Meerwein–Ponndorf–Verley reduction of carbonyl compounds catalysed by Mg–Al hydrotalcite

(Note: The full text of this document is currently only available in the PDF Version )

Pramod S. Kumbhar, Jaime Sanchez-Valente, Joseph Lopez and François Figueras


Abstract

Properly activated Mg–Al hydrotalcite (Mg:Al = 3:1) is found to be a highly active, selective and regenerable heterogeneous catalyst for Meerwein–Ponndorf–Verley reduction of carbonyl compounds in the liquid phase.


References

  1. For a review, see: C. F. Grauw,, J. A. Peters, H. Van Bekkum and J. Huskens, Synthesis, 1994, 10, 1007 Search PubMed.
  2. G. H. Posner, A. W. Runquist and M. J. Chapdelaine, J. Org. Chem., 1977, 42, 1202 CrossRef CAS.
  3. E. J. Creyghton, S. D. Ganeshie, R. S. Downing and H. Van Bekkum, J. Chem. Soc., Chem. Commun., 1995, 1859 RSC; J. Mol. Catal., A: Chem., 1997, 115, 457 Search PubMed.
  4. J. Kaspar, A. Trovarelli, M. Lenarda and M. Graziani, Tettrahedron Lett., 1989, 30, 2705 Search PubMed.
  5. V. A. Ivanov, J. Bachelier, F. Audry and J. C. Lavalley, J. Mol. Catal., 1994, 91, 45 CrossRef CAS.
  6. H. Niyama and E. Echigoya, Bull. Chem. Soc. Jpn., 1972, 45, 938 CAS.
  7. S. Miyata, T. Kumura and M. Shimada, US Pat., 1975, 3 879 523 Search PubMed.
  8. K. Rao, F. Figueras, J. Sanchez and M. Gravelle, J. Catal., in the press Search PubMed.
Click here to see how this site uses Cookies. View our privacy policy here.