Imine-functionalized polysiloxanes for supramolecular elastomers with tunable mechanical properties

Han Hu, Linlin Wang, Lili Wang, Lei Li and Shengyu Feng

Polym. Chem., 2020, 11, 7721
DOI: 10.1039/D0PY01253J

Synthesis of functionalized disiloxanes with nonconventional fluorescence via oxa-Michael addition reaction

Rui Wang, Shengyu Feng, Hailong Liu, Gang Yi and Dengxu Wang

New J. Chem., 2024, 48, 244
DOI: 10.1039/D3NJ04004F

Novel clickable and fluorescent poly(siloxane amine)s for reusable adhesives and reprocessable elastomers

Jie Zhou, Linlin Wang, Lei Li and Shengyu Feng

Polym. Chem., 2020, 11, 4780
DOI: 10.1039/D0PY00741B

Preparation and characterization of diphenyl silicone rubber/microfiber glass wool composite thermal control films

Lin Li, Xin Fu, Xiang Xu, Dafu Wei and Yong Guan

RSC Adv., 2023, 13, 15401
DOI: 10.1039/D3RA02118A

Ring-opening polymerization of six-membered 1,3-dioxa-2-silacycloalkanes by an organobase catalyst: precision polymerization and monomer regeneration by polymer degradation

Ikuto Tanaka, Sadahito Aoshima and Arihiro Kanazawa

Polym. Chem., 2025, 16, 2211
DOI: 10.1039/D5PY00204D

Design of a mechanically strong and highly stretchable thermoplastic silicone elastomer based on coulombic interactions

Jinfeng Shi, Na Zhao, Dongying Yan, Jianhui Song, Wenxin Fu and Zhibo Li

J. Mater. Chem. A, 2020, 8, 5943
DOI: 10.1039/D0TA01593H

Well-defined hydrogen and organofunctional polysiloxanes with spiro-fused siloxane backbones

Takahiro Kawatsu, Keita Fuchise, Katsuhiko Takeuchi, Jun-Chul Choi, Kazuhiko Sato and Kazuhiro Matsumoto

Polym. Chem., 2021, 12, 2222
DOI: 10.1039/D0PY01503B

A transparent cyclo-linear polyphenylsiloxane elastomer integrating high refractive index, thermal stability and flexibility

Xianpeng Fan, Xinyu Cao, Xinxin Shang, Xianglan Zhang, Cheng Huang, Jingnan Zhang, Kun Zheng and Yongmei Ma

Polym. Chem., 2021, 12, 5149
DOI: 10.1039/D1PY00688F

Synthesis of guanidinophosphazene superbase for the facile preparation of high molecular weight polysiloxane under mild conditions

Wensheng Duan, Zhongwei Li, Zhizhou Yang, Fuyan He, Shisen Chen, Congde Qiao, Jinshui Yao, Changbin Zhang, Hui Zhao, Mei Li and Guihua Yang

Polym. Chem., 2023, 14, 172
DOI: 10.1039/D2PY01294D

Structure–melt viscosity relationship of discrete sequence-specific linear oligo(dimethylsiloxane-co-diphenylsiloxane)s

Hiroyuki Minamikawa, Takahiro Kawatsu and Kazuhiro Matsumoto

Polym. Chem., 2026, 17, 946
DOI: 10.1039/D5PY00958H

Synthesis and characterization of novel poly(sulfone siloxane)s with good solubility and recyclability based on siloxane units

Yunfan Xu, Mengdong Guo, Shilong Lu, Zengyue Wei and Shengyu Feng

New J. Chem., 2022, 46, 10237
DOI: 10.1039/D2NJ00934J

Fast, selective and metal-free ring-opening polymerization to synthesize polycarbonate/polyester copolymers with high incorporation of ethylene carbonate using an organocatalytic phosphazene base

Chuanzhi Wei, Xinhui Kou, Shaofeng Liu and Zhibo Li

Polym. Chem., 2019, 10, 5905
DOI: 10.1039/C9PY01319A

Superbasicity of imines with bicyclo[5.1.0]octa-1,3,5,7-tetraene scaffold due to electron delocalization in the conjugated acids

Younes Valadbeigi and Reza Taheri

Computational and Theoretical Chemistry, 2023, 1222, 114076
DOI: 10.1016/j.comptc.2023.114076

Facile Synthesis of Polyorganosiloxanes via Photo‐Induced Anionic Ring‐Opening Polymerization Using a Latent Catalyst

Wenxu Zhang, Tian‐Tian Wang, Shen Li, Chunhui Zhao, Chao Bian, Yin‐Ning Zhou and Zheng‐Hong Luo

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202503923

Model-Guided Design and Solvent-Free Synthesis of Polysiloxanes with High Refractive Index and Low Viscosity

Donglin Zhong, Suyun Jie, Miao Du, Pengju Pan and Guorong Shan

Chem Bio Eng., 2026, 3, 331
DOI: 10.1021/cbe.5c00138

Preparation, Optical, and Heat Resistance Properties of Phenyl-Modified Silicone Gel

Xueming Chen, Xuan Wu, Chen Jin, Leiyu Hou, Shuting Zhang, Yipin Zhang, Hong Dong, Yanjiang Song, Zhirong Qu and Chuan Wu

Polymers, 2024, 17, 9
DOI: 10.3390/polym17010009

Dynamic Covalent Bond Cross‐Linked Luminescent Silicone Elastomer with Self‐Healing and Recyclable Properties

Ning Wang, Lei Feng, Xing‐Dong Xu and Shengyu Feng

Macromol. Rapid Commun., 2022, 43
DOI: 10.1002/marc.202100885

Facile Synthesis of Sequence‐Defined Oligo(Dimethylsiloxane‐co‐Diphenylsiloxane)s

Takahiro Kawatsu, Jun‐Chul Choi, Kazuhiko Sato and Kazuhiro Matsumoto

Macromol. Rapid Commun., 2021, 42
DOI: 10.1002/marc.202000593

Upgrade Traditional KOH Catalyzed Ring-Opening Polymerization of Cyclosiloxanes to More Efficient Process by Adding Catalytic Phosphazenium Salt as Cocatalyst

Xiaoyu Guo, Zhedong Li, Jinfeng Shi, Chuanli Ren, Na Zhao and Zhibo Li

Macromolecules, 2025, 58, 1652
DOI: 10.1021/acs.macromol.4c02388

Effects of chain structure on damping property and local dynamics of phenyl silicone rubber: Insights from experiment and molecular simulation

Lin Zhu, Shigui Zhao, Chen Zhang, Xiao Cheng, Jinghao Hao, Xiaoqing Shao and Chuanjian Zhou

Polymer Testing, 2021, 93, 106885
DOI: 10.1016/j.polymertesting.2020.106885

Synthesis of Diverse Polycarbonates by Organocatalytic Copolymerization of CO2 and Epoxides: From High Pressure and Temperature to Ambient Conditions

Jinbo Zhang, Lebin Wang, Shaofeng Liu and Zhibo Li

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202111197

Direct Synthesis of Epoxy-Functionalized Polysiloxanes with Tunable Epoxy-Siloxane Contents via Phosphazene Base-Catalyzed Ring-Opening Polymerization

Xiaoyu Guo, Jinfeng Shi, Junzheng Feng, Na Zhao and Zhibo Li

Macromolecules, 2026, 59, 3813
DOI: 10.1021/acs.macromol.5c03208

Synthesis and Characterization of Polymethylphenylsiloxane With Arbitrarily Tunable Phenylsiloxane Contents via Phosphazenium Salt/KOH Catalyzed Ring‐Opening Polymerization

Xiangpeng Lin, Jinfeng Shi, Na Zhao and Zhibo Li

Journal of Polymer Science, 2025, 63, 2693
DOI: 10.1002/pol.20250262

A new highly efficient method for the preparation of phenyl-containing siloxanes by condensation of phenylsilanols in liquid ammonia

Tatyana Ershova, Anton Anisimov, Fedor Krylov, Natalia Polshchikova, Maxim Temnikov, Olga Shchegolikhina and Aziz Muzafarov

Chemical Engineering Science, 2022, 247, 116916
DOI: 10.1016/j.ces.2021.116916

Synthesis of Tris-Phosphazene Bases with Triazine as Core and Their Applications for Efficient Ring-Opening Alternating Copolymerization of Epoxide and Anhydride: Notable Effect of Basicity and Molecular Size

Lebin Wang, Jinbo Zhang, Na Zhao, Chuanli Ren, Shaofeng Liu and Zhibo Li

ACS Macro Lett., 2020, 9, 1398
DOI: 10.1021/acsmacrolett.0c00564

Polystyrene beads supported phosphazene superbase as recyclable organocatalyst for ring-opening polymerization of δ-valerolactone

Chuanli Ren, Xun Zhu, Na Zhao, Yong Shen, Longfei Chen, Shaofeng Liu and Zhibo Li

European Polymer Journal, 2019, 119, 130
DOI: 10.1016/j.eurpolymj.2019.07.022

Multifunctional Fluorescent Self-Healing Elastomers Consisting of Polydimethylsiloxane and Carbon Dots Linked via a Schiff Base Reaction

Xiaoying Lu, Ying Dong, Kai Yang, Lujie Song, Youping Wu and Jianping Deng

ACS Appl. Polym. Mater., 2023, 5, 10458
DOI: 10.1021/acsapm.3c02322

Phosphazene/Lewis Acids as Highly Efficient Cooperative Catalyst for Synthesis of High‐Molecular‐Weight Polyesters by Ring‐Opening Alternating Copolymerization of Epoxide and Anhydride

Jinbo Zhang, Lebin Wang, Shaofeng Liu and Zhibo Li

Journal of Polymer Science, 2020, 58, 803
DOI: 10.1002/pol.20190175

Effect of zinc oxide/layered double hydroxide on the mechanics of silicone rubber at low temperature

Xiaosen Wang, Yanbin Zhang, Shuaiyang Ren, Zehua Xu, Kangshuai Li, Xiaxia Hao and Qiang He

European Polymer Journal, 2023, 200, 112478
DOI: 10.1016/j.eurpolymj.2023.112478

Facile synthesis of functionalized polysiloxanes with nonconventional fluorescence by oxa-Michael addition reaction

Shiyao Jia, Shengyu Feng and Dengxu Wang

Designed Monomers and Polymers, 2023, 26, 223
DOI: 10.1080/15685551.2023.2278230

Synthesis, characterization and properties of vinyl-terminated poly[dimethylsiloxane-co-methyl(phenyl)siloxane]

Shengqiang Wang, Zhenbo Peng, Yanhua Huang, Mingquan Zhu, Yayun Liu and Yong Zhang

Polymer, 2024, 311, 127554
DOI: 10.1016/j.polymer.2024.127554

Fast synthesis of high molecular weights polydiethylsiloxanes and random poly(dimethylsiloxane-co-diethylsiloxane) copolysiloxanes via cyclic trimeric phosphazene base catalyzed ring-opening (co)polymerization

Zhengyang Liu, Jinfeng Shi, Na Zhao and Zhibo Li

European Polymer Journal, 2022, 173, 111280
DOI: 10.1016/j.eurpolymj.2022.111280

Tuning thermal and chemical stability of silicone rubbers via incorporation of diphenylsiloxane and methyltrifluoropropylsiloxane units

Su Min Oh, Yoon Chan Chung, Jang Hyun Kim, Kyung Hoon Min, Byeongseok Kim and Sang Eun Shim

Polymer, 2026, 345, 129597
DOI: 10.1016/j.polymer.2026.129597

Liquid Crystal‐Engineered Polydimethylsiloxane: Enhancing Intrinsic Thermal Conductivity through High Grafting Density of Mesogens

Haitian Zhang, Yongqiang Guo, Yizhi Zhao, Qiuyu Zhu, Mukun He, Hua Guo, Xuetao Shi, Kunpeng Ruan, Jie Kong and Junwei Gu

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202500173

Polydimethylsiloxane-based phase change composites with excellent low-temperature flexibility for battery thermal management

Chun Wang, Yingdong Wu and Junping Zheng

Materials Today Communications, 2025, 44, 111958
DOI: 10.1016/j.mtcomm.2025.111958

Polyphosphazene‐Functionalized Microspheres as Efficient Catalysts for the Knoevenagel Reaction under Mild Conditions

Shisen Chen, Zhongwei Li, Wenbo Yuan, Wensheng Duan, Congde Qiao, Jinshui Yao, Changbin Zhang, Hui Zhao, Mei Li and Guihua Yang

ChemPlusChem, 2022, 87
DOI: 10.1002/cplu.202200249

Molecular Insights into Sequence Distributions and Conformation-Dependent Properties of High-Phenyl Polysiloxanes

Lin Zhu, Xiao Cheng, Wenlu Su, Jiaxin Zhao and Chuanjian Zhou

Polymers, 2019, 11, 1989
DOI: 10.3390/polym11121989

Highly Active Organocatalysts for Stereoselective Ring-Opening Polymerization of Racemic Lactide at Room Temperature

Yongxin Liu, Jinbo Zhang, Xinhui Kou, Shaofeng Liu and Zhibo Li

ACS Macro Lett., 2022, 11, 1183
DOI: 10.1021/acsmacrolett.2c00425

High-Molecular-Weight Poly(fluorophenylsiloxane) Elastomers via Postpolymerization Macromolecular Chain Exchange Reaction for Optimized Comprehensive Properties

Linyu Li, Zhen Niu, Hang Zheng, Zhanwei Feng, Xiaoning Hou, Weifeng Fan, Jianyun He and Chenxi Bai

ACS Appl. Polym. Mater., 2025, 7, 15111
DOI: 10.1021/acsapm.5c03360

Synthesis of Functionalized PDMS Fluids by Linear Chlorinated Phosphazene Acid Catalyst

Chen Jin, Yang Zhang, Hao Yang, Hong Dong, Yanjiang Song, Zhirong Qu and Chuan Wu

Silicon, 2025, 17, 231
DOI: 10.1007/s12633-024-03182-7

Synthesis of Functionalized (Poly)Siloxanes via Iron‐Catalyzed C–H Bond Alkylation with Polar Olefins†

Rong Zeng, Chengxiang Zhou, Zuguang Yang, Weiping Liu, Sichang Wang and Congyu Ke

Chin. J. Chem., 2025, 43, 3489
DOI: 10.1002/cjoc.70272

Facile Synthesis of Polyorganosiloxanes via Photo‐Induced Anionic Ring‐Opening Polymerization Using a Latent Catalyst

Wenxu Zhang, Tian‐Tian Wang, Shen Li, Chunhui Zhao, Chao Bian, Yin‐Ning Zhou and Zheng‐Hong Luo

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202503923

Superior Low‐Temperature Reversible Adhesion Based on Bio‐Inspired Microfibrillar Adhesives Fabricated by Phenyl Containing Polydimethylsiloxane Elastomers

Shuang Xia, Yukun Chen, Jinfeng Tian, Jinfeng Shi, Chengzhen Geng, Huawei Zou, Mei Liang and Zhibo Li

Adv Funct Materials, 2021, 31
DOI: 10.1002/adfm.202101143

Imidodiphosphorimidate (IDPi) as an efficient organocatalyst for controlled/living ring-opening polymerization of lactones

Xun Zhang, Yu Jiang, Qiang Ma, Siping Hu, Qinggang Wang and Saihu Liao

European Polymer Journal, 2020, 123, 109449
DOI: 10.1016/j.eurpolymj.2019.109449

Organocatalytic Ring‐Opening Polymerization of ϵ‐Caprolactone with Phosphoramidimidates (PADIs) as a Bifunctional Brønsted Acid Catalyst

Xun Zhang, Pan Sun, Yu Jiang and Saihu Liao

Chemistry An Asian Journal, 2023, 18
DOI: 10.1002/asia.202201127

Metal‐Free Ring‐Opening Alternating Copolymerization of Epoxides and Cyclic Anhydrides Mediated by a Ternary Phosphazene Base and Carboxylic Acids

Xinhui Kou, Yongzheng Li, Yong Shen and Zhibo Li

Macro Chemistry & Physics, 2019, 220
DOI: 10.1002/macp.201900416

Photomediated Cationic Ring-Opening Polymerization of Cyclosiloxanes with Temporal Control

Wenxu Zhang, Shen Li, Shuting Liu, Tian-Tian Wang, Zheng-Hong Luo, Chao Bian and Yin-Ning Zhou

JACS Au, 2024, 4, 4317
DOI: 10.1021/jacsau.4c00682

Preparation of robust diphenyl silicone elastomers with enhanced mechanical properties and thermal-aging resistances by using phosphazene as catalyst

Shiwei Duan, Zhedong Li, Yuetao Liu, Na Zhao and Zhibo Li

Polymer, 2023, 272, 125855
DOI: 10.1016/j.polymer.2023.125855

Synthesis of Diverse Polycarbonates by Organocatalytic Copolymerization of CO2 and Epoxides: From High Pressure and Temperature to Ambient Conditions

Jinbo Zhang, Lebin Wang, Shaofeng Liu and Zhibo Li

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202111197

Liquid Crystal‐Engineered Polydimethylsiloxane: Enhancing Intrinsic Thermal Conductivity through High Grafting Density of Mesogens

Haitian Zhang, Yongqiang Guo, Yizhi Zhao, Qiuyu Zhu, Mukun He, Hua Guo, Xuetao Shi, Kunpeng Ruan, Jie Kong and Junwei Gu

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202500173

Effect of Diphenyl Content on Viscoelasticity of Poly(dimethyl-co-diphenyl)siloxane Melt and Network

Weikang Xian, Chung-Hao Liu, Behrad Kangarlou, Shing-Yun Chang, Chao Wu, Yang Cao, Luyi Sun, Anson W. K. Ma, Mu-Ping Nieh, Amitesh Maiti, Andrew P. Saab and Ying Li

ACS Appl. Polym. Mater., 2023, 5, 1915
DOI: 10.1021/acsapm.2c01979

Ring-Opening Polymerization (ROP) and Catalytic Rearrangement as a Way to Obtain Siloxane Mono- and Telechelics, as Well as Well-Organized Branching Centers: History and Prospects

Kseniya A. Bezlepkina, Sergey A. Milenin, Natalia G. Vasilenko and Aziz M. Muzafarov

Polymers, 2022, 14, 2408
DOI: 10.3390/polym14122408

Reprocessable Supramolecular Elastomers of Poly(Siloxane–Urethane) via Self‐Complementary Quadruple Hydrogen Bonding

Xiyang Ma, Debo Zhou, Lei Liu, Linlin Wang, Huidong Yu, Lei Li and Shengyu Feng

Macro Chemistry & Physics, 2021, 222
DOI: 10.1002/macp.202100116

Controlled Ring-Opening Polymerization of Hexamethylcyclotrisiloxane Catalyzed by Trisphosphazene Organobase to Well-Defined Poly(dimethylsiloxane)s

Jinfeng Shi, Zhengyang Liu, Na Zhao, Shaofeng Liu and Zhibo Li

Macromolecules, 2022, 55, 2844
DOI: 10.1021/acs.macromol.1c02654

Hydrogen bonding mediated nucleophilicity strategy for the controlled anionic ring-opening polymerization of D3F

Lixin Sun, Yanan Sun, Chenliang Tang, Zhuoming Duan, Chuanxing Wang, Lei Xu, Li Ding and Yuetao Liu

Chemical Engineering Science, 2026, 323, 123241
DOI: 10.1016/j.ces.2025.123241

A Poly(dimethyl-co-methylvinyl)siloxane-based elastomer with excellent ultra-low temperature elasticity driven by flexible alkyl branches

Zhen Niu, Ruiyao Wu, Lingyun Huang, Yinxin Yang, Zhu Xia, Weifeng Fan, Wu Sun, Quanquan Dai, Jianyun He and Chenxi Bai

European Polymer Journal, 2022, 174, 111303
DOI: 10.1016/j.eurpolymj.2022.111303

Polymers Containing Diethylsiloxane Segment and Active Functional Group by Ring-Opening Polymerization of Hexaethylcyclotrisiloxane under the Catalysis of Linear Chlorinated Phosphazene Acid

Chen Jin, Hao Yang, Yang Zhang, Shuting Zhang, Xu Long, Hong Dong, Yanjiang Song, Zhirong Qu and Chuan Wu

Polymers, 2024, 16, 2835
DOI: 10.3390/polym16192835

Basicity characterization of novel designed phosphorus containing cyclic structures by a computational approach

Nastaran Bormanzadeh, Morteza Rouhani and Bahareh Sadeghi

Phosphorus, Sulfur, and Silicon and the Related Elements, 2024, 199, 856
DOI: 10.1080/10426507.2024.2424276

Initiator Activation and Active Chain End Stabilization Strategy via the Dual Hydrogen Bond for the Controlled Synthesis of Poly(fluorosiloxane)

Lixin Sun, Yanan Sun, Chenliang Tang, Fangfei Xin, Chuanxing Wang, Lei Xu, Li Ding and Yuetao Liu

Macromolecules, 2025, 58, 8399
DOI: 10.1021/acs.macromol.5c01288

Cyclo-linear synthesis of amino silicone oil and study on the catalytic polymerization mechanism of phosphazene base

Naifan Dong, Jintang Duan, Cailiang Zhang, Xueping Gu, Lianfang Feng and Liu Liu

Polymer, 2025, 323, 128163
DOI: 10.1016/j.polymer.2025.128163

Phosphazene superbase P4-t-Bu: a versatile and efficient catalyst in morden organic synthesis

Yue-Jie Diao, Tian-Hua Zheng, Ping-Gui Li and Liang-Hua Zou

Discov. Chem., 2025, 2
DOI: 10.1007/s44371-025-00277-x

Synthesis of molecularly engineered polysiloxane nanocomposites adhesive enabled by long-chain end-capping and synergistic silica/iron oxide reinforcement

Mahdi Hashemi, Ehsan Chehrazi, Majid Haghgoo and Majid Mokhtari

J Polym Res, 2026, 33
DOI: 10.1007/s10965-026-04801-0

Mechanism and kinetics of melt transesterification with siloxane diol

Zedong He, Lei Feng, Ju Xie, Hailong Liu, William W. Yu and Jie Zhang

Chemical Engineering Journal, 2023, 455, 140816
DOI: 10.1016/j.cej.2022.140816

Using recyclable polystyrene supported cyclic trimeric phosphazene base as catalyst to directly prepare hypotoxic polyesters via ring-opening polymerizations

Chuanli Ren, Xun Zhu, Na Zhao, Sha Fang and Zhibo Li

Polymer, 2020, 204, 122797
DOI: 10.1016/j.polymer.2020.122797