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Synthesis of N-isoindolinonyl peptides via Pd-catalyzed C(sp2)–H olefination–activation and their conformational studies

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Cobalt(iii)-catalyzed redox-neutral [4+2]-annulation of N-chlorobenzamides/acrylamides with alkylidenecyclopropanes at room temperature

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Cobalt-catalyzed cyclization of benzamides with alkynes: a facile route to isoquinolones with hydrogen evolution

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Org. Biomol. Chem., 2018, 16, 8384
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A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

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Modification of [2.2]paracyclophane through cobalt-catalyzed ortho-C–H allylation and acyloxylation

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Pd-Catalyzed C(sp2)–H olefination: synthesis of N-alkylated isoindolinone scaffolds from aryl amides of amino acid esters

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Green strategies for transition metal-catalyzed C–H activation in molecular syntheses

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Cobalt-catalysed C–H carbonylative cyclisation of aliphatic amides

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Isoxazole as a nitrile synthon: en routes to the ortho-alkenylated isoxazole and benzonitrile with allyl sulfone catalyzed by Ru(ii)

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Rh(iii)-catalyzed selective mono- and dual-functionalization/cyclization of 1-aryl-5-aminopyrazoles with iodonium ylides

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Remote alkylation ofN-(quinolin-8-yl)benzamides with alkyl bromidesviaruthenium(ii)-catalyzed C–H bond activation

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Org. Biomol. Chem., 2018, 16, 3419
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Cobalt catalyzed carbonylation of unactivated C(sp3)–H bonds

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Salicylaldehyde-Enabled Co(II)-Catalyzed Oxidative C–H Alkenylation of Indoles with Olefins

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Thioamide-Directed Cp*Co(III)-Catalyzed C–H Allylation of Ferrocenes

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Manganese(I) Catalyzed ortho C−H Allylation of Benzoic Acids

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Regiospecific ortho‐C−H Allylation of Benzoic Acids

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Palladium-Catalyzed Directed Alkenylation of Alkyl Amides with Unactivated Alkenes: Access to γ-Alkenyl γ-Lactams

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Imidate as the Intact Directing Group for the Cobalt-Catalyzed C–H Allylation

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Ru(II)-Catalyzed C–H Alkenylation of Benzimidates with Unactivated Olefins: A Route to ortho-Alkenylated Benzonitriles

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Cobalt‐Catalyzed Oxidative C−H Activation: Strategies and Concepts

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Directed Copper-Catalyzed Intermolecular Heck-Type Reaction of Unactivated Olefins and Alkyl Halides

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Bidentate Directing Groups: An Efficient Tool in C–H Bond Functionalization Chemistry for the Expedient Construction of C–C Bonds

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Mangan(I) katalysierte ortho C–H‐Allylierung von Benzoesäuren

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Cationic Co(I) Catalysts for Regiodivergent Hydroalkenylation of 1,6-Enynes: An Uncommon cis-β-C–H Activation Leads to Z-Selective Coupling of Acrylates

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ACS Catal., 2021, 11, 9605
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Cobalt-Catalyzed C(sp2)–H Allylation of Biphenyl Amines with Unbiased Terminal Olefins

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Ruthenium(II)-Catalyzed Redox-Neutral C–H Alkylation of Arylamides with Unactivated Olefins

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Org. Lett., 2021, 23, 4849
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Rh(III)-Catalyzed Enone Carbonyl/Ketone-Directed Aerobic C–H Olefination of Aromatics with Unactivated Olefins

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J. Org. Chem., 2022, 87, 13236
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Iridium-catalyzed carbonyl group-directed oxidative coupling of arenes with alkenes

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An Oxidative Palladium-Catalyzed Remote meta-Selective Homo-Biaryl Coupling Assisted by Nitrile Directing Templates

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Rh(III)-Catalyzed Selective Olefination of N-Carboxamide Indoles with Unactivated Olefins at Room Temperature via an Internal Oxidation

Priyambada Prusty, Subramanian Jambu and Masilamani Jeganmohan

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Peptide-guided functionalization and macrocyclization of bioactive peptidosulfonamides by Pd(II)-catalyzed late-stage C–H activation

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Directing Group Assisted Unsymmetrical Multiple Functionalization of Arene C−H Bonds

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The Chemical Record, 2020, 20, 1017
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Cobalt(II)-Catalyzed Selective C2–H Heck Reaction of Native (N–H) Indoles Enabled by Salicylaldehyde Ligand

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Chiral Transient Ligand Enabled Enantioselective Synthesis of Atropisomers Decorated with Unactivated Olefins via a Palladium-Catalyzed C–H Olefination

Vadivel Arjun and Masilamani Jeganmohan

Org. Lett., 2023, 25, 7606
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Rhodium(III)-Catalyzed C–H Olefination of Aromatic/Vinyl Acids with Unactivated Olefins at Room Temperature

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Org. Lett., 2020, 22, 5057
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(Pentamethylcyclopentadienyl)cobalt(III)‐Catalyzed C–H Bond Functionalization: From Discovery to Unique Reactivity and Selectivity

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Adv Synth Catal, 2017, 359, 1245
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Mechanistic Investigations of Cobalt-Catalyzed, Aminoquinoline-Directed C(sp2)–H Bond Functionalization

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J. Am. Chem. Soc., 2025, 147, 2476
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3d Transition Metals for C–H Activation

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Chem. Rev., 2019, 119, 2192
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Palladium-Catalyzed Ligand-Enabled Cyclization of Substituted Aliphatic Carboxylic Acids with Allylic Electrophiles

Gouranga Naskar and Masilamani Jeganmohan

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Rh/O2-Catalyzed C8 Olefination of Quinoline N-Oxides with Activated and Unactivated Olefins

Ritika Sharma, Rakesh Kumar and Upendra Sharma

J. Org. Chem., 2019, 84, 2786
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Palladium-Catalyzed Regioselective C–H Alkenylation of Arylacetamides via Distal Weakly Coordinating Primary Amides as Directing Groups

Yogesh Jaiswal, Yogesh Kumar and Amit Kumar

J. Org. Chem., 2018, 83, 1223
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Incorporating Unbiased, Unactivated Aliphatic Alkenes in Pd(II)-Catalyzed Olefination of Benzyl Phosphonamide

Kapileswar Seth, Milan Bera, Massimo Brochetta, Soumitra Agasti, Ashis Das, Andrea Gandini, Alessio Porta, Giuseppe Zanoni and Debabrata Maiti

ACS Catal., 2017, 7, 7732
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Additive-Free Pd-Catalyzed α-Allylation of Imine-Containing Heterocycles

Marko Kljajic, Johannes G. Puschnig, Hansjörg Weber and Rolf Breinbauer

Org. Lett., 2017, 19, 126
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Cobalt‐Catalyzed Directed sp2 C−H Acetoxylation of Arenes Employing Mn(OAc)3 ⋅ 2H2O as Acetoxy Source

Writhabrata Sarkar, Arup Bhowmik, Aniket Mishra, Tripta Kumari Vats and Indubhusan Deb

Adv Synth Catal, 2018, 360, 3228
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Mechanochemical Oxidative Heck Coupling of Activated and Unactivated Alkenes: A Chemo‐, Regio‐ and Stereo‐Controlled Synthesis of Alkenylbenzenes

Jingbo Yu, Haowen Shou, Wangyang Yu, Haodong Chen and Weike Su

Adv Synth Catal, 2019, 361, 5133
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Cobalta-Electrocatalyzed C–H Allylation with Unactivated Alkenes

Uttam Dhawa, Cong Tian, Weizhao Li and Lutz Ackermann

ACS Catal., 2020, 10, 6457
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Rhodium-catalyzed C–H olefination of aromatic acids with unactivated olefins to achieve branched vinylated or linear allylated product: A theoretical investigation

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Ruthenium(II)-Catalyzed Redox-Free [3 + 2] Cycloaddition of N-Sulfonyl Aromatic Aldimines with Maleimides

Masilamani Tamizmani, Balu Ramesh and Masilamani Jeganmohan

J. Org. Chem., 2018, 83, 3746
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Rhodium(III)-Catalyzed Redox-Neutral [4 + 1]-Annulation of Unactivated Alkenes with Sulfoxonium Ylides

Pinki Sihag and Masilamani Jeganmohan

J. Org. Chem., 2022, 87, 11073
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A Fujiwara‐Moritani‐Type Alkenylation Using a Traceless Directing Group Strategy: A Rare Example of C−C Bond Formation towards the C2‐Carbon of Terminal Alkenes

Raheleh Pourkaveh, Maren Podewitz and Michael Schnürch

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Regiospecific ortho‐C−H Allylation of Benzoic Acids

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Angew Chem Int Ed, 2018, 57, 14580
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Aerobic Oxidative C–H Olefination of Arylamides with Unactivated Olefins via a Rh(III)-Catalyzed C–H Activation

Subramanian Jambu, Chikkabagilu Nagaraju Shambhavi and Masilamani Jeganmohan

Org. Lett., 2021, 23, 2964
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Transition‐Metal‐Catalyzed, Chelation‐Assisted C−H Alkenylation and Allylation of Organic Molecules with Unactivated Alkenes

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Adv Synth Catal, 2022, 364, 2113
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Recent Advances in Cobalt‐catalyzed Functionalization of Unactivated Olefins

Monak Patel, Uppuluru Ajay, Kishor Padala and Togati Naveen

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Palladium-Catalyzed Regioselective C–H Functionalization/Annulation Reaction of Amides and Allylbenzenes for the Synthesis of Isoquinolinones and Pyridinones

Rong Zhong, Yong Xu, Manman Sun and Yurong Wang

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Oxidative Alkenylation of (Hetero)aromatics with Unactivated Alkenes: Control of the Reaction Selectivity

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Rhodium(III)-Catalyzed Aerobic Oxidative C–H Olefination of Unsaturated Acrylamides with Unactivated Olefins

Ravichandran Logeswaran and Masilamani Jeganmohan

Org. Lett., 2021, 23, 767
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Directed C−H Allylation of Aromatic Carboxamides with Allyl Aryl Ethers under Cp*Co(III)‐Catalysis

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Ligand-Dependent Multi-State Reactivity in Cobalt(III)-Catalyzed C–H Activations

Pengchen Ma and Hui Chen

ACS Catal., 2019, 9, 1962
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Recyclable Aliphatic Nitrile-Template Enabled Remote meta-C–H Functionalization at Room Temperature

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Cobalt-Catalyzed Oxidative Cyclization of Benzamides with Maleimides: Synthesis of Isoindolone Spirosuccinimides

Ramasamy Manoharan and Masilamani Jeganmohan

Org. Lett., 2017, 19, 5884
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Cobalt(II)-catalyzed C H functionalization using an N,N′-bidentate directing group

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Coordination Chemistry Reviews, 2017, 350, 117
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Dehydrogenative Cross-Coupling of α,β-Unsaturated Compounds with Unactivated Olefins via Co(III) Catalysis

Ravichandran Logeswaran and Masilamani Jeganmohan

Org. Lett., 2023, 25, 6284
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