Phillips, Alejandra V. Chavez and Tina M. Nenoff

Abstract

The solution-mediated syntheses and single crystal structures of the new open-framework phases (CH3NH3)3·Zn4O(AsO4)3 and (CH3NH3)3·Zn4O(PO4)3 are reported. These compounds are built up from vertex-sharing three-dimensional “OZn4” + ZnO4 + AsO4/PO4 tetrahedral frameworks encapsulating methylammonium cations in three-dimensional channel systems. These phases are closely related to the zeolite-like M3Zn4O(XO4)3·nH2O family of phases.

References

  1. A. K. Cheetham, G. Férey and T. Loiseau, Angew. Chem., Int. Ed., 1999, in press, and references therein Search PubMed.
  2. M. E. Davis and R. F. Lobo, Chem. Mater., 1992, 4, 756 CrossRef CAS.
  3. S. L. Lawton and W. J. Rohrbaugh, Science, 1990, 247, 1319 CrossRef CAS.
  4. W. T. A. Harrison, Z. Bircsak, L. Hannooman and Z. Zhang, J. Solid State Chem., 1998, 136, 93 CrossRef CAS.
  5. M. Roca, M. D. Marcos, P. Amorós, J. Alamo, A. Beltrán-Porter and D. Beltrán-Porter, Inorg. Chem., 1997, 36, 3414 CrossRef CAS.
  6. W. T. A. Harrison, R. W. Broach, R. A. Bedard, T. E. Gier, X. Bu and G. D. Stucky, Chem. Mater., 1996, 8, 691 CrossRef CAS.
  7. W. T. A. Harrison, T. E. Gier, T. E. Martin and G. D. Stucky, J. Mater. Chem., 1992, 2, 175 RSC.
  8. M. Wallau, J. Patarin, I. Widmer, P. Caullet, J. L. Guth and L. Huve, Zeolites, 1994, 14, 402 CrossRef CAS.
  9. T. J. B. Holland and S. A. T. Redfern, Mineral. Mag., 1997, 61, 65 Search PubMed.
  10. G. M. Sheldrick, SHELXS86 User Guide, University of Göttingen, Germany, 1986 Search PubMed.
  11. R. Herbst-Irmer and G. M. Sheldrick, Acta Crystallogr., Sect. B, 1998, 54, 443 CrossRef.
  12. D. J. Watkin, J. R. Carruthers and P. W. Betteridge, CRYSTALS User Guide, Chemical Crystallography Laboratory, University of Oxford, UK, 1999 Search PubMed.
  13. Program SMART, Siemens Inc., Madison, Wisconsin, 1997.
  14. Program SADABS, Siemens Inc., Madison, Wisconsin, 1997.
  15. L. J. Farrugia, J. Appl. Crystallogr., 1997, 30, 565 CrossRef CAS.
  16. I. D. Brown, J. Appl. Crystallogr., 1996, 29, 479 CrossRef CAS.
  17. JCPDS cards 1-798 (Zn2As2O7) and 36-1451 (ZnO).
  18. A. L. Spek, Acta Crystallogr., Sect. A, 1990, 46, C34.
  19. T. M. Nenoff, W. T. A. Harrison, T. E. Gier and G. D. Stucky, J. Am. Chem. Soc., 1991, 113, 378 CrossRef CAS.
  20. W. T. A. Harrison, M. L. F. Phillips and X. Bu, unpublished work.
  21. S. Neeraj, S. Natarajan and C. N. R. Rao, Chem. Mater., 1999, 11, 1390 CrossRef CAS.
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