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Looking deep into C–H functionalization: the synthesis and application of cyclopentadienyl and related metal catalysts

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Isatoic anhydride as a masked directing group and internal oxidant for Rh(iii)-catalyzed decarbonylative annulation through C–H activation: insights from DFT calculations

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One-step synthesis of cyanated pyrazolo[1,5-a]pyridines utilizing N-aminopyridines as a 1,3-dipole and a nitrogen source

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Transition metal- and oxidant-free [3 + 2] cyclization of azomethine imines utilizing vinylene carbonate as dual synthons

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Site-selective rhodium carbene transfer of 2 hydroxy-β-nitrostyrenes with diazo compounds En route to 2-alkylated benzofurans

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Practical conversion of gem-difluorocyclopropenes for the chemodivergent assembly of fluorinated heterocyclic frameworks

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Ru(ii)-Catalyzed C–H bond activation/annulation of N-iminopyridinium ylides with sulfoxonium ylides

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Rhodium-catalyzed transformations of diazo compounds via a carbene-based strategy: recent advances

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Rh(iii)-catalyzed cascade annulation reaction of N,N-dimethyl enaminones with iodonium ylides to give substituted isocoumarins

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Rhodium‐Catalyzed C−H Bond Annulation for the Synthesis of 5‐ and 6‐Membered N‐Heterocyclic Building Blocks

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Enantioconvergent Radical–Radical Cross-Coupling via Magnesium-Mediated Charge-Transfer Photocatalysis

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J. Am. Chem. Soc., 2025, 147, 25264
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Sulfilimines as Transformable and Retainable Directing Groups in Rhodium-Catalyzed ortho-C–H Bond Functionalization

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Ir(III)-catalyzed C–H alkenylation/annulation of N-iminopyridinium ylides with acrylates and alkynes

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Recent advances in developing highly atom-economic C–H annulation reactions in water

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Recent advances in synthesis of isocoumarins: An overview

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Recent Advances in the Synthesis of Nitrogen‐Containing Heterocycles Based on Hydrazine‐Directed C−H Bond Activation/Annulation Reactions

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Isoquinolone Syntheses by Annulation Protocols

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Silver-Catalyzed Cascade Approach to Access Fused Pyrazolo-naphthyridine and -isoquinoline Backbones and Investigation of Their Photophysical Properties

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ACS Omega, 2025, 10, 14063
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Cu(II)-Catalyzed C–H Amidation/Cyclization of Azomethine Imines with Dioxazolones via Acyl Nitrenes: A Direct Access to Diverse 1,2,4-Triazole Derivatives

Xiang Liu, Wen Li, Wenxuan Jiang, Hao Lu, Jiali Liu, Yijun Lin and Hua Cao

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Rh(III)-Catalyzed C–H Diamidation and Diamidation/Intramolecular Cyclization of N-Iminopyridinium Ylides with Dioxazolones

Xiang Li, Qing Zhao, Yang Shen and Ran Ma

J. Org. Chem., 2022, 87, 3468
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Synthesis of Diazo Compounds by Using NaN3 and Inexpensive SO2F2

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Rh-Catalyzed Cascade C-H Activation/Annulation of N-Hydroxybenzamides and Propargylic Acetates for Modular Access to Isoquinolones

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Synthesis of Functionalized Indoles by an Iridium-Catalyzed N–H Insertion Cascade: Nucleophilic Cyclization of Naphthylamines with α-Diazocarbonyl Compounds

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