Defect characterisation in Cu2ZnSnSe4kesteritesviaresonance Raman spectroscopy and the impact on optoelectronic solar cell properties

Mirjana Dimitrievska, Florian Oliva, Maxim Guc, Sergio Giraldo, Edgardo Saucedo, Alejandro Pérez-Rodríguez and Victor Izquierdo-Roca

J. Mater. Chem. A, 2019, 7, 13293
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Defects in kesterite materials towards high-efficiency solar cells: origin, impact, characterization, and engineering

Lijing Wang, Jintang Ban, Litao Han, Zhengji Zhou, Wenhui Zhou, Dongxing Kou, Yuena Meng, Yafang Qi, Shengjie Yuan and Sixin Wu

J. Mater. Chem. A, 2024, 12, 25643
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Understanding quaternary compound Cu2ZnSnSe4 synthesis by microscopic scale analyses at an identical location

A. Crossay, D. Colombara, M. Melchiorre, M. Guennou, B. G. Mendis and P. J. Dale

J. Mater. Chem. C, 2016, 4, 4626
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Sodium-assisted passivation of grain boundaries and defects in Cu2ZnSnSe4 thin films

Juran Kim, Gee Yeong Kim, Trang Thi Thu Nguyen, Seokhyun Yoon, Yoon-Koo Kim, Seung-Yong Lee, Miyoung Kim, Dae-Hyung Cho, Yong-Duck Chung, Je-Ho Lee, Maeng-Je Seong and William Jo

Phys. Chem. Chem. Phys., 2020, 22, 7597
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A critical review on rational composition engineering in kesterite photovoltaic devices: self-regulation and mutual synergy

Jiajia Guo, Jianping Ao and Yi Zhang

J. Mater. Chem. A, 2023, 11, 16494
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Combinatorial Analysis Methodologies for Accelerated Research: The Case of Chalcogenide Thin‐Film Photovoltaic Technologies

Robert Fonoll-Rubio, Ignacio Becerril-Romero, Pedro Vidal-Fuentes, Enric Grau-Luque, Fabien Atlan, Alejandro Perez-Rodriguez, Victor Izquierdo-Roca and Maxim Guc

Solar RRL, 2022, 6
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Accelerating the Development of Thin Film Photovoltaic Technologies: An Artificial Intelligence Assisted Methodology Using Spectroscopic and Optoelectronic Techniques

Enric Grau‐Luque, Ignacio Becerril‐Romero, Fabien Atlan, Daniel Huber, Martina Harnisch, Andreas Zimmermann, Alejandro Pérez‐Rodríguez, Maxim Guc and Victor Izquierdo‐Roca

Small Methods, 2024, 8
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Effect of pre-deposition annealing on physical properties of CZTSSe thin films deposed by RF-sputtering based on nanoparticles synthesized by solvothermal technique

M. Jaouali, M. Nouiri, N. Ihzaz, A. Sagna, K. Mejnoun, M. Zouaoui, A. Bouloufa, J. El Haskouri, K. Djessas, L. El Mir and Z. Ben Ayadi

J Mater Sci: Mater Electron, 2022, 33, 20867
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Secondary Crystalline Phases Influence on Optical Properties in Off-Stoichiometric Cu2S–ZnS–SnS2 Thin Films

Florinel Sava, Ousmane Diagne, Aurelian-Catalin Galca, Iosif-Daniel Simandan, Elena Matei, Mihail Burdusel, Nicu Becherescu, Virginia Becherescu, Claudia Mihai and Alin Velea

Materials, 2020, 13, 4624
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Secondary phase and Cu substitutional defect dynamics in kesterite solar cells: Impact on optoelectronic properties

Mirjana Dimitrievska, Andrew Fairbrother, Edgardo Saucedo, Alejandro Pérez-Rodríguez and Victor Izquierdo-Roca

Solar Energy Materials and Solar Cells, 2016, 149, 304
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Valence engineering of copper in kesterite precursors via chalcogen modulation for defect-controlled solar cells

Zhenghao Liu, Hongfei Zhou, Xue Zheng, Wei Li, Guo-Hua Zhong, Xin Fu, Shulan Wang, Jixiang Hu, Shuting Chen, Ye Feng and Chunlei Yang

Solar Energy, 2025, 300, 113830
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Raman scattering analysis of the surface chemistry of kesterites: Impact of post-deposition annealing and Cu/Zn reordering on solar cell performance

Mirjana Dimitrievska, Sergio Giraldo, Paul Pistor, Edgardo Saucedo, Alejandro Pérez-Rodríguez and Victor Izquierdo-Roca

Solar Energy Materials and Solar Cells, 2016, 157, 462
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Intrinsic point defects in off-stoichiometric Cu2ZnSnSe4: A neutron diffraction study

Galina Gurieva, Laura Elisa Valle Rios, Alexandra Franz, Pamela Whitfield and Susan Schorr

Journal of Applied Physics, 2018, 123
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Controllable Multinary Alloy Electrodeposition for Thin-Film Solar Cell Fabrication: A Case Study of Kesterite Cu2ZnSnS4

Jie Ge and Yanfa Yan

iScience, 2018, 1, 55
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Modulation Effect of the Zn/Sn Ratio on Performance of Chloride-Fabricated CZTSSe Cells for Boosting 10%-Beyond Efficiencies

Fengxia Yang, Xiaofei Dong, Lei Yu, Xudong Sun, Jiangtao Chen, Yun Zhao and Yan Li

ACS Appl. Energy Mater., 2022, 5, 11431
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Progress and Perspectives of Thin Film Kesterite Photovoltaic Technology: A Critical Review

Sergio Giraldo, Zacharie Jehl, Marcel Placidi, Victor Izquierdo‐Roca, Alejandro Pérez‐Rodríguez and Edgardo Saucedo

Advanced Materials, 2019, 31
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Is the Cu/Zn Disorder the Main Culprit for the Voltage Deficit in Kesterite Solar Cells?

Stéphane Bourdais, Christophe Choné, Bruno Delatouche, Alain Jacob, Gerardo Larramona, Camille Moisan, Alain Lafond, Fabrice Donatini, Germain Rey, Susanne Siebentritt, Aron Walsh and Gilles Dennler

Advanced Energy Materials, 2016, 6
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Structural Polymorphism in “Kesterite” Cu2ZnSnS4: Raman Spectroscopy and First-Principles Calculations Analysis

Mirjana Dimitrievska, Federica Boero, Alexander P. Litvinchuk, Simona Delsante, Gabriella Borzone, Alejandro Perez-Rodriguez and Victor Izquierdo-Roca

Inorg. Chem., 2017, 56, 3467
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Enhanced Hetero‐Junction Quality and Performance of Kesterite Solar Cells by Aluminum Hydroxide Nanolayers and Efficiency Limitation Revealed by Atomic‐resolution Scanning Transmission Electron Microscopy

Haibing Xie, Yudania Sánchez, Pengyi Tang, Moisés Espíndola‐Rodríguez, Maxim Guc, Lorenzo Calvo‐Barrio, Simon López‐Marino, Yu Liu, Joan R. Morante, Andreu Cabot, Victor Izquierdo‐Roca, Jordi Arbiol, Alejandro Pérez‐Rodríguez and Edgardo Saucedo

Solar RRL, 2019, 3
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Cu2ZnSnS4 thin film solar cells grown by fast thermal evaporation and thermal treatment

E. Garcia-Llamas, J.M. Merino, R. Gunder, K. Neldner, D. Greiner, A. Steigert, S. Giraldo, V. Izquierdo-Roca, E. Saucedo, M. León, S. Schorr and R. Caballero

Solar Energy, 2017, 141, 236
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Influence of the precursor composition on the resulting absorber properties and defect concentration in Cu2ZnSnSe4 absorbers

David Nowak, Fabien Atlan, Devendra Pareek, Maxim Guc, Alejandro Perez-Rodriguez, Victor Izquierdo-Roca and Levent Gütay

Solar Energy Materials and Solar Cells, 2023, 256, 112342
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The effect of stoichiometry on Cu-Zn ordering kinetics in Cu2ZnSnS4 thin films

Katharina Rudisch, Alexandra Davydova, Charlotte Platzer-Björkman and Jonathan Scragg

Journal of Applied Physics, 2018, 123
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Direct evidence of causality between chemical purity and band-edge potential fluctuations in nanoparticle ink-based Cu2ZnSn(S,Se)4 solar cells

S Campbell, Y Qu, J D Major, D Lagarde, C Labbé, P Maiello, V Barrioz, N S Beattie and G Zoppi

J. Phys. D: Appl. Phys., 2019, 52, 135102
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Short- and Long-Range Cation Disorder in (AgxCu1–x)2ZnSnSe4 Kesterites

Shaham Quadir, Mohammad Qorbani, Amr Sabbah, Tai-Sing Wu, Aswin kumar Anbalagan, Wei-Tin Chen, Suneesh Meledath Valiyaveettil, Ho-Thi Thong, Chin-Wei Wang, Cheng-Ying Chen, Chih-Hao Lee, Kuei-Hsien Chen and Li-Chyong Chen

Chem. Mater., 2022, 34, 7058
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Efficient and Composition‐Tolerant Kesterite Cu2ZnSn(S, Se)4 Solar Cells Derived From an In Situ Formed Multifunctional Carbon Framework

Xiao Xu, Linbao Guo, Jiazheng Zhou, Biwen Duan, Dongmei Li, Jiangjian Shi, Huijue Wu, Yanhong Luo and Qingbo Meng

Advanced Energy Materials, 2021, 11
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Compositional Dependence of Chemical and Electrical Properties in Cu2ZnSnS4Thin Films

Eric Garcia-Hemme, Andrew Fairbrother, L. Calvo-Barrio, Edgardo Saucedo and Ignacio Martil

IEEE J. Photovoltaics, 2016, 6, 990
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Discrepancy between integral and local composition in off-stoichiometric Cu2ZnSnSe4 kesterites: A pitfall for classification

Philipp Schöppe, Galina Gurieva, Sergio Giraldo, Gema Martínez-Criado, Carsten Ronning, Edgardo Saucedo, Susan Schorr and Claudia S. Schnohr

Applied Physics Letters, 2017, 110
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Temperature dependent electroreflectance study of Cu2ZnSnSe4 solar cells

Jüri Krustok, Taavi Raadik, Maarja Grossberg, Sergio Giraldo, Markus Neuschitzer, Simon López-Marino and Edgardo Saucedo

Materials Science in Semiconductor Processing, 2015, 39, 251
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The Single Phase Region in Cu2ZnSnS4 Thin Films from Theory and Combinatorial Experiments

Alexandra Davydova, Katharina Rudisch and Jonathan J. S. Scragg

Chem. Mater., 2018, 30, 4624
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Thin film photovoltaic devices prepared with Cu3BiS3 ternary compound

J. Hernádez-Mota, M. Espíndola-Rodríguez, Y. Sánchez, Israel López, Y. Peña and E. Saucedo

Materials Science in Semiconductor Processing, 2018, 87, 37
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Tuning of Precursor Composition and Formation Pathway of Kesterite Absorbers Using an In‐Process Composition Shift: A Path toward Higher Efficiencies?

David Nowak, Teoman Taskesen, Devendra Pareek, Timo Pfeiffelmann, Ulf Mikolajczak and Levent Gütay

Solar RRL, 2021, 5
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