Molecular-based dielectric switching compounds [ClEt-Dabco][ReO4]2 and [BrEt-Dabco][ReO4]2 with high-temperature phase transition.
We report the synthesis of actinide–osmium polyhydrides and demonstrate their ability to promote photo-induced intra- and intermolecular C–H activation.
Metal phosphides (MPs) with unique and desirable physicochemical properties provide promising potential in implementable sustainable catalytic fields including electrocatalysis, photocatalysis, mild thermocatalysis, and interdisciplinary hybrid systems.
Facile syntheses of the first cyclopropametalla-2-benzopyrylium complexes containing fused metallapyrylium and metallacyclopropene units.
Fused rhena-phenalene complexes demonstrate Hückel aromaticity, σ-aromaticity (in the saturated rhenaoxirane ring and the unsaturated rhenacyclopropene ring), and pseudo π anti-aromaticity (induced paramagnetic properties).