DOI: 10.1039/A907681F
(Paper)
Reference Section for: Chem. Commun., 1999, 2287-2288
Cation-controlled formation of [{MCl4}n]2n– chains in [4,4′-H2bipy][MCl4] (M = Mn, Cd): an alternative to the A2MCl4 <100> layer perovskite structure†
(Note: The full text of this document is currently only available in the PDF Version )
Amy L. Gillon, A. Guy Orpen, Jonathan Starbuck, Xi-Meng Wang, Yolanda Rodríguez-Martín and Catalina Ruiz-Pérez
Abstract
The cis-MCl2‥HN+ chelated hydrogen bond synthon has been exploited in preparation of crystalline [4,4′- H2bipy][MCl4] (M = Mn 2 and Cd 3), which shows a one-dimensional substructure of the form [{MCl4}n]2n– consisting of a kinked chain of doubly edge sharing MCl6 octahedra. These chains are cross-linked by hydrogen bonding to the [4,4′-H2bipy]2+ ions.
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