Embedding flexible fibers into responsive gels to create composites with controllable dexterity

Awaneesh Singh, Olga Kuksenok and Anna C. Balazs

Soft Matter, 2016, 12, 9170
DOI: 10.1039/C6SM02006B

4D printing innovations and the embracing of additive manufacturing transformations

Debarupa Dutta Chakraborty, Prithviraj Chakraborty, Subhasish Pramanik, Manali Dutta, Arpan Sen, Sudarshana Borah, Pallab Kumar Nath and Sabnam Nargis

RSC Pharm., 2026, 3, 22
DOI: 10.1039/D5PM00192G

Materials and technical innovations in 3D printing in biomedical applications

Hiroyuki Tetsuka and Su Ryon Shin

J. Mater. Chem. B, 2020, 8, 2930
DOI: 10.1039/D0TB00034E

Magttice: a lattice model for hard-magnetic soft materials

Huilin Ye, Ying Li and Teng Zhang

Soft Matter, 2021, 17, 3560
DOI: 10.1039/D0SM01662D

Modeling the response characteristics of photo-sensitive hydrogel electrolytes in Hofmeister salt solution for the development of smart energy storage devices

Xiao Chen, Zhixin Zhan, Qimin Liu and Tao Wu

Sustainable Energy Fuels, 2020, 4, 6112
DOI: 10.1039/D0SE00639D

Dehydration-triggered shape morphing based on asymmetric bubble hydrogel microfibers

Zhe Liang, Yupeng Liu, Feng Zhang, Yongjian Ai and Qionglin Liang

Soft Matter, 2018, 14, 6623
DOI: 10.1039/C8SM00984H

Design and fabrication of nanofibrillated cellulose-containing bilayer hydrogel actuators with temperature and near infrared laser responses

Qian Zhao, Yunhong Liang, Lei Ren, Zhenglei Yu, Zhihui Zhang, Feng Qiu and Luquan Ren

J. Mater. Chem. B, 2018, 6, 1260
DOI: 10.1039/C7TB02853A

A supramolecular assembly of a novel green fluorescent protein chromophore-based analogue and its application in fluorescence anti-counterfeiting

Yifei Ren and Chusen Huang

J. Mater. Chem. B, 2025, 13, 2327
DOI: 10.1039/D4TB02112F

Spiro-[4,5]-cyclohexadiene-8-one polymers: photoactivated crosslinking and switch-on fluorescence for lithography

Yi Yuan, Mi Chao, Yunyi Shang, Yujia Gao, Guangle Niu, Wanggang Fang, Liqing He and Hui Wang

Mater. Chem. Front., 2025, 9, 122
DOI: 10.1039/D4QM00688G

“Patterning with loops” to dynamically reconfigure polymer gels

Santidan Biswas, Victor V. Yashin and Anna C. Balazs

Soft Matter, 2018, 14, 3361
DOI: 10.1039/C8SM00270C

An insight into biomimetic 4D printing

Nand Jee Kanu, Eva Gupta, Umesh Kumar Vates and Gyanendra Kumar Singh

RSC Adv., 2019, 9, 38209
DOI: 10.1039/C9RA07342F

Fibers on the surface of thermo-responsive gels induce 3D shape changes

Tao Zhang, Victor V. Yashin and Anna C. Balazs

Soft Matter, 2018, 14, 1822
DOI: 10.1039/C8SM00009C

Harnessing biomimetic cryptic bonds to form self-reinforcing gels

Santidan Biswas, Victor V. Yashin and Anna C. Balazs

Soft Matter, 2020, 16, 5120
DOI: 10.1039/D0SM00145G

Multi-stage hydrogel rockets with stage dropping-off by thermal/light stimulation

Yuling Liang, Yibin Xu, Wei Ye, Dahua Yao, Yunhua Chen and Chaoyang Wang

J. Mater. Chem. A, 2018, 6, 16838
DOI: 10.1039/C8TA06715E

New modeling approach for 4D printing by using kinetic components

Woorim Choi, Dahong Kim, Sungjae Lee and Yong-Gu Lee

Journal of Computational Design and Engineering, 2021, 8, 1013
DOI: 10.1093/jcde/qwab029

4D printing of polymeric materials for tissue and organ regeneration

Shida Miao, Nathan Castro, Margaret Nowicki, Lang Xia, Haitao Cui, Xuan Zhou, Wei Zhu, Se-jun Lee, Kausik Sarkar, Giovanni Vozzi, Yasuhiko Tabata, John Fisher and Lijie Grace Zhang

Materials Today, 2017, 20, 577
DOI: 10.1016/j.mattod.2017.06.005

Hydrogel Production Platform with Dynamic Movement Using Photo-Crosslinkable/Temperature Reversible Chitosan Polymer and Stereolithography 4D Printing Technology

Jeong Wook Seo, Su Ryon Shin, Yeon Joo Park and Hojae Bae

Tissue Eng Regen Med, 2020, 17, 423
DOI: 10.1007/s13770-020-00264-6

Formation of helices with controllable chirality in gel-fiber composites

Tao Zhang, Victor V. Yashin, James T. Waters and Anna C. Balazs

Polymer, 2021, 212, 123191
DOI: 10.1016/j.polymer.2020.123191

Complicated deformation simulating on temperature-driven 4D printed bilayer structures based on reduced bilayer plate model

Junjie Song, Yixiong Feng, Yong Wang, Siyuan Zeng, Zhaoxi Hong, Hao Qiu and Jianrong Tan

Appl. Math. Mech.-Engl. Ed., 2021, 42, 1619
DOI: 10.1007/s10483-021-2788-9

4D Printing of Hydrogels: A Review

Mathilde Champeau, Daniel Alves Heinze, Thiago Nunes Viana, Edcarlos Rodrigues de Souza, Anne Cristine Chinellato and Silvia Titotto

Adv Funct Materials, 2020, 30
DOI: 10.1002/adfm.201910606

Integration of 3D Printing and Industry 4.0 into Engineering Teaching

Siewhui Chong, Guan-Ting Pan, Jitkai Chin, Pau Loke Show, Thomas Chung Kuang Yang and Chao-Ming Huang

Sustainability, 2018, 10, 3960
DOI: 10.3390/su10113960

4D Printing: A Review on Recent Progresses

Honghui Chu, Wenguang Yang, Lujing Sun, Shuxiang Cai, Rendi Yang, Wenfeng Liang, Haibo Yu and Lianqing Liu

Micromachines, 2020, 11, 796
DOI: 10.3390/mi11090796

4D Printing Pre-Strained Structures for Fast Thermal Actuation

Yu Zou, Zhongyi Huang, Xiying Li and Pengyu Lv

Front. Mater., 2021, 8
DOI: 10.3389/fmats.2021.661999

Exploring wastewater treatment potential through analytical 3D printed structures and pattern filming: a honeycomb biomimicry approach

S. K. Saha, N. Sakib, M. A. Jalil, T. Islam, Md. I. Hosen, M. M. Rahman and H. T. M. Q. Newaz

Int. J. Environ. Sci. Technol., 2025, 22, 12151
DOI: 10.1007/s13762-025-06538-7

Synergistic combination of 4D printing and electroless metallic plating for the fabrication of a highly conductive electrical device

Benjamin Qi Yu Chan, Yi Ting Chong, Shengqin Wang, Coryl Jing Jun Lee, Cally Owh, Fei Wang and FuKe Wang

Chemical Engineering Journal, 2022, 430, 132513
DOI: 10.1016/j.cej.2021.132513

Programmable Shape Transformation of 4D Printed Fibre-Reinforced Composites

Erdem Yildiz, Byung Chul Kim and Richard S. Trask

SSP, 2025, 381, 3
DOI: 10.4028/p-LLM6Xr

Smart materials for four-dimensional printing: An overview

Adil Wazeer, Apurba Das and Arijit Sinha

Proceedings of the Institution of Mechanical Engineers, Part E: Journal of Process Mechanical Engineering, 2023, 237, 571
DOI: 10.1177/09544089221117945

Comprehensive review of 3D/4D printing of soft materials, methods and applications

Muhammad Raies Abdullah, Zhen Peng, Vignesh babu Rajendren, Farooq Ahmad, Syed Sohail Ahmed Shah, Abdul Wasy Zia, Amjad Ali, Guanjun Qiao and Khurram Shehzad

Applied Materials Today, 2025, 43, 102667
DOI: 10.1016/j.apmt.2025.102667

Intelligent Nanofiber Composites: Dynamic Communication between Materials and Their Environment

Symone L. M. Alexander, Lindsay E. Matolyak and LaShanda T. J. Korley

Macro Materials & Eng, 2017, 302
DOI: 10.1002/mame.201700133

4D printing of liquid crystal elastomer composites with continuous fiber reinforcement

Huan Jiang, Christopher Chung, Martin L. Dunn and Kai Yu

Nat Commun, 2024, 15
DOI: 10.1038/s41467-024-52716-5

Trends in 3D Printing Processes for Biomedical Field: Opportunities and Challenges

Alina Ghilan, Aurica P. Chiriac, Loredana E. Nita, Alina G. Rusu, Iordana Neamtu and Vlad Mihai Chiriac

J Polym Environ, 2020, 28, 1345
DOI: 10.1007/s10924-020-01722-x

Supramolecular Polymers with Photoswitchable Multistate Fluorescence for Anti-Counterfeiting and Encryption

Jia Tang, Yong Tian, Zhong Lin, Chonghua Zhang, Peisheng Zhang, Rongjin Zeng, Si Wu, Xudong Chen and Jian Chen

ACS Appl. Mater. Interfaces, 2023, 15, 2237
DOI: 10.1021/acsami.2c19227

A Review on 4D Printing Material Composites and Their Applications

Amol Rayate and Prashant K. Jain

Materials Today: Proceedings, 2018, 5, 20474
DOI: 10.1016/j.matpr.2018.06.424

Modeling Biofilm Formation on Dynamically Reconfigurable Composite Surfaces

Ya Liu and Anna C. Balazs

Langmuir, 2018, 34, 1807
DOI: 10.1021/acs.langmuir.7b03765

Utilization of Ethyl Cellulose in the Osmotically-Driven and Anisotropically-Actuated 4D Printing Concept of Edible Food Composites

Ezgi Pulatsu, Jheng-Wun Su, Jian Lin and Mengshi Lin

Carbohydrate Polymer Technologies and Applications, 2022, 3, 100183
DOI: 10.1016/j.carpta.2022.100183

Design for 4D printing: Modeling and computation of smart materials distributions

Germain Sossou, Frédéric Demoly, Hadrien Belkebir, H. Jerry Qi, Samuel Gomes and Ghislain Montavon

Materials & Design, 2019, 181, 108074
DOI: 10.1016/j.matdes.2019.108074

4D Printing: Future Insight in Additive Manufacturing

Muhammad Qasim Zafar and Haiyan Zhao

Met. Mater. Int., 2020, 26, 564
DOI: 10.1007/s12540-019-00441-w

Multi‐Material 3D and 4D Printing: A Survey

Mohammad Rafiee, Rouhollah D. Farahani and Daniel Therriault

Advanced Science, 2020, 7
DOI: 10.1002/advs.201902307

Autonomic self-regulating systems based on polyelectrolyte microcapsules and microgel particles

Hongda Zhou, Rui Cheng, Matthew Quarrell and Dmitry Shchukin

Journal of Colloid and Interface Science, 2023, 638, 403
DOI: 10.1016/j.jcis.2023.01.111

Design of a continuous fiber trajectory for 4D printing of thermally stimulated composite structures

XiaoYong Tian, QingRui Wang and DiChen Li

Sci. China Technol. Sci., 2020, 63, 571
DOI: 10.1007/s11431-019-1485-5

Additive manufacturing method of electrothermal 4D bimorph microactuator

Masaaki Hashimoto, Takaya Sato and Yoshihiro Taguchi

Sensors and Actuators A: Physical, 2023, 356, 114348
DOI: 10.1016/j.sna.2023.114348

Stimuli-responsive materials for 4D Printing: Mechanical, Manufacturing, and Biomedical Applications

Pankaj Kumar, Purushottam Suryavanshi, Santosha Kumar Dwivedy and Subham Banerjee

Journal of Molecular Liquids, 2024, 410, 125553
DOI: 10.1016/j.molliq.2024.125553

Influence of Process Parameters on the Characteristics of Additively Manufactured Parts Made from Advanced Biopolymers

Tomaž Pepelnjak, Josip Stojšić, Luka Sevšek, Dejan Movrin and Mladomir Milutinović

Polymers, 2023, 15, 716
DOI: 10.3390/polym15030716

UV-mediated synthesis of pNIPAM-crosslinked double-network alginate hydrogels: Enhanced mechanical and shape-memory properties by metal ions and temperature

Eun Jung Choi, Seonggyun Ha, Jookyeong Lee, Thathan Premkumar and Changsik Song

Polymer, 2018, 149, 206
DOI: 10.1016/j.polymer.2018.06.080

Progressive transpose from 3D to 4D printed materials for drug delivery and biomedical applications

Mansi Sharma, Sunil Kumar Sah, Subhadeep Roy and Santanu Kaity

Reactive and Functional Polymers, 2025, 216, 106455
DOI: 10.1016/j.reactfunctpolym.2025.106455

Programmable morphing composites with embedded continuous fibers by 4D printing

Qingrui Wang, Xiaoyong Tian, Lan Huang, Dichen Li, Andrei V. Malakhov and Alexander N. Polilov

Materials & Design, 2018, 155, 404
DOI: 10.1016/j.matdes.2018.06.027

Critical appraisal and systematic review of 3D & 4D printing in sustainable and environment-friendly smart manufacturing technologies

Keshav Lalit Ameta, Vijendra Singh Solanki, Vineeta Singh, Ahanthem Priyanca Devi, R.S. Chundawat and Shafiul Haque

Sustainable Materials and Technologies, 2022, 34, e00481
DOI: 10.1016/j.susmat.2022.e00481

Additive manufacturing of cementitious composites: Materials, methods, potentials, and challenges

Fatemeh Hamidi and Farhad Aslani

Construction and Building Materials, 2019, 218, 582
DOI: 10.1016/j.conbuildmat.2019.05.140

A review on spacers and membranes: Conventional or hybrid additive manufacturing?

Jing Wee Koo, Jia Shin Ho, Jia An, Yi Zhang, Chee Kai Chua and Tzyy Haur Chong

Water Research, 2021, 188, 116497
DOI: 10.1016/j.watres.2020.116497

Advanced Materials, Technologies, and Complex Systems Analyses: Emerging Opportunities to Enhance Urban Water Security

Katherine R. Zodrow, Qilin Li, Regina M. Buono, Wei Chen, Glen Daigger, Leonardo Dueñas-Osorio, Menachem Elimelech, Xia Huang, Guibin Jiang, Jae-Hong Kim, Bruce E. Logan, David L. Sedlak, Paul Westerhoff and Pedro J. J. Alvarez

Environ. Sci. Technol., 2017, 51, 10274
DOI: 10.1021/acs.est.7b01679

Recent advances in 4D printing of fiber-reinforced polymer composites: A review and outlook

Wanglin Qiu, Xuguang Xu, Ke Dong, Yaohui Wang and Yi Xiong

Composites Part B: Engineering, 2024, 283, 111645
DOI: 10.1016/j.compositesb.2024.111645

Polymers for additive manufacturing and 4D-printing: Materials, methodologies, and biomedical applications

Carmen M. González-Henríquez, Mauricio A. Sarabia-Vallejos and Juan Rodriguez-Hernandez

Progress in Polymer Science, 2019, 94, 57
DOI: 10.1016/j.progpolymsci.2019.03.001

Bioinspired Pattern-Driven Single-Material 4D Printing for Self-Morphing Actuators

Yousif Saad Alshebly, Khameel B. Mustapha, Ali Zolfagharian, Mahdi Bodaghi, Mohamed Sultan Mohamed Ali, Haider Abbas Almurib and Marwan Nafea

Sustainability, 2022, 14, 10141
DOI: 10.3390/su141610141

Developments in 4D-printing: a review on current smart materials, technologies, and applications

Zhizhou Zhang, Kahraman G. Demir and Grace X. Gu

International Journal of Smart and Nano Materials, 2019, 10, 205
DOI: 10.1080/19475411.2019.1591541

Effects of material heterogeneity on self-rolling of strained membranes

Cheng Chen, Pengfei Song, Fanchao Meng, Pengfei Ou, Guoqiang Lan, Xinyu Liu and Jun Song

Extreme Mechanics Letters, 2019, 29, 100451
DOI: 10.1016/j.eml.2019.100451

High-Temperature-Aging Induced Sequential Recovery of Shape Memory Nitrile Butadiene Rubber Composites

Jihua Zhang, Xiaoyan Liu, Weitao Zao, Huadong Feng, Yange Hou and Aijuan Huo

ACS Appl. Mater. Interfaces, 2021, 13, 10376
DOI: 10.1021/acsami.0c20528

Energy Consumption Modeling of 4D Printing Thermal-responsive Polymers with Integrated Compositional Design for Material

Muyue Han, Yiran Yang and Lin Li

Additive Manufacturing, 2020, 34, 101223
DOI: 10.1016/j.addma.2020.101223

Research on imminent enlargements of smart materials and structures towards novel 4D printing (4DP: SMs-SSs)

Muhammad Imran Farid, Wenzheng Wu, Li Guiwei and Zhao Yu

Int J Adv Manuf Technol, 2023, 126, 2803
DOI: 10.1007/s00170-023-11180-z

Dynamically adaptive materials

Sung Hoon Kang

MRS Bulletin, 2024, 49, 1121
DOI: 10.1557/s43577-024-00798-3

The Design of 4D‐Printed Hygromorphs: State‐of‐the‐Art and Future Challenges

Charles de Kergariou, Frédéric Demoly, Adam Perriman, Antoine Le Duigou and Fabrizio Scarpa

Adv Funct Materials, 2023, 33
DOI: 10.1002/adfm.202210353

Additive manufacturing landscape and materials perspective in 4D printing

Muhammad Imran Farid, Wenzheng Wu, Xilin Liu and PeiPei Wang

Int J Adv Manuf Technol, 2021, 115, 2973
DOI: 10.1007/s00170-021-07233-w

An ontology-based framework to formalize and represent 4D printing knowledge in design

Saoussen Dimassi, Frédéric Demoly, Christophe Cruz, H. Jerry Qi, Kyoung-Yun Kim, Jean-Claude André and Samuel Gomes

Computers in Industry, 2021, 126, 103374
DOI: 10.1016/j.compind.2020.103374

A review of 4D printing

Farhang Momeni, Seyed M.Mehdi Hassani.N, Xun Liu and Jun Ni

Materials & Design, 2017, 122, 42
DOI: 10.1016/j.matdes.2017.02.068

4D printing and stimuli-responsive materials in biomedical aspects

Yuan Siang Lui, Wan Ting Sow, Lay Poh Tan, Yunlong Wu, Yuekun Lai and Huaqiong Li

Acta Biomaterialia, 2019, 92, 19
DOI: 10.1016/j.actbio.2019.05.005

4D printing: a new approach for food printing; effect of various stimuli on 4D printed food properties. A comprehensive review

Muhammed Navaf, Kappat Valiyapeediyekkal Sunooj, Basheer Aaliya, Plachikkattu Parambil Akhila, Cherakkathodi Sudheesh, Shabir Ahmad Mir and Johnsy George

Applied Food Research, 2022, 2, 100150
DOI: 10.1016/j.afres.2022.100150

4D printing: From emergence to innovation over 3D printing

Snehal Shinde, Rutuja Mane, Akhilesh Vardikar, Akash Dhumal and Amarjitsing Rajput

European Polymer Journal, 2023, 197, 112356
DOI: 10.1016/j.eurpolymj.2023.112356

Advances in 4D Printing: Materials and Applications

Xiao Kuang, Devin J. Roach, Jiangtao Wu, Craig M. Hamel, Zhen Ding, Tiejun Wang, Martin L. Dunn and Hang Jerry Qi

Adv Funct Materials, 2019, 29
DOI: 10.1002/adfm.201805290

Review of mechanisms and deformation behaviors in 4D printing

Han Ding, Xiang Zhang, Yong Liu and Seeram Ramakrishna

Int J Adv Manuf Technol, 2019, 105, 4633
DOI: 10.1007/s00170-019-03871-3

Supramolecular–covalent hybrid polymers for light-activated mechanical actuation

Chuang Li, Aysenur Iscen, Hiroaki Sai, Kohei Sato, Nicholas A. Sather, Stacey M. Chin, Zaida Álvarez, Liam C. Palmer, George C. Schatz and Samuel I. Stupp

Nat. Mater., 2020, 19, 900
DOI: 10.1038/s41563-020-0707-7

3D and 4D Printing of Multistable Structures

Hoon Yeub Jeong, Soo-Chan An, Yeonsoo Lim, Min Ji Jeong, Namhun Kim and Young Chul Jun

Applied Sciences, 2020, 10, 7254
DOI: 10.3390/app10207254

Design for 4D printing: rapidly exploring the design space around smart materials

Germain Sossou, Frédéric Demoly, Ghislain Montavon and Samuel Gomes

Procedia CIRP, 2018, 70, 120
DOI: 10.1016/j.procir.2018.02.032

Mechanical Adaptability of Patterns in Constrained Hydrogel Membranes

Yao Xiong and Olga Kuksenok

Langmuir, 2021, 37, 4900
DOI: 10.1021/acs.langmuir.1c00138

4D printing: Fundamentals, materials, applications and challenges

Aamir Ahmed, Sandeep Arya, Vinay Gupta, Hidemitsu Furukawa and Ajit Khosla

Polymer, 2021, 228, 123926
DOI: 10.1016/j.polymer.2021.123926

Preparation and application of environmentally-responsive hydrogels in tissue engineering

Leixin Liu, Haohua Liu, Ruoqin Wang, Jian Zhou, Lingling Zhao, Qiao Li and Ziyu Liu

Materials Today Communications, 2024, 40, 109493
DOI: 10.1016/j.mtcomm.2024.109493

Application and Prospects of Hydrogel Additive Manufacturing

Changlong Zhao, Qiyin Lv and Wenzheng Wu

Gels, 2022, 8, 297
DOI: 10.3390/gels8050297

4D printing technology in medical engineering: a narrative review

Iman Sahafnejad-Mohammadi, Mojtaba Karamimoghadam, Ali Zolfagharian, Mohammad Akrami and Mahdi Bodaghi

J Braz. Soc. Mech. Sci. Eng., 2022, 44
DOI: 10.1007/s40430-022-03514-x

Rapid and selective actuation of 3D-printed shape-memory composites via microwave heating

Soo-Chan An, Yeonsoo Lim and Young Chul Jun

Sci Rep, 2023, 13
DOI: 10.1038/s41598-023-45519-z

Edible Robotics: The Role of 4D/5D Food Printing in Sustainable Food Systems and Waste Reduction

Desmond Antwi Arthur, Min Zhang, Rumbani Moyo and Courage S. Dzah

Food Reviews International, 2026, 1
DOI: 10.1080/87559129.2026.2621103

Additive Manufacturing of Epoxy Resins: Materials, Methods, and Latest Trends

Mazhar Peerzada, Sadaf Abbasi, Kin Tak Lau and Nishar Hameed

Ind. Eng. Chem. Res., 2020, 59, 6375
DOI: 10.1021/acs.iecr.9b06870

4D printing: A detailed review of materials, techniques, and applications

Lana Joharji, Rishabh B. Mishra, Fahad Alam, Serhii Tytov, Fhad Al-Modaf and Nazek El-Atab

Microelectronic Engineering, 2022, 265, 111874
DOI: 10.1016/j.mee.2022.111874

Influence of interlocking blocks assembly on the actuation time, shape change, and reversibility of voxel-based multi-material 4D structures

Kheira Benyahia, Samuel Gomes, Jean-Claude André, H Jerry Qi and Frédéric Demoly

Smart Mater. Struct., 2023, 32, 065011
DOI: 10.1088/1361-665X/acd092

Recent Advances in 4D Printing: A Review of Current Smart Materials, Technologies, and Drug Delivery Systems

Rabinarayan Parhi and Anuj Garg

CPD, 2025, 31, 1180
DOI: 10.2174/0113816128341715241216060613

Leveraging Instabilities in Multifunctional Soft Materials: A Cutting Edge Review

Prathik Narayanan, Ratnadeep Pramanik and Arunachalakasi Arockiarajan

Adv Eng Mater, 2025
DOI: 10.1002/adem.202500125

Design and Application of Stimuli-Responsive Hydrogels for 4D Printing: A Review of Adaptive Materials in Engineering

Muhammad F. Siddique, Farag K. Omar and Ali H. Al-Marzouqi

Gels, 2026, 12, 138
DOI: 10.3390/gels12020138

A Material Combination Concept to Realize 4D Printed Products with Newly Emerging Property/Functionality

Hongzhi Wu, Xuan Zhang, Zheng Ma, Ce Zhang, Jingwei Ai, Peng Chen, Chunze Yan, Bin Su and Yusheng Shi

Advanced Science, 2020, 7
DOI: 10.1002/advs.201903208

Magnetic Stimulation for Programmed Shape Morphing: Review of Four-Dimensional Printing, Challenges and Opportunities

Vera G. Kortman, Ellen de Vries, Jovana Jovanova and Aimée Sakes

3D Printing and Additive Manufacturing, 2024, 11, 977
DOI: 10.1089/3dp.2023.0198

A solid-shell finite element method for the anisotropic swelling of hydrogels with reinforced fibers

Jianhua Wang, Yisong Qiu, Hongwu Zhang, Yonggang Zheng and Hongfei Ye

European Journal of Mechanics - A/Solids, 2021, 86, 104197
DOI: 10.1016/j.euromechsol.2020.104197

4D Printing of Hydrogels Controlled by Hinge Structure and Spatially Gradient Swelling for Soft Robots

Masanari Kameoka, Yosuke Watanabe, MD Nahin Islam Shiblee, Masaru Kawakami, Jun Ogawa, Ajit Khosla, Hidemitsu Furukawa, Shengyang Zhang, Shinichi Hirai and Zhongkui Wang

Machines, 2023, 11, 103
DOI: 10.3390/machines11010103

Current status of 4D printing technology and the potential of light-reactive smart materials as 4D printable materials

Steven K. Leist and Jack Zhou

Virtual and Physical Prototyping, 2016, 11, 249
DOI: 10.1080/17452759.2016.1198630

4D printed thermally activated self-healing and shape memory polycaprolactone-based polymers

Marta Invernizzi, Stefano Turri, Marinella Levi and Raffaella Suriano

European Polymer Journal, 2018, 101, 169
DOI: 10.1016/j.eurpolymj.2018.02.023

Phase field topology optimisation for 4D printing

Harald Garcke, Kei Fong Lam, Robert Nürnberg and Andrea Signori

ESAIM: COCV, 2023, 29, 24
DOI: 10.1051/cocv/2023012

The status, barriers, challenges, and future in design for 4D printing

Frédéric Demoly, Martin L. Dunn, Kristin L. Wood, H. Jerry Qi and Jean-Claude André

Materials & Design, 2021, 212, 110193
DOI: 10.1016/j.matdes.2021.110193

Programming the time into 3D printing: current advances and future directions in 4D printing

Beijun Shen, Ozan Erol, Lichen Fang and Sung Hoon Kang

Multifunct. Mater., 2020, 3, 012001
DOI: 10.1088/2399-7532/ab54ea

Evolution and emerging trends of 4D printing: a bibliometric analysis

Wencai Zhang, Zhenghao Ge and Duanling Li

Manufacturing Rev., 2022, 9, 30
DOI: 10.1051/mfreview/2022028

Plants and architecture: the role of biology and biomimetics in materials development for buildings

R. T. Durai Prabhakaran, Morwenna J. Spear, Simon Curling, Peter Wootton-Beard, Philip Jones, Iain Donnison and Graham A. Ormondroyd

Intelligent Buildings International, 2019, 11, 178
DOI: 10.1080/17508975.2019.1669134

Development of hybrid magnetorheological elastomers by 3D printing

A.K. Bastola, M. Paudel and L. Li

Polymer, 2018, 149, 213
DOI: 10.1016/j.polymer.2018.06.076

A Review on Printing of Responsive Smart and 4D Structures Using 2D Materials

Pietro Cataldi, Mufeng Liu, Mark Bissett and Ian A. Kinloch

Adv Materials Technologies, 2022, 7
DOI: 10.1002/admt.202200025

Bioprinting of Cells, Organoids and Organs-on-a-Chip Together with Hydrogels Improves Structural and Mechanical Cues

Claudia Tanja Mierke

Cells, 2024, 13, 1638
DOI: 10.3390/cells13191638

Designing polymer gels and composites that undergo bio-inspired phototactic reconfiguration and motion

Olga Kuksenok, Awaneesh Singh and Anna C Balazs

Bioinspir. Biomim., 2018, 13, 035004
DOI: 10.1088/1748-3190/aaad1c

Programmable 4D Printing of Bioinspired Solvent‐Driven Morphing Composites

Luquan Ren, Zhuoshi Li, Qingping Liu, Lei Ren, Qian Wu, Bingqian Li, Guiwei Li, Zhengyi Song and Xueli Zhou

Adv Materials Technologies, 2021, 6
DOI: 10.1002/admt.202001289

Negative and Reversible Magnetorheological Response for Magnetic Rubbers

Rentaro Kanamori, Tomoya Sako, Hiroaki Okazaki, Mika Kawai and Tetsu Mitsumata

Gels, 2025, 11, 969
DOI: 10.3390/gels11120969

4D Bioprinting: Technological Advances in Biofabrication

Gi Hoon Yang, Miji Yeo, Young Won Koo and Geun Hyung Kim

Macromolecular Bioscience, 2019, 19
DOI: 10.1002/mabi.201800441

A multiphysics model of photo-sensitive hydrogels in response to light-thermo-pH-salt coupled stimuli for biomedical applications

Xiao Chen, Hua Li and K.Y. Lam

Bioelectrochemistry, 2020, 135, 107584
DOI: 10.1016/j.bioelechem.2020.107584

Revolutionizing manufacturing: A review of 4D printing materials, stimuli, and cutting-edge applications

Ayyaz Mahmood, Tehmina Akram, Chen Shenggui and Huafu Chen

Composites Part B: Engineering, 2023, 266, 110952
DOI: 10.1016/j.compositesb.2023.110952

4D Printing of Physical Stimuli-Responsive Hydrogels for Localized Drug Delivery and Tissue Engineering

Alireza Sadraei and Seyed Morteza Naghib

Polymer Reviews, 2025, 65, 104
DOI: 10.1080/15583724.2024.2427184

Exploring materials, technologies, applications, and future outlooks in 4D printing: a comprehensive survey

C. Rathinasuriyan, J. Bharani Chandar, N. Lenin and M. Puviyarasan

Prog Addit Manuf, 2025, 10, 5883
DOI: 10.1007/s40964-025-01034-3

4D printing: reality or myth?

Joana F. Henriques, Ana M. Sousa and Ana P. Piedade

4D Printing, 2025, 1, 5
DOI: 10.1108/4DP-12-2024-0002

Technological considerations for 4D printing: an overview

Eujin Pei and Giselle Hsiang Loh

Prog Addit Manuf, 2018, 3, 95
DOI: 10.1007/s40964-018-0047-1

MXene 3D/4D Printing: Ink Formulation and Electrochemical Energy Storage Applications

Shaista Nouseen and Martin Pumera

Adv Funct Materials, 2025, 35
DOI: 10.1002/adfm.202421987

A Comprehensive Review of 4D Printing: State of the Arts, Opportunities, and Challenges

Faisal Khaled Aldawood

Actuators, 2023, 12, 101
DOI: 10.3390/act12030101

4D Printing of Thermoresponsive OEGMA‐Based Hydrogels with Tunable Response

H. B. Duc Tran, Christoph A. Spiegel and Eva Blasco

Macro Materials & Eng, 2025, 310
DOI: 10.1002/mame.202500096

Preparation of Smart Materials by Additive Manufacturing Technologies: A Review

Kunal Mondal and Prabhat Kumar Tripathy

Materials, 2021, 14, 6442
DOI: 10.3390/ma14216442

4D Printing Materials for Soft Robots

Sunhee Lee

FTRJ, 2022, 24, 667
DOI: 10.5805/SFTI.2022.24.6.667

Review of Polymeric Materials in 4D Printing Biomedical Applications

Ming-You Shie, Yu-Fang Shen, Suryani Dyah Astuti, Alvin Kai-Xing Lee, Shu-Hsien Lin, Ni Luh Bella Dwijaksara and Yi-Wen Chen

Polymers, 2019, 11, 1864
DOI: 10.3390/polym11111864

Next-generation epidermal patches: Bridging 3D and multidimensional printing for biomedical and personal care innovations

Labiba K. El-Khordagui, Salma E. El-Habashy, Abdolreza Simchi, Hebat-Allah S. Tohamy, Maria Letizia Focarete, Mariangela Rea, Luana Di Lisa, Snigdha Roy Barman, Amit Nain, Ovidio Catanzano, Joshua Boateng and Jagan Mohan Dodda

Bioactive Materials, 2026, 63, 239
DOI: 10.1016/j.bioactmat.2026.03.054

4D Printed Hydrogels: Fabrication, Materials, and Applications

Yuting Dong, Shancheng Wang, Yujie Ke, Liucheng Ding, Xianting Zeng, Shlomo Magdassi and Yi Long

Adv Materials Technologies, 2020, 5
DOI: 10.1002/admt.202000034

On the Evolution of Additive Manufacturing (3D/4D Printing) Technologies: Materials, Applications, and Challenges

Ayyaz Mahmood, Tehmina Akram, Huafu Chen and Shenggui Chen

Polymers, 2022, 14, 4698
DOI: 10.3390/polym14214698

Effective software solutions for 4D printing: A review and proposal

Sungwook Chung, Sang Eun Song and Young Tae Cho

Int. J. of Precis. Eng. and Manuf.-Green Tech., 2017, 4, 359
DOI: 10.1007/s40684-017-0041-y

3D printing for membrane separation, desalination and water treatment

Leonard D. Tijing, John Ryan C. Dizon, Idris Ibrahim, Arman Ray N. Nisay, Ho Kyong Shon and Rigoberto C. Advincula

Applied Materials Today, 2020, 18, 100486
DOI: 10.1016/j.apmt.2019.100486

A review of 3D and 4D printable discontinuous and continuous fibre reinforcement polymers for soft robotics

Charbel Matta, Charbel Tawk and Pierre Rahme

Smart Materials & Methods, 2024, 1, 295
DOI: 10.1080/29963176.2024.2419860