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Trapping an Oxidized and Protonated Intermediate of the [FeFe]-Hydrogenase Cofactor under Mildly Reducing Conditions

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Hemilabile Bridging Thiolates as Proton Shuttles in Bioinspired H2 Production Electrocatalysts

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Proton‐Coupled Reduction of the Catalytic [4Fe‐4S] Cluster in [FeFe]‐Hydrogenases

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Electrochemical CO2 and Proton Reduction by a Co(dithiacyclam) Complex

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Artificial Metalloproteins: At the Interface between Biology and Chemistry

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Sensitized Photocatalytic CO2 Reduction With Earth Abundant 3d Metal Complexes Possessing Dipicolyl-Triazacyclononane Derivatives

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Stepwise isotope editing of [FeFe]-hydrogenases exposes cofactor dynamics

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Extending electron paramagnetic resonance to nanoliter volume protein single crystals using a self-resonant microhelix

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Second and Outer Coordination Sphere Effects in Nitrogenase, Hydrogenase, Formate Dehydrogenase, and CO Dehydrogenase

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Spin Polarization Reveals the Coordination Geometry of the [FeFe] Hydrogenase Active Site in Its CO-Inhibited State

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Bridging Hydride at Reduced H-Cluster Species in [FeFe]-Hydrogenases Revealed by Infrared Spectroscopy, Isotope Editing, and Quantum Chemistry

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Structure and electrochemistry of proteins harboring iron-sulfur clusters of different nuclearities. Part I. [4Fe-4S] + [2Fe-2S] iron-sulfur proteins

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Wasserstoffkatalyse in Mikroalgen

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Vibrational Perturbation of the [FeFe] Hydrogenase H-Cluster Revealed by 13C2H-ADT Labeling

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A Dynamic Water Channel Affects O2 Stability in [FeFe]‐Hydrogenases

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Spectroscopical Investigations on the Redox Chemistry of [FeFe]-Hydrogenases in the Presence of Carbon Monoxide

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A personal account on 25 years of scientific literature on [FeFe]-hydrogenase

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The Molecular Proceedings of Biological Hydrogen Turnover

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Mechanism of Hydrogen Sulfide-Dependent Inhibition of FeFe Hydrogenase

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Spectroscopic and Computational Evidence that [FeFe] Hydrogenases Operate Exclusively with CO-Bridged Intermediates

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Metallocavitins as Advanced Enzyme Mimics and Promising Chemical Catalysts

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Semisynthetic Hydrogenases Propel Biological Energy Research into a New Era

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Interplay between CN– Ligands and the Secondary Coordination Sphere of the H-Cluster in [FeFe]-Hydrogenases

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Differential Protonation at the Catalytic Six-Iron Cofactor of [FeFe]-Hydrogenases Revealed by 57Fe Nuclear Resonance X-ray Scattering and Quantum Mechanics/Molecular Mechanics Analyses

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Bioassembly of complex iron–sulfur enzymes: hydrogenases and nitrogenases

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In Vivo EPR Characterization of Semi‐Synthetic [FeFe] Hydrogenases

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[FeFe]-hydrogenases as biocatalysts in bio-hydrogen production

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Insights into the Molecular Mechanism of Formaldehyde Inhibition of [FeFe]-Hydrogenases

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Tuning Catalytic Bias of Hydrogen Gas Producing Hydrogenases

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Sunlight‐Dependent Hydrogen Production by Photosensitizer/Hydrogenase Systems

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ChemSusChem, 2017, 10, 894
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Electrochemical Investigations of the Mechanism of Assembly of the Active-Site H-Cluster of [FeFe]-Hydrogenases

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