Insights into the intricate charge photoaccumulation in a polyoxometalate–bodipy covalent hybrid

Christian Cariño, Naguy Moussa, Sébastien Blanchard, Albert Solé-Daura, Anna Proust and Guillaume Izzet

Inorg. Chem. Front., 2025, 12, 8231
DOI: 10.1039/D5QI01202C

A photo-switchable molecular capsule: sequential photoinduced processes

Manjiri Choudhari, Jingjing Xu, Alasdair I. McKay, Clément Guerrin, Craig Forsyth, Howard Z. Ma, Lars Goerigk, Richard A. J. O'Hair, Antoine Bonnefont, Laurent Ruhlmann, Stephane Aloise and Chris Ritchie

Chem. Sci., 2022, 13, 13732
DOI: 10.1039/D2SC04613J

[MW12O44] clusters: unprecedented central heteroatoms atomically dispersed in the eight coordination state bridging the 1 : 12 polyoxometalate family of Keggin and Silverton

Yongdong Chen, Shanli Tian, Zhaoxian Qin, Jiangwei Zhang, Youhai Cao, Shengqi Chu, Lanlu Lu and Gao Li

Nanoscale, 2019, 11, 22270
DOI: 10.1039/C9NR05913J

Stepwise synthesis of symmetric and asymmetric Anderson-polyoxometalates for light-driven hydrogen evolution

Patrick Endres, Garima Sachdeva, Andreas Winter, Dolores Díaz, Helmar Görls, Nicole Fritz, Christof Neumann, Andrey Turchanin, Carsten Streb and Ulrich S. Schubert

Inorg. Chem. Front., 2026, 13, 1442
DOI: 10.1039/D5QI02141C

Post-functionalization through covalent modification of organic counter ions: a stepwise and controlled approach for novel hybrid polyoxometalate materials

Aranya Kar and Chullikkattil P. Pradeep

Dalton Trans., 2020, 49, 12174
DOI: 10.1039/D0DT01410A

Is electron ping-pong limiting the catalytic hydrogen evolution activity in covalent photosensitizer–polyoxometalate dyads?

Yusen Luo, Salam Maloul, Maria Wächtler, Andreas Winter, Ulrich S. Schubert, Carsten Streb and Benjamin Dietzek

Chem. Commun., 2020, 56, 10485
DOI: 10.1039/D0CC04509H

A rare polyoxometalate cluster [NiW12O44]14−based solid as a pre-catalyst for efficient and long-term oxygen evolution

Parul Sood, Arti Joshi and Monika Singh

Nanoscale Adv., 2022, 4, 5015
DOI: 10.1039/D2NA00646D

Covalent POM–Ir hybrid assemblies: tuning redox properties for light-driven multiple charge accumulation

Nicolas Queyriaux, Maria Wächtler, Christian Cariño, Sandra Alves, Benjamin Dietzek-Ivanšić, Vincent Artero, Anna Proust, Murielle Chavarot-Kerlidou and Guillaume Izzet

Chem. Commun., 2025, 61, 9682
DOI: 10.1039/D5CC01951F

Organic linkage controls the photophysical properties of covalent photosensitizer–polyoxometalate hydrogen evolution dyads

Yusen Luo, Salam Maloul, Patrick Endres, Stefanie Schönweiz, Chris Ritchie, Maria Wächtler, Andreas Winter, Ulrich S. Schubert, Carsten Streb and Benjamin Dietzek

Sustainable Energy Fuels, 2020, 4, 4688
DOI: 10.1039/D0SE00582G

Optical, third order non-linear optical and electrochemical properties of dipolar, centrosymmetric andC2vorganoimido polyoxometalate derivatives

Ahmed Al-Yasari, Hani El Moll, Ryan Purdy, Kevin B. Vincent, Philip Spence, Jean-Pierre Malval and John Fielden

Phys. Chem. Chem. Phys., 2021, 23, 11807
DOI: 10.1039/D0CP06610A

Acid-triggering of light-induced charge-separation in hybrid organic/inorganic molecular photoactive dyads for harnessing solar energy

Elisabetta Benazzi, Joshua Karlsson, Youssef Ben M'Barek, Pavel Chabera, Sébastien Blanchard, Sandra Alves, Anna Proust, Tönu Pullerits, Guillaume Izzet and Elizabeth A. Gibson

Inorg. Chem. Front., 2021, 8, 1610
DOI: 10.1039/D0QI01368D

Photoinduced electron transfer between a noble-metal-free [Mo6I8Cl6]2− cluster and polyoxometalates

Anam Fatima, Yevheniia Smortsova, Clément Falaise, Nathalie Leclerc, Mohamed Haouas, Emmanuel Cadot, Stéphane Cordier, Yann Molard, Thomas Pino, Céline Dablemont, Rachel Méallet, Karine Steenkeste and Minh-Huong Ha-Thi

Chem. Commun., 2023, 59, 10988
DOI: 10.1039/D3CC03334A

Unveiling photoinduced electron transfers in photosensitized polyoxometalates for solar energy conversion

Christian Cariño, Anna Proust, Geoffroy Guillemot, Ludivine K/Bidi, Sébastien Blanchard, Elizabeth A. Gibson and Guillaume Izzet

Chem. Sci., 2025, 16, 19493
DOI: 10.1039/D5SC04351D

Hybrid polyoxometalates as post-functionalization platforms: from fundamentals to emerging applications

Alexander V. Anyushin, Aleksandar Kondinski and Tatjana N. Parac-Vogt

Chem. Soc. Rev., 2020, 49, 382
DOI: 10.1039/C8CS00854J

Tuning Photoinduced Electron Transfer in POM‐Bodipy Hybrids by Controlling the Environment: Experiment and Theory

Georgios Toupalas, Joshua Karlsson, Fiona A. Black, Albert Masip‐Sánchez, Xavier López, Youssef Ben M'Barek, Sébastien Blanchard, Anna Proust, Sandra Alves, Pavel Chabera, Ian P. Clark, Tönu Pullerits, Josep M. Poblet, Elizabeth A. Gibson and Guillaume Izzet

Angewandte Chemie, 2021, 133, 6592
DOI: 10.1002/ange.202014677

New insights into quantifying the solvatochromism of BODIPY based fluorescent probes

Felix Y. Telegin and Yuriy S. Marfin

Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2021, 255, 119683
DOI: 10.1016/j.saa.2021.119683

Exploring BODIPY Derivatives as Singlet Oxygen Photosensitizers for PDT

Ruth Prieto‐Montero, Alejandro Prieto‐Castañeda, Rebeca Sola‐Llano, Antonia R. Agarrabeitia, David García‐Fresnadillo, Iñigo López‐Arbeloa, Angeles Villanueva, María J. Ortiz, Santiago de la Moya and Virginia Martínez‐Martínez

Photochem & Photobiology, 2020, 96, 458
DOI: 10.1111/php.13232

Rational design of bromine-modified Ir(III) photosensitizer for photocatalytic hydrogen generation

Lin Qin, Xing Xin, Ruijie Wang, Hongjin Lv and Guo-Yu Yang

Journal of Catalysis, 2023, 417, 89
DOI: 10.1016/j.jcat.2022.11.027

Supramolecular Aggregation Control in Polyoxometalates Covalently Functionalized with Oligoaromatic Groups

Sebastian Knoll, Matthias Hänle, Alexander K. Mengele, Dieter Sorsche, Sven Rau and Carsten Streb

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202203469

The Intrinsic Charge Carrier Behaviors and Applications of Polyoxometalate Clusters Based Materials

Le Yang, Jie Lei, Jing‐Min Fan, Ru‐Ming Yuan, Ming‐Sen Zheng, Jia‐Jia Chen and Quan‐Feng Dong

Advanced Materials, 2021, 33
DOI: 10.1002/adma.202005019

Bodipy-Based Metal–Organic Frameworks Transformed in Solid States from 1D Chains to 2D Layer Structures as Efficient Visible Light Heterogeneous Photocatalysts for Forging C–B and C–C Bonds

Qingchun Xia, Jingli Yang, Suzhen Zhang, Jie Zhang, Zhiyong Li, Jianji Wang and Xuenian Chen

J. Am. Chem. Soc., 2023, 145, 6123
DOI: 10.1021/jacs.2c11647

Covalent Grafting of Eosin Y to the Giant Keplerate {Mo132} through an Organosilicon Linker in Homogeneous Regime

Andrey Denikaev, Grigory Kim, Evgeny Greshnyakov, Nikolai Moskalenko and Kirill Grzhegorzhevskii

Inorganics, 2023, 11, 239
DOI: 10.3390/inorganics11060239

When Identification of the Reduction Sites in Mixed Molybdenum/Tungsten Keggin-Type Polyoxometalate Hybrids Turns Out Tricky

Maxime Laurans, Michele Mattera, Raphaël Salles, Ludivine K’Bidi, Pierre Gouzerh, Séverine Renaudineau, Florence Volatron, Geoffroy Guillemot, Sébastien Blanchard, Guillaume Izzet, Albert Solé-Daura, Josep M. Poblet and Anna Proust

Inorg. Chem., 2022, 61, 7700
DOI: 10.1021/acs.inorgchem.2c00866

Evolution of BODIPY as triplet photosensitizers from homogeneous to heterogeneous: The strategies of functionalization to various forms and their recent applications

Danfeng Wang, Xin Wang, Shiyuan Zhou, Peiyang Gu, Xiaolin Zhu, Chengyuan Wang and Qichun Zhang

Coordination Chemistry Reviews, 2023, 482, 215074
DOI: 10.1016/j.ccr.2023.215074

Photoinduced Electron Transfer and Energy Transfer Processes in a Flexible BODIPY-C60 Dyad

Thu-Trang Tran, Jad Rabah, Minh-Huong Ha-Thi, Emmanuel Allard, Stanislaw Nizinski, Gotard Burdzinski, Stéphane Aloïse, Hélène Fensterbank, Krystyna Baczko, Houssein Nasrallah, Anne Vallée, Gilles Clavier, Fabien Miomandre, Thomas Pino and Rachel Méallet-Renault

J. Phys. Chem. B, 2020, 124, 9396
DOI: 10.1021/acs.jpcb.0c05187

Reinforced catalytic oxidation of polyoxometalate@charge transfer complex by on-site heating from photothermal conversion

Xiaofei Chen, Aibing Yang, Gengxin Wang, Mingfeng Wei, Ning Liu, Bao Li and Lixin Wu

Chemical Engineering Journal, 2022, 446, 137134
DOI: 10.1016/j.cej.2022.137134

Tailoring the Solid-State Fluorescence of BODIPY by Supramolecular Assembly with Polyoxometalates

Patricia Bolle, Tarik Benali, Clotilde Menet, Marin Puget, Eric Faulques, Jérôme Marrot, Pierre Mialane, Anne Dolbecq, Hélène Serier-Brault, Olivier Oms and Rémi Dessapt

Inorg. Chem., 2021, 60, 12602
DOI: 10.1021/acs.inorgchem.1c01983

A dual-functional supramolecular assembly for enhanced photocatalytic hydrogen evolution

Lin Qin, Ruijie Wang, Xing Xin, Mo Zhang, Tianfu Liu, Hongjin Lv and Guo-Yu Yang

Applied Catalysis B: Environmental, 2022, 312, 121386
DOI: 10.1016/j.apcatb.2022.121386

Polyoxometalates: Tailoring metal oxides in molecular dimension toward energy applications

Lei Zhang and Zhiqiao Chen

Int J Energy Res, 2020, 44, 3316
DOI: 10.1002/er.5124

Multifunctional Polyoxometalate Platforms for Supramolecular Light‐Driven Hydrogen Evolution**

Salam Maloul, Matthias van den Borg, Carolin Müller, Linda Zedler, Alexander K. Mengele, Daniel Gaissmaier, Timo Jacob, Sven Rau, Benjamin Dietzek‐Ivanšić and Carsten Streb

Chemistry A European J, 2021, 27, 16846
DOI: 10.1002/chem.202103817

36‐Nuclearity Organophosphonate‐Functionalized Polyoxomolybdates: Synthesis, Characterization and Selective Catalytic Oxidation of Sulfides

Qiaofei Xu, Xinmiao Liang, Baijie Xu, Jiawei Wang, Peipei He, Pengtao Ma, Jiwen Feng, Jingping Wang and Jingyang Niu

Chemistry A European J, 2020, 26, 14896
DOI: 10.1002/chem.202001468

Substantial second‐order nonlinear optical properties of novel hexamolybdate‐julolidine hybrids: A density functional theory (DFT) study

Ashraf H. S. AlSilaykhee, Ahmed Al‐Yasari and Hasan F. Alesary

Int J of Quantum Chemistry, 2023, 123
DOI: 10.1002/qua.27086

Photoactive Organic/Inorganic Hybrid Materials with Nanosegregated Donor–Acceptor Arrays

Xiaolei Zhu, Cheriehan Hessin, Aude Salamé, Lydia Sosa‐Vargas, David Kreher, Chihaya Adachi, Anna Proust, Pierre Mialane, Jérome Marrot, Aude Bouchet, Michel Sliwa, Stéphane Méry, Benoît Heinrich, Fabrice Mathevet and Guillaume Izzet

Angew Chem Int Ed, 2021, 60, 8419
DOI: 10.1002/anie.202014319

Covalent Linkage of BODIPY‐Photosensitizers to Anderson‐Type Polyoxometalates Using CLICK Chemistry

Seda Cetindere, Simon T. Clausing, Montaha Anjass, Yusen Luo, Stephan Kupfer, Benjamin Dietzek and Carsten Streb

Chemistry A European J, 2021, 27, 17181
DOI: 10.1002/chem.202102897

Synthesis, Crystal Structure, and Theoretical Screening of Solvatochromism and Light-Harvesting Performance of Hexamine V-Substituted Lindqvist-Based Photosensitizer for Photovoltaic Solar Cells

Ahlem Maalaoui, Baya Toumi, Ernest C. Agwamba, Gideon A. Okon, Mohamed Rzaigui and Samah Akriche

ACS Omega, 2024, 9, 38066
DOI: 10.1021/acsomega.4c05150

Photoactive Organic/Inorganic Hybrid Materials with Nanosegregated Donor–Acceptor Arrays

Xiaolei Zhu, Cheriehan Hessin, Aude Salamé, Lydia Sosa‐Vargas, David Kreher, Chihaya Adachi, Anna Proust, Pierre Mialane, Jérome Marrot, Aude Bouchet, Michel Sliwa, Stéphane Méry, Benoît Heinrich, Fabrice Mathevet and Guillaume Izzet

Angewandte Chemie, 2021, 133, 8500
DOI: 10.1002/ange.202014319

Yield—not only Lifetime—of the Photoinduced Charge‐Separated State in Iridium Complex–Polyoxometalate Dyads Impact Their Hydrogen Evolution Reactivity

Yusen Luo, Salam Maloul, Stefanie Schönweiz, Maria Wächtler, Carsten Streb and Benjamin Dietzek

Chemistry A European J, 2020, 26, 8045
DOI: 10.1002/chem.202000982

Polyoxometalate-based boron dipyrromethene (BODIPY) conjugates: syntheses, characterization and photophysical properties

Seda Cetindere

J IRAN CHEM SOC, 2023, 20, 3069
DOI: 10.1007/s13738-023-02898-4

Light‐Induced Charge Separation in Covalently Linked BODIPY‐Quinone‐Alkyne Dyads

Sebastian Knoll, Clara Zens, Tamar Maisuradze, Heiner Schmidt, Stephan Kupfer, Linda Zedler, Benjamin Dietzek‐Ivanšić and Carsten Streb

Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202303250

{P2V3W15}-Polyoxometalates Functionalized with Phthalocyaninato Y and Yb Moieties

Ricarda Pütt, Piotr Kozłowski, Irina Werner, Jan Griebel, Sebastian Schmitz, Jonas Warneke and Kirill Yu. Monakhov

Inorg. Chem., 2021, 60, 80
DOI: 10.1021/acs.inorgchem.0c02257

Unveiling polyoxometalate redox properties at the nanoscale

Florence Volatron, Guillaume Izzet, Dominique Vuillaume and Anna Proust

Comptes Rendus. Chimie, 2024, 27, 255
DOI: 10.5802/crchim.344

Photocatalytic Recovery of Noble Metals by Covalent Silyl Polyoxophosphotungstate–Porphyrin Copolymers

Zhaohui Huo, Brahim Akhsassi, Jiamin Yu, Mingxiu Zheng, Tongying Lan, Qianting He, Corinne Boudon, Guojun Xu, Anna Proust, Guillaume Izzet and Laurent Ruhlmann

Inorg. Chem., 2025, 64, 3371
DOI: 10.1021/acs.inorgchem.4c04890

A photosensitizer–polyoxometalate dyad that enables the decoupling of light and dark reactions for delayed on-demand solar hydrogen production

Sebastian Amthor, Sebastian Knoll, Magdalena Heiland, Linda Zedler, Chunyu Li, Djawed Nauroozi, Willi Tobaschus, Alexander K. Mengele, Montaha Anjass, Ulrich S. Schubert, Benjamin Dietzek-Ivanšić, Sven Rau and Carsten Streb

Nat. Chem., 2022, 14, 321
DOI: 10.1038/s41557-021-00850-8

Structure and Electronic Properties of Large Oligomeric Heterometallic 3d/CeIV Polyoxometalates

Olivier Oms, Nishith Maity, Jérôme Marrot, Jiahao Yu, Eric Rivière, William Shepard, Youven Benseghir, Khadija Talbi, Anne Dolbecq, Minh-Huong Ha-Thi, Jose-Ramon Galan-Mascaros and Pierre Mialane

Inorg. Chem., 2023, 62, 18856
DOI: 10.1021/acs.inorgchem.3c02078

A Dual-Functional Supramolecular Assembly for Enhanced Photocatalytic Hydrogen Evolution

Lin Qin, Ruijie Wang, Xing Xin, Mo Zhang, Tianfu Liu, Hongjin Lv and Guo-Yu Yang

SSRN Journal, 2022
DOI: 10.2139/ssrn.4049378

Highly Efficient Electron Transfer in a Carbon Dot–Polyoxometalate Nanohybrid

Antonino Madonia, Mercè Martin-Sabi, Alice Sciortino, Simonpietro Agnello, Marco Cannas, Souad Ammar, Fabrizio Messina and Delphine Schaming

J. Phys. Chem. Lett., 2020, 11, 4379
DOI: 10.1021/acs.jpclett.0c01078

Tuning Photoinduced Electron Transfer in POM‐Bodipy Hybrids by Controlling the Environment: Experiment and Theory

Georgios Toupalas, Joshua Karlsson, Fiona A. Black, Albert Masip‐Sánchez, Xavier López, Youssef Ben M'Barek, Sébastien Blanchard, Anna Proust, Sandra Alves, Pavel Chabera, Ian P. Clark, Tönu Pullerits, Josep M. Poblet, Elizabeth A. Gibson and Guillaume Izzet

Angew Chem Int Ed, 2021, 60, 6518
DOI: 10.1002/anie.202014677

A Dual-Functional Supramolecular Assembly for Enhanced Photocatalytic Hydrogen Evolution

Lin Qin, Ruijie Wang, Xing Xin, Mo Zhang, Tianfu Liu, Hongjin Lv and Guo-Yu Yang

SSRN Journal, 2022
DOI: 10.2139/ssrn.4049410

Diiodo-BODIPY Sensitizing of the [Mo3S13]2– Cluster for Noble-Metal-Free Visible-Light-Driven Hydrogen Evolution within a Polyampholytic Matrix

Daniel Costabel, Afshin Nabiyan, Avinash Chettri, Franz Jacobi, Magdalena Heiland, Julien Guthmuller, Stephan Kupfer, Maria Wächtler, Benjamin Dietzek-Ivanšić, Carsten Streb, Felix H. Schacher and Kalina Peneva

ACS Appl. Mater. Interfaces, 2023, 15, 20833
DOI: 10.1021/acsami.2c18529

Latest progress in covalently modified polyoxometalates-based molecular assemblies and advanced materials

Huaiying Zhang, Wan-Lei Zhao, Hongqiang Li, Qinghe Zhuang, Zeqian Sun, Dongyuan Cui, Xuejie Chen, Ao Guo, Xiang Ji, Sai An, Wei Chen and Yu-Fei Song

Polyoxometalates, 2022, 1, 9140011
DOI: 10.26599/POM.2022.9140011