A convenient access to fluorophosphonium triflate salts by electrophilic fluorination and anion exchange

Chun-Xiang Guo, Sivathmeehan Yogendra, Rosa M. Gomila, Antonio Frontera, Felix Hennersdorf, Johannes Steup, Kai Schwedtmann and Jan J. Weigand

Inorg. Chem. Front., 2021, 8, 2854
DOI: 10.1039/D1QI00322D

Controlled scrambling reactions to polyphosphanes via bond metathesis reactions

Robin Schoemaker, Kai Schwedtmann, Antonio Franconetti, Antonio Frontera, Felix Hennersdorf and Jan J. Weigand

Chem. Sci., 2019, 10, 11054
DOI: 10.1039/C9SC04501E

Synthesis of a monomolecular anionic FLP complex

A. W. Kyri, R. Kunzmann, G. Schnakenburg, Z.-W. Qu, S. Grimme and R. Streubel

Chem. Commun., 2016, 52, 13361
DOI: 10.1039/C6CC07081G

Proton transfer vs. oligophosphine formation by P–C/P–H σ-bond metathesis: decoding the competing Brønsted and Lewis type reactivities of imidazolio-phosphines

Mario Cicač-Hudi, Christoph M. Feil, Nicholas Birchall, Martin Nieger and Dietrich Gudat

Dalton Trans., 2020, 49, 17401
DOI: 10.1039/D0DT03633A

A convenient access to N-phosphonio-substituted NHC metal complexes [M = Ag(i), Rh(i), Pd(ii)]

Idir Benaissa, Rachid Taakili, Noël Lugan and Yves Canac

Dalton Trans., 2017, 46, 12293
DOI: 10.1039/C7DT02759A

Charge assisted halogen and pnictogen bonds: insights from the Cambridge Structural Database and DFT calculations

Rosa M. Gomila and Antonio Frontera

CrystEngComm, 2020, 22, 7162
DOI: 10.1039/D0CE00220H

Symmetrical and unsymmetrical diphosphanes with diversified alkyl, aryl, and amino substituents

Natalia Szynkiewicz, Łukasz Ponikiewski and Rafał Grubba

Dalton Trans., 2018, 47, 16885
DOI: 10.1039/C8DT03775B

Amidine functionalized phosphines: tuneable ligands for transition metals

Lewis C. Wilkins, Rebecca L. Melen, James A. Platts and Paul D. Newman

Dalton Trans., 2017, 46, 14234
DOI: 10.1039/C7DT03343E

New class of RSO2-NHC ligands and Pd/RSO2-NHC complexes with tailored electronic properties and high performance in catalytic C–C and C–N bonds formation

Dmitry V. Pasyukov, Maxim A. Shevchenko, Alexander V. Astakhov, Mikhail E. Minyaev, Yu Zhang, Victor M. Chernyshev and Valentine P. Ananikov

Dalton Trans., 2023, 52, 12067
DOI: 10.1039/D3DT02296J

Exploring the chemistry of backbone amino(chloro)phosphanyl-substituted imidazole-2-thiones

Abhishek Koner, Spencer C. Serin, Gregor Schnakenburg, Brian O. Patrick, Derek P. Gates and Rainer Streubel

Dalton Trans., 2017, 46, 10504
DOI: 10.1039/C7DT01859B

N-Cyclopropenio-imidazol-2-ylidene: An N-heterocyclic carbene bearing an N-cationic substituent

Cécile Barthes, Carine Duhayon, Yves Canac and Vincent César

Chem. Commun., 2020, 56, 3305
DOI: 10.1039/D0CC00477D

A selective route to aryl-triphosphiranes and their titanocene-induced fragmentation

André Schumann, Fabian Reiß, Haijun Jiao, Jabor Rabeah, Jan-Erik Siewert, Ivo Krummenacher, Holger Braunschweig and Christian Hering-Junghans

Chem. Sci., 2019, 10, 7859
DOI: 10.1039/C9SC02322D

Phosphine-catalysed reductive coupling of dihalophosphanes

Jan-Erik Siewert, André Schumann and Christian Hering-Junghans

Dalton Trans., 2021, 50, 15111
DOI: 10.1039/D1DT03095G

Photocatalytic functionalization of white phosphorus with aryl bromides and chlorides

Martin Gawron, Jannes Rückel and Robert Wolf

Chem. Commun., 2024, 60, 9777
DOI: 10.1039/D4CC02891K

N-Heterotricyclic cationic carbene ligands. Synthesis, reactivity and coordination chemistry

Javier Iglesias-Sigüenza, Cristina Izquierdo, Elena Díez, Rosario Fernández and José M. Lassaletta

Dalton Trans., 2018, 47, 5196
DOI: 10.1039/C8DT00213D

Self‐Assembled Monolayers of N‐Heterocyclic Olefins on Au(111)

Iris Berg, Luca Schio, Justus Reitz, Elena Molteni, Linoy Lahav, Carolina Gutiérrez Bolaños, Andrea Goldoni, Cesare Grazioli, Guido Fratesi, Max M. Hansmann, Luca Floreano and Elad Gross

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202311832

4‐Halomethyl‐Substituted Imidazolium Salts: A Versatile Platform for the Synthesis of Functionalized NHC Precursors

Dmitry V. Pasyukov, Maxim A. Shevchenko, Mikhail E. Minyaev, Victor M. Chernyshev and Valentine P. Ananikov

Chemistry An Asian Journal, 2024, 19
DOI: 10.1002/asia.202400866

Quinoxaline-anellated N,N´-dialkylimidazolium salts and iPr2quinox-NHC-Pd halide complexes

Saravanakumar Shanmuganathan, Carola Schulzke, Peter G. Jones and Joachim W. Heinicke

Journal of Organometallic Chemistry, 2020, 926, 121487
DOI: 10.1016/j.jorganchem.2020.121487

Carbeniophosphines versus Phosphoniocarbenes: The Role of the Positive Charge

Yves Canac

Chemistry An Asian Journal, 2018, 13, 1872
DOI: 10.1002/asia.201800483

N-Heterocyclic Carbene Adducts of Main Group Elements and Their Use as Ligands in Transition Metal Chemistry

Adinarayana Doddi, Marius Peters and Matthias Tamm

Chem. Rev., 2019, 119, 6994
DOI: 10.1021/acs.chemrev.8b00791

Electronic Properties of N-Heterocyclic Carbenes and Their Experimental Determination

Han Vinh Huynh

Chem. Rev., 2018, 118, 9457
DOI: 10.1021/acs.chemrev.8b00067

Recent Advances in Imidazoliumyl‐Substituted Phosphorus Compounds

Kai Schwedtmann, Giuseppe Zanoni and Jan J. Weigand

Chemistry An Asian Journal, 2018, 13, 1388
DOI: 10.1002/asia.201800199

Introducing Cationic Selenium-Containing Triazapentadiene Ligand Framework: Synthesis, Coordination Chemistry, and Antifungal Activity

Alexander A. Sapronov, Victor N. Khrustalev, Olga G. Chusova, Alexey S. Kubasov, Andreii S. Kritchenkov, Valentine G. Nenajdenko, Rosa M. Gomila, Antonio Frontera and Alexander G. Tskhovrebov

Inorg. Chem., 2024, 63, 13924
DOI: 10.1021/acs.inorgchem.4c01188

1,1-Enediamines as highly polarized olefin ligands

Lukas Körner, Linpan Yang, Dirk Bockfeld and Matthias Tamm

Journal of Organometallic Chemistry, 2023, 984, 122572
DOI: 10.1016/j.jorganchem.2022.122572

Synthese N‐heterocyclischer Carbene und ihrer Komplexe durch Chloroniumionabstraktion von 2‐Chlorazoliumsalzen mit elektronenreichen Phosphanen

Matthias D. Böhme, Tobias Eder, Maike B. Röthel, Patrick D. Dutschke, Lukas F. B. Wilm, F. Ekkehardt Hahn and Fabian Dielmann

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202202190

Synthesis and Reactivity of Monocyclic Homoleptic Oligophosphanes

Tim Wellnitz and Christian Hering‐Junghans

Eur J Inorg Chem, 2021, 2021, 8
DOI: 10.1002/ejic.202000878

Zwitterionic 2‐Phosphaethene‐thiolates [(LC)P=CS(LC/P)]+ as PCS Building Blocks (LC=NHC, LP=PR3)

Philipp Royla, Kai Schwedtmann, Rosa M. Gomila, Antonio Frontera and Jan J. Weigand

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202419502

An Extremely Electron Poor Cationic Triazoliumylidene N-Heterocyclic Carbene: Experimental and Computational Studies

Torsten Hölzel, Maximilian Otto, Hannes Buhl and Christian Ganter

Organometallics, 2017, 36, 4443
DOI: 10.1021/acs.organomet.7b00670

Zwitterionic 2‐Phosphaethene‐thiolates [(LC)P=CS(LC/P)]+ as PCS Building Blocks (LC=NHC, LP=PR3)

Philipp Royla, Kai Schwedtmann, Rosa M. Gomila, Antonio Frontera and Jan J. Weigand

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202419502

Self‐Assembled Monolayers of N‐Heterocyclic Olefins on Au(111)

Iris Berg, Luca Schio, Justus Reitz, Elena Molteni, Linoy Lahav, Carolina Gutiérrez Bolaños, Andrea Goldoni, Cesare Grazioli, Guido Fratesi, Max M. Hansmann, Luca Floreano and Elad Gross

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202311832

Impact of the Carbene Derivative Charge on the Decomposition Rates of Hoveyda–Grubbs-like Metathesis Catalysts

Magdalena Jawiczuk, Anna Marczyk, Katarzyna Młodzikowska-Pieńko and Bartosz Trzaskowski

J. Phys. Chem. A, 2020, 124, 6158
DOI: 10.1021/acs.jpca.0c03096

Formation of a Hexaphosphido Cobalt Complex through P−P Condensation

Christian M. Hoidn, Karolina Trabitsch, Kai Schwedtmann, Clemens Taube, Jan J. Weigand and Robert Wolf

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202301930

Hydrogen/Halogen Exchange of Phosphines for the Rapid Formation of Cyclopolyphosphines

Adam N. Barrett, Callum R. Woof, Christopher A. Goult, Danila Gasperini, Mary F. Mahon and Ruth L. Webster

Inorg. Chem., 2021, 60, 16826
DOI: 10.1021/acs.inorgchem.1c02734

Asymmetric Cationic Phosphines: Synthesis, Coordination Chemistry, and Reactivity

Benson M. Kariuki and Paul D. Newman

Inorg. Chem., 2018, 57, 9554
DOI: 10.1021/acs.inorgchem.8b01657

Bis(N-cyclopropenio)-imidazol-2-ylidene: An N-Heterocyclic Carbene Bearing Two N-Cationic Substituents

Ajay Padunnappattu, Carine Duhayon, Vincent César and Yves Canac

Organometallics, 2022, 41, 2868
DOI: 10.1021/acs.organomet.2c00429

Iron and Cobalt Metallotropism in Remote‐Substituted NHC Ligands: Metalation to Abnormal NHC Complexes or NHC Ring Opening

Andreas A. Danopoulos, Alexandre Massard, Gilles Frison and Pierre Braunstein

Angewandte Chemie, 2018, 130, 14758
DOI: 10.1002/ange.201808008

Stable Mesoionic N‐Heterocyclic Olefins (mNHOs)

Max M. Hansmann, Patrick W. Antoni and Henner Pesch

Angewandte Chemie, 2020, 132, 5831
DOI: 10.1002/ange.201914571

Metal complexes of backbone-halogenated imidazol-2-ylidenes

Alejandro Bugarin, Siddappa A. Patil, Ryan Q. Tran and Kostiantyn O. Marichev

Inorganica Chimica Acta, 2024, 572, 122263
DOI: 10.1016/j.ica.2024.122263

Ruthenium Metathesis Catalysts Bearing Anionic N-Heterocyclic Carbenes: A Computational Study on Failed Approaches to Their Synthesis

Anna Marczyk and Bartosz Trzaskowski

Organometallics, 2023, 42, 689
DOI: 10.1021/acs.organomet.3c00068

An N-Heterocyclic carbene with a sulfonamide group embedded within the heterocyclic backbone

Markus Jonek, Abdelaziz Makhloufi and Christian Ganter

Journal of Organometallic Chemistry, 2017, 838, 37
DOI: 10.1016/j.jorganchem.2017.03.035

Stable Mesoionic N‐Heterocyclic Olefins (mNHOs)

Max M. Hansmann, Patrick W. Antoni and Henner Pesch

Angew Chem Int Ed, 2020, 59, 5782
DOI: 10.1002/anie.201914571

Experimental Assessment of the π‐Acidity of Anionic and Neutral Malonate‐Derived N‐Heterocyclic Carbenes

Mirko Ruamps, Noël Lugan and Vincent César

Eur J Inorg Chem, 2017, 2017, 4167
DOI: 10.1002/ejic.201700883

Synthesis of N‐Heterocyclic Carbenes and Their Complexes by Chloronium Ion Abstraction from 2‐Chloroazolium Salts Using Electron‐Rich Phosphines

Matthias D. Böhme, Tobias Eder, Maike B. Röthel, Patrick D. Dutschke, Lukas F. B. Wilm, F. Ekkehardt Hahn and Fabian Dielmann

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202202190

Iron and Cobalt Metallotropism in Remote‐Substituted NHC Ligands: Metalation to Abnormal NHC Complexes or NHC Ring Opening

Andreas A. Danopoulos, Alexandre Massard, Gilles Frison and Pierre Braunstein

Angew Chem Int Ed, 2018, 57, 14550
DOI: 10.1002/anie.201808008

Toward N,P-Doped π-Extended PAHs: A One-Pot Synthesis to Diannulated 1,4,2-Diazaphospholium Triflate Salts

Robin Schoemaker, Kai Schwedtmann, Felix Hennersdorf, Antonio Bauzá, Antonio Frontera and Jan J. Weigand

J. Org. Chem., 2020, 85, 14420
DOI: 10.1021/acs.joc.0c00577

N‐Heterocyclic Carbene and Cyclic (Alkyl)(amino)carbene Adducts of Antimony(III)

Michael S. M. Philipp, Mirjam J. Krahfuss, Krzysztof Radacki and Udo Radius

Eur J Inorg Chem, 2021, 2021, 4007
DOI: 10.1002/ejic.202100632

Monodentate Ligands in X-Cu(I)-Y Complexes—Structural Aspects

Milan Melník, Veronika Mikušová and Peter Mikuš

Inorganics, 2024, 12, 279
DOI: 10.3390/inorganics12110279

A Cationic N-Heterocyclic Carbene Containing an Ammonium Moiety

Mirko Ruamps, Noël Lugan and Vincent César

Organometallics, 2017, 36, 1049
DOI: 10.1021/acs.organomet.7b00017

Deprotonation of Group 14 Metal Amide Complexes Bearing Ditopic Carbanionic N-Heterocyclic Carbene Ligands. Constitutional Isomerism and Dynamic Behavior

Jordan B. Waters, Lajoy S. Tucker and Jose M. Goicoechea

Organometallics, 2018, 37, 655
DOI: 10.1021/acs.organomet.7b00352

Tailoring metal complexes with N-heterocyclic carbene ligands using Electron-Withdrawing Groups: Impact on catalytic activity and property development

Roman O. Pankov, Darya O. Prima and Valentine P. Ananikov

Coordination Chemistry Reviews, 2024, 516, 215897
DOI: 10.1016/j.ccr.2024.215897

Correlation Between NMR Coupling Constants and σ‐Donating Properties of N‐Heterocyclic Carbenes and Their Derivatives

Radhika Gupta and Gilles Frison

Chemistry A European J, 2025, 31
DOI: 10.1002/chem.202403403

Influence of ring substituents on the electronic properties of 1,2,4-triazolylidenes

Torsten Hölzel and Christian Ganter

Journal of Organometallic Chemistry, 2020, 915, 121234
DOI: 10.1016/j.jorganchem.2020.121234

Stereoelectronic Evaluation of Pyrazole- and Indazole-Derived N-Heterocyclic Carbenes

Nemanja D̵ord̵ević and Han Vinh Huynh

Organometallics, 2022, 41, 335
DOI: 10.1021/acs.organomet.1c00675

N-Heterocyclic Carbene Complexes of Copper, Nickel, and Cobalt

Andreas A. Danopoulos, Thomas Simler and Pierre Braunstein

Chem. Rev., 2019, 119, 3730
DOI: 10.1021/acs.chemrev.8b00505