Polyhedral oligomeric silsesquioxane-based hybrid materials and their applications

Hui Zhou, Qun Ye and Jianwei Xu

Mater. Chem. Front., 2017, 1, 212
DOI: 10.1039/C6QM00062B

Relationship between crosslinking structure and low dielectric constant of hydrophobic epoxies based on substituted biphenyl mesogenic units

Huilong Guo, Jian Zheng, Jianqun Gan, Liyan Liang, Kun Wu and Mangeng Lu

RSC Adv., 2015, 5, 88014
DOI: 10.1039/C5RA16540G

Robust spin-on-glass poly(methyl)silsesquioxane-based low-k materials derived from a cyclic siloxane precursor

Albert S. Lee, Sung Yeoun Oh, Seung-Sock Choi, He Seung Lee, Seung Sang Hwang and Kyung-Youl Baek

RSC Adv., 2015, 5, 66511
DOI: 10.1039/C5RA11110B

An insight into the amphiphobicity and thermal degradation behavior of PDMS-based block copolymers bearing POSS and fluorinated units

Junyan Liang, Ling He, Yanyan Zuo, Zhaoyu Chen and Tao Peng

Soft Matter, 2018, 14, 5235
DOI: 10.1039/C8SM00608C

Cardanol benzoxazines – interplay of oxazine functionality (mono to tetra) and properties

Swapnil Shukla, Arup Mahata, Biswarup Pathak and Bimlesh Lochab

RSC Adv., 2015, 5, 78071
DOI: 10.1039/C5RA14214H

Cardanol based benzoxazine blends and bio-silica reinforced composites: thermal and dielectric properties

H. Arumugam, S. Krishnan, M. Chavali and A. Muthukaruppan

New J. Chem., 2018, 42, 4067
DOI: 10.1039/C7NJ04506A

Development and characterization of fully bio‐based polybenzoxazine‐silica hybrid composites for low‐k and flame‐retardant applications

Krishnadevi Krishnamoorthy, Devaraju Subramani, Naveena Eeda and Alagar Muthukaruppan

Polymers for Advanced Techs, 2019, 30, 1856
DOI: 10.1002/pat.4618

Role of POSS as Coupling Agent for DGEBA/GF Reinforced Nanocomposites

Duraibabu Dhanapal, Ananda Kumar Srinivasan and Neelakandan Ramalingam

Silicon, 2018, 10, 537
DOI: 10.1007/s12633-016-9487-8

Towards the Development of Green Flame Retardancy by Polybenzoxazines

Irlaine Machado, Cecilia Shaer, Kalan Hurdle, Veronica Calado and Hatsuo Ishida

Progress in Polymer Science, 2021, 121, 101435
DOI: 10.1016/j.progpolymsci.2021.101435

Mechanically Robust Hybrid POSS Thermoplastic Polyurethanes with Enhanced Surface Hydrophobicity

Xiuhuan Song, Xiaoxiao Zhang, Tianduo Li, Zibiao Li and Hong Chi

Polymers, 2019, 11, 373
DOI: 10.3390/polym11020373

Hybrid Nonisocyanate Polyurethanes (H‐NIPUs): A Pathway towards a Broad Range of Novel Materials

Boris Bizet, Etienne Grau, José M. Asua and Henri Cramail

Macro Chemistry & Physics, 2022, 223
DOI: 10.1002/macp.202100437

From plant phenols to novel bio-based polymers

Chaoqun Zhang, Junqi Xue, Xiangyu Yang, Yanzi Ke, Rongxian Ou, Yang Wang, Samy A. Madbouly and Qingwen Wang

Progress in Polymer Science, 2022, 125, 101473
DOI: 10.1016/j.progpolymsci.2021.101473

Fluorinated polyimide nanocomposites for low K dielectric applications

S. Kurinchyselvan, A. Hariharan, P. Prabunathan, P. Gomathipriya and M. Alagar

J Polym Res, 2019, 26
DOI: 10.1007/s10965-019-1852-z

Recent Advance in Low‐Dielectric‐Constant Organosilicon Polymers

Jiaren Hou, Jing Sun and Qiang Fang

Chin. J. Chem., 2023, 41, 2371
DOI: 10.1002/cjoc.202300125

A new p-cresol-bisphenol based hybrid polybenzoxazine composites for high-k dielectrics: The role of Palmyra sprout carbon activation

Poornesh Devaraj, Sasikumar Ramachandran, Nishanth Govindaraju and Alagar Muthukaruppan

European Polymer Journal, 2025, 239, 114234
DOI: 10.1016/j.eurpolymj.2025.114234

Hydrothermal Synthesis of Polyoxometalate Containing Cobalt Ion, and Its Polyurethane Composites for Dielectric Material Applications

Ilhan Küçük, Sema Vural, Nilüfer Kıvılcım, Ibrahim Adıgüzel, Süleyman Köytepe and Turgay Seçkin

Polymer-Plastics Technology and Materials, 2020, 59, 1822
DOI: 10.1080/25740881.2020.1768543

Benzoxazine Based High Performance Materials with Low Dielectric Constant: A Review

Lei Zhang, Jiale Mao, Shuang Wang, Yiting Zheng, Xiangdong Liu and Yonghong Cheng

COC, 2019, 23, 809
DOI: 10.2174/1385272823666190422130917

Review on the Accelerated and Low-Temperature Polymerization of Benzoxazine Resins: Addition Polymerizable Sustainable Polymers

Bimlesh Lochab, Monisha Monisha, Nagarjuna Amarnath, Pratibha Sharma, Sourav Mukherjee and Hatsuo Ishida

Polymers, 2021, 13, 1260
DOI: 10.3390/polym13081260

Study on Silicon-Containing Main Chain Type Polybenzoxazines with Both High Heat Resistance and Low Dielectric Constant

Qichao Ran, Wei Zhang and Pengcheng Li

Ind. Eng. Chem. Res., 2023
DOI: 10.1021/acs.iecr.3c00260

Recent Advances in Modification and Application of Polyhedral Oligomeric Silsesquioxane/Polyurethane Composites: A Comprehensive Review

Jizeng Shang, Si Zhang, Xianping Qiu, Jian Zhang, Kaifeng Lin, Debin Xia, Lizhu Zhang and Yulin Yang

Macromol. Rapid Commun., 2025, 46
DOI: 10.1002/marc.202500337

Waterborne POSS-silane-urethane hybrid polymer and the fluorinated films

Siyu Chen, Longhai Guo, Dianxin Du, Jianling Rui, Teng Qiu, Jun Ye and Xiaoyu Li

Polymer, 2016, 103, 27
DOI: 10.1016/j.polymer.2016.09.034

Synthesis, modification and properties of rosin-based non-isocyanate polyurethanes coatings

Guifeng Liu, Guomin Wu, Jian Chen and Zhenwu Kong

Progress in Organic Coatings, 2016, 101, 461
DOI: 10.1016/j.porgcoat.2016.09.019

Facile preparation of the novel castor oil-based benzoxazine–urethane copolymer with improved high-frequency dielectric properties

Ming Zeng, Tao Pang, Jiangbing Chen, Yiwan Huang, Qingyu Xu and Yi Gu

J Mater Sci: Mater Electron, 2018, 29, 5391
DOI: 10.1007/s10854-017-8505-y

Synthesis and characterization of heterocyclic core‐based polybenzoxazine matrices

M. Selvi, S. Devaraju, M. R. Vengatesan and M. Alagar

J of Applied Polymer Sci, 2019, 136
DOI: 10.1002/app.47134

A research on benzoxazine/cyanate ester/epoxy POSS nanocomposite with low dielectric constant and improved toughness

Xiaodan Li, Xiaoqing Liu, Jiacheng Feng, Rui He, Hongyu Liu, Xinyu Hu and Xiaoping Liu

Polym. Bull., 2023, 80, 12989
DOI: 10.1007/s00289-023-04694-9

Preparation of self-healing organic–inorganic nanocomposites with the reactions between methacrylated polyhedral oligomeric silsesquioxanes and furfurylamine

Tsai-Wei Chuo and Ying-Ling Liu

Composites Science and Technology, 2015, 118, 236
DOI: 10.1016/j.compscitech.2015.09.005

Liquid Crystalline Epoxies with Lateral Substituents Showing a Low Dielectric Constant and High Thermal Conductivity

Huilong Guo, Mangeng Lu, Liyan Liang, Kun Wu, Dong Ma and Wei Xue

Journal of Elec Materi, 2017, 46, 982
DOI: 10.1007/s11664-016-5003-6

Balancing Optical Property and Enhancing Stability for High-Refractive Index Polythiourethane with Assistance of Cubic Thiol-Functionalized Silsesquioxanes

Yuanyu Chen, Zongyi Qin, Guofeng Tang, Lijun Wei, Houlin Du and Weiping Du

ACS Appl. Polym. Mater., 2021, 3, 153
DOI: 10.1021/acsapm.0c00917

Synthesis and properties of POSS-containing gallic acid-based non-isocyanate polyurethanes coatings

Guifeng Liu, Guomin Wu, Jian Chen, Shuping Huo, Can Jin and Zhenwu Kong

Polymer Degradation and Stability, 2015, 121, 247
DOI: 10.1016/j.polymdegradstab.2015.09.013

Dielectric properties of organophosphorus polyurethane ionomers

Ilsiya Davletbaeva, Oleg Sazonov, Elizaveta Nikitina, Victoria Kapralova, Aidar Nizamov, Ildar Akhmetov, Alexander Arkhipov and Nicolay Sudar

J of Applied Polymer Sci, 2022, 139
DOI: 10.1002/app.51751

Examining the thermal behaviour of novel aromatic polybenzoxazine blends containing an organophosphorous compound and polyhedral oligomeric silsesquioxane reagents

Sotirios Kopsidas and Ian Hamerton

Polymer International, 2016, 65, 1015
DOI: 10.1002/pi.5139

Synthesis and characterization of waterborne polyurethane/polyhedral oligomeric silsesquioxane composites with low dielectric constants

Hui Zhao, Si‐Qi Zhao, Guo‐Hua Hu, Qun‐Chao Zhang, Yang Liu, Chong‐Xing Huang, Wei Li, Tao Jiang and Shuang‐Fei Wang

Polymers for Advanced Techs, 2019, 30, 2313
DOI: 10.1002/pat.4659

Poly(arylene ether ketone)s with low dielectric constants derived from polyhedral oligomeric silsesquioxane and difluorinated aromatic ketones

Jinmeng Hao, Yanfeng Wei, Xuesong Li and Jianxin Mu

J of Applied Polymer Sci, 2018, 135
DOI: 10.1002/app.46084

3D cross-linked POSS-containing borate single ion conductor organic-inorganic hybrid gel electrolytes for dendrite-free lithium metal batteries

Xingfa Zeng, Puyan Huang, Jia Zhou, Xiangrong Wei, Xiao Wang, Liya Chen, Yu Ding and Jifang Fu

Chemical Engineering Journal, 2024, 487, 150707
DOI: 10.1016/j.cej.2024.150707

Polybenzoxazine/Polyhedral Oligomeric Silsesquioxane (POSS) Nanocomposites

Mohamed Mohamed and Shiao-Wei Kuo

Polymers, 2016, 8, 225
DOI: 10.3390/polym8060225

A novel ultra low-k nanocomposites of benzoxazinyl modified polyhedral oligomeric silsesquioxane and cyanate ester

Shuai Zhang, Yihan Yan, Xiaodan Li, Haojun Fan, Qichao Ran, Qiang Fu and Yi Gu

European Polymer Journal, 2018, 103, 124
DOI: 10.1016/j.eurpolymj.2018.03.013

A Review on the Design, Preparation, and Performance Control of Low Dielectric Constant Polybenzoxazine-Based Materials

Yu Luo, Lu Zhang, Liwu Zu, Shaobo Dong, Tianyu Lan, Jun Liu, Wei Zhang and Litao Xu

ACS Appl. Mater. Interfaces, 2025
DOI: 10.1021/acsami.5c17732