[AuPh(CNPh)]2 complexes are modeled, and their electronic properties, optical properties, and solid state chemistry are studied.
Some MAX phase can be narrowband semiconductor with superior thermoelectric performance.
Phosphine-boranes do not promote oxidative addition of acyl chlorides to gold, but the phosphine-borane gold triflimide complex [iPr2P(o-C6H4)BCy2]AuNTf2 was found to catalyze the coupling of acyl chlorides and aryl stannanes.
The synthesis of Au(I)–IMT complexes via gold(I) coordination with imidazole-2-thione ligands is reported, forming mononuclear and dinuclear species. Ligand design influences structural variations and aurophilic interactions.
CR)n]
Two distinct stimuli-responsive luminescent assemblies (G and Y) of the title clusters are reported: the G-assembly exhibits photochromic luminescence, while the Y-assembly shows thermochromic luminescence.