We report a radical pathway for the synthesis of pyridine carboxamides from pyridine carbohydrazides and amines in EtOH/H2O via electrochemistry.
A non-traditional, divergent approach to the synthesis of pyrrole carboxamides from pyrrole carboxaldehydes and formamides or amines via oxidative amination in the presence of TBHP and a catalytic amount of TBAI is reported.
This review systematically summarizes the photocatalytic strategies for constructing ketones from carboxylic acids and their derivatives, emphasizing single-electron radical pathways.
This review highlights the recent advances in radical acylated difunctionalization of unsaturated carbon–carbon bonds and focuses on the mechanistic insights of these transformations.
We describe how N-hydroxyphthalimide (NHPI) promotes hydrogen atom transfer from aldehydes under electrochemical conditions. NHPI plays a multifunctional role, enabling the consideration of aldehydes or alcohols as sp3-carbon centered radicals.