Phytic acid–based flame retardant and its application to poly(lactic acid) composites

Mengfei Zhang, Yang Wang, Jing Huang, Dong Wang, Ting Li, Shibo Wang and Weifu Dong

New J. Chem., 2023, 47, 19494
DOI: 10.1039/D3NJ03460G

Structural modification and encapsulation process of palygorskite for development of flame retardant additives: study of their thermal and mechanical properties in PLA/EVA blends

Saul Sánchez-Valdes, Gerardo Pozos-Sanchez, Jose Alberto Rodríguez-Gonzalez, Jorge Enrique Rivera-Salinas, Jorge Alonso Uribe-Calderon, Mario Valera-Zaragoza, Gabriela Yolatzin. Romero-Zúñiga, Ernesto Hernandez-Hernandez, Eedgar Cabrera-ALvarez and L. Da Silva

Iran Polym J, 2024, 33, 1189
DOI: 10.1007/s13726-024-01318-5

Structure–fire-retardant property correlations in biodegradable polymers

Yijiao Xue, Meng Zhang, Jiabing Feng, Yan Zhang, Venkata Chevali, Fei Song, Zheng Pan, Hong Peng, Yonghong Zhou and Pingan Song

Applied Physics Reviews, 2024, 11
DOI: 10.1063/5.0210839

Synergistic effect of SiO2 doped g-C3N4 and ammonium polyphosphate on flame retardancy of PA6 composites

Heng Li, Limiao Chen, Zhongbei Li, Wengui Wang, Ying Liu, Xuemei Huang and Yaochi Liu

J Polym Res, 2023, 30
DOI: 10.1007/s10965-023-03707-5

Thermal degradation, visco-elastic and fire-retardant behavior of hybrid Cyrtostachys Renda/kenaf fiber-reinforced MWCNT-modified phenolic composites

Tamil Moli Loganathan, Mohamed Thariq Hameed Sultan, Qumrul Ahsan, Mohammad Jawaid, Jesuarockiam Naveen, Ain Umaira Md Shah, Abd. Rahim Abu Talib and Adi Azriff Basri

J Therm Anal Calorim, 2022, 147, 14079
DOI: 10.1007/s10973-022-11557-4

Dual effect of dynamic vulcanization of biobased unsaturated polyester: Simultaneously enhance the toughness and fire safety of Poly(lactic acid)

De-Fu Li, Xi Zhao, Yun-Wan Jia, Lu He, Xiu-Li Wang and Yu-Zhong Wang

Composites Part B: Engineering, 2019, 175, 107069
DOI: 10.1016/j.compositesb.2019.107069

Advances and challenges in eco-benign fire-retardant polylactide

Yijiao Xue, Jiabing Feng, Zhewen Ma, Lina Liu, Yan Zhang, Jinfeng Dai, Zhiguang Xu, Serge Bourbigot, Hao Wang and Pingan Song

Materials Today Physics, 2021, 21, 100568
DOI: 10.1016/j.mtphys.2021.100568

Achieving high flame retardancy, crystallization and biodegradability PLA based on 1 wt% addition of novel fully bio-based flame retardant

Jian Xu, Junhao Fei, Tao Tang, Meng Ma, Yanqin Shi, Huiwen He, Si Chen and Xu Wang

Polymer, 2022, 258, 125263
DOI: 10.1016/j.polymer.2022.125263

An effective flame retardant containing hypophosphorous acid for poly (lactic acid): Fire performance, thermal stability and mechanical properties

Xingguo Wang, Jun Sun, Xiaodong Liu, Shengling Jiang, Julin Wang, Hongfei Li, Serge Bourbigot, Xiaoyu Gu and Sheng Zhang

Polymer Testing, 2019, 78, 105940
DOI: 10.1016/j.polymertesting.2019.105940

The flammability and mechanical properties of poly (lactic acid) composites containing Ni-MOF nanosheets with polyhydroxy groups

Xingguo Wang, Shuheng Wang, Wenjia Wang, Hongfei Li, Xiaodong Liu, Xiaoyu Gu, Serge Bourbigot, Zhongwei Wang, Jun Sun and Sheng Zhang

Composites Part B: Engineering, 2020, 183, 107568
DOI: 10.1016/j.compositesb.2019.107568

A molecularly engineered bioderived polyphosphate for enhanced flame retardant, UV-blocking and mechanical properties of poly(lactic acid)

Yan Zhang, Jian Jing, Ting Liu, Liangdong Xi, Ting Sai, Shiya Ran, Zhengping Fang, Siqi Huo and Pingan Song

Chemical Engineering Journal, 2021, 411, 128493
DOI: 10.1016/j.cej.2021.128493

Preparation of a biobased core‐shell flame retardant and its application in polylactic acid

Xiaolong Wang, Weiguang Gong, Xin Meng, Chenyang Li and Jin Gao

J of Applied Polymer Sci, 2022, 139
DOI: 10.1002/app.52720

A Phosphorus/Nitrogen-containing Phosphaphenanthrene Derivative as Flame Retardant for Poly(lactic acid)

Shan Lin, Hong-Yan Zhu, Chun-Meng You and Da-Ming Ban

Chin J Polym Sci, 2026
DOI: 10.1007/s10118-026-3634-5

An intumescent flame-retardant layer with β-cyclodextrin as charring agent and its flame retardancy in jute/polypropylene composites

Yanli Dou, Xuefei Li, Tianqi Zhang and Hong Xu

Polym. Bull., 2021, 78, 4281
DOI: 10.1007/s00289-020-03315-z

The synergistic role of acidic molecular sieve on flame retardant performance in PLA/MF@APP composite

Qin Ma, Jing Lu, Jianqi Yao, Jiajie Yin, Ruiyan Zhang and Faliang Luo

J Polym Res, 2022, 29
DOI: 10.1007/s10965-022-03037-y

Green and economic flame retardant prepared by the one-step method for polylactic acid

Hongyan Cheng, Yincai Wu, Wayne Hsu, Fenglong Lin, Shenglong Wang, Junwei Zeng, Qiuyin Zhu and Lijun Song

International Journal of Biological Macromolecules, 2023, 253, 127291
DOI: 10.1016/j.ijbiomac.2023.127291

A triazine-based hyperbranched char-forming agent for efficient intumescent flame retardant Poly(lactic acid) composites

Wenhao Liang, Bin Yu, Wei Wang, Yi Xiao and Yao Yuan

Composites Communications, 2022, 33, 101225
DOI: 10.1016/j.coco.2022.101225

Synthesis of P-/N-Containing Bamboo-Activated Carbon toward Enhanced Thermal Stability and Flame Retardancy of Polylactic Acid

Ningning Yin, Jinhuan Zhong, Huayu Tian, Zenan Zhou, Weijun Ying, Jinfeng Dai, Wenzhu Li and Wenbiao Zhang

Materials, 2022, 15, 6802
DOI: 10.3390/ma15196802

A novel high-efficient P/N/Si-containing APP-based flame retardant with a silane coupling agent in its molecular structure for epoxy resin

Qiang Sun, Jinlei Wang, Xue Meng, Jie Zhang and Hong Yan

Chinese Journal of Chemical Engineering, 2023, 55, 137
DOI: 10.1016/j.cjche.2022.06.004

Effect of nickel phytate on flame retardancy of intumescent flame retardant polylactic acid

Weiguang Gong, Min Fan, Ji Luo, Juan Liang and Xin Meng

Polymers for Advanced Techs, 2021, 32, 1548
DOI: 10.1002/pat.5190

Preparation of methacrylic acid modified microcrystalline cellulose and their applications in polylactic acid: flame retardancy, mechanical properties, thermal stability and crystallization behavior

Tao Zhu, Jia Guo, Bin Fei, Zhengyu Feng, Xiaoyu Gu, Hongfei Li, Jun Sun and Sheng Zhang

Cellulose, 2020, 27, 2309
DOI: 10.1007/s10570-019-02931-x

Passive fire protection of wood using some bio-derived fire retardants

Ananya Thomas, Khalid Moinuddin, Haijin Zhu and Paul Joseph

Fire Safety Journal, 2021, 120, 103074
DOI: 10.1016/j.firesaf.2020.103074

Layered charring agent with super strong carbonization for IFR system: Achieving highly efficient flame retardancy of PLA by ultra-low addition IFR

Yadong Wang, Yingao Zhang, Li Ma, Jingjing Gao, Hui Ge and Zongmin Zhu

Sustainable Materials and Technologies, 2024, 40, e00924
DOI: 10.1016/j.susmat.2024.e00924

Construction of a core-shell structure compound: Ammonium polyphosphate wrapped by rare earth compound to achieve superior smoke and toxic gases suppression for flame retardant flexible polyurethane foam composites

Zhenting Yin, Jingyi Lu, Xiaoli Yu, Pengfei Jia, Gang Tang, Xiaodong Zhou, Tingting Lu, Liying Guo, Bibo Wang, Lei Song and Yuan Hu

Composites Communications, 2021, 28, 100939
DOI: 10.1016/j.coco.2021.100939

Development of Flame-retardant Thermosetting Poly (Lactic acid) (PLA) and Its Curing Kinetics

Zixuan Chen, Fei Sun, Huakun Zhao, Tao Yu, Weidong Yang, Qian Li and Yan Li

J Polym Environ, 2023, 31, 3573
DOI: 10.1007/s10924-023-02834-w

Rare earth-based auxiliary agents in synthesis and functionalization of biodegradable polymers: application and prospect

Yuxuan Qi, Jia Niu, Huhu Tian, Tingting Lu, Hongzhang Cao, Yanlin Feng and Xiaoli Yu

Journal of Rare Earths, 2025
DOI: 10.1016/j.jre.2025.07.015

Iron-based MOF with rodlike morphology boosting flame retardancy and mechanical strength of epoxy containing ammonium polyphosphate

Xiaoran Wang and Song Wang

J Mater Sci, 2026, 61, 240
DOI: 10.1007/s10853-025-11774-w

A phosphorus- and nitrogen-containing DOPO derivative as flame retardant for polylactic acid (PLA)

Xinxin Wang, Wentao He, Lijuan Long, Shaowen Huang, Shuhao Qin and Guomin Xu

J Therm Anal Calorim, 2021, 145, 331
DOI: 10.1007/s10973-020-09688-7

Synthesis of a novel N‐alkoxyamine containing macromolecular intumescent flame retardant and its synergism in flame‐retarding polypropylene

Binglin Wang, Jiaxin Li, Xuejun Lai, Hongqiang Li, Yishen Chen and Xingrong Zeng

Polymers for Advanced Techs, 2021, 32, 2452
DOI: 10.1002/pat.5275

Novel Dihydroxy-Containing Ammonium Phosphate Based Poly(Lactic Acid): Synthesis, Characterization and Flame Retardancy

Rong-Kun Jian, Long Xia, Yuan-Fang Ai and De-Yi Wang

Polymers, 2018, 10, 871
DOI: 10.3390/polym10080871

P/N Zinc salt containing biological groups for synchronously enhanced the fire safety, anti-dripping and mechanical properties of polylactic acid

Ning Zhang, Yefang Teng, Dong Zhao, Zongsheng Liu, Jian Xu and Meng Ma

International Journal of Biological Macromolecules, 2025, 311, 144134
DOI: 10.1016/j.ijbiomac.2025.144134

Coumarin-DPPO a new bio-based phosphorus additive for poly(lactic acid): Processing and flame retardant application

Daniele Roncucci, Marie-Odile Augé, Sithiprumnea Dul, Jiuke Chen, Ali Gooneie, Daniel Rentsch, Sandro Lehner, Milijana Jovic, Alexandra Rippl, Vanesa Ayala, Fanny Bonnet, Serge Bourbigot, Hansjörg Grützmacher, Gaëlle Fontaine and Sabyasachi Gaan

Polymer Degradation and Stability, 2024, 223, 110737
DOI: 10.1016/j.polymdegradstab.2024.110737

Functionalization of PET with Phosphazene Grafted Graphene Oxide for Synthesis, Flammability, and Mechanism

Lifei Wei, Rui Wang, Zhiguo Zhu, Wenqing Wang and Hanguang Wu

Materials, 2021, 14, 1470
DOI: 10.3390/ma14061470

Recent advances in flame retardant and mechanical properties of polylactic acid: A review

Xiao-Mei Yang, Shuang Qiu, Abdulmalik Yusuf, Jun Sun, Zhongjie Zhai, Junhuan Zhao and Guang-Zhong Yin

International Journal of Biological Macromolecules, 2023, 243, 125050
DOI: 10.1016/j.ijbiomac.2023.125050

Toward Flame Retardancy, Antimelt Dripping, and UV Resistance Properties of Polylactic Acid Based on Eco-Friendly Core–Shell Flame Retardant

Meng Ma, Zhaoliang Jiang, Zongsheng Liu, Baoli Huang, Ni Sun, Si Chen, Yanqin Shi, Huiwen He, Yulu Zhu and Xu Wang

ACS Appl. Polym. Mater., 2024, 6, 3814
DOI: 10.1021/acsapm.3c03137

An effective multi-hydroxy-containing ammonium phosphate towards flame-retarding poly(lactic acid): Flame retardance, thermal and pyrolysis behaviors

Long Xia, Rong-kun Jian, Yuan-fang Ai, Xue-lin Zheng and Bin Zhao

Journal of Analytical and Applied Pyrolysis, 2018, 134, 265
DOI: 10.1016/j.jaap.2018.06.016

An overview of the recent advances in flame retarded poly(lactic acid)

Li Baochai, Aznizam Abu Bakar and Zurina Mohamad

Polymers for Advanced Techs, 2023, 34, 1435
DOI: 10.1002/pat.5990

A state-of-the-art review of environmental behavior and potential risks of biodegradable microplastics in soil ecosystems: Comparison with conventional microplastics

Jiao Fei, Xue Bai, Chuanjia Jiang, Xianqiang Yin and Bing-Jie Ni

Science of The Total Environment, 2024, 954, 176342
DOI: 10.1016/j.scitotenv.2024.176342

One-Pot, Solvent- and Catalyst-Free Synthesis of Polyphosphoramide as an Eco-Benign and Effective Flame Retardant for Poly(lactic acid)

Jiabing Feng, Xiaodong Xu, Zhiguang Xu, Hongyan Xie, Pingan Song, Lujuan Li, Guobo Huang and Hao Wang

ACS Sustainable Chem. Eng., 2020, 8, 16612
DOI: 10.1021/acssuschemeng.0c05931

Synergistic effect between ammonium polyphosphate-functionalized poly(lactic acid) and phosphated avocado seed on the flame-retardant properties of poly(lactic acid)/ethylene–vinyl acetate copolymer composites

José David Zuluaga-Parra, Luis Francisco Ramos-de Valle, Saúl Sánchez-Valdéz, Rachel Faverzani-Magnago, Adriano da Silva and Luciano da Silva

Iran Polym J, 2025, 34, 1
DOI: 10.1007/s13726-024-01345-2

Natural fibre composite selection for two-stroke marine engine under-piston door using hybrid AHP and TOPSIS methods

Ru Vern Yiow, Muhd Ridzuan Mansor and Mohd Adrinata Shaharuzaman

International Journal of Lightweight Materials and Manufacture, 2025, 8, 66
DOI: 10.1016/j.ijlmm.2024.07.006

Core–Shell Bioderived Flame Retardants Based on Chitosan/Alginate Coated Ammonia Polyphosphate for Enhancing Flame Retardancy of Polylactic Acid

Yan Zhang, Zhengquan Xiong, Haodong Ge, Leikun Ni, Tao Zhang, Siqi Huo, Pingan Song and Zhengping Fang

ACS Sustainable Chem. Eng., 2020, 8, 6402
DOI: 10.1021/acssuschemeng.0c00634

Fabrication of a flame retardant, strong mechanical toughness and antimicrobial polylactic acid by chitosan Schiff base/ ammonium polyphosphate

Yadong Wang, Li Ma, Hua Wang, Chunzu Cheng, Xianze Yin and Zongmin Zhu

Polymer Degradation and Stability, 2023, 216, 110492
DOI: 10.1016/j.polymdegradstab.2023.110492

Simple preparation, big effect: Chitosan-based flame retardant towards simultaneous enhancement of flame retardancy, antibacterial, crystallization and mechanical properties of PLA

Guoping Zhu, Jie Wang, Jingjing Gao, Xuebao Lin and Zongmin Zhu

International Journal of Biological Macromolecules, 2025, 303, 140668
DOI: 10.1016/j.ijbiomac.2025.140668

Semi-aromatic copolyesters with high strength and fire safety via hydrogen bonds and π-π stacking

Yan-Peng Ni, Qi-Tian Li, Lin Chen, Wan-Shou Wu, Zi-Hao Qin, Yi Zhang, Li Chen, Xiu-Li Wang and Yu-Zhong Wang

Chemical Engineering Journal, 2019, 374, 694
DOI: 10.1016/j.cej.2019.05.212

Governing effects of melt viscosity on fire performances of polylactide and its fire-retardant systems

Yueming Yu, Liangdong Xi, Miaohong Yao, Linghui Liu, Yan Zhang, Siqi Huo, Zhengping Fang and Pingan Song

iScience, 2022, 25, 103950
DOI: 10.1016/j.isci.2022.103950

Improving the toughness and flame retardancy of poly (lactic acid) with phosphorus‐containing core‐shell particles

Xinyi Dong, Zhenggui Wu, Yang Wang, Ting Li, Hao Yuan, Xuhui Zhang, Piming Ma, Mingqing Chen, Jing Huang and Weifu Dong

J of Applied Polymer Sci, 2022, 139
DOI: 10.1002/app.52390