Azo-oximate metal-carbonyl to metallocarboxylic acid via the intermediate Ir(iii) radical congener: quest for co-ligand driven stability of open- and closed-shell complexes

Soumitra Dinda, Shuvam Pramanik, Jaydeep Basu, Sarat Chandra Patra, Kausikisankar Pramanik and Sanjib Ganguly

Dalton Trans., 2022, 51, 10121
DOI: 10.1039/D2DT00345G

Visible-light promoted γ-cyanoalkyl radical generation: three-component cyanopropylation/etherification of unactivated alkenes

Linyong Li, Haoguo Chen, Mingjing Mei and Lei Zhou

Chem. Commun., 2017, 53, 11544
DOI: 10.1039/C7CC07347J

Catalytic β C–H amination via an imidate radical relay

Leah M. Stateman, Ethan A. Wappes, Kohki M. Nakafuku, Kara M. Edwards and David A. Nagib

Chem. Sci., 2019, 10, 2693
DOI: 10.1039/C8SC05685D

Catalytic three-component carboamination of unactivated alkenes with primary sulfonamides

Ying Zhang, Kai-Dian Li, Chang-Quan Zhou, Zhi-Xi Xing and Huan-Ming Huang

Green Chem., 2024, 26, 10434
DOI: 10.1039/D4GC02879A

Remote radical alkynylation of unactivated C(sp3)–H bonds of ethynesulfonamides

Pan Zhou, Mengru Guo, Jiawei Li, Xu Li, Danyang Xie, Bo Qin and Yong Xia

Chem. Commun., 2025, 61, 7109
DOI: 10.1039/D5CC01215E

Copper-catalyzed C–N bond formation with imidazo[1,2-a]pyridines

Kai Sun, Shiqiang Mu, Zhenhua Liu, Ranran Feng, Yali Li, Kui Pang and Bing Zhang

Org. Biomol. Chem., 2018, 16, 6655
DOI: 10.1039/C8OB01853G

Electrochemical intramolecular C–H/N–H functionalization for the synthesis of isoxazolidine-fused isoquinolin-1(2H)-ones

Lin-Bao Zhang, Rui-Sen Geng, Zi-Chen Wang, Guang-Yi Ren, Li-Rong Wen and Ming Li

Green Chem., 2020, 22, 16
DOI: 10.1039/C9GC03290H

Recent advances in cyclization reactions of unsaturated oxime esters (ethers): synthesis of versatile functionalized nitrogen-containing scaffolds

Chen Chen, Jinghui Zhao, Xiaonan Shi, Liying Liu, Yan-Ping Zhu, Wan Sun and Bolin Zhu

Org. Chem. Front., 2020, 7, 1948
DOI: 10.1039/D0QO00397B

Electrochemical strategies for C–H functionalization and C–N bond formation

Markus D. Kärkäs

Chem. Soc. Rev., 2018, 47, 5786
DOI: 10.1039/C7CS00619E

Stereoselective synthesis of the isoxazolidine ring via manganese(iii)-catalysed aminoperoxidation of unactivated alkenes using molecular oxygen in air under ambient conditions

Daisuke Yamamoto, Issei Hirano, Yuki Narushima, Masayuki Soga, Hiromasa Ansai and Kazuishi Makino

Green Chem., 2022, 24, 7162
DOI: 10.1039/D2GC02205B

Organic photoredox catalytic radical sulfonamidation/cyclization of unactivated alkenes towards polycyclic quinazolinones

Changduo Pan, Dongdong Chen, Yuefeng Chen, Jin-Tao Yu and Chengjian Zhu

Org. Chem. Front., 2022, 9, 6290
DOI: 10.1039/D2QO01430K

Visible-light promoted intramolecular carboamination of alkynes for the synthesis of oxazolidinone-fused isoquinolinones

Qihang Guo, Dongpo Lu, Yihui Mao and Zhan Lu

Chem. Commun., 2023, 59, 1979
DOI: 10.1039/D2CC06542H

Cobalt-catalysed unactivated C(sp3)–H amination: two-state reactivity and multi-reference electronic character

Yang Yu, Gen Luo, Jimin Yang and Yi Luo

Catal. Sci. Technol., 2019, 9, 1879
DOI: 10.1039/C9CY00239A

Photocatalysed C–H amidation of indoles enabled by tert-butyl alkyl((perfluoropyridin-4-yl)oxy)carbamate

Ke-yi Deng, Zhi-wei Wang, Zhen-zhen Xie, Jun-tao He, Jian-ping Guan, Kai Chen, Hao-yue Xiang and Hua Yang

Chem. Commun., 2023, 59, 11401
DOI: 10.1039/D3CC03532H

Transition-metal-free radical relay cyclization of vinyl azides with 1,4-dihydropyridines involving a 1,5-hydrogen-atom transfer: access to α-tetralone scaffolds

Yangzhen Liao, Yu Ran, Guijun Liu, Peijun Liu and Xiaozu Liu

Org. Chem. Front., 2020, 7, 3638
DOI: 10.1039/D0QO01042A

Square-planar imido complexes of cobalt: synthesis, reactivity and computational study

Jackson A. Reyna, V. Mahesh Krishnan, Roberto Silva Villatoro, Hadi D. Arman, Sebastian A. Stoian and Zachary J. Tonzetich

Dalton Trans., 2024, 53, 12128
DOI: 10.1039/D4DT01483A

Strain-release enabled [3 + 2] annulation of 3-aminooxetanes with simple CN bonds: facile synthesis of imidazolidines

Jing Zhang, Yi-Fei Li, Feng-Cheng Jia, Yang Gao and Xiao-Qiang Hu

Org. Chem. Front., 2021, 8, 6616
DOI: 10.1039/D1QO01164B

The trianionic hydrazido radical (N2)3−: a promising platform for transforming N2

Josué Rolando Aguilar-Calderón, Junnian Wei and Zhenfeng Xi

Inorg. Chem. Front., 2023, 10, 1952
DOI: 10.1039/D2QI02543D

Metal-free synthesis of carboxamides via the Lossen rearrangement

Chong Li, Yi-Fei Liu, Wei Yang, Lian-Jie Zhao, Lin-Yuan Song, Yu-Shuang Deng, Ke-Yu Mou, Jing-Wen Wang, Sheng Cao and Feng Li

Org. Chem. Front., 2025, 12, 1550
DOI: 10.1039/D4QO02155J

Photoinduced 1,5-HAT-enabled 1,7-hydrosulfonylation of allylic ethers and amides

Ke-Yi Deng, Zhen-Zhen Xie, Chu-Ping Yuan, Jian-Ping Guan, Kai Chen, Hao-Yue Xiang and Hua Yang

Chem. Commun., 2024, 60, 11984
DOI: 10.1039/D4CC03557G

Theoretical studies on the N–X (X = Cl, O) bond activation mechanism in catalytic C–H amination

Yang Yu, Gen Luo, Jimin Yang and Yi Luo

Catal. Sci. Technol., 2020, 10, 1914
DOI: 10.1039/C9CY02555C

Transition-metal-free decarboxylative ipso amination of aryl carboxylic acids

Jing Zhang, Ye-Xing Hou, Yan-Liu Tang, Ji-Hang Xu, Zi-Kui Liu, Yang Gao and Xiao-Qiang Hu

Org. Chem. Front., 2021, 8, 3434
DOI: 10.1039/D1QO00442E

Visible-light-promoted N-centered radical generation for remote heteroaryl migration

Chengkou Liu, Chen Cai, Chengcheng Yuan, Qiang Jiang, Zheng Fang and Kai Guo

Org. Biomol. Chem., 2020, 18, 7663
DOI: 10.1039/D0OB01594F

A visible-light photocatalytic N-radical cascade of hydrazones for the synthesis of dihydropyrazole-fused benzosultams

Quan-Qing Zhao, Xiao-Qiang Hu, Meng-Nan Yang, Jia-Rong Chen and Wen-Jing Xiao

Chem. Commun., 2016, 52, 12749
DOI: 10.1039/C6CC05897C

Visible light-induced cyclization reactions for the synthesis of 1,2,4-triazolines and 1,2,4-triazoles

Hongyu Wang, Yanfei Ren, Kaiye Wang, Yunquan Man, Yanan Xiang, Na Li and Bo Tang

Chem. Commun., 2017, 53, 9644
DOI: 10.1039/C7CC04911K

Deboronative functionalization of alkylboron species via a radical-transfer strategy

Fuyang Yue, Mingxing Li, Kangkang Yang, Hongjian Song, Yuxiu Liu and Qingmin Wang

Chem. Sci., 2024, 15, 14241
DOI: 10.1039/D4SC02889A

Visible light mediated organocatalytic dehydrogenative aza-coupling of 1,3-diones using aryldiazonium salts

Ramanand Das, Taraknath Kundu and Joneswar Basumatary

RSC Adv., 2023, 13, 3147
DOI: 10.1039/D2RA07807D

Ni single atoms on carbon nitride for visible-light-promoted full heterogeneous dual catalysis

Minjoon Kwak, Jinsol Bok, Byoung-Hoon Lee, Jongchan Kim, Youngran Seo, Sumin Kim, Hyunwoo Choi, Wonjae Ko, Wytse Hooch Antink, Chan Woo Lee, Guk Hee Yim, Hyojin Seung, Chansul Park, Kug-Seung Lee, Dae-Hyeong Kim, Taeghwan Hyeon and Dongwon Yoo

Chem. Sci., 2022, 13, 8536
DOI: 10.1039/D2SC02174A

Copper-catalyzed room-temperature cross-dehydrogenative coupling of secondary amides with terminal alkynes: a chemoselective synthesis of ynamides

Shuang-Yan Zhuo, Jian-Liang Ye and Xiao Zheng

Org. Biomol. Chem., 2024, 22, 1299
DOI: 10.1039/D3OB02032K

Photoinduced remote regioselective radical alkynylation of unactivated C–H bonds

Qu-Ping Hu, Yu-Tao Liu, Yong-Ze Liu and Fei Pan

Chem. Commun., 2022, 58, 2295
DOI: 10.1039/D1CC06885G

Highly chemoselective deoxygenation of N-heterocyclic N-oxides under transition metal-free conditions

Se Hyun Kim, Ju Hyeon An and Jun Hee Lee

Org. Biomol. Chem., 2021, 19, 3735
DOI: 10.1039/D1OB00260K

Electrochemical dehydrogenative C–N coupling of hydrazones for the synthesis of 1H-indazoles

Hong Zhang, Zenghui Ye, Na Chen, Zhenkun Chen and Fengzhi Zhang

Green Chem., 2022, 24, 1463
DOI: 10.1039/D1GC04534B

n-BuLi-promoted nucleophilic addition of unactivated C(sp3)–H bonds to diazo compounds as N-terminal electrophiles: efficient synthesis of hydrazine derivatives

Lu Zhang, Ming Yang, Yue Gong, Jie Wang and Yu-Long Zhao

Org. Chem. Front., 2023, 10, 499
DOI: 10.1039/D2QO01594C

Visible-light-induced C–H alkylation of 2-amino-1,4-naphthoquinones

Yuanyuan Li, Pingping Ruan, Jian Chen, Kang Chen, Zhaohui Ma, Li Guo, Guanghui Lv and Yong Wu

Org. Biomol. Chem., 2024, 22, 6016
DOI: 10.1039/D4OB00764F

Electrochemically enabled synthesis of sulfide imidazopyridines via a radical cyclization cascade

Ping-Fu Zhong, Hong-Min Lin, Lin-Wei Wang, Zu-Yu Mo, Xiu-Jin Meng, Hai-Tao Tang and Ying-Ming Pan

Green Chem., 2020, 22, 6334
DOI: 10.1039/D0GC02125C

Transition metal-catalyzed iodine(iii)-mediated nitrene transfer reactions: efficient tools for challenging syntheses

B. Darses, R. Rodrigues, L. Neuville, M. Mazurais and P. Dauban

Chem. Commun., 2017, 53, 493
DOI: 10.1039/C6CC07925C

Oxidative cascade cyclization of 2-cyano-3-arylaniline derived acrylamides with toluenes, ethers, aliphatic alcohols or simple alkanes

Wen-Jin Xia, Yangchun Xin, Zhi-Wei Zhao, Xin Chen, Xiang-Xiang Wang, Yi Li, Guanlin Wang and Ya-Min Li

Org. Chem. Front., 2020, 7, 1997
DOI: 10.1039/D0QO00535E

Post-assembly dimension-dependent face-selective etching of fullerene crystals

Cheng-Tien Hsieh, Shan-hui Hsu, Subrata Maji, Mandeep K. Chahal, Jingwen Song, Jonathan P. Hill, Katsuhiko Ariga and Lok Kumar Shrestha

Mater. Horiz., 2020, 7, 787
DOI: 10.1039/C9MH01866B

Dehydro-oxazole, thiazole and imidazole radicals: insights into the electronic structure, stability and reactivity aspects

Anamika Mukhopadhyay, Lilit Jacob and Sugumar Venkataramani

Phys. Chem. Chem. Phys., 2017, 19, 394
DOI: 10.1039/C6CP05677F

Differential formation of nitrogen-centered radicals leading to unprecedented, regioselective bromination of N,N′-(1,2-phenylene)bisamides and 2-amidophenols

Damoder Reddy Motati, Dilipkumar Uredi, Amarender Goud Burra, J. Phillip Bowen, Frank R. Fronczek, Clint R. Smith and E. Blake Watkins

Org. Chem. Front., 2020, 7, 1095
DOI: 10.1039/C9QO01508F

A HAT process of N-pyridyl radical cations for the synthesis of benzophenone-type bioisosteres

Yuying Wang, Jianyang Dong, Fei Li, Chenya Wang, Xuechen Zhou, Qin Jiang, Huijuan Liao, Jiayi Dang, Gang Li and Dong Xue

Org. Chem. Front., 2024, 11, 5712
DOI: 10.1039/D4QO01338G

Copper(i)-catalysed oxidative C–N coupling of 2-aminopyridine with terminal alkynes featuring a CC bond cleavage promoted by visible light

Ayyakkannu Ragupathi, Arunachalam Sagadevan, Chun-Cheng Lin, Jih-Ru Hwu and Kuo Chu Hwang

Chem. Commun., 2016, 52, 11756
DOI: 10.1039/C6CC05506K

Copper-catalyzed radical cascade reaction of simple cyclobutanes: synthesis of highly functionalized cyclobutene derivatives

Chunyang Liu, Xiaoyan Shangguan, Yan Li and Qian Zhang

Chem. Sci., 2022, 13, 7886
DOI: 10.1039/D2SC00765G

Exploring the behavior of the NFSI reagent as a nitrogen source

Sushmita, Trapti Aggarwal, Sonu Kumar and Akhilesh K. Verma

Org. Biomol. Chem., 2020, 18, 7056
DOI: 10.1039/D0OB01429J

Recent advances in Fe-catalyzed C–H aminations using azides as nitrene precursors

Bernd Plietker and Annika Röske

Catal. Sci. Technol., 2019, 9, 4188
DOI: 10.1039/C9CY00675C

Copper-catalyzed aerobic benzylic C(sp3)–H lactonization of 2-alkylbenzamides via N-centered radicals

Kanako Nozawa-Kumada, Kanako Ono, Satoshi Kurosu, Masanori Shigeno and Yoshinori Kondo

Org. Biomol. Chem., 2022, 20, 5948
DOI: 10.1039/D2OB00281G

Divergent synthesis of fused N-heterocyclesviarhodium-catalysed [4 + 2] cyclization of pyrazolidinones with iodonium ylides

Run Li, Ye-Xing Hou, Ji-Hang Xu, Yang Gao and Xiao-Qiang Hu

Org. Chem. Front., 2022, 9, 2181
DOI: 10.1039/D2QO00144F

Visible light-driven photocatalytic generation of sulfonamidyl radicals for alkene hydroamination of unsaturated sulfonamides

Jun Chen, Hong-Mei Guo, Quan-Qing Zhao, Jia-Rong Chen and Wen-Jing Xiao

Chem. Commun., 2018, 54, 6780
DOI: 10.1039/C7CC09871E

Nitrene-mediated aminative N–N–N coupling: facile access to triazene 1-oxides

Shiyang Zhu, Hairuo Zhang, Boyang Sun, Ziqian Bai, Gang He, Gong Chen and Hao Wang

Chem. Sci., 2025, 16, 6458
DOI: 10.1039/D5SC00064E

Recent advances in the sulfonylation of C–H bonds with the insertion of sulfur dioxide

Guanyinsheng Qiu, Kaida Zhou and Jie Wu

Chem. Commun., 2018, 54, 12561
DOI: 10.1039/C8CC07434H

Hypoxic tumor therapy based on free radicals

Jingtao Zheng, Yanyan Pan, Yubin Chen, Junyan Li and Weishuo Li

Mater. Chem. Front., 2023, 7, 3576
DOI: 10.1039/D3QM00206C

Oxidative cascade cyclization of N-arylacrylamides with TMSN3

Bo Jiang, Tai-Gang Fan, Yu-Song Ran, Yun-Tao Shen, Cui Zhang, Wei Jiang and Ya-Min Li

Org. Biomol. Chem., 2024, 22, 1186
DOI: 10.1039/D3OB01951A

Unveiling the mechanism and regioselectivity of iron-dipyrrinato-catalyzed intramolecular C(sp3)–H amination of alkyl azides

Jia Zheng, Zheyuan Liu, Xiaojiao Jin and Yanfeng Dang

Catal. Sci. Technol., 2019, 9, 1279
DOI: 10.1039/C8CY02479K

Synthetic routes to bicyclo[1.1.1]pentylamines: booming toolkits for drug design

Zhiyou Yu and Lei Shi

Org. Chem. Front., 2022, 9, 3591
DOI: 10.1039/D2QO00703G

Uncatalyzed, on water oxygenative cleavage of inert C–N bond with concomitant 8,7-amino shift in 8-aminoquinoline derivatives

Vinayak Botla, NavyaSree Pilli and Chandrasekharam Malapaka

Green Chem., 2019, 21, 1735
DOI: 10.1039/C9GC00289H

Deoxygenation of oximes for the synthesis of pyrrolinesviahydroimination cyclization

Wencheng Han, Wen-Deng Liu, Junqi Su and Jiannan Zhao

Org. Biomol. Chem., 2023, 21, 3350
DOI: 10.1039/D3OB00072A

Synthesis of imidazo[1,2-a]pyridinones via a visible light-photocatalyzed functionalization of alkynes/nitrile insertion/cyclization tandem sequence using micro-flow technology

Minghui Wei, Jiankun Chen, Chengkou Liu, Zhao Yang, Hong Qin, Yujing Hu, Jindian Duan, Yuguang Li, Zheng Fang and Kai Guo

Org. Chem. Front., 2024, 11, 83
DOI: 10.1039/D3QO01508D

Electrochemical asymmetric synthesis of biologically active substances

Ana Maria Faisca Phillips and Armando J. L. Pombeiro

Org. Biomol. Chem., 2020, 18, 7026
DOI: 10.1039/D0OB01425G

Synthesis of functionalized pyrroloindolinesviaa visible-light-induced radical cascade reaction: rapid synthesis of (±)-flustraminol B

Kui Wu, Yuliu Du, Zheng Wei and Ting Wang

Chem. Commun., 2018, 54, 7443
DOI: 10.1039/C8CC03575J

Manganese-catalyzed cascade annulations of alkyne-tethered N-alkoxyamides: synthesis of polycyclic isoquinolin-1(2H)-ones

Gui-Xian Kong, Jiao-Na Han, Dandan Yang, Jun-Long Niu and Mao-Ping Song

Org. Biomol. Chem., 2019, 17, 10167
DOI: 10.1039/C9OB02364J

Cobalt-catalyzed enantioselective radical hydroamination of alkenes with N-fluorobenzenesulfonimides: theoretical insight of enantio-determining SN2-like reductive elimination

Yu-Jie Liang, Bo Zhu, Ya-Bin Jiang and Wei Guan

Org. Chem. Front., 2025
DOI: 10.1039/D5QO00696A

Transition-metal-free Intramolecular C–H amination of sulfamate esters andN-alkylsulfamides

Kensuke Kiyokawa, Shogo Nakamura, Keisuke Jou, Kohji Iwaida and Satoshi Minakata

Chem. Commun., 2019, 55, 11782
DOI: 10.1039/C9CC06410A

Radical functionalization of allenes

Rongnan Yi, Qiang Li, Long-Yong Xie and Wen-Ting Wei

Chem. Commun., 2025, 61, 6426
DOI: 10.1039/D5CC00597C

Visible-light-induced selective amination of enol ethers with N-alkoxyamides by using DDQ as a photoredox catalyst

Yan Zhang, Wei Chen, Lei Wang and Pinhua Li

Org. Chem. Front., 2018, 5, 3562
DOI: 10.1039/C8QO00980E

Visible light-induced N-radical 5-exo/6-endo cyclization of alkenyl amides: facile access to isoindolinones/isoquinolinones

Zhen-Yao Lei, Kui Hu, Yuan-Xiang He, Shu Geng, Li-Na Chen, Shuai Zou, Li Pan, Zhi-Jun Ding and Feng Huang

Org. Biomol. Chem., 2022, 20, 2397
DOI: 10.1039/D2OB00317A

Ligand-free copper-catalyzed C(sp3)–H imidation of aromatic and aliphatic methyl sulfides with N-fluorobenzenesulfonimide

Si-Chang Wang, Ming-Nan Feng, Yue Ji, Wei-Wei Han, Cong-Yu Ke, Qun-Zheng Zhang and Xun-Li Zhang

RSC Adv., 2021, 11, 12136
DOI: 10.1039/D1RA00686J

Iron(iii)-catalyzed direct C–H radical amination of (hetero)arenes

Bin Lv, Pan Gao, Shuwei Zhang, Xiaodong Jia, Minyan Wang and Yu Yuan

Org. Chem. Front., 2021, 8, 5440
DOI: 10.1039/D1QO00710F

Electro-oxidative intermolecular CSP2–H amination of heteroarenes via proton-coupled electron transfer

Shuai Liu, Xin Liu, Tian-Shu Zhang, Xiaoyu Bao, Xiaoyu Sheng, Zhenjie Qi and Dongfang Jiang

Org. Biomol. Chem., 2024, 22, 2549
DOI: 10.1039/D4OB00164H

N-Hydroxyphthalimide imidate esters as amidyl radical precursors in the visible light photocatalyzed C–H amidation of heteroarenes

Long-Hai Li, Yin Wei and Min Shi

Org. Chem. Front., 2021, 8, 1935
DOI: 10.1039/D0QO01641A

A novel metal-free amidosulfenylation of alkenes leading to β-azolyl sulfides

Kai Sun, Yunhe Lv, Zuodong Shi, Shiqiang Mu, Changhao Li and Xin Wang

Org. Biomol. Chem., 2017, 15, 5258
DOI: 10.1039/C7OB01061C

Copper and manganese co-mediated cascade aza-Michael addition/cyclization and azidation of 1,3-enynes: regioselective synthesis of fully substituted azido pyrroles

Junying Ge, Qiuping Ding, Man Yang, Tian He and Yiyuan Peng

Org. Biomol. Chem., 2020, 18, 8908
DOI: 10.1039/D0OB01927E

Decarboxylative cascade cyclization of α-keto acids with 2-cyano-3-arylaniline-derived acrylamides

Jia-Qi Shang, Xiang-Xiang Wang, Yangchun Xin, Yi Li, Bin Zhou and Ya-Min Li

Org. Biomol. Chem., 2019, 17, 9447
DOI: 10.1039/C9OB02023C

Intermolecular radical carboamination of alkenes

Heng Jiang and Armido Studer

Chem. Soc. Rev., 2020, 49, 1790
DOI: 10.1039/C9CS00692C

Copper-catalyzed synthesis of arylcarboxamides from aldehydes and isocyanides: the isocyano group as an N1 synthon

Jian-Quan Liu, Xuanyu Shen, Zhenhua Liu and Xiang-Shan Wang

Org. Biomol. Chem., 2017, 15, 6314
DOI: 10.1039/C7OB01449J

Oxygen atom transfer: a mild and efficient method for generating iminyl radicals

Youngsuk Kim, Christopher W. Bielawski and Eunsung Lee

Chem. Commun., 2019, 55, 7061
DOI: 10.1039/C9CC03521D

Cobalt-catalyzed regioselective hydroazidation of 1-aryl-1,3-dienes: facile access to allylic azides

Mei-Hua Shen, Xiao-Wen Qi, De-Xia Li, Xin-Yi Wang, Chi-Fan Zhu and Hua-Dong Xu

Org. Chem. Front., 2023, 10, 3010
DOI: 10.1039/D3QO00431G

Diastereoselective olefin amidoacylation via photoredox PCET/nickel-dual catalysis: reaction scope and mechanistic insights

Shuai Zheng, Shuo-Qing Zhang, Borna Saeednia, Jiawang Zhou, Jessica M. Anna, Xin Hong and Gary A. Molander

Chem. Sci., 2020, 11, 4131
DOI: 10.1039/D0SC01459A

Radical cascade synthesis of azoles via tandem hydrogen atom transfer

Andrew D. Chen, James H. Herbort, Ethan A. Wappes, Kohki M. Nakafuku, Darsheed N. Mustafa and David A. Nagib

Chem. Sci., 2020, 11, 2479
DOI: 10.1039/C9SC06239D

A photoredox catalyzed iminyl radical-triggered C–C bond cleavage/addition/Kornblum oxidation cascade of oxime esters and styrenes: synthesis of ketonitriles

Bin-Qing He, Xiao-Ye Yu, Peng-Zi Wang, Jia-Rong Chen and Wen-Jing Xiao

Chem. Commun., 2018, 54, 12262
DOI: 10.1039/C8CC07072E

Chemical versatility of azide radical: journey from a transient species to synthetic accessibility in organic transformations

Maniklal Shee and N. D. Pradeep Singh

Chem. Soc. Rev., 2022, 51, 2255
DOI: 10.1039/D1CS00494H

Alkene functionalization for the stereospecific synthesis of substituted aziridines by visible-light photoredox catalysis

Wan-Lei Yu, Jian-Qiang Chen, Yun-Long Wei, Zhu-Yin Wang and Peng-Fei Xu

Chem. Commun., 2018, 54, 1948
DOI: 10.1039/C7CC09151F

PhI(OAc)2 and iodine-mediated synthesis of N-alkyl sulfonamides derived from polycyclic aromatic hydrocarbon scaffolds and determination of their antibacterial and cytotoxic activities

Megan D. Hopkins, Garett L. Ozmer, Ryan C. Witt, Zachary C. Brandeburg, David A. Rogers, Claire E. Keating, Presley L. Petcoff, Robert J. Sheaff and Angus A. Lamar

Org. Biomol. Chem., 2021, 19, 1133
DOI: 10.1039/D0OB02429E

Recent advances in the sulfonylation of alkenes with the insertion of sulfur dioxide via radical reactions

Guanyinsheng Qiu, Lifang Lai, Jiang Cheng and Jie Wu

Chem. Commun., 2018, 54, 10405
DOI: 10.1039/C8CC05847D

Palladium-catalyzed radical cascade cyanoalkylsulfonylation/cyclization of 3-arylethynyl-[1,1′-biphenyl]-2-carbonitriles with cyclobutanone oxime esters and DABSO

Nengneng Zhou, Qiankun Xu, Ziqin Xia, Kaimo Kuang, Sixin Wu, Wenping Li and Man Zhang

Chem. Commun., 2022, 58, 2335
DOI: 10.1039/D1CC06825C

Photoredox ketone catalysis for the direct C–H imidation and acyloxylation of arenes

Chandra Bhushan Tripathi, Tsuyoshi Ohtani, Michael T. Corbett and Takashi Ooi

Chem. Sci., 2017, 8, 5622
DOI: 10.1039/C7SC01700F

Recent advances in radical transformations of internal alkynes

Min-Hua Huang, Wen-Juan Hao, Guigen Li, Shu-Jiang Tu and Bo Jiang

Chem. Commun., 2018, 54, 10791
DOI: 10.1039/C8CC04618B

Nitrogen-centered radical-mediated α-sulfonimidation of ketones

Wenbin Shang, Fengyuan Peng, Qianlang Feng, Fei Fang, Zhiqiang Pan, Xu Ji and Chengfeng Xia

Org. Chem. Front., 2022, 9, 2680
DOI: 10.1039/D2QO00198E

Ring-opening C(sp3)–C coupling of cyclobutanone oxime esters for the preparation of cyanoalkyl containing heterocycles enabled by photocatalysis

Wei Zhang, Yu-Liang Pan, Chen Yang, Xin Li and Bin Wang

Org. Chem. Front., 2019, 6, 2765
DOI: 10.1039/C9QO00625G

Nitrogen-centered radicals driving unusual enzyme reactions in biosynthetic pathways

Richiro Ushimaru and Ikuro Abe

Chem. Soc. Rev., 2025, 54, 6385
DOI: 10.1039/D5CS00342C

Recent advances in radical-based C–N bond formation via photo-/electrochemistry

Yating Zhao and Wujiong Xia

Chem. Soc. Rev., 2018, 47, 2591
DOI: 10.1039/C7CS00572E

Discovery of a tetraarylhydrazine catalyst for electrocatalytic synthesis of imidazo-fused N-heteroaromatic compounds

Zhong-Wei Hou, Zhong-Yi Mao and Hai-Chao Xu

Org. Biomol. Chem., 2021, 19, 8789
DOI: 10.1039/D1OB01644J

Nitrogen-centered radical reaction leading to energetic materials: a mild and efficient access to N–N bridged compounds

Zhiwei Zeng, Yuji Liu, Guangbin Cheng, Wei Huang, Hao Wei, Jean'ne M. Shreeve and Yongxing Tang

J. Mater. Chem. A, 2021, 9, 21685
DOI: 10.1039/D1TA06659E

Visible-light-promoted iminyl radical formation from vinyl azides: synthesis of 6-(fluoro)alkylated phenanthridines

Xiaoyang Sun and Shouyun Yu

Chem. Commun., 2016, 52, 10898
DOI: 10.1039/C6CC05756J

Rhodium/copper-cocatalyzed coupling-cyclization of o-alkenyl arylisocyanides with vinyl azides: one-pot synthesis of α-carbolines

Ming Yang, Xiang-He Meng, Zhuo Wang, Yue Gong and Yu-Long Zhao

Org. Chem. Front., 2020, 7, 3493
DOI: 10.1039/D0QO00994F

Synthesis of cyano-substituted γ-lactams through a copper-catalyzed cascade cyclization/cyanation reaction

Wen Liu, Liang Wang, Haiping Mu, Qian Zhang, Zeguo Fang and Dong Li

Org. Biomol. Chem., 2023, 21, 1168
DOI: 10.1039/D2OB02086F

Photochemical regioselective C–H arylation of imidazo[1,2-a]pyridine derivatives using chlorophyll as a biocatalyst and diazonium salts

Ali Moazzam, Sara Moghadam Farid, Nima Khaleghi, Naeimeh Alizadeh and Mohammad Mahdavi

New J. Chem., 2022, 46, 10814
DOI: 10.1039/D1NJ06059G

Computational insights into Ir(iii)-catalyzed allylic C–H amination of terminal alkenes: mechanism, regioselectivity, and catalytic activity

Deng Pan, Gen Luo, Yang Yu, Jimin Yang and Yi Luo

RSC Adv., 2021, 11, 19113
DOI: 10.1039/D1RA03842G

Metal-free deoxygenative sulfonylation of quinoline N-oxides with sodium sulfinates via a dual radical coupling process

Long-Yong Xie, Sha Peng, Fang Liu, Guan-Rong Chen, Wen Xia, Xianyong Yu, Wen-Feng Li, Zhong Cao and Wei-Min He

Org. Chem. Front., 2018, 5, 2604
DOI: 10.1039/C8QO00661J

Copper-mediated [3 + 2] oxidative cyclization of oxime acetate and its utility in the formal synthesis of fentiazac

Nitin L Jadhao, Harish B. Musale, Jayant M. Gajbhiye and Vivek T. Humne

Org. Biomol. Chem., 2024, 22, 521
DOI: 10.1039/D3OB01882B

Synthesis and identification of heteroaromaticN-benzyl sulfonamides as potential anticancer agents

Megan D. Hopkins, Felagot A. Abebe, Kristina A. Scott, Garett L. Ozmer, Alec A. Sheir, Lucas J. Schroeder, Robert J. Sheaff and Angus A. Lamar

Org. Biomol. Chem., 2019, 17, 8391
DOI: 10.1039/C9OB01694E

Iron-catalyzed cross-dehydrogenative C–H amidation of benzofurans and benzothiophenes with anilines

Yang Ni, Xiang Wan, Honghua Zuo, Muhammad Adnan Bashir, Yu Liu, Huaibin Yu, Rong-Zhen Liao, Guojiao Wu and Fangrui Zhong

Org. Chem. Front., 2021, 8, 1490
DOI: 10.1039/D0QO01651A

Catalyst-free amination of α-cyanoarylacetates enabled by single-electron transfer

Wei Zhang, Han-Liang Zheng, Yang Liu, Ao Yu, Chen Yang, Xin Li and Jin-Pei Cheng

Org. Chem. Front., 2019, 6, 1900
DOI: 10.1039/C9QO00346K

A radical-mediated multicomponent cascade reaction for the synthesis of azide-biindole derivatives

Xiaoyu Liu, Kun He, Na Gao, Peiyun Jiang, Jun Lin and Yi Jin

Chem. Commun., 2021, 57, 9696
DOI: 10.1039/D1CC03853B

Enantioselective catalytic β-amination through proton-coupled electron transfer followed by stereocontrolled radical–radical coupling

Zijun Zhou, Yanjun Li, Bowen Han, Lei Gong and Eric Meggers

Chem. Sci., 2017, 8, 5757
DOI: 10.1039/C7SC02031G

Copper-catalyzed amino radical tandem cyclization toward the synthesis of indolo-[2,1-a]isoquinolines

Mei-Ling Liu, Jing-Ling Wang, Xue-Song Li, Wen-Hui Sun and Xue-Yuan Liu

Org. Chem. Front., 2022, 9, 2438
DOI: 10.1039/D2QO00051B

Iminyl radical initiated sulfonylation of alkenes with rongalite under photoredox conditions

Fu-Sheng He, Man Zhang, Mengke Zhang, Xiangxiang Luo and Jie Wu

Org. Chem. Front., 2021, 8, 3746
DOI: 10.1039/D1QO00556A

Silver-catalyzed cascade cyclization and functionalization of N-aryl-4-pentenamides: an efficient route to γ-lactam-substituted quinone derivatives

Zeguo Fang, Lin Xie, Liang Wang, Qian Zhang and Dong Li

RSC Adv., 2022, 12, 26776
DOI: 10.1039/D2RA05283K

Switchable assembly of substituted pyrimidines and 2H-imidazoles via Cu(i)-catalysed ring expansion of 2 methoxyl-2H-azirines

Shaofa Sun, Jie Huang, Cheng Yuan, Gangqiang Wang, Donghui Guo and Jian Wang

Org. Chem. Front., 2022, 9, 3006
DOI: 10.1039/D2QO00341D

Spin characteristics in conjugated stable diradicals

Dacheng Dai, Qian Zhan, Tianfang Shi, Dongsheng Wang and Yonghao Zheng

Chem. Commun., 2024, 60, 8997
DOI: 10.1039/D4CC03067B

Transition metal-free aminofluorination of β,γ-unsaturated hydrazones: base-controlled regioselective synthesis of fluorinated dihydropyrazole and tetrahydropyridazine derivatives

Juan Zhao, Min Jiang and Jin-Tao Liu

Org. Chem. Front., 2018, 5, 1155
DOI: 10.1039/C7QO01105A

Photoinduced fragmentation-rearrangement sequence of cycloketoxime esters

Binlin Zhao, Cheng Chen, Jiahang Lv, Zexian Li, Yu Yuan and Zhuangzhi Shi

Org. Chem. Front., 2018, 5, 2719
DOI: 10.1039/C8QO00747K

Copper-catalyzed nitrene transfer/cyclization cascade to synthesize 3a-nitrogenous furoindolines and pyrroloindolines

Guang-Yi Zhang, Yi Peng, Jing Xue, Yan-Hui Fan and Qing-Hai Deng

Org. Chem. Front., 2019, 6, 3934
DOI: 10.1039/C9QO01124B

Visible-light-activated C–C and C–N bond formation in the synthesis of imidazo[1,2-a]pyridines and imidazo[2,1-b]thiazoles under catalyst and solvent-free conditions

Km Neha Shivhare, Manish K. Jaiswal, Anushree Srivastava, Saurabh K. Tiwari and I. R. Siddiqui

New J. Chem., 2018, 42, 16591
DOI: 10.1039/C8NJ03339K

Cooperativity and serial ligand catalysis in an allylic amination reaction by Pd(ii)-bis-sulfoxide and Brønsted acids

Dilna B. Sreedhar and Raghavan B. Sunoj

Org. Biomol. Chem., 2019, 17, 7723
DOI: 10.1039/C9OB01330J

Visible-light-promoted radical amidoarylation of arylacrylamides towards amidated oxindoles

Yu-Zhao Wang, Wu-Jie Lin, Hong-Chao Liu and Wei Yu

Org. Chem. Front., 2022, 9, 2164
DOI: 10.1039/D2QO00127F

Silver-promoted regioselective [4+2] annulation reaction of indoles with alkenes to construct dihydropyrimidoindolone scaffolds

Lin-Bao Zhang, Ming-Hui Zhu, Wu-Bo Du, Shao-Fei Ni, Li-Rong Wen and Ming Li

Chem. Commun., 2019, 55, 14383
DOI: 10.1039/C9CC07098B

Visible-light-mediated cascade cyanoalkylsulfonylation/cyclization of alkynoates leading to coumarins via SO2 insertion

Pu Chen, Zan Chen, Bi-Quan Xiong, Yun Liang, Ke-Wen Tang, Jun Xie and Yu Liu

Org. Biomol. Chem., 2021, 19, 3181
DOI: 10.1039/D1OB00142F

Dual-nickel/photoredox-catalyzed acylation of spiro-dihydroquinazolinones with carboxylic acids via an aromatization-driven deconstructive strategy

Wen-Chao Gao, Yong Teng, Jie Yang, Wen-Dian Li, Wen-Guang Li, Ke-Xin Huang and Ting Li

Chem. Commun., 2025, 61, 8743
DOI: 10.1039/D5CC01289A

Catalyst-free regioselective hydroxyfluorination and aminofluorination of α,β-unsaturated ketones

Jiadi Zhou, Ye Fang, Fang Wang and Jianjun Li

Org. Biomol. Chem., 2019, 17, 4470
DOI: 10.1039/C9OB00467J

Insertion of sulfur dioxide via a radical process: an efficient route to sulfonyl compounds

Guanyinsheng Qiu, Kaida Zhou, Liang Gao and Jie Wu

Org. Chem. Front., 2018, 5, 691
DOI: 10.1039/C7QO01073G

Copper-catalysed radical amino-oxygenation of alkenes for the exclusive synthesis of 5-substituted 2-oxazolidinones

Xuan Zhou, Xi Hu, Yi Chen, Hongxing Zhu, Muyang Yang, Guo-Jun Deng and Wen Shao

Green Chem., 2025, 27, 5616
DOI: 10.1039/D5GC00917K

The advent of electrophilic hydroxylamine-derived reagents for the direct preparation of unprotected amines

Valentina C. M. Gasser, Szabolcs Makai and Bill Morandi

Chem. Commun., 2022, 58, 9991
DOI: 10.1039/D2CC02431D

Electro-oxidative C–H amination of heteroarenes with aniline derivatives via radical–radical cross coupling

Xichao Peng, Junhao Zhao, Guojian Ma, Yan Wu, Shiyu Hu, Zhixiong Ruan and Pengju Feng

Green Chem., 2021, 23, 8853
DOI: 10.1039/D1GC02821A

Anodic benzylic C(sp3)–H amination: unified access to pyrrolidines and piperidines

Sebastian Herold, Daniel Bafaluy and Kilian Muñiz

Green Chem., 2018, 20, 3191
DOI: 10.1039/C8GC01411F

Regioselective intramolecular sp2 C–H amination: direct vs. mediated electrooxidation

Jianxue Shi, Jingjing Li, Wenjing Zhao, Mengru Cui, Wanying Ni, Lijun Li, Wenmin Liu, Kun Xu and Sheng Zhang

Org. Chem. Front., 2021, 8, 1581
DOI: 10.1039/D0QO01584A

Origins of ligand-controlled diastereoselectivity in dirhodium-catalysed direct amination of aliphatic C(sp3)–H bonds

Qiannan Li, Wenjing Liu and Yanfeng Dang

Catal. Sci. Technol., 2021, 11, 6960
DOI: 10.1039/D1CY01583D

Recent advances in enantioselective construction of C–N bonds involving radical intermediates

Jiaqiong Sun, Guangfan Zheng, Ge Zhang, Yan Li and Qian Zhang

Org. Chem. Front., 2025, 12, 1671
DOI: 10.1039/D4QO02268H

A photocatalytic iminyl radical-mediated C–C bond cleavage/addition/cyclization cascade for the synthesis of 1,2,3,4-tetrahydrophenanthrenes

Peng-Zi Wang, Xiao-Ye Yu, Chan-Yun Li, Bin-Qing He, Jia-Rong Chen and Wen-Jing Xiao

Chem. Commun., 2018, 54, 9925
DOI: 10.1039/C8CC06145A

Electrochemical remote C(sp3)–H thiocyanation

Xinyu Pang, Hui He, Xiangrui Meng, Linbao Zhang, Shaofei Ni, Ming Li and Weisi Guo

Org. Chem. Front., 2024, 11, 2283
DOI: 10.1039/D4QO00032C

Photoredox catalysed synthesis of amino alcohol

Vishal Srivastava, Pravin K. Singh, Sudhanshu Kanaujia and Praveen P. Singh

New J. Chem., 2018, 42, 688
DOI: 10.1039/C7NJ03068A

Organo-initiator enabled undirected C–H amination of arenes

Zongxing Hu, Yanhui Bai and Honghui Lei

Org. Chem. Front., 2024, 11, 5511
DOI: 10.1039/D4QO01196A

Synthesis and biological evaluation of N-alkyl sulfonamides derived from polycyclic hydrocarbon scaffolds using a nitrogen-centered radical approach

Megan D. Hopkins, Ryan C. Witt, Ann Marie E. Flusche, John E. Philo, Garett L. Ozmer, Gordon H. Purser, Robert J. Sheaff and Angus A. Lamar

Org. Biomol. Chem., 2022, 20, 6680
DOI: 10.1039/D2OB01291J

Precision single-atom editing: new frontiers in nitrogen insertion and substitution for the generation of N-heterocycles

Xue Li, Jia Xu and Zhi-Gang Xu

Org. Chem. Front., 2024, 11, 4041
DOI: 10.1039/D4QO00812J

Photo-induced cyclization of olefinic amides towards sulfonamidylated iminoisobenzofurans and benzoxazines

Changduo Pan, Shipeng Luo, Yechun Wu, Jin-Tao Yu and Chengjian Zhu

Org. Chem. Front., 2023, 10, 3479
DOI: 10.1039/D3QO00675A

Direct amidation of metallaaromatics: access to N-functionalized osmapentalynes via a 1,5-bromoamidated intermediate

Hongjian Wang, Yonghong Ruan, Yu-Mei Lin and Haiping Xia

Chem. Sci., 2021, 12, 6315
DOI: 10.1039/D1SC01571K

Recent advances in phosphoranyl radical-mediated deoxygenative functionalisation

Xiao-Qiang Hu, Ye-Xing Hou, Zi-Kui Liu and Yang Gao

Org. Chem. Front., 2020, 7, 2319
DOI: 10.1039/D0QO00643B

Recent advances in visible light-activated radical coupling reactions triggered by (i) ruthenium, (ii) iridium and (iii) organic photoredox agents

Jonathan D. Bell and John A. Murphy

Chem. Soc. Rev., 2021, 50, 9540
DOI: 10.1039/D1CS00311A

Photoredox-mediated N-centered radical addition/semipinacol rearrangement for the convenient synthesis of β-amino (spiro)cyclic ketones

Tian-Cong Ma, Sheng Yao, Ming-Ming Qiao, Fan Yuan, De-Qing Shi and Wen-Jing Xiao

Org. Chem. Front., 2021, 8, 4224
DOI: 10.1039/D1QO00543J

Selective Piperidine Synthesis Exploiting Iodine-Catalyzed Csp3–H Amination under Visible Light

Hongwei Zhang and Kilian Muñiz

ACS Catal., 2017, 7, 4122
DOI: 10.1021/acscatal.7b00928

Fluoro Nitrenoid Complexes FN=MF2 (M=Co, Rh, Ir): Electronic Structure Dichotomy and Formation of Nitrido Fluorides N≡MF3

Tony Stüker, Thomas Hohmann, Helmut Beckers and Sebastian Riedel

Angewandte Chemie, 2020, 132, 23374
DOI: 10.1002/ange.202010950

Intramolecular Radical Amidooxygenation of Alkenes for the Construction of Pyrrolidinones

Anirban Maity and Armido Studer

Org. Lett., 2024, 26, 4784
DOI: 10.1021/acs.orglett.4c01607

A diastereoselective approach to axially chiral biaryls via electrochemically enabled cyclization cascade

Hong Yan, Zhong-Yi Mao, Zhong-Wei Hou, Jinshuai Song and Hai-Chao Xu

Beilstein J. Org. Chem., 2019, 15, 795
DOI: 10.3762/bjoc.15.76

Enantioselective Copper‐Catalyzed Intermolecular Amino‐ and Azidocyanation of Alkenes in a Radical Process

Dinghai Wang, Fei Wang, Pinghong Chen, Zhenyang Lin and Guosheng Liu

Angew Chem Int Ed, 2017, 56, 2054
DOI: 10.1002/anie.201611850

Synthesis of a Carbene-Stabilized (Diphospha)aminyl Radical and Its One Electron Oxidation and Reduction to Nonclassical Nitrenium and Amide Species

Etienne A. LaPierre, Lara K. Watanabe, Brian O. Patrick, Jeremy M. Rawson, Heikki M. Tuononen and Ian Manners

J. Am. Chem. Soc., 2023, 145, 9223
DOI: 10.1021/jacs.3c01408

Controlling Enantioselectivity and Diastereoselectivity in Radical Cascade Cyclization for Construction of Bicyclic Structures

Congzhe Zhang, Duo-Sheng Wang, Wan-Chen Cindy Lee, Alexander M. McKillop and X. Peter Zhang

J. Am. Chem. Soc., 2021, 143, 11130
DOI: 10.1021/jacs.1c04719

Photocatalytic Neophyl Rearrangement and Reduction of Distal Carbon Radicals by Iminyl Radical‐Mediated C−C Bond Cleavage

Xiao‐Ye Yu, Peng‐Zi Wang, Dong‐Mei Yan, Bin Lu, Jia‐Rong Chen and Wen‐Jing Xiao

Adv Synth Catal, 2018, 360, 3601
DOI: 10.1002/adsc.201800834

Nitrogen Atom Transfer Catalysis by Metallonitrene C−H Insertion: Photocatalytic Amidation of Aldehydes

Till Schmidt‐Räntsch, Hendrik Verplancke, Jonas N. Lienert, Serhiy Demeshko, Matthias Otte, Gerard P. Van Trieste, Kaleb A. Reid, Joseph H. Reibenspies, David C. Powers, Max C. Holthausen and Sven Schneider

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202115626

Elusive Terminal Copper Arylnitrene Intermediates

Abolghasem (Gus) Bakhoda, Quan Jiang, Jeffery A. Bertke, Thomas R. Cundari and Timothy H. Warren

Angewandte Chemie, 2017, 129, 6526
DOI: 10.1002/ange.201611275

Synthesis of Six‐Membered N‐Heterocycle Frameworks Based on Intramolecular Metal‐Free N‐Centered Radical Chemistry

Yan Gao, Qianyi Zhao, Lixin Li and Yan‐Na Ma

The Chemical Record, 2022, 22
DOI: 10.1002/tcr.202100218

A Facile Approach to Oximes and Ethers by a Tandem NO+‐Initiated Semipinacol Rearrangement and H‐Elimination

Jia‐Wei Dong, Tongmei Ding, Shu‐Yu Zhang, Zhi‐Min Chen and Yong‐Qiang Tu

Angew Chem Int Ed, 2018, 57, 13192
DOI: 10.1002/anie.201807861

N-Hydroxyphthalimides as Nitrogen Radical Precursors in the Copper-Catalyzed Radical Cross-Coupling Amination of Arylboronic Acids: Synthesis of Arylamines

Hafiz Noor, Shuwei Zhang, Xiaodong Jia, Pan Gao and Yu Yuan

J. Org. Chem., 2024, 89, 17960
DOI: 10.1021/acs.joc.4c01366

Sulfamate Esters Guide Selective Radical‐Mediated Chlorination of Aliphatic C−H Bonds

Melanie A. Short, J. Miles Blackburn and Jennifer L. Roizen

Angew Chem Int Ed, 2018, 57, 296
DOI: 10.1002/anie.201710322

Photoredox-Catalyzed Difunctionalization of Alkenes with Sulfilimines

Tingwei Yu, Zhe Jin, Yan Ji, Aihong Yang and Penghao Jia

Org. Lett., 2024, 26, 7944
DOI: 10.1021/acs.orglett.4c02971

Nitrogen Atom Transfer Catalysis by Metallonitrene C−H Insertion: Photocatalytic Amidation of Aldehydes

Till Schmidt‐Räntsch, Hendrik Verplancke, Jonas N. Lienert, Serhiy Demeshko, Matthias Otte, Gerard P. Van Trieste, Kaleb A. Reid, Joseph H. Reibenspies, David C. Powers, Max C. Holthausen and Sven Schneider

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202115626

Radical Polarity

Jacob J. A. Garwood, Andrew D. Chen and David A. Nagib

J. Am. Chem. Soc., 2024
DOI: 10.1021/jacs.4c06774

Visible-Light-Induced Photoaddition of N-Nitrosoalkylamines to Alkenes: One-Pot Tandem Approach to 1,2-Diamination of Alkenes from Secondary Amines

Dilip V. Patil, Tengda Si, Hun Young Kim and Kyungsoo Oh

Org. Lett., 2021, 23, 3105
DOI: 10.1021/acs.orglett.1c00786

Lignocellulosic Biomass Upgrading into Valuable Nitrogen-Containing Compounds by Heterogeneous Catalysts

Xi Chen, Ying Liu and Jingyu Wang

Ind. Eng. Chem. Res., 2020, 59, 17008
DOI: 10.1021/acs.iecr.0c01815

The emerging role of radical chemistry in the amination transformation of highly strained [1.1.1]propellane: Bicyclo[1.1.1]pentylamine as bioisosteres of anilines

Qiwen Pang, Yang Li, Xin Xie, Jie Tang, Qian Liu, Cheng Peng, Xiang Li and Bo Han

Front. Chem., 2022, 10
DOI: 10.3389/fchem.2022.997944

Photogenerated Neutral Nitrogen Radical Catalyzed Bifunctionalization of Alkenes

Quan‐Qing Zhao, Jun Chen, Xue‐Song Zhou, Xiao‐Ye Yu, Jia‐Rong Chen and Wen‐Jing Xiao

Chemistry A European J, 2019, 25, 8024
DOI: 10.1002/chem.201901665

Design and Scalable Synthesis of N‐Alkylhydroxylamine Reagents for the Direct Iron‐Catalyzed Installation of Medicinally Relevant Amines**

Eric Falk, Szabolcs Makai, Tristan Delcaillau, Laura Gürtler and Bill Morandi

Angew Chem Int Ed, 2020, 59, 21064
DOI: 10.1002/anie.202008247

Direct Photochemical C–H Carboxylation of Aromatic Diamines with CO2 under Electron-Donor- and Base-free Conditions

Takeshi Matsumoto, Daiki Uchijo, Takuji Koike, Ryoya Namiki and Ho-Chol Chang

Sci Rep, 2018, 8
DOI: 10.1038/s41598-018-33060-3

Synthesis of 1H-Indazoles via Silver(I)-Mediated Intramolecular Oxidative C–H Bond Amination

Areum Park, Kyu-Sung Jeong, Hyuk Lee and Hyunwoo Kim

ACS Omega, 2021, 6, 6498
DOI: 10.1021/acsomega.1c00025

Regiospecific Three-Component Aminofluorination of Olefins via Photoredox Catalysis

Jia-Nan Mo, Wan-Lei Yu, Jian-Qiang Chen, Xiu-Qin Hu and Peng-Fei Xu

Org. Lett., 2018, 20, 4471
DOI: 10.1021/acs.orglett.8b01760

Photocatalytic Additions of 1‐Sulfoximidoyl‐1,2‐Benziodoxoles to Styrenes

Han Wang, Duo Zhang and Carsten Bolm

Chemistry A European J, 2018, 24, 14942
DOI: 10.1002/chem.201803975

Visible-Light-Promoted Cascade Cyclization of 3-Ethynyl-[1,1′-biphenyl]-2-Carbonitriles with Unsaturated α-Bromocarbonyls

Yu-Song Ran, Bo Jiang, Yun-Tao Shen, Tai-Gang Fan, Wei Jiang, Cui Zhang and Ya-Min Li

Org. Lett., 2023, 25, 7412
DOI: 10.1021/acs.orglett.3c02938

Direct Synthesis of Unprotected 2-Azidoamines from Alkenes via an Iron-Catalyzed Difunctionalization Reaction

Szabolcs Makai, Eric Falk and Bill Morandi

J. Am. Chem. Soc., 2020, 142, 21548
DOI: 10.1021/jacs.0c11025

Electrophilic Aminating Agents in Total Synthesis

Lauren G. O'Neil and John F. Bower

Angewandte Chemie, 2021, 133, 25844
DOI: 10.1002/ange.202102864

C–N Cross-Coupling via Photoexcitation of Nickel–Amine Complexes

Chern-Hooi Lim, Max Kudisch, Bin Liu and Garret M. Miyake

J. Am. Chem. Soc., 2018, 140, 7667
DOI: 10.1021/jacs.8b03744

De Novo Synthesis of Highly Functionalized Benzimidazolones and Benzoxazolones through an Electrochemical Dehydrogenative Cyclization Cascade

Fan Xu, Hao Long, Jinshuai Song and Hai‐Chao Xu

Angewandte Chemie, 2019, 131, 9115
DOI: 10.1002/ange.201904931

CH‐Functionalization of Heterocycles with the Formation of C−O, C−N, C−S/Se, and C−P Bonds by Intermolecular Addition of Heteroatom‐Centered Radicals

Alexander S. Budnikov, Igor B. Krylov, Olga M. Mulina, Dmitry A. Lapshin and Alexander O. Terent'ev

Adv Synth Catal, 2023, 365, 1714
DOI: 10.1002/adsc.202300144

Visible-Light-Promoted Carboimination of Unactivated Alkenes for the Synthesis of Densely Functionalized Pyrroline Derivatives

Sai-Hu Cai, Jia-Hao Xie, Shengjin Song, Lu Ye, Chao Feng and Teck-Peng Loh

ACS Catal., 2016, 6, 5571
DOI: 10.1021/acscatal.6b01230

Amidinyl Radical Formation through Anodic N−H Bond Cleavage and Its Application in Aromatic C−H Bond Functionalization

Huai‐Bo Zhao, Zhong‐Wei Hou, Zhan‐Jiang Liu, Ze‐Feng Zhou, Jinshuai Song and Hai‐Chao Xu

Angew Chem Int Ed, 2017, 56, 587
DOI: 10.1002/anie.201610715

Advances in N-centered intermediates by energy transfer photocatalysis

Milan Bera, Da Seul Lee and Eun Jin Cho

Trends in Chemistry, 2021, 3, 877
DOI: 10.1016/j.trechm.2021.06.001

New mode of asymmetric induction for enantioselective radical N-heterobicyclization via kinetically stable chiral radical center

Hao Xu, Duo-Sheng Wang, Zhenyu Zhu, Arghya Deb and X. Peter Zhang

Chem, 2024, 10, 283
DOI: 10.1016/j.chempr.2023.09.010

Sulfamate Esters Guide C(3)-Selective Xanthylation of Alkanes

Suraj K. Ayer and J. L. Roizen

J. Org. Chem., 2019, 84, 3508
DOI: 10.1021/acs.joc.9b00105

Dynamic Kinetic Resolution-Enabled Highly Stereoselective Nucleophilic Fluoroalkylation to Access Chiral β-Fluoro Amines

Qinghe Liu, Taige Kong, Chuanfa Ni and Jinbo Hu

Org. Lett., 2022, 24, 5982
DOI: 10.1021/acs.orglett.2c02250

Recent Advances in the Construction of C–N Bonds Through Coupling Reactions between Carbon Radicals and Nitrogen Radicals

Junfei Luo and Wen‐Ting Wei

Adv Synth Catal, 2018, 360, 2076
DOI: 10.1002/adsc.201800205

Metal‐Free One‐Pot Three‐Component Synthesis of Quinazoline Derivatives via Peroxide‐Mediated Direct Oxidative Amination of C(sp3)–H Bonds

Tien V. Huynh, Son H. Doan, Khang H. Trinh, Trang H. Ly, Anh L. T. Phan, Tung T. Nguyen, Anh N. Q. Phan and Nam T. S. Phan

ChemistrySelect, 2019, 4, 11808
DOI: 10.1002/slct.201903154

Mechanism of Photoredox-Initiated C–C and C–N Bond Formation by Arylation of IPrAu(I)–CF3 and IPrAu(I)–Succinimide

Suhong Kim and F. Dean Toste

J. Am. Chem. Soc., 2019, 141, 4308
DOI: 10.1021/jacs.8b11273

Mechanistic Study on AgI-Catalyzed Oxidative Cross-Coupling/Cyclization between Terminal Alkynes and β-Enamino Esters under Base Conditions

Shanshan Cao, Haiyan Yuan and Jingping Zhang

J. Org. Chem., 2020, 85, 4408
DOI: 10.1021/acs.joc.0c00132

A Molecular Iron-Based System for Divergent Bond Activation: Controlling the Reactivity of Aldehydes

Basujit Chatterjee, Soumyashree Jena, Vishal Chugh, Thomas Weyhermüller and Christophe Werlé

ACS Catal., 2021, 11, 7176
DOI: 10.1021/acscatal.1c00733

Visible-Light-Driven [3 + 2]/[4 + 2] Annulation Reactions of Alkenes withN-Aminopyridinium Salts

Yu-Zhao Wang, Peng-Yu Liang, Hong-Chao Liu, Wu-Jie Lin, Pan-Pan Zhou and Wei Yu

Org. Lett., 2022, 24, 6037
DOI: 10.1021/acs.orglett.2c02323

Sulfoximidations of Benzylic C−H bonds by Photocatalysis

Han Wang, Duo Zhang and Carsten Bolm

Angewandte Chemie, 2018, 130, 5965
DOI: 10.1002/ange.201801660

Electrochemically Tuned Oxidative [4+2] Annulation and Dioxygenation of Olefins with Hydroxamic Acids

Bang‐Yi Wei, Dong‐Tai Xie, Sheng‐Qiang Lai, Yu Jiang, Hong Fu, Dian Wei and Bing Han

Angew Chem Int Ed, 2021, 60, 3182
DOI: 10.1002/anie.202012209

Diastereoselective Radical Aminoacylation of Olefins through N-Heterocyclic Carbene Catalysis

Wen-Deng Liu, Woojin Lee, Hanyu Shu, Chuyu Xiao, Huiwei Xu, Xiangyang Chen, Kendall N. Houk and Jiannan Zhao

J. Am. Chem. Soc., 2022, 144, 22767
DOI: 10.1021/jacs.2c11209

Sulfonamide-Directed Chemo- and Site-Selective Oxidative Halogenation/Amination Using Halogenating Reagents Generated in Situ from Cyclic Diacyl Peroxides

Denghu Chang, Rong Zhao, Congyin Wei, Yuan Yao, Yang Liu and Lei Shi

J. Org. Chem., 2018, 83, 3305
DOI: 10.1021/acs.joc.8b00243

Direct Enamido C(sp2)−H Diphosphorylation Enabled by a PCET‐Triggered Double Radical Relay: Access to gem‐Bisphosphonates

Hao‐Qiang Cao, Hao‐Nan Liu, Zhe‐Yuan Liu, Bao‐Kun Qiao, Fa‐Guang Zhang and Jun‐An Ma

Chemistry A European J, 2020, 26, 5515
DOI: 10.1002/chem.202000517

Generation of Aromatic N‐Heterocyclic Radicals for Functionalization of Unactivated Alkenes

Lu Wang, Minxu Shi, Xiaoping Chen, Nicholas Su, Weili Luo and Xiaheng Zhang

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202314312

Molecular Oxygen Mediated Radical Dicarbofunctionalization of Olefin with Aldehyde

Promita Biswas and Joyram Guin

J. Org. Chem., 2018, 83, 5629
DOI: 10.1021/acs.joc.8b00618

Copper-Catalyzed Intramolecular Olefinic C(sp2)–H Amidation for the Synthesis of γ-Alkylidene-γ-lactams

Kanako Nozawa-Kumada, Masahito Hayashi, Eunsang Kwon, Masanori Shigeno, Akira Yada and Yoshinori Kondo

Molecules, 2023, 28, 6682
DOI: 10.3390/molecules28186682

Structure-selectivity relationship in the cleavage of spirocyclopropyl oxindoles: An experimental and theoretical investigation

J. Benjamín García-Vázquez, Angel E. Bañuelos-Hernández, Joel J. Trujillo-Serrato, Oscar R. Suárez-Castillo, Armando Ariza-Castolo and Martha S. Morales-Ríos

Journal of Molecular Structure, 2017, 1145, 184
DOI: 10.1016/j.molstruc.2017.05.099

Tunable Electrochemical C−N versus N−N Bond Formation of Nitrogen‐Centered Radicals Enabled by Dehydrogenative Dearomatization: Biological Applications

Shide Lv, Xiaoxin Han, Jian‐Yong Wang, Mingyang Zhou, Yanwei Wu, Li Ma, Liwei Niu, Wei Gao, Jianhua Zhou, Wei Hu, Yuezhi Cui and Jianbin Chen

Angewandte Chemie, 2020, 132, 11680
DOI: 10.1002/ange.202001510

Nitrene Radical Intermediates in Catalytic Synthesis

Petrus F. Kuijpers, Jarl Ivar van der Vlugt, Sven Schneider and Bas de Bruin

Chemistry A European J, 2017, 23, 13819
DOI: 10.1002/chem.201702537

Electrochemical Iodoamination of Indoles Using Unactivated Amines

Ning Lei, Yanling Shen, Yujun Li, Pan Tao, Liquan Yang, Zhishan Su and Ke Zheng

Org. Lett., 2020, 22, 9184
DOI: 10.1021/acs.orglett.0c03158

Stereoselective and Regioselective Synthesis of Heterocycles via Copper-Catalyzed Additions of Amine Derivatives and Alcohols to Alkenes

Sherry R. Chemler, Shuklendu D. Karyakarte and Zainab M. Khoder

J. Org. Chem., 2017, 82, 11311
DOI: 10.1021/acs.joc.7b02072

Copper-Catalyzed Radical Cascade Reaction of Indole with Benzimidazole to Synthesize 3-Haloindole-Benzimidazoles

Xiaoyu Liu, Kun He, Junhong Pan, Weikun Zeng, Jun Lin and Yi Jin

SSRN Journal, 2022
DOI: 10.2139/ssrn.4109387

α‐Quaternary Mannich Bases through Copper‐Catalyzed Amination‐Induced 1,2‐Rearrangement of Allylic Alcohols

Wei‐Zhi Weng, Jian‐Guo Sun, Ping Li and Bo Zhang

Chemistry A European J, 2017, 23, 9752
DOI: 10.1002/chem.201702428

Development of N-centered radical scavengers that enables photoredox-catalyzed transition-metal-free radical amination of alkyl pinacol boronates

Changlei Zhu, Jiaxin Lin, Xiaoguang Bao and Jingjing Wu

Nat Commun, 2025, 16
DOI: 10.1038/s41467-025-58347-8

Sulfonylation of Benzylic C−H Bonds through the Reaction of Aryl(o‐tolyl)methanones with Sulfonyl Hydrazides or Sulfonyl Chlorides

Xinxing Gong, Jiahao Chen, Xiaofang Li, Wenlin Xie and Jie Wu

Chemistry An Asian Journal, 2018, 13, 2543
DOI: 10.1002/asia.201800591

Understanding the Chemistry of Nitrene and Highlighting its Remarkable Catalytic Capabilities as a Non-Heme Iron Enzyme

Nneka Damola Ajayi, Samson Abidemi Ajayi, John Oizamsi Boyi and Oluwaseun Oladeji Olaniyi

SSRN Journal, 2024
DOI: 10.2139/ssrn.4682019

C–N Bond Activation of N,N′-Dialkylacylhydrazines Mediated by β-Fragmentation of Nitrogen-Centered Radical

Yuxian Zhang, Shuwei Zhang, Zheng Sun, Kaixuan He, Qian Chen, Yu Yuan and Xiaodong Jia

J. Org. Chem., 2019, 84, 14202
DOI: 10.1021/acs.joc.9b01851

Recent advances in radical-mediated transformations of 1,3-dienes

Peng-Zi Wang, Wen-Jing Xiao and Jia-Rong Chen

Chinese Journal of Catalysis, 2022, 43, 548
DOI: 10.1016/S1872-2067(21)63919-0

Pyridiniumsalze als redoxaktive Reagenzien zur Übertragung funktioneller Gruppen

Simon L. Rössler, Benson J. Jelier, Emmanuel Magnier, Guillaume Dagousset, Erick M. Carreira and Antonio Togni

Angewandte Chemie, 2020, 132, 9350
DOI: 10.1002/ange.201911660

Three‐Component Aminoarylation of Electron‐Rich Alkenes by Merging Photoredox with Nickel Catalysis

Heng Jiang, Xiaoye Yu, Constantin G. Daniliuc and Armido Studer

Angew Chem Int Ed, 2021, 60, 14399
DOI: 10.1002/anie.202101775

Photoinduced Sulfonylation Reactions through the Insertion of Sulfur Dioxide

Shengqing Ye, Xiaofang Li, Wenlin Xie and Jie Wu

Eur J Org Chem, 2020, 2020, 1274
DOI: 10.1002/ejoc.201900396

Carboamination of Unactivated Alkenes through Three‐Component Radical Conjugate Addition

Heng Jiang, Gesa Seidler and Armido Studer

Angew Chem Int Ed, 2019, 58, 16528
DOI: 10.1002/anie.201910926

Enantioselective Hydroamination of Alkenes with Sulfonamides Enabled by Proton-Coupled Electron Transfer

Casey B. Roos, Joachim Demaerel, David E. Graff and Robert R. Knowles

J. Am. Chem. Soc., 2020, 142, 5974
DOI: 10.1021/jacs.0c01332

Enhanced Photoredox Activity in Nitrogen‐Doped Carbon Nitride for Heterogeneous Nitrogen and Oxygen Radical Reactions

Lan Qin, Huan Liu, Yi Wei, Lian‐Qing Chen and Xiao‐Qiang Hu

Advanced Science, 2025, 12
DOI: 10.1002/advs.202417752

Bifunctional sulfilimines enable synthesis of multiple N-heterocycles from alkenes

Qiang Cheng, Zibo Bai, Srija Tewari and Tobias Ritter

Nat. Chem., 2022, 14, 898
DOI: 10.1038/s41557-022-00997-y

Enantioselective Intermolecular Radical C–H Amination

Li-Mei Jin, Pan Xu, Jingjing Xie and X. Peter Zhang

J. Am. Chem. Soc., 2020, 142, 20828
DOI: 10.1021/jacs.0c10415

Copper-Catalyzed Allylic C(sp3)—H Sulfonylation of Cyclic Olefins

Chunyang Liu, Yan Li and Qian Zhang

Chinese Journal of Organic Chemistry, 2023, 43, 1091
DOI: 10.6023/cjoc202211028

α‐Aminoxy‐Acid‐Auxiliary‐Enabled Intermolecular Radical γ‐C(sp3)−H Functionalization of Ketones

Heng Jiang and Armido Studer

Angew Chem Int Ed, 2018, 57, 1692
DOI: 10.1002/anie.201712066

Copper-catalyzed tandem radical amination/1,2-carbon migration of allylic alcohols: Direct access to α-quaternary-β-amino ketones

Jiaqiong Sun, Guangfan Zheng, Yongmei Fu, Qiao Zhang, Yimin Wang, Qian Zhang, Yan Li and Qian Zhang

Chinese Journal of Catalysis, 2018, 39, 138
DOI: 10.1016/S1872-2067(18)63028-1

Tin(II)–Nitrene Radical Complexes Formed by Electron Transfer from Redox-Active Ligand to Organic Azides and Their Reactivity in C(sp3)–H Activation

Hideki Sugimoto, Mayuka Yano, Kazunobu Sato, Mayuko Miyanishi, Kenji Sugisaki, Yoshihito Shiota, Akira Kaga, Kazunari Yoshizawa and Shinobu Itoh

Inorg. Chem., 2021, 60, 18603
DOI: 10.1021/acs.inorgchem.1c02806

Radical Formation by Direct Single Electron Transfer between Nitrobenzene and Anionic Organo Bases

Shivaprasad Achary Balahoju, Nicholus Bhattacharjee, Luis Lezama, Xabier Lopez, Pablo Salcedo-Abraira, Antonio Rodríguez-Diéguez and Daniel Reta

ACS Omega, 2025, 10, 23798
DOI: 10.1021/acsomega.5c02989

Mechanistic study on silver-catalyzed direct amination of unactivated C H bond

Xiang Zhang

Journal of Organometallic Chemistry, 2017, 832, 1
DOI: 10.1016/j.jorganchem.2017.01.006

Nitrogen-Centered Radical Cyclization Initiated by Proton-Coupled Electron Transfer: A Mechanistic Study of 5-Exo-trig and 6-Endo-trig Cyclization Pathways

Yu-Qi Tang, Ming-Tian Zhang and Lei Jiao

J. Org. Chem., 2025, 90, 11162
DOI: 10.1021/acs.joc.5c01102

Visible-Light-Mediated Synthesis of Amidyl Radicals: Transition-Metal-Free Hydroamination and N-Arylation Reactions

Jacob Davies, Thomas D. Svejstrup, Daniel Fernandez Reina, Nadeem S. Sheikh and Daniele Leonori

J. Am. Chem. Soc., 2016, 138, 8092
DOI: 10.1021/jacs.6b04920

Reactivity Tuning for Radical–Radical Cross-Coupling via Selective Photocatalytic Energy Transfer: Access to Amine Building Blocks

Vineet Kumar Soni, Sumin Lee, Jihee Kang, Yu Kyung Moon, Ho Seong Hwang, Youngmin You and Eun Jin Cho

ACS Catal., 2019, 9, 10454
DOI: 10.1021/acscatal.9b03435

Nitrogen‐Centered Radical‐Directed C(sp3)−H Amination and Aminoalkylation Using (Diarylmethylene)amino Benziodoxolones

Kensuke Kiyokawa, Mari Sugimura, Megumi Abe, Daiki Wada, Hikaru Kaneba and Satoshi Minakata

ChemistryEurope, 2025
DOI: 10.1002/ceur.202500188

Paired Electrosynthesis of Aromatic Azo Compounds from Aryl Diazonium Salts with Pyrroles or Indoles

Mu‐Xue He, Yu‐Zheng Wu, Yan Yao, Zu‐Yu Mo, Ying‐Ming Pan and Hai‐Tao Tang

Adv Synth Catal, 2021, 363, 2752
DOI: 10.1002/adsc.202001457

Visible-Light-Promoted Fe(III)-Catalyzed N–H Alkylation of Amides and N-Heterocycles

Hangcheng Ni, Chaoming Li, Xingzi Shi, Xianyue Hu and Hui Mao

J. Org. Chem., 2022, 87, 9797
DOI: 10.1021/acs.joc.2c00854

Synthesis and Biological Evaluation of a Library of Sulfonamide Analogs of Memantine to Target Glioblastoma

John E. Philo, Jenna D. Caudle, Reema N. Moussa, Patrick M. Kampmeyer, Tasfia R. Hasin, David K. Seo, Robert J. Sheaff and Angus A. Lamar

ChemMedChem, 2023, 18
DOI: 10.1002/cmdc.202300134

Catalyst-Free Organic Transformations under Visible-Light

Mina Tavakolian and Mona Hosseini-Sarvari

ACS Sustainable Chem. Eng., 2021, 9, 4296
DOI: 10.1021/acssuschemeng.0c06657

Visible Light-Driven Radical-Mediated C–C Bond Cleavage/Functionalization in Organic Synthesis

Xiao-Ye Yu, Jia-Rong Chen and Wen-Jing Xiao

Chem. Rev., 2021, 121, 506
DOI: 10.1021/acs.chemrev.0c00030

Iron(II) Chloride‐Catalyzed Nitrene Transfer Reaction for Dearomative Amination of β‐Naphthols with Aryl Azides

Dun‐Qi Wu, Zhen‐Yu Guan, Yi Peng, Jian Sun, Cheng Zhong and Qing‐Hai Deng

Adv Synth Catal, 2018, 360, 4720
DOI: 10.1002/adsc.201800810

Site-Selective C(sp3)–H Functionalizations Mediated by Hydrogen Atom Transfer Reactions via α-Amino/α-Amido Radicals

Jaspreet Kaur and Joshua P. Barham

Synthesis, 2022, 54, 1461
DOI: 10.1055/a-1677-6619

Radical‐Induced, Palladium‐Catalyzed C–H Activation: An Approach to Functionalize 4H‐Benzo[d][1,3]oxazin‐4‐one Derivatives by Using Toluenes, Aldehydes, and Benzyl Alcohols

Prashant Kumar, Mohit Gupta, Vijay Bahadur, Virinder S. Parmar and Brajendra K. Singh

Eur J Org Chem, 2018, 2018, 1552
DOI: 10.1002/ejoc.201800263

Fluoro Nitrenoid Complexes FN=MF2 (M=Co, Rh, Ir): Electronic Structure Dichotomy and Formation of Nitrido Fluorides N≡MF3

Tony Stüker, Thomas Hohmann, Helmut Beckers and Sebastian Riedel

Angew Chem Int Ed, 2020, 59, 23174
DOI: 10.1002/anie.202010950

Transition Metal-Catalyzed C–H Amination: Scope, Mechanism, and Applications

Yoonsu Park, Youyoung Kim and Sukbok Chang

Chem. Rev., 2017, 117, 9247
DOI: 10.1021/acs.chemrev.6b00644

Synthesis of CF3-Substituted 1,6-Dihydropyridazines by Copper-Promoted Cascade Oxidation/Cyclization of Trifluoromethylated Homoallylic N-Acylhydrazines

Tianyu Yang, Zhoubin Deng, Ke-Hu Wang, Pengfei Li, Danfeng Huang, Yingpeng Su and Yulai Hu

J. Org. Chem., 2020, 85, 12304
DOI: 10.1021/acs.joc.0c01568

Photochemical and Electrochemical Applications of Proton-Coupled Electron Transfer in Organic Synthesis

Philip R. D. Murray, James H. Cox, Nicholas D. Chiappini, Casey B. Roos, Elizabeth A. McLoughlin, Benjamin G. Hejna, Suong T. Nguyen, Hunter H. Ripberger, Jacob M. Ganley, Elaine Tsui, Nick Y. Shin, Brian Koronkiewicz, Guanqi Qiu and Robert R. Knowles

Chem. Rev., 2022, 122, 2017
DOI: 10.1021/acs.chemrev.1c00374

Recent advances in visible-light photoredox-catalyzed nitrogen radical cyclization

Pengzi Wang, Quanqing Zhao, Wenjing Xiao and Jiarong Chen

Green Synthesis and Catalysis, 2020, 1, 42
DOI: 10.1016/j.gresc.2020.05.003

Synthesis of Hypervalent Iodine(III) Reagents Containing a Transferable (Diarylmethylene)amino Group and Their Use in the Oxidative Amination of Silyl Ketene Acetals

Kensuke Kiyokawa, Daichi Okumatsu and Satoshi Minakata

Angew Chem Int Ed, 2019, 58, 8907
DOI: 10.1002/anie.201904971

Amidyl Radicals by Oxidation of α‐Amido‐oxy Acids: Transition‐Metal‐Free Amidofluorination of Unactivated Alkenes

Heng Jiang and Armido Studer

Angew Chem Int Ed, 2018, 57, 10707
DOI: 10.1002/anie.201804966

Photoredox-Catalyzed Diamidation and Oxidative Amidation of Alkenes: Solvent-Enabled Synthesis of 1,2-Diamides and α-Amino Ketones

Qixue Qin, Yue-Yue Han, Yan-Yan Jiao, Yanyan He and Shouyun Yu

Org. Lett., 2017, 19, 2909
DOI: 10.1021/acs.orglett.7b01145

Metal-Free C(sp2)–H/N–H Cross-Dehydrogenative Coupling of Quinoxalinones with Aliphatic Amines under Visible-Light Photoredox Catalysis

Wei Wei, Leilei Wang, Pengli Bao, Yun Shao, Huilan Yue, Daoshan Yang, Xiaobo Yang, Xiaohui Zhao and Hua Wang

Org. Lett., 2018, 20, 7125
DOI: 10.1021/acs.orglett.8b03079

Copper-Promoted Regioselective Synthesis of Polysubstituted Pyrroles from Aldehydes, Amines, and Nitroalkenes via 1,2-Phenyl/Alkyl Migration

Dimitrios Andreou, Michael G. Kallitsakis, Edward Loukopoulos, Catherine Gabriel, George E. Kostakis and Ioannis N. Lykakis

J. Org. Chem., 2018, 83, 2104
DOI: 10.1021/acs.joc.7b03051

Palladium-Catalyzed Direct Intramolecular C–N Bond Formation: Access to Multisubstituted Dihydropyrroles

Bing Jiang, Fei-Fan Meng, Qiu-Ju Liang, Yun-He Xu and Teck-Peng Loh

Org. Lett., 2017, 19, 914
DOI: 10.1021/acs.orglett.7b00072

Access to Aminated Saturated Oxygen Heterocycles via Copper-Catalyzed Aminooxygenation of Alkenes

Jian Xie, Yue-Wei Wang, Lian-Wen Qi and Bo Zhang

Org. Lett., 2017, 19, 1148
DOI: 10.1021/acs.orglett.7b00182

Manganese-Catalyzed N–F Bond Activation for Hydroamination and Carboamination of Alkenes

Yun-Xing Ji, Jinxia Li, Chun-Min Li, Shuanglin Qu and Bo Zhang

Org. Lett., 2021, 23, 207
DOI: 10.1021/acs.orglett.0c03916

Three‐Component Aminoarylation of Electron‐Rich Alkenes by Merging Photoredox with Nickel Catalysis

Heng Jiang, Xiaoye Yu, Constantin G. Daniliuc and Armido Studer

Angewandte Chemie, 2021, 133, 14520
DOI: 10.1002/ange.202101775

Room-temperature Formal Aza-Wacker Cyclization through Synergistic Copper/TEMPO-catalyzed Radical Relay

Dong Yang, Jiaming Chen, Yanping Huang, Huiquan Pan, Jingqi Shi, Yingyue Zhang, Fang Wang and Ziyuan Li

ACS Catal., 2021, 11, 9860
DOI: 10.1021/acscatal.1c02721

Cathode Material Determines Product Selectivity for Electrochemical C−H Functionalization of Biaryl Ketoximes

Huai‐Bo Zhao, Pin Xu, Jinshuai Song and Hai‐Chao Xu

Angewandte Chemie, 2018, 130, 15373
DOI: 10.1002/ange.201809679

Electrochemical Synthesis of Polycyclic N-Heteroaromatics through Cascade Radical Cyclization of Diynes

Zhong-Wei Hou, Zhong-Yi Mao, Jinshuai Song and Hai-Chao Xu

ACS Catal., 2017, 7, 5810
DOI: 10.1021/acscatal.7b02105

Generation and Reactivity of Amidyl Radicals: Manganese‐Mediated Atom‐Transfer Reaction

Run‐Zhou Liu, Jinxia Li, Jun Sun, Xian‐Guan Liu, Shuanglin Qu, Ping Li and Bo Zhang

Angew Chem Int Ed, 2020, 59, 4428
DOI: 10.1002/anie.201913042

Coordination Chemistry of the Redox Non‐Innocent Ligand Bis(2‐amino‐3,5‐di‐tert‐butylphenyl)amine with Group 10 Metal Ions (Ni, Pd, Pt)

Nicolas Leconte, Jules Moutet, Thibaut Constantin, Florian Molton, Christian Philouze and Fabrice Thomas

Eur J Inorg Chem, 2018, 2018, 1752
DOI: 10.1002/ejic.201701448

Engineering Molecular Iodine Catalysis for Alkyl–Nitrogen Bond Formation

Thomas Duhamel, Christopher J. Stein, Claudio Martínez, Markus Reiher and Kilian Muñiz

ACS Catal., 2018, 8, 3918
DOI: 10.1021/acscatal.8b00286

Indole Alkaloid Synthesis Facilitated by Photoredox Catalytic Radical Cascade Reactions

Xiao-Yu Liu and Yong Qin

Acc. Chem. Res., 2019, 52, 1877
DOI: 10.1021/acs.accounts.9b00246

Dual Role of Aryl Iodide in Cascade C–H Arylation/Amination: Arylation Reagent and Cocatalyst for C–N Formation

Deng-Yuan Li, Shuo Liu, Shuang Chen, An Wang, Xiao-Ping Zhu and Pei-Nian Liu

ACS Catal., 2018, 8, 6407
DOI: 10.1021/acscatal.8b01071

Elusive Terminal Copper Arylnitrene Intermediates

Abolghasem (Gus) Bakhoda, Quan Jiang, Jeffery A. Bertke, Thomas R. Cundari and Timothy H. Warren

Angew Chem Int Ed, 2017, 56, 6426
DOI: 10.1002/anie.201611275

Photoenzymatic enantioselective intermolecular radical hydroamination

Zhengyi Zhang, Jianqiang Feng, Chao Yang, Haiyang Cui, Wesley Harrison, Dongping Zhong, Binju Wang and Huimin Zhao

Nat Catal, 2023, 6, 687
DOI: 10.1038/s41929-023-00994-5

Allylic Amination of Alkenes with Iminothianthrenes to Afford Alkyl Allylamines

Qiang Cheng, Junting Chen, Songyun Lin and Tobias Ritter

J. Am. Chem. Soc., 2020, 142, 17287
DOI: 10.1021/jacs.0c08248

Iron‐Catalyzed, Iminyl Radical‐Triggered Cascade 1,5‐Hydrogen Atom Transfer/(5+2) or (5+1) Annulation: Oxime as a Five‐Atom Assembling Unit

Wu Liang, Kun Jiang, Fei Du, Jie Yang, Li Shuai, Qin Ouyang, Ying‐Chun Chen and Ye Wei

Angewandte Chemie, 2020, 132, 19384
DOI: 10.1002/ange.202007825

Asymmetric Copper-Catalyzed Intermolecular Aminoarylation of Styrenes: Efficient Access to Optical 2,2-Diarylethylamines

Dinghai Wang, Lianqian Wu, Fei Wang, Xiaolong Wan, Pinhong Chen, Zhenyang Lin and Guosheng Liu

J. Am. Chem. Soc., 2017, 139, 6811
DOI: 10.1021/jacs.7b02455

Electrochemical generation and in situ EPR- and UV–vis- observation of aminyl-radical diarylamido/bis(phosphine) pincer complexes of Ni, Pd and Pt

Alexey A. Kagilev, Zufar N. Gafurov, Il'yas F. Sakhapov, Vladimir I. Morozov, Artyom O. Kantyukov, Ruslan B. Zaripov, Ekaterina M. Zueva, Ilya K. Mikhailov, Alexey B. Dobrynin, Vasilisa A. Kulikova, Vladislava A. Kirkina, Evgenii I. Gutsul, Elena S. Shubina, Natalia V. Belkova, Oleg G. Sinyashin and Dmitry G. Yakhvarov

Journal of Electroanalytical Chemistry, 2024, 956, 118084
DOI: 10.1016/j.jelechem.2024.118084

Visible Light‐Driven Catalyst‐Free Amination of Indoles Initiated by Electron Donor‐Acceptor Complexes

Jiahong Sui, Zhonglie Yang, Shuangqiao Li, Xueqin Chen, Xiaobin Zhang, Qing Shen, Hezhong Jiang and Jiahong Li

Chin. J. Chem., 2023, 41, 1485
DOI: 10.1002/cjoc.202200772

General Strategy for Improving the Quantum Efficiency of Photoredox Hydroamidation Catalysis

Serge Ruccolo, Yangzhong Qin, Christoph Schnedermann and Daniel G. Nocera

J. Am. Chem. Soc., 2018, 140, 14926
DOI: 10.1021/jacs.8b09109

Bismuth Amides Mediate Facile and Highly Selective Pn–Pn Radical‐Coupling Reactions (Pn=N, P, As)

Kai Oberdorf, Anna Hanft, Jacqueline Ramler, Ivo Krummenacher, F. Matthias Bickelhaupt, Jordi Poater and Crispin Lichtenberg

Angew Chem Int Ed, 2021, 60, 6441
DOI: 10.1002/anie.202015514

Advanced Synthesis Using Photocatalysis Involved Dual Catalytic System

Fenfen Guo, Hong Wang, Xinyi Ye and Choon‐Hong Tan

Eur J Org Chem, 2022, 2022
DOI: 10.1002/ejoc.202200326

Visible-Light Photocatalyzed Deoxygenation of N-Heterocyclic N-Oxides

Kyu Dong Kim and Jun Hee Lee

Org. Lett., 2018, 20, 7712
DOI: 10.1021/acs.orglett.8b03446

Direct Access to Versatile Electrophiles via Catalytic Oxidative Cyanation of Alkenes

De-Wei Gao, Ekaterina V. Vinogradova, Sri Krishna Nimmagadda, Jose M. Medina, Yiyang Xiao, Radu M. Suciu, Benjamin F. Cravatt and Keary M. Engle

J. Am. Chem. Soc., 2018, 140, 8069
DOI: 10.1021/jacs.8b03704

Visible-light induced generation of bifunctional nitrogen-centered radicals: a concise synthetic strategy to construct bicyclo[3.2.1] octane and azepane cores

Wan-Lei Yu, Hao-Wen Jiang, Lei Yan, Zhi-Tao Feng, Yong-Chun Luo and Peng-Fei Xu

Sci. China Chem., 2021, 64, 274
DOI: 10.1007/s11426-020-9852-8

Sulfamate Esters Guide Selective Radical‐Mediated Chlorination of Aliphatic C−H Bonds

Melanie A. Short, J. Miles Blackburn and Jennifer L. Roizen

Angewandte Chemie, 2018, 130, 302
DOI: 10.1002/ange.201710322

Palladium‐Catalyzed Fluorinative Bifunctionalization of Aziridines and Azetidines with gem‐Difluorocyclopropanes

Dongdong Li, Chaoren Shen, Zhiyao Si and Lu Liu

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202310283

Base‐Controlled Chemoselective Reaction of High‐Valent Cu(III)−CF3Compounds with Anilines: Access to Formamides or Hydrazines

Zhen‐Mei Zheng, Ning Chen, Ming‐Suo Dai and Song‐Lin Zhang

Adv Synth Catal, 2023, 365, 1262
DOI: 10.1002/adsc.202300017

Photoinduced α‐C−H Amination of Cyclic Amine Scaffolds Enabled by Polar‐Radical Relay

Wongyu Lee, Dongwook Kim, Sangwon Seo and Sukbok Chang

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202202971

Cobalt‐Porphyrin‐Catalysed Intramolecular Ring‐Closing C−H Amination of Aliphatic Azides: A Nitrene‐Radical Approach to Saturated Heterocycles

Petrus F. Kuijpers, Martijn J. Tiekink, Willem B. Breukelaar, Daniël L. J. Broere, Nicolaas P. van Leest, Jarl Ivar van der Vlugt, Joost N. H. Reek and Bas de Bruin

Chemistry A European J, 2017, 23, 7945
DOI: 10.1002/chem.201700358

Transition‐Metal Catalyzed Enantioselective Aziridination Reaction: Recent Development in Catalysis and Future Perspectives

Gui‐Lin Hao, Juanjuan Wang, Shu‐Bin Mou, Mu‐Peng Luo, Qiaoqiao Teng and Shou‐Guo Wang

ChemCatChem, 2024, 16
DOI: 10.1002/cctc.202400791

Glycal Metallanitrenes for 2-Amino Sugar Synthesis: Amidoglycosylation of Gulal-, Allal-, Glucal-, and Galactal 3-Carbamates

Simran Buttar, Julia Caine, Evelyne Goné, Reneé Harris, Jennifer Gillman, Roxanne Atienza, Ritu Gupta, Kimberly M. Sogi, Lauren Jain, Nadia C. Abascal, Yetta Levine, Lindsay M. Repka and Christian M. Rojas

J. Org. Chem., 2018, 83, 8054
DOI: 10.1021/acs.joc.8b00893

Photoinduced, Copper-Catalyzed Radical Cross-Coupling of Cycloketone Oxime Esters, Alkenes, and Terminal Alkynes

Jun Chen, Bin-Qing He, Peng-Zi Wang, Xiao-Ye Yu, Quan-Qing Zhao, Jia-Rong Chen and Wen-Jing Xiao

Org. Lett., 2019, 21, 4359
DOI: 10.1021/acs.orglett.9b01529

Electrochemically Tuned Oxidative [4+2] Annulation and Dioxygenation of Olefins with Hydroxamic Acids

Bang‐Yi Wei, Dong‐Tai Xie, Sheng‐Qiang Lai, Yu Jiang, Hong Fu, Dian Wei and Bing Han

Angewandte Chemie, 2021, 133, 3219
DOI: 10.1002/ange.202012209

A Facile Approach to Oximes and Ethers by a Tandem NO+‐Initiated Semipinacol Rearrangement and H‐Elimination

Jia‐Wei Dong, Tongmei Ding, Shu‐Yu Zhang, Zhi‐Min Chen and Yong‐Qiang Tu

Angewandte Chemie, 2018, 130, 13376
DOI: 10.1002/ange.201807861

Tuning radical reactivity for selective radical/radical cross-coupling

Shengchun Wang, Shan Tang and Aiwen Lei

Science Bulletin, 2018, 63, 1006
DOI: 10.1016/j.scib.2018.06.004

Exploiting Imine Photochemistry for Masked N‐Centered Radical Reactivity

Daryl Staveness, James L. Collins, Rory C. McAtee and Corey R. J. Stephenson

Angew Chem Int Ed, 2019, 58, 19000
DOI: 10.1002/anie.201909492

Hypervalent Iodine Reagent‐Mediated Selective Vinyl C−H Amidation of 4‐Alkoxystyrenes with Diarylsulfonimides for Preparation of Enamides

Xia Wang, Hao Liu, Dehu Xiang, Qian Zhang and Dong Li

ChemistrySelect, 2020, 5, 5970
DOI: 10.1002/slct.202001689

Recent Advances in Copper‐Catalyzed C−N Bond Formation Involving N‐Centered Radicals

Yan‐Nan Zheng, Hongxing Zheng, Ting Li and Wen‐Ting Wei

ChemSusChem, 2021, 14, 5340
DOI: 10.1002/cssc.202102243

Synthesis of Functionalized Pyrrolines via Microwave-Promoted Iminyl Radical Cyclizations

Jatinder Singh, Garrison A. Nickel, Yu Cai, Dakota D. Jones, Tanner J. Nelson, Jeshurun E. Small and Steven L. Castle

Org. Lett., 2021, 23, 3970
DOI: 10.1021/acs.orglett.1c01148

Solvent‐Dependent Etherification of 4‐Hydroxycoumarins with Diazo Esters under Visible‐Light Irradiation

Zixian Yang, Xian Wu, Chengli Xiang, Jin‐Tao Yu and Changduo Pan

Asian J Org Chem, 2023, 12
DOI: 10.1002/ajoc.202300357

Silver‐Based Radical Reactions: Development and Insights

Guichun Fang, Xuefeng Cong, Giuseppe Zanoni, Qun Liu and Xihe Bi

Adv Synth Catal, 2017, 359, 1422
DOI: 10.1002/adsc.201601179

Copper-catalyzed primary amination of arene C H bond with hydroxylamine derivative

Xiaobin Tan, Wenfang Xiong, Baiyao Zhu, Hongjian Liu, Wanqing Wu and Huanfeng Jiang

Tetrahedron Letters, 2023, 129, 154699
DOI: 10.1016/j.tetlet.2023.154699

Recent Advance in Electrochemical C(sp2)—H Amination of Arenes

Zile Zhu, Pengfei Li and Youai Qiu

Chinese Journal of Organic Chemistry, 2024, 44, 871
DOI: 10.6023/cjoc202310033

Cobalt‐Catalyzed Radical Hydroamination of Alkenes with N‐Fluorobenzenesulfonimides

Tao Qin, Guowei Lv, Qi Meng, Ge Zhang, Tao Xiong and Qian Zhang

Angewandte Chemie, 2021, 133, 26153
DOI: 10.1002/ange.202110178

Cobalt-Catalyzed Synthesis of Alkenyl Heterocycles via Regioselective Intramolecular 1,4-Hydrofunctionalization of Dienes

Chi-Fan Zhu, Yuan Tian, Jun-Ju Mai, Mingyuan Shi, Xiasen Dong, Dongping Shen, Mei-Hua Shen and Hua-Dong Xu

Org. Lett., 2024, 26, 8260
DOI: 10.1021/acs.orglett.4c02884

Light on Unsaturated Hydrocarbons – “Gotta Heterofunctionalize Them All”

Doriane Menigaux, Philippe Belmont and Etienne Brachet

Eur J Org Chem, 2017, 2017, 2008
DOI: 10.1002/ejoc.201601626

Bismutamide als einfache Vermittler hochselektiver Pn−Pn‐Radikal‐Kupplungsreaktionen (Pn=N, P, As)

Kai Oberdorf, Anna Hanft, Jacqueline Ramler, Ivo Krummenacher, F. Matthias Bickelhaupt, Jordi Poater and Crispin Lichtenberg

Angewandte Chemie, 2021, 133, 6513
DOI: 10.1002/ange.202015514

Anti‐Markovnikov Radical Hydro‐ and Deuteroamidation of Unactivated Alkenes

Heng Jiang and Armido Studer

Chemistry A European J, 2019, 25, 7105
DOI: 10.1002/chem.201901566

Tunable Electrochemical C−N versus N−N Bond Formation of Nitrogen‐Centered Radicals Enabled by Dehydrogenative Dearomatization: Biological Applications

Shide Lv, Xiaoxin Han, Jian‐Yong Wang, Mingyang Zhou, Yanwei Wu, Li Ma, Liwei Niu, Wei Gao, Jianhua Zhou, Wei Hu, Yuezhi Cui and Jianbin Chen

Angew Chem Int Ed, 2020, 59, 11583
DOI: 10.1002/anie.202001510

Photocatalytic Hydrazonyl Radical-Mediated Radical Cyclization/Allylation Cascade: Synthesis of Dihydropyrazoles and Tetrahydropyridazines

Quan-Qing Zhao, Jun Chen, Dong-Mei Yan, Jia-Rong Chen and Wen-Jing Xiao

Org. Lett., 2017, 19, 3620
DOI: 10.1021/acs.orglett.7b01609

Metal-Free C(sp3)–H Azidation in a Radical Strategy for the Synthesis of 3-Azido-2-oxindoles at Room Temperature

Wei-Ting Chen, Le-Han Gao, Wen-Hui Bao and Wen-Ting Wei

J. Org. Chem., 2018, 83, 11074
DOI: 10.1021/acs.joc.8b01678

Copper-catalyzed enantioselective Sonogashira-type oxidative cross-coupling of unactivated C(sp3)−H bonds with alkynes

Zhen-Hua Zhang, Xiao-Yang Dong, Xuan-Yi Du, Qiang-Shuai Gu, Zhong-Liang Li and Xin-Yuan Liu

Nat Commun, 2019, 10
DOI: 10.1038/s41467-019-13705-1

Design and Scalable Synthesis of N‐Alkylhydroxylamine Reagents for the Direct Iron‐Catalyzed Installation of Medicinally Relevant Amines**

Eric Falk, Szabolcs Makai, Tristan Delcaillau, Laura Gürtler and Bill Morandi

Angewandte Chemie, 2020, 132, 21250
DOI: 10.1002/ange.202008247

Dearomative 1,4-difunctionalization of naphthalenes via palladium-catalyzed tandem Heck/Suzuki coupling reaction

Bo Zhou, Hongliang Wang, Zhong-Yan Cao, Jia-Wen Zhu, Ren-Xiao Liang, Xin Hong and Yi-Xia Jia

Nat Commun, 2020, 11
DOI: 10.1038/s41467-020-18137-w

Recent Advances in Application of Alkoxy Radical in Organic Synthesis

Munsaf Ali, Shi Sewell, Juncheng Li and Ting Wang

Organics, 2023, 4, 459
DOI: 10.3390/org4040033

Photoinduced Azidoamination of Styrenes Using Sodium Azide and (Diphenylmethylene)amino Benziodoxolone

Kensuke Kiyokawa, Koki Nakano, Daichi Okumatsu and Satoshi Minakata

Chemistry An Asian Journal, 2025, 20
DOI: 10.1002/asia.202401493

Boryl Radical Addition to Multiple Bonds in Organic Synthesis

Tsuyoshi Taniguchi

Eur J Org Chem, 2019, 2019, 6308
DOI: 10.1002/ejoc.201901010

Electrochemical Cascade Cyclization of N‐Centered Radicals with Electro‐Deficient Alkynes

Wei‐Feng Qian, Yan‐Yan Ouyang, Cuiju Zhu and Hao Xu

ChemCatChem, 2024, 16
DOI: 10.1002/cctc.202301572

Metal- and Reagent-Free Intramolecular Oxidative Amination of Tri- and Tetrasubstituted Alkenes

Peng Xiong, He-Huan Xu and Hai-Chao Xu

J. Am. Chem. Soc., 2017, 139, 2956
DOI: 10.1021/jacs.7b01016

Copper‐Catalyzed N−F Bond Activation for Uniform Intramolecular C−H Amination Yielding Pyrrolidines and Piperidines

Daniel Bafaluy, José María Muñoz‐Molina, Ignacio Funes‐Ardoiz, Sebastian Herold, Adiran J. de Aguirre, Hongwei Zhang, Feliu Maseras, Tomás R. Belderrain, Pedro J. Pérez and Kilian Muñiz

Angew Chem Int Ed, 2019, 58, 8912
DOI: 10.1002/anie.201902716

Recent Advances in Molecule Synthesis Involving C-C Bond Cleavage of Ketoxime Esters

Pu Chen, Huawen Huang, Qi Tan, Xiaochen Ji and Feng Zhao

Molecules, 2023, 28, 2667
DOI: 10.3390/molecules28062667

Visible-Light-Mediated Annulation of Electron-Rich Alkenes and Nitrogen-Centered Radicals from N-Sulfonylallylamines: Construction of Chloromethylated Pyrrolidine Derivatives

Lorène N. S. Crespin, Andreas Greb, David C. Blakemore and Steven V. Ley

J. Org. Chem., 2017, 82, 13093
DOI: 10.1021/acs.joc.7b02146

Prediction of the Thermochemical Properties of Nitrogen-Containing Species: A Quantum Chemical Calculation and Group Additivity Approach

Xin Wang, Frederick Nii Ofei Bruce, Xuan Ren, Siyu Cheng, Yinjun Chen, Ruining He, Xin Bai, Shuyuan Liu, Fang Wang, Yiheng Tong, Wei Lin, Xu Xia, Xiaolong Fu, Yun Hin Taufiq-Yap, Henry J. Curran and Yang Li

J. Phys. Chem. A, 2025
DOI: 10.1021/acs.jpca.5c01264

C–H Imidation and Dual C–H Bond Aminobromination of Five-Membered Heterocycles

Kai Sun, Yali Li, Ranran Feng, Shiqiang Mu, Xin Wang and Bing Zhang

J. Org. Chem., 2020, 85, 1001
DOI: 10.1021/acs.joc.9b02941

Photocatalyzed syntheses of phenanthrenes and their aza-analogues. A review

Alessandra Del Tito, Havall Othman Abdulla, Davide Ravelli, Stefano Protti and Maurizio Fagnoni

Beilstein J. Org. Chem., 2020, 16, 1476
DOI: 10.3762/bjoc.16.123

Nickel Dual Photoredox Catalysis for the Synthesis of Aryl Amines

Ryan J. Key and Aaron K. Vannucci

Organometallics, 2018, 37, 1468
DOI: 10.1021/acs.organomet.8b00121

Generation and Reactivity of Amidyl Radicals: Manganese‐Mediated Atom‐Transfer Reaction

Run‐Zhou Liu, Jinxia Li, Jun Sun, Xian‐Guan Liu, Shuanglin Qu, Ping Li and Bo Zhang

Angewandte Chemie, 2020, 132, 4458
DOI: 10.1002/ange.201913042

Cobalt(III) hydride HAT mediated enantioselective intramolecular hydroamination access to chiral pyrrolidines

Qi Meng, Tao Qin, Huanran Miao, Ge Zhang and Qian Zhang

Sci. China Chem., 2024, 67, 2002
DOI: 10.1007/s11426-023-1882-5

Substituent-Controlled Regioselective Photoinduced Cyclization of N-Allylbenzamides with N-Sulfonylaminopyridinium Salts

Changduo Pan, Zixian Yang, Xian Wu, Jin-Tao Yu and Chengjian Zhu

Org. Lett., 2023, 25, 494
DOI: 10.1021/acs.orglett.2c04190

Copper-catalyzed cascade reaction of indole and benzimidazole radicals to synthesize 3-haloindole-benzimidazole compounds

Xiaoyu Liu, Kun He, Junhong Pan, Weikun Zeng, Jun Lin and Yi Jin

Tetrahedron Letters, 2022, 103, 153979
DOI: 10.1016/j.tetlet.2022.153979

1,6-Aza-Michael addition of para-quinone methides with N-heterocycles catalyzed by Zn(OTf)2: A regioselective approach to N-diarylmethyl-substituted heterocycles

Soumitra Guin, Hemonta K. Saha, Ashvani K. Patel, Santosh K. Gudimella, Subhankar Biswas and Sampak Samanta

Tetrahedron, 2020, 76, 131338
DOI: 10.1016/j.tet.2020.131338

Pentamethylcyclopentadienyl Metalloradical Iron Complexes Containing Redox Noninnocent α-Diimine-Type Ligands: Synthesis, Molecular, and Electronic Structures

Yoonsu Park, Hongyu Zhong, Tyler P. Pabst, Junho Kim and Paul J. Chirik

Organometallics, 2023, 42, 465
DOI: 10.1021/acs.organomet.3c00027

Photoredox-Catalyzed Oxidation of Anions for the Atom-Economical Hydro-, Amido-, and Dialkylation of Alkenes

Katherine C. Forbes, Anne Marie Crooke, Yuri Lee, Masamu Kawada, Kian M. Shamskhou, Rachel A. Zhang and Jeffrey S. Cannon

J. Org. Chem., 2022, 87, 3498
DOI: 10.1021/acs.joc.1c03055

Catalytic Asymmetric Radical Diamination of Alkenes

Fu-Li Wang, Xiao-Yang Dong, Jin-Shun Lin, Yang Zeng, Guan-Yuan Jiao, Qiang-Shuai Gu, Xian-Qi Guo, Can-Liang Ma and Xin-Yuan Liu

Chem, 2017, 3, 979
DOI: 10.1016/j.chempr.2017.10.008

Organic Electrosynthesis: Applications in Complex Molecule Synthesis

Andrey Shatskiy, Helena Lundberg and Markus D. Kärkäs

ChemElectroChem, 2019, 6, 4067
DOI: 10.1002/celc.201900435

Copper-Catalyzed Intermolecular Cross-dehydrogenative C–N Coupling at Room Temperature via Remote Activating Group Enabled Radical Relay Strategy

Xiaoqi Jia, Xiangmin Tian, Dailin Zhuang, Zhenyang Wan, Jiahao Gu and Ziyuan Li

Org. Lett., 2023, 25, 2012
DOI: 10.1021/acs.orglett.3c00267

Copper-catalyzed fragmentation-rearrangement sequence of cycloketoxime esters

Yixiao Wu, Binlin Zhao, Zhuangzhi Shi and Yu Yuan

Tetrahedron, 2020, 76, 130873
DOI: 10.1016/j.tet.2019.130873

Amidinyl Radical Formation through Anodic N−H Bond Cleavage and Its Application in Aromatic C−H Bond Functionalization

Huai‐Bo Zhao, Zhong‐Wei Hou, Zhan‐Jiang Liu, Ze‐Feng Zhou, Jinshuai Song and Hai‐Chao Xu

Angewandte Chemie, 2017, 129, 602
DOI: 10.1002/ange.201610715

Asymmetric Induction and Enantiodivergence in Catalytic Radical C–H Amination via Enantiodifferentiative H-Atom Abstraction and Stereoretentive Radical Substitution

Kai Lang, Sebastian Torker, Lukasz Wojtas and X. Peter Zhang

J. Am. Chem. Soc., 2019, 141, 12388
DOI: 10.1021/jacs.9b05850

Copper‐Catalyzed Oxidative C(sp3)−H/N−H Cross‐Coupling of Hydrocarbons with P(O)−NH Compounds: the Accelerating Effect Induced by Carboxylic Acid Coproduct

Jian Lei, Yincai Yang, Lingteng Peng, Lesong Wu, Ping Peng, Renhua Qiu, Yi Chen, Chak‐Tong Au and Shuang‐Feng Yin

Adv Synth Catal, 2019, 361, 1689
DOI: 10.1002/adsc.201801694

Electrochemical Synthesis of (Aza)indolines via Dehydrogenative [3+2] Annulation: Application to Total Synthesis of (±)‐Hinckdentine A

Zhong‐Wei Hou, Hong Yan, Jin‐Shuai Song and Hai‐Chao Xu

Chin. J. Chem., 2018, 36, 909
DOI: 10.1002/cjoc.201800301

Cobalt-Catalyzed Hydrofunctionalizations of Alkenes with sp3-Hybridized Electrophiles

Yucheng Liu, Hai-Wu Du, Muneer-ul-Shafi Bhat, Yulong Li and Wei Shu

Synlett, 2025
DOI: 10.1055/a-2529-5575

1,2-Amino oxygenation of alkenes with hydrogen evolution reaction

Shengzhang Liu, Shengchun Wang, Pengjie Wang, Zhiliang Huang, Tao Wang and Aiwen Lei

Nat Commun, 2022, 13
DOI: 10.1038/s41467-022-32084-8

Recent Advances in Iron‐Catalyzed C—H Bond Amination via Iron Imido Intermediate

Peng Wang and Liang Deng

Chin. J. Chem., 2018, 36, 1222
DOI: 10.1002/cjoc.201800427

Crystal structure of 4′-amino-3′,5′-diisopropyl-(1,1′-biphenyl)-4-carbonitrile, C19H22N2

Shuang-Ming Mo and Da-Bin Shi

Zeitschrift für Kristallographie - New Crystal Structures, 2020, 235, 837
DOI: 10.1515/ncrs-2020-0038

Transition metal-free cross-coupling reactions to form carbon–heteroatom bonds

D. I. Bugaenko, A. V. Karchava and M. A. Yurovskaya

RUSS CHEM REV, 2022, 91, RCR5022
DOI: 10.1070/RCR5022

Direct Photocatalytic Synthesis of Medium‐Sized Lactams by C−C Bond Cleavage

Na Wang, Qiang‐Shuai Gu, Zhong‐Liang Li, Zhuang Li, Yu‐Long Guo, Zhen Guo and Xin‐Yuan Liu

Angew Chem Int Ed, 2018, 57, 14225
DOI: 10.1002/anie.201808890

Aminium-Radical-Mediated Intermolecular Hydroamination of Nonactivated Olefins

Si-Ming Jia, Yi-Hang Huang and Fei Wang

Synlett, 2023, 34, 93
DOI: 10.1055/s-0042-1751390

Metal‐to‐Ligand Ratio‐Dependent Chemodivergent Asymmetric Synthesis

Min Zheng, Ke Gao, Haitao Qin, Guigen Li and Hongjian Lu

Angewandte Chemie, 2021, 133, 23074
DOI: 10.1002/ange.202108617

Visible-Light-Induced Amination of Quinoline at the C8 Position via a Postcoordinated Interligand-Coupling Strategy under Mild Conditions

He-Long Peng, Yinwu Li, Xing-Yang Chen, Li-Ping Li, Zhuofeng Ke and Bao-Hui Ye

Inorg. Chem., 2021, 60, 908
DOI: 10.1021/acs.inorgchem.0c03026

N‐Radical‐Initiated Cyclization through Insertion of Sulfur Dioxide under Photoinduced Catalyst‐Free Conditions

Runyu Mao, Zheng Yuan, Yuewen Li and Jie Wu

Chemistry A European J, 2017, 23, 8176
DOI: 10.1002/chem.201702040

Copper‐Catalyzed [3+2] Annulation of 2‐Arylidene‐1,3‐Indandiones with N‐Acetyl Enamides for the Synthesis of Spiropyrrolines

Jindian Duan, Yiyang Mao, Lei Zhang, Ning Zhu, Zheng Fang and Kai Guo

Adv Synth Catal, 2020, 362, 695
DOI: 10.1002/adsc.201901333

Electrochemical Formation of N-Acyloxy Amidyl Radicals and Their Application: Regioselective Intramolecular Amination of sp2 and sp3 C–H Bonds

Sheng Zhang, Lijun Li, Mengyu Xue, Ruike Zhang, Kun Xu and Chengchu Zeng

Org. Lett., 2018, 20, 3443
DOI: 10.1021/acs.orglett.8b00981

Advances in C−N Bond Formation via N‐Centered Radicals from N‐Aminopyridinium Reagents

Farrukh Sajjad, Cheng Lu and Tie‐Gen Chen

Eur J Org Chem, 2025, 28
DOI: 10.1002/ejoc.202401220

Recent Advances of Radical Reactions for Synthesis of Functionalized Heterocycles from Alkyne‐Tethered Cyclohexadienones and Indoles: An Overview

Pranesh Pal and Ujjwal Pal

ChemistrySelect, 2025, 10
DOI: 10.1002/slct.202501624

Facile access to C-N bonds via unexpected side reactions of Knoevenagel condensation and their application in high-efficiency organic solar cells

Daobin Yang, Shuncheng Yang, Hongqian Wang, Lin Xie, Pengyu Yan and Ziyi Ge

Sci. China Chem., 2024, 67, 323
DOI: 10.1007/s11426-023-1752-3

Visible-Light-Catalyzed Tandem Cyanoalkylsulfonylation/ Cyclization of Alkynes

Yu Liu, Zan Chen, Pu Chen, Biquan Xiong, Jun Xie, An Liu, Yun Liang and Kewen Tang

Chinese Journal of Organic Chemistry, 2021, 41, 2290
DOI: 10.6023/cjoc202102051

Prospects and challenges for nitrogen-atom transfer catalysis

Mario N. Cosio and David C. Powers

Nat Rev Chem, 2023, 7, 424
DOI: 10.1038/s41570-023-00482-1

Palladium‐Catalyzed Fluorinative Bifunctionalization of Aziridines and Azetidines with gem‐Difluorocyclopropanes

Dongdong Li, Chaoren Shen, Zhiyao Si and Lu Liu

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202310283

Nickel/Photoredox Dual Catalytic Cross-Coupling of Alkyl and Amidyl Radicals to Construct C(sp3)–N Bonds

Shaofang Zhou, Kang Lv, Rui Fu, Changlei Zhu and Xiaoguang Bao

ACS Catal., 2021, 11, 5026
DOI: 10.1021/acscatal.1c00731

Photocatalytic cyclization of nitrogen-centered radicals with carbon nitride through promoting substrate/catalyst interaction

Mingcheng Yang, Ronghong Lian, Xirui Zhang, Chong Wang, Jiajia Cheng and Xinchen Wang

Nat Commun, 2022, 13
DOI: 10.1038/s41467-022-32623-3

Cooperative NHC and Photoredox Catalyzed Radical Aminoacylation of Alkenes to Tetrahydropyridazines

Wen‐Deng Liu, Jiyuan Gao, Jia‐Nan Mo, Yuqiao Zhou and Jiannan Zhao

Chemistry A European J, 2024
DOI: 10.1002/chem.202402288

Recent advances in visible light-induced C(sp3)–N bond formation

Mónica Rivas, Vitalii Palchykov, Xiangqing Jia and Vladimir Gevorgyan

Nat Rev Chem, 2022, 6, 544
DOI: 10.1038/s41570-022-00403-8

Electrooxidative [3 + 2] annulation of amidines with alkenes for the synthesis of spiroimidazolines

Sai Zhang, Gaochen Xu, Huan Yan, Qinghuan Wu, Jingjing Meng, Jindian Duan and Kai Guo

Chinese Chemical Letters, 2022, 33, 5128
DOI: 10.1016/j.cclet.2022.04.006

Metal-Free Sulfonylation of 3,4-Dihalo-2(5H)-furanones (X = Cl, Br) with Sodium Sulfinates under Air Atmosphere in Aqueous Media via a Radical Pathway

Liang Cao, Jian-Xiao Li, Han-Qing Wu, Kai Jiang, Zhi-Feng Hao, Shi-He Luo and Zhao-Yang Wang

ACS Sustainable Chem. Eng., 2018, 6, 4147
DOI: 10.1021/acssuschemeng.7b04564

Visible-Light-Promoted Photoaddition of N-Nitrosopiperidines to Alkynes: Continuous Flow Chemistry Approach to Tetrahydroimidazo[1,2-a]pyridine 1-Oxides

Dilip V. Patil, Yulim Lee, Hun Young Kim and Kyungsoo Oh

Org. Lett., 2022, 24, 5840
DOI: 10.1021/acs.orglett.2c02402

Direct Photocatalytic Synthesis of Medium‐Sized Lactams by C−C Bond Cleavage

Na Wang, Qiang‐Shuai Gu, Zhong‐Liang Li, Zhuang Li, Yu‐Long Guo, Zhen Guo and Xin‐Yuan Liu

Angewandte Chemie, 2018, 130, 14421
DOI: 10.1002/ange.201808890

Cobalt-catalyzed Divergent Markovnikov and Anti-Markovnikov Hydroamination

Xiang-Gui Zhang, Zi-Xin He, Peng Guo, Zheng Chen and Ke-Yin Ye

Org. Lett., 2022, 24, 22
DOI: 10.1021/acs.orglett.1c03511

Desulfurization of Thiols for Nucleophilic Substitution

Mu-Xian Fu, Jin-Hong Lin and Ji-Chang Xiao

Org. Lett., 2024, 26, 6065
DOI: 10.1021/acs.orglett.4c02256

Copper‐Catalyzed Radical Cross‐Coupling of Redox‐Active Oxime Esters, Styrenes, and Boronic Acids

Xiao‐Ye Yu, Quan‐Qing Zhao, Jun Chen, Jia‐Rong Chen and Wen‐Jing Xiao

Angewandte Chemie, 2018, 130, 15731
DOI: 10.1002/ange.201809820

Square-planar iron imido complexes containing strong-field pincer ligands as models for active species in catalytic nitrene transfer

Jackson A. Reyna, Hadi D. Arman and Zachary J. Tonzetich

Tetrahedron, 2024, 162, 134109
DOI: 10.1016/j.tet.2024.134109

Copper-Catalyzed Aerobic Cyclization of β,γ-Unsaturated Hydrazones with Concomitant C═C Bond Cleavage

Zhenwei Fan, Jiahao Feng, Yuchen Hou, Min Rao and Jiajia Cheng

Org. Lett., 2020, 22, 7981
DOI: 10.1021/acs.orglett.0c02911

Integrating Olefin Carboamination and Hofmann‐Löffler‐Freytag Reaction by Radical Deconstruction of Hydrazonyl N−N Bond

Si‐Pei Hu, Chen‐Hui Gao, Tu‐Ming Liu, Bing‐Yang Miao, Hong‐Chen Wang, Wei Yu and Bing Han

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202400168

Amplification of Trichloroisocyanuric Acid (TCCA) Reactivity for Chlorination of Arenes and Heteroarenes via Catalytic Organic Dye Activation

David A. Rogers, Adam T. Bensalah, Alvaro Tomas Espinosa, John L. Hoerr, Fares H. Refai, Amy K. Pitzel, Juan J. Alvarado and Angus A. Lamar

Org. Lett., 2019, 21, 4229
DOI: 10.1021/acs.orglett.9b01414

Metal-free remote oxidative benzylic C−H amination of 4-methylanilides with N -fluorobenzenesulfonimide

Yaocheng Yang, Yanting Yu, Yang Wang, Qian Zhang and Dong Li

Tetrahedron, 2018, 74, 1085
DOI: 10.1016/j.tet.2018.01.041

Recent Progress in the Construction of C−N Bonds via Metal‐Free Radical C(sp3)−H Functionalization

Si‐Zhe Song, Ya‐Nan Meng, Qiang Li and Wen‐Ting Wei

Adv Synth Catal, 2020, 362, 2120
DOI: 10.1002/adsc.202000055

Recent Advances of Producing Biobased N-Containing Compounds via Thermo-Chemical Conversion with Ammonia Process

Lujiang Xu, Chenchen Shi, Zijian He, Huan Zhang, Mingying Chen, Zhen Fang and Ying Zhang

Energy Fuels, 2020, 34, 10441
DOI: 10.1021/acs.energyfuels.0c01993

Light-Driven N-Heterocyclic Carbene-Catalyzed Multi-Component Reaction for the Synthesis of β-Amino Ketones

Chengcheng Shi, Nan Zhong, Lin Guo, Jiawen Yin, Chao Yang and Wujiong Xia

Org. Lett., 2024, 26, 8848
DOI: 10.1021/acs.orglett.4c03288

Radical Addition to Strained σ-Bonds Enables the Stereocontrolled Synthesis of Cyclobutyl Boronic Esters

Mattia Silvi and Varinder K. Aggarwal

J. Am. Chem. Soc., 2019, 141, 9511
DOI: 10.1021/jacs.9b03653

Transition-Metal-Free Intramolecular Radical Aminoboration of Unactivated Alkenes

Danqing Zheng, Kalipada Jana, Fatmah Ali Alasmary, Constantin G. Daniliuc and Armido Studer

Org. Lett., 2021, 23, 7688
DOI: 10.1021/acs.orglett.1c03024

Photoredox-Catalyzed C–H Functionalization Reactions

Natalie Holmberg-Douglas and David A. Nicewicz

Chem. Rev., 2022, 122, 1925
DOI: 10.1021/acs.chemrev.1c00311

New heterocycles via an intriguing visible-light-promoted 5-endo-dig cyclization

Igor V. Alabugin and Chaowei Hu

Chem Catalysis, 2021, 1, 976
DOI: 10.1016/j.checat.2021.10.004

Steuerbare C‐H‐Funktionalisierung durch Photokatalyse mit sichtbarem Licht

Xiao‐Qiang Hu, Jia‐Rong Chen and Wen‐Jing Xiao

Angewandte Chemie, 2017, 129, 1988
DOI: 10.1002/ange.201611463

Photoredox-catalyzed C(sp2)–N coupling reactions

Xiao-De An and Shouyun Yu

Tetrahedron Letters, 2018, 59, 1605
DOI: 10.1016/j.tetlet.2018.03.050

Post-Transition State Bifurcation in Iron-Catalyzed Arene Aminations

Bo Li, Yuli Li, Yanfeng Dang and K. N. Houk

ACS Catal., 2021, 11, 6816
DOI: 10.1021/acscatal.1c01291

Electrocatalytic Synthesis of Substituted Pyrazoles via Hypervalent Iodine Mediated Intramolecular C−N Coupling

Stanislav A. Paveliev, Oleg O. Segida, Oleg V. Bityukov, Hai‐Tao Tang, Ying‐Ming Pan, Gennady I. Nikishin and Alexander O. Terent'ev

Adv Synth Catal, 2022, 364, 3910
DOI: 10.1002/adsc.202200696

Iron‐Catalyzed, Iminyl Radical‐Triggered Cascade 1,5‐Hydrogen Atom Transfer/(5+2) or (5+1) Annulation: Oxime as a Five‐Atom Assembling Unit

Wu Liang, Kun Jiang, Fei Du, Jie Yang, Li Shuai, Qin Ouyang, Ying‐Chun Chen and Ye Wei

Angew Chem Int Ed, 2020, 59, 19222
DOI: 10.1002/anie.202007825

Enantioselective functionalization at the C4 position of pyridinium salts through NHC catalysis

Hangyeol Choi, Gangadhar Rao Mathi, Seonghyeok Hong and Sungwoo Hong

Nat Commun, 2022, 13
DOI: 10.1038/s41467-022-29462-7

Copper‐Catalyzed Arylation of Remote C(sp3)−H Bonds in Carboxamides and Sulfonamides

Zhaodong Li, Qian Wang and Jieping Zhu

Angewandte Chemie, 2018, 130, 13472
DOI: 10.1002/ange.201807623

Transformation of an Amine Moiety of Atenolol during Water Treatment with Chlorine/UV: Reaction Kinetics, Products, and Mechanisms

Jiwoon Ra, Hoonsik Yoom, Heejong Son, Tae-Mun Hwang and Yunho Lee

Environ. Sci. Technol., 2019, 53, 7653
DOI: 10.1021/acs.est.9b01412

Cu-Catalyzed Intermolecular γ-Site C–H Amination of Cyclohexenone Derivatives: The Benefit of Bifunctional Ligands

Xin Zhao, Fang Yang, Shao-Yu Zou, Qian-Qian Zhou, Zi-Sheng Chen and Kegong Ji

ACS Catal., 2022, 12, 1732
DOI: 10.1021/acscatal.1c05439

Copper-catalyzed radical cascade reaction of isocyanate and ethers

Lifeng Wang, Qingshan Tian, Chen Bin and Guozhu Zhang

Tetrahedron Letters, 2019, 60, 2084
DOI: 10.1016/j.tetlet.2019.07.013

Metal‐free Photocatalytic Intermolecular anti‐Markovnikov Hydroamination of Unactivated Alkenes

Gaoyuan Zhao, Juncheng Li and Ting Wang

Eur J Org Chem, 2021, 2021, 2650
DOI: 10.1002/ejoc.202100049

Electrochemical N‐Centered Radical‐Triggered Intramolecular N−N Coupling for the Cyclization of o‐Aminyl Azobenzenes

Anna Gao, Kangjia Chen, Fang Ma, Anni Li and Hongji Li

Eur J Org Chem, 2024, 27
DOI: 10.1002/ejoc.202400854

Succinimide-Promoted Malonylamination of Alkenes with Amines and Iodonium Ylides via Trapping of Transient Aminium Radical Cations

Liang Zhang, Xiangjin Kong, Shuya Liu, Zhiguo Zhao, Qun Yu, Wei Wang and Yao Wang

Org. Lett., 2019, 21, 2923
DOI: 10.1021/acs.orglett.9b00983

Eine Kupfer‐katalysierte N‐F‐Bindungsaktivierung für die einheitliche intramolekulare C‐H‐Aminierung zu Pyrrolidinen und Piperidinen

Daniel Bafaluy, José Maria Muñoz‐Molina, Ignacio Funes‐Ardoiz, Sebastian Herold, Adiran de Aguirre, Hongwei Zhang, Feliu Maseras, Tomás R. Belderrain, Pedro J. Pérez and Kilian Muñiz

Angewandte Chemie, 2019, 131, 9004
DOI: 10.1002/ange.201902716

Ferrocene as a Redox Catalyst for Organic Electrosynthesis

Na Chen, Zheng‐Jian Wu and Hai‐Chao Xu

Israel Journal of Chemistry, 2024, 64
DOI: 10.1002/ijch.202300097

Copper-Mediated C–H Amination of Imidazopyridines with N-Fluorobenzenesulfonimide

Shuai Lu, Lu-Lu Tian, Tian-Wei Cui, Yu-Shen Zhu, Xinju Zhu, Xin-Qi Hao and Mao-Ping Song

J. Org. Chem., 2018, 83, 13991
DOI: 10.1021/acs.joc.8b02348

Reversible C−C Bond Cleavage of a Cobalt Diketimide into an Elusive Cobalt Aryl Nitrenoid Complex

Yunjung Baek and Theodore A. Betley

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202115437

Metal- and acid-free, TBN-mediated direct C H nitration of arenes

Guangqiang Xu, Li Zhou, Chengdong Lv, Mo Xian and Qinggang Wang

Journal of Saudi Chemical Society, 2019, 23, 896
DOI: 10.1016/j.jscs.2019.01.002

Site-selective remote C(sp3)–H heteroarylation of amides via organic photoredox catalysis

Hui Chen, Wenjing Fan, Xiang-Ai Yuan and Shouyun Yu

Nat Commun, 2019, 10
DOI: 10.1038/s41467-019-12722-4

A Combined Spectroscopic and Computational Study on the Mechanism of Iron-Catalyzed Aminofunctionalization of Olefins Using Hydroxylamine Derived N–O Reagent as the “Amino” Source and “Oxidant”

Sayanti Chatterjee, Ingolf Harden, Giovanni Bistoni, Rebeca G. Castillo, Sonia Chabbra, Maurice van Gastel, Alexander Schnegg, Eckhard Bill, James A. Birrell, Bill Morandi, Frank Neese and Serena DeBeer

J. Am. Chem. Soc., 2022, 144, 2637
DOI: 10.1021/jacs.1c11083

Aliphatic Aldehydes: Novel Radical Alkylating Reagents

Wen‐Chao Yang, Jian‐Guo Feng, Lei Wu and Yong‐Qiang Zhang

Adv Synth Catal, 2019, 361, 1700
DOI: 10.1002/adsc.201801355

Reversible C−C Bond Cleavage of a Cobalt Diketimide into an Elusive Cobalt Aryl Nitrenoid Complex

Yunjung Baek and Theodore A. Betley

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202115437

Strategic Use of Nitrogen Free Radicals in Natural Product Synthesis: Total Synthesis of Agelastatin A

Takehiko Yoshimitsu

J. Synth. Org. Chem. Jpn., 2019, 77, 472
DOI: 10.5059/yukigoseikyokaishi.77.472

PhI(OAc)2-mediated oxidative C H sulfoximination of imidazopyridines under mild conditions

Nannan Luan, Zhenwei Liu, Shuaijun Han, Linhua Shen, Jingya Li, Dapeng Zou, Yangjie Wu and Yusheng Wu

Tetrahedron Letters, 2020, 61, 151362
DOI: 10.1016/j.tetlet.2019.151362

C–H Amination of Arenes with Hydroxylamine

Yi Yang See and Melanie S. Sanford

Org. Lett., 2020, 22, 2931
DOI: 10.1021/acs.orglett.0c00598

Radical C–C Bond Cleavage/Addition Cascade of Benzyl Cycloketone Oxime Ethers Enabled by Photogenerated Cyclic Iminyl Radicals

Peng-Zi Wang, Bin-Qing He, Ying Cheng, Jia-Rong Chen and Wen-Jing Xiao

Org. Lett., 2019, 21, 6924
DOI: 10.1021/acs.orglett.9b02535

Synthesis of difluoromethylated allenes through trifunctionalization of 1,3-enynes

Munira Taj Muhammad, Yihang Jiao, Changqing Ye, Mong-Feng Chiou, Muhammad Israr, Xiaotao Zhu, Yajun Li, Zhenhai Wen, Armido Studer and Hongli Bao

Nat Commun, 2020, 11
DOI: 10.1038/s41467-019-14254-3

Pyridinium Salts as Redox‐Active Functional Group Transfer Reagents

Simon L. Rössler, Benson J. Jelier, Emmanuel Magnier, Guillaume Dagousset, Erick M. Carreira and Antonio Togni

Angew Chem Int Ed, 2020, 59, 9264
DOI: 10.1002/anie.201911660

Intramolecular Hydroamidation of ortho‐Vinyl Benzamides Promoted by Potassium tert‐Butoxide/N,N‐Dimethylformamide

Zhen‐yu Chen, Liang‐yu Wu, Hai‐sheng Fang, Ting Zhang, Zhi‐feng Mao, Yong Zou, Xue‐jing Zhang and Ming Yan

Adv Synth Catal, 2017, 359, 3894
DOI: 10.1002/adsc.201700369

Regioselective Synthesis of Unsymmetrical Vicinal Diamines via Azidoimination of Alkenes with TMSN3 and Ketimines

Yongzhuo Xu, Boqiang Wang, Jiajia Wang, Xuan Zhou, Jiaxing Chen, Xinjia Guo, Guo-Jun Deng and Wen Shao

Org. Lett., 2023, 25, 8716
DOI: 10.1021/acs.orglett.3c03642

Enantioselective Copper‐Catalyzed Intermolecular Amino‐ and Azidocyanation of Alkenes in a Radical Process

Dinghai Wang, Fei Wang, Pinghong Chen, Zhenyang Lin and Guosheng Liu

Angewandte Chemie, 2017, 129, 2086
DOI: 10.1002/ange.201611850

Copper‐Catalyzed Intramolecular Radical Amination of Tertiary C(sp3)−H Bonds to Access α‐Quaternary Pyrrolidines

Ang Gao, Yang‐Qing Ren, Cheng Luan, Yu Tian, Lin Liu, Qiang‐Shuai Gu, Zhong‐Liang Li, Chang‐Jiang Yang and Xin‐Yuan Liu

Asian J Org Chem, 2023, 12
DOI: 10.1002/ajoc.202300220

Photoredox-Catalyzed Difunctionalization of Unactivated Olefins for Synthesizing Lactam-Substituted gem-Difluoroalkenes

Jie Shi, Li-Yun Guo, Qu-Ping Hu, Yu-Tao Liu, Qing Li and Fei Pan

Org. Lett., 2021, 23, 8822
DOI: 10.1021/acs.orglett.1c03329

Rhodium(III)-catalyzed chelation-assisted C-H imidation of arenes via umpolung of the imidating reagent

Guangfan Zheng, Jiaqiong Sun, Youwei Xu, Xukai Zhou, Hui Gao and Xingwei Li

Chinese Journal of Catalysis, 2020, 41, 1723
DOI: 10.1016/S1872-2067(20)63587-2

Nitrogen-Centered Radicals in Functionalization of sp2 Systems: Generation, Reactivity, and Applications in Synthesis

Cassie Pratley, Sabine Fenner and John A. Murphy

Chem. Rev., 2022, 122, 8181
DOI: 10.1021/acs.chemrev.1c00831

Copper‐Catalyzed Remote C−H Amination of Quinolines with N‐Fluorobenzenesulfonimide

Yao Yin, Jian Xie, Feng‐Qing Huang, Lian‐Wen Qi and Bo Zhang

Adv Synth Catal, 2017, 359, 1037
DOI: 10.1002/adsc.201600947

Hexafluoroisopropanol-assisted selective intramolecular synthesis of heterocycles by single-electron transfer

Jiale Xie, Jiayu Zhang, Sitthichok Kasemthaveechok, Sara López-Resano, Eric Cots, Feliu Maseras and Mónica H. Pérez-Temprano

Nat. Synth, 2024, 3, 1021
DOI: 10.1038/s44160-024-00566-w

Emerging Strategies for Asymmetric Synthesis: Combining Enzyme Promiscuity and Photo‐/Electro‐redox Catalysis

Chao‐Jiu Long, Yan‐Hong He and Zhi Guan

Asian J Org Chem, 2023, 12
DOI: 10.1002/ajoc.202200685

Iron‐catalyzed C‐7 Selective NH2 Amination of Indoles

Zhan‐Lin Wang, Jin‐Kai Cheng and Fei Wang

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202412103

Iron‐Catalysed Direct Aromatic Amination withN‐Chloroamines

Gayle E. Douglas, Steven A. Raw and Stephen P. Marsden

Eur J Org Chem, 2019, 2019, 5508
DOI: 10.1002/ejoc.201900614

Visible-Light-Mediated β-C(sp3)–H Amination of Glycosylimidates: En Route to Oxazoline-Fused/Spiro Nonclassical Bicyclic Sugars

Mukta Shaw and Amit Kumar

Org. Lett., 2019, 21, 3108
DOI: 10.1021/acs.orglett.9b00763

Metal‐Free Oxidative C−H Amination of 8‐Acylaminoquinolines and Anilides with N‐Fluorobenzenesulfonimide

Yang Wang, Ying Wang, Zhenyu Guo, Qian Zhang and Dong Li

Asian J Org Chem, 2016, 5, 1438
DOI: 10.1002/ajoc.201600389

Cu-Catalyzed Oxyalkynylation and Aminoalkynylation of Unactivated Alkenes: Synthesis of Alkynyl-Featured Isoxazolines and Cyclic Nitrones

Wen-Jun Han, Yuan-Rui Wang, Jian-Wu Zhang, Fei Chen, Bo Zhou and Bing Han

Org. Lett., 2018, 20, 2960
DOI: 10.1021/acs.orglett.8b01004

Formylation of Fluoroalkyl Imines through Visible-Light-Enabled H-Atom Transfer Catalysis: Access to Fluorinated α-Amino Aldehydes

Sen Yang, Shuangyu Zhu, Dengfu Lu and Yuefa Gong

Org. Lett., 2019, 21, 2019
DOI: 10.1021/acs.orglett.9b00128

Quinazolinones/Benzothiadiazines as Amidyl/Aminyl Radical Precursors for Controlled Cascade Cyclization via Photocatalyzed PCET

Mandapati Bhargava Reddy, Kesavan Prasanth, Nalladhambi Neerathilingam and Ramasamy Anandhan

Org. Lett., 2022, 24, 8158
DOI: 10.1021/acs.orglett.2c03222

Photo‐Induced Oxyamination of Alkenyl Acids towards Amino Lactones

Changduo Pan, Dongdong Chen, Miao Zeng, Haoyang Tian and Jin‐Tao Yu

Eur J Org Chem, 2023, 26
DOI: 10.1002/ejoc.202301065

Cu-Catalyzed Radical Cascade Annulations of Alkyne-Tethered N-Alkoxyamides with Air: Facile Access to Isoxazolidine/1,2-Oxazinane-Fused Isoquinolin-1(2H)-ones

Fei Chen, Sheng-Qiang Lai, Fei-Fei Zhu, Qiang Meng, Yu Jiang, Wei Yu and Bing Han

ACS Catal., 2018, 8, 8925
DOI: 10.1021/acscatal.8b02445

A Green Approach: Vicinal Oxidative Electrochemical Alkene Difunctionalization

Guilherme M. Martins, Bahareh Shirinfar, Tomas Hardwick and Nisar Ahmed

ChemElectroChem, 2019, 6, 1300
DOI: 10.1002/celc.201801466

Hypervalent Iodine Reagents Enable C(sp2)–H Amidation of (Hetero)arenes with Iminophenylacetic Acids

Yue Pan, Zhengyi Liu, Peng Zou, Yali Chen and Yiyun Chen

Org. Lett., 2022, 24, 6681
DOI: 10.1021/acs.orglett.2c02751

Merging Photochemical Olefin Metathesis with an Amination Reaction

Biprajit Paul, Surajit Das, Sanat Kumar Mahapatra, Lisa Roy and Indranil Chatterjee

ACS Catal., 2025, 13810
DOI: 10.1021/acscatal.5c03952

Metal‐Free Synthesis of (E)‐Vinyl Sulfones via An Insertion of Sulfur Dioxide/1,5‐Hydrogen Atom Transfer Sequence

Fu‐Sheng He, Yanfang Yao, Wenlin Xie and Jie Wu

Adv Synth Catal, 2020, 362, 4744
DOI: 10.1002/adsc.202000778

Iminoxyl Radical-Promoted Oxycyanation and Aminocyanation of Unactivated Alkenes: Synthesis of Cyano-Featured Isoxazolines and Cyclic Nitrones

Fei Chen, Fei-Fei Zhu, Man Zhang, Rui-Hua Liu, Wei Yu and Bing Han

Org. Lett., 2017, 19, 3255
DOI: 10.1021/acs.orglett.7b00826

Cyclic Amine Synthesis via Catalytic Radical‐Polar Crossover Cycloadditions

Ying Zhang, Shu‐Sheng Chen, Kai‐Dian Li and Huan‐Ming Huang

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202401671

Visible‐Light‐Induced C4‐Selective Functionalization of Pyridinium Salts with Cyclopropanols

Mari Vellakkaran, Taehwan Kim and Sungwoo Hong

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202113658

Aminoacylation of Alkenes by Cooperative NHC and Photoredox Catalysis

Lena Lezius, Jannik Reimler, Nadine Döben, Michael Hamm, Constantin G. Daniliuc and Armido Studer

Synlett, 2024, 35, 445
DOI: 10.1055/a-2145-8697

Cobalt‐Catalyzed Radical Hydroamination of Alkenes with N‐Fluorobenzenesulfonimides

Tao Qin, Guowei Lv, Qi Meng, Ge Zhang, Tao Xiong and Qian Zhang

Angew Chem Int Ed, 2021, 60, 25949
DOI: 10.1002/anie.202110178

Visible‐Light‐Mediated 5‐exo‐dig Cyclizations of Amidyl Radicals

Daniel Fernandez Reina, Elizabeth M. Dauncey, Sara P. Morcillo, Thomas D. Svejstrup, Mihai V. Popescu, James J. Douglas, Nadeem S. Sheikh and Daniele Leonori

Eur J Org Chem, 2017, 2017, 2108
DOI: 10.1002/ejoc.201601607

Organonitrogen Chemicals from Oxygen-Containing Feedstock over Heterogeneous Catalysts

Yunzhu Wang, Shinya Furukawa, Xinpu Fu and Ning Yan

ACS Catal., 2020, 10, 311
DOI: 10.1021/acscatal.9b03744

Visible-Light Photoredox-Catalyzed Iminyl Radical Formation by N–H Cleavage with Hydrogen Release and Its Application in Synthesis of Isoquinolines

Wan-Fa Tian, Dang-Po Wang, Shao-Feng Wang, Ke-Han He, Xiao-Ping Cao and Yang Li

Org. Lett., 2018, 20, 1421
DOI: 10.1021/acs.orglett.8b00193

A Single Electron Transfer (SET) Approach to C–H Amidation of Hydrazones via Visible-Light Photoredox Catalysis

Muliang Zhang, Yingqian Duan, Weipeng Li, Pan Xu, Jian Cheng, Shouyun Yu and Chengjian Zhu

Org. Lett., 2016, 18, 5356
DOI: 10.1021/acs.orglett.6b02711

Photoredox‐Catalyzed Metal‐Free Regio‐ & Stereoselective C(sp2)–H Amination of Enamides with N‐Aminopyridium Salts

Zheng‐Bao Qin, Kun Ni, Li Wang, Xiao‐Di Wu, Yu Zhang and Kai Zhao

Chin. J. Chem., 2024, 42, 2235
DOI: 10.1002/cjoc.202400350

Copper-Catalyzed Radical Aminotrifluoromethylation of Alkenes

Haiwen Xiao, Haigen Shen, Lin Zhu and Chaozhong Li

J. Am. Chem. Soc., 2019, 141, 11440
DOI: 10.1021/jacs.9b06141

Integrating Olefin Carboamination and Hofmann‐Löffler‐Freytag Reaction by Radical Deconstruction of Hydrazonyl N−N Bond

Si‐Pei Hu, Chen‐Hui Gao, Tu‐Ming Liu, Bing‐Yang Miao, Hong‐Chen Wang, Wei Yu and Bing Han

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202400168

Stereoselective synthesis of tetra- and tri-substituted alkenyl nitriles via aminative ring-opening of cyclopropenes with iron-aminyl radical

Qian Wang, Jin-Kai Cheng, Shi-Xiong Tang, Kendall N. Houk and Fei Wang

Nat Commun, 2025, 16
DOI: 10.1038/s41467-025-58555-2

Synthesis and theoretical study of pyrrole formiate derivatives through ring contraction of 1,4-dihydropyridines

Qiangwen Fan, Runzhi Sun, Zhichang Zhao and Hong Yan

Tetrahedron, 2018, 74, 7457
DOI: 10.1016/j.tet.2018.11.021

N–O Bond Activation by Energy Transfer Photocatalysis

Da Seul Lee, Vineet Kumar Soni and Eun Jin Cho

Acc. Chem. Res., 2022, 55, 2526
DOI: 10.1021/acs.accounts.2c00444

(Diacetoxy)iodobenzene-Mediated Regioselective Imidation of Imidazoheterocycles with N-Fluorobenzenesulfonimide

Mukta Singsardar, Susmita Mondal, Rajib Sarkar and Alakananda Hajra

ACS Omega, 2018, 3, 12505
DOI: 10.1021/acsomega.8b02088

Radical C−H‐Amination of Heteroarenes using Dual Initiation by Visible Light and Iodine

Nicola Lucchetti, Anastasia Tkacheva, Serena Fantasia and Kilian Muñiz

Adv Synth Catal, 2018, 360, 3889
DOI: 10.1002/adsc.201800677

Pyrroline Synthesis via Visible‐Light‐Promoted Hydroimination of Unactivated Alkenes with N,N′‐Dimethylpropylene Urea as H‐Donor

Sai‐Hu Cai, Ding‐Xing Wang, Lu Ye, Ze‐Yao Liu, Chao Feng and Teck‐Peng Loh

Adv Synth Catal, 2018, 360, 1262
DOI: 10.1002/adsc.201700937

β-Selective Cu(II)-Catalyzed Dehydrogenative Enamination of Alkylbenzenes

Jian-Guo Zhao and Dong-Hui Wang

Org. Lett., 2020, 22, 9473
DOI: 10.1021/acs.orglett.0c03430

Nitrene Transfer and Carbene Transfer in Gold Catalysis

Long-Wu Ye, Xin-Qi Zhu, Rajkumar Lalji Sahani, Yin Xu, Peng-Cheng Qian and Rai-Shung Liu

Chem. Rev., 2021, 121, 9039
DOI: 10.1021/acs.chemrev.0c00348

Organic Dye-Catalyzed, Visible-Light Photoredox Bromination of Arenes and Heteroarenes Using N-Bromosuccinimide

David A. Rogers, Roxanne G. Brown, Zachary C. Brandeburg, Eric Y. Ko, Megan D. Hopkins, Gabriel LeBlanc and Angus A. Lamar

ACS Omega, 2018, 3, 12868
DOI: 10.1021/acsomega.8b02320

Cyclic Amine Synthesis via Catalytic Radical‐Polar Crossover Cycloadditions

Ying Zhang, Shu‐Sheng Chen, Kai‐Dian Li and Huan‐Ming Huang

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202401671

Visible-Light-Induced Copper-Catalyzed Intermolecular Markovnikov Hydroamination of Alkenes

Yang Xiong and Guozhu Zhang

Org. Lett., 2019, 21, 7873
DOI: 10.1021/acs.orglett.9b02863

Electrophilic Aminating Agents in Total Synthesis

Lauren G. O'Neil and John F. Bower

Angew Chem Int Ed, 2021, 60, 25640
DOI: 10.1002/anie.202102864

Visible‐Light‐Induced 1,3‐Aminopyridylation of [1.1.1]Propellane with N‐Aminopyridinium Salts

Sanghoon Shin, Seojin Lee, Wonjun Choi, Namhoon Kim and Sungwoo Hong

Angewandte Chemie, 2021, 133, 7952
DOI: 10.1002/ange.202016156

Fixation of carbon dioxide to aryl/aromatic carboxylic acids

Ashutosh Rawat, Sonu Dhakla, Prem Lama and Tapan K. Pal

Journal of CO2 Utilization, 2022, 59, 101939
DOI: 10.1016/j.jcou.2022.101939

Visible light promoted synthesis of 2-amino sugar analogues from glycals and N-aminopyridinium salts

Yanzhen Chen, Chunyan Shu, Jin-Bu Xu, Feng Gao, Zongrui Hou and Xiaohuan Li

Tetrahedron, 2024, 163, 134144
DOI: 10.1016/j.tet.2024.134144

Sulfamyl Radicals Direct Photoredox-Mediated Giese Reactions at Unactivated C(3)–H Bonds

Anastasia L. G. Kanegusuku, Thomas Castanheiro, Suraj K. Ayer and Jennifer L. Roizen

Org. Lett., 2019, 21, 6089
DOI: 10.1021/acs.orglett.9b02234

Formation Mechanisms of Nitro Products from Transformation of Aliphatic Amines by UV/Chlorine Treatment

Zhechao Hua, Jieying Liang, Ding Wang, Zhihong Zhou and Jingyun Fang

Environ. Sci. Technol., 2023, 57, 18754
DOI: 10.1021/acs.est.3c00744

Remote Radical Azidation of Unactivated C(sp3)–H Bonds in Sulfamoyl Azides

Jiawei Li, Sishi Zhong, Pan Zhou, Xu Li, Danyang Xie, Yunfei Cai and Yong Xia

Org. Lett., 2024, 26, 3519
DOI: 10.1021/acs.orglett.4c00862

Carboamination of Unactivated Alkenes through Three‐Component Radical Conjugate Addition

Heng Jiang, Gesa Seidler and Armido Studer

Angewandte Chemie, 2019, 131, 16680
DOI: 10.1002/ange.201910926

Directed Copper-Catalyzed Intermolecular Aminative Difunctionalization of Unactivated Alkenes

Yang Li, Yujie Liang, Junchao Dong, Yi Deng, Chunyang Zhao, Zhongmin Su, Wei Guan, Xihe Bi, Qun Liu and Junkai Fu

J. Am. Chem. Soc., 2019, 141, 18475
DOI: 10.1021/jacs.9b07607

Using a nitrogen-centered radical as a selective mediator in electrochemical C(sp3)-H amination

Yating Liang, Xuan Zhan, Fengyi Li, Hong Bi, Weigang Fan, Sheng Zhang and Man-Bo Li

Chem Catalysis, 2023, 3, 100582
DOI: 10.1016/j.checat.2023.100582

Carbon nitride photocatalyzes regioselective aminium radical addition to the carbonyl bond and yields N-fused pyrroles

Bogdan Kurpil, Katharina Otte, Artem Mishchenko, Paolo Lamagni, Wojciech Lipiński, Nina Lock, Markus Antonietti and Aleksandr Savateev

Nat Commun, 2019, 10
DOI: 10.1038/s41467-019-08652-w

Free radicals for cancer theranostics

Xiao-Qiang Wang, Wenjing Wang, Mengyun Peng and Xian-Zheng Zhang

Biomaterials, 2021, 266, 120474
DOI: 10.1016/j.biomaterials.2020.120474

Alkoxy Radicals See the Light: New Paradigms of Photochemical Synthesis

Liang Chang, Qing An, Lingfei Duan, Kaixuan Feng and Zhiwei Zuo

Chem. Rev., 2022, 122, 2429
DOI: 10.1021/acs.chemrev.1c00256

Multimodal Reactivity of N–H Bonds in Triazanes and Isolation of a Triazinyl Radical

Aleksandr Koronatov, Assaf Mauda, Boris Tumansky, Alexander Kaushansky, Natalia Fridman, Dmitry Bravo-Zhivotovskii and Mark Gandelman

J. Am. Chem. Soc., 2022, 144, 23642
DOI: 10.1021/jacs.2c11113

The Highly Regioselective Halogenation of N‐(8‐quinolinyl)amides on the C‐5 Position with Cuprous Halides Under Mild Conditions

Junshuai Ding, Wanru Li, Kaiqi Ye and Jizhen Li

ChemistrySelect, 2016, 1, 5874
DOI: 10.1002/slct.201601108

Pyrimidopteridine-Catalyzed Hydroamination of Stilbenes with Primary Amines: A Dual Photoredox and Hydrogen Atom Transfer Catalyst

Tobias Taeufer, Richy Hauptmann, Firas El-Hage, Thea S. Mayer, Haijun Jiao, Jabor Rabeah and Jola Pospech

ACS Catal., 2021, 11, 4862
DOI: 10.1021/acscatal.0c05540

Exploiting Iminoquinones as Electrophilic at Nitrogen “N+” Synthons for C–N Bond Construction

Luis M. Mori-Quiroz, Chelsea G. Comadoll, Jonathan E. Super and Michael D. Clift

Org. Lett., 2021, 23, 7008
DOI: 10.1021/acs.orglett.1c00867

Highly Diastereoselective Synthesis of γ-Lactams Enabled by Photoinduced Deaminative [3 + 2] Annulation Reaction

Chengcheng Shi, Lin Guo, Han Gao, Mengqi Luo, Chao Yang and Wujiong Xia

Org. Lett., 2022, 24, 4365
DOI: 10.1021/acs.orglett.2c01565

Hydroamination of Unactivated Alkenes with Aliphatic Azides

Si-Ming Jia, Yi-Hang Huang, Zhan-Lin Wang, Fang-Xu Fan, Bo-Han Fan, Hao-Xiang Sun, Hao Wang and Fei Wang

J. Am. Chem. Soc., 2022, 144, 16316
DOI: 10.1021/jacs.2c07643

1,4-Fluoroamination of 1,3-Enynes en Route to Fluorinated Allenes

Qi Zhang, Munira Taj Muhammad, Mong-Feng Chiou, Yihang Jiao, Hongli Bao and Yajun Li

Org. Lett., 2020, 22, 5261
DOI: 10.1021/acs.orglett.0c01953

Catalytic Alkene Difunctionalization via Imidate Radicals

Kohki M. Nakafuku, Stacy C. Fosu and David A. Nagib

J. Am. Chem. Soc., 2018, 140, 11202
DOI: 10.1021/jacs.8b07578

Visible-Light-Driven C–H Imidation of Arenes and Heteroarenes by a Phosphonium Ylide Organophotoredox Catalyst: Application to C–H Functionalization of Alkenes

Yasunori Toda, Toya Kobayashi, Fumiya Hirai, Takamichi Yano, Makoto Oikawa, Kimiya Sukegawa, Masahiro Shimizu, Fuyuki Ito and Hiroyuki Suga

J. Org. Chem., 2023, 88, 9574
DOI: 10.1021/acs.joc.3c00988

Synthesis of Halomethyl Isoxazoles/Cyclic Nitrones via Cascade Sequence: 1,2-Halogen Radical Shift as a Key Link

Hong-Lei Chen, Dian Wei, Jian-Wu Zhang, Cheng-Lin Li, Wei Yu and Bing Han

Org. Lett., 2018, 20, 2906
DOI: 10.1021/acs.orglett.8b00967

Electrochemical generation of nitrogen-centered radicals for organic synthesis

Na Chen and Hai-Chao Xu

Green Synthesis and Catalysis, 2021, 2, 165
DOI: 10.1016/j.gresc.2021.03.002

Visible‐Light‐Induced Direct Oxidative C−H Amidation of Heteroarenes with Sulfonamides

Kun Tong, Xiaodong Liu, Yan Zhang and Shouyun Yu

Chemistry A European J, 2016, 22, 15669
DOI: 10.1002/chem.201604014

Controllable Remote C−H Bond Functionalization by Visible‐Light Photocatalysis

Xiao‐Qiang Hu, Jia‐Rong Chen and Wen‐Jing Xiao

Angew Chem Int Ed, 2017, 56, 1960
DOI: 10.1002/anie.201611463

Neutral Stable Nitrogen‐Centered Radicals: Structure, Properties, and Recent Functional Application Progress

Shengxiang Gao and Feng Li

Adv Funct Materials, 2023, 33
DOI: 10.1002/adfm.202304291

Olefin Oxyamination with Unfunctionalized N‐Alkylanilines

Shuang Gao and Meike Niggemann

Adv Synth Catal, 2019, 361, 1549
DOI: 10.1002/adsc.201801407

Construction of Bidentate Phosphines Enabled by Photoinduced Reductive Diphosphination of Alkenes

Hongchi Liu and Hanmin Huang

Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202304109

Modular synthesis of unsaturated aza-heterocycles via copper catalyzed multicomponent cascade reaction

Siqi Wei, Guocong Zhang, Yahui Wang, Mengwei You, Yanan Wang, Liejin Zhou and Zuxiao Zhang

iScience, 2023, 26, 106137
DOI: 10.1016/j.isci.2023.106137

Electrochemically Enabled C3-Formylation and -Acylation of Indoles with Aldehydes

Liquan Yang, Zhaoran Liu, Yujun Li, Ning Lei, Yanling Shen and Ke Zheng

Org. Lett., 2019, 21, 7702
DOI: 10.1021/acs.orglett.9b02433

A Systematic Evaluation of the N–F Bond Strength of Electrophilic N–F Reagents: Hints for Atomic Fluorine Donating Ability

Jin-Dong Yang, Ya Wang, Xiao-Song Xue and Jin-Pei Cheng

J. Org. Chem., 2017, 82, 4129
DOI: 10.1021/acs.joc.7b00036

α‐Aminoxy‐Acid‐Auxiliary‐Enabled Intermolecular Radical γ‐C(sp3)−H Functionalization of Ketones

Heng Jiang and Armido Studer

Angewandte Chemie, 2018, 130, 1708
DOI: 10.1002/ange.201712066

Enantioconvergent Amination of Racemic Tertiary C–H Bonds

Kai Lang, Chaoqun Li, Isaac Kim and X. Peter Zhang

J. Am. Chem. Soc., 2020, 142, 20902
DOI: 10.1021/jacs.0c11103

Transition-metal free C–N bond formation from alkyl iodides and diazonium salts via halogen-atom transfer

Jing Zhang, Min Jiang, Chang-Sheng Wang, Kai Guo, Quan-Xin Li, Cheng Ma, Shao-Fei Ni, Gen-Qiang Chen, Yan Zong, Hua Lu, Li-Wen Xu and Xinxin Shao

Nat Commun, 2022, 13
DOI: 10.1038/s41467-022-35613-7

Divergent regioselective Heck-type reaction of unactivated alkenes and N-fluoro-sulfonamides

Chunyang Zhao, Yang Li, Yujiao Dong, Miao Li, Dan Xia, Shuangqiu Gao, Qian Zhang, Qun Liu, Wei Guan and Junkai Fu

Nat Commun, 2022, 13
DOI: 10.1038/s41467-022-33996-1

Cathode Material Determines Product Selectivity for Electrochemical C−H Functionalization of Biaryl Ketoximes

Huai‐Bo Zhao, Pin Xu, Jinshuai Song and Hai‐Chao Xu

Angew Chem Int Ed, 2018, 57, 15153
DOI: 10.1002/anie.201809679

Hypervalent iodine mediated oxidative radical amination of heteroarenes under metal-free conditions

Feng Zhao, Ting Sun, Hefeng Sun, Gaolei Xi and Kai Sun

Tetrahedron Letters, 2017, 58, 3132
DOI: 10.1016/j.tetlet.2017.06.081

Heteroannulation of N-Fluoro-N-alkylsulfonamides with Terminal Alkynes via Remote C(sp3)–H Functionalization

Long-Jin Zhong, Yang Li, De-Lie An and Jin-Heng Li

ACS Catal., 2021, 11, 383
DOI: 10.1021/acscatal.0c03853

Controlled Relay Process to Access N-Centered Radicals for Catalyst-free Amidation of Aldehydes under Visible Light

Wongyu Lee, Hyun Ji Jeon, Hoimin Jung, Dongwook Kim, Sangwon Seo and Sukbok Chang

Chem, 2021, 7, 495
DOI: 10.1016/j.chempr.2020.12.004

Is the Electrophilicity of the Metal Nitrene the Sole Predictor of Metal-Mediated Nitrene Transfer to Olefins? Secondary Contributing Factors as Revealed by a Library of High-Spin Co(II) Reagents

Anshika Kalra, Vivek Bagchi, Patrina Paraskevopoulou, Purak Das, Lin Ai, Yiannis Sanakis, Grigorios Raptopoulos, Sudip Mohapatra, Amitava Choudhury, Zhicheng Sun, Thomas R. Cundari and Pericles Stavropoulos

Organometallics, 2021, 40, 1974
DOI: 10.1021/acs.organomet.1c00267

Metal‐to‐Ligand Ratio‐Dependent Chemodivergent Asymmetric Synthesis

Min Zheng, Ke Gao, Haitao Qin, Guigen Li and Hongjian Lu

Angew Chem Int Ed, 2021, 60, 22892
DOI: 10.1002/anie.202108617

Alternative and Sustainable Route to Explore a New Class of Amidines by Photochemical Synergistic Effect of Copper/Nitroxyl Radical Catalysis via Halogen‐Atom Transfer

Chandrasekaran Sivaraj and Thirumanavelan Gandhi

Chemistry A European J, 2025, 31
DOI: 10.1002/chem.202404599

Visible‐Light‐Induced C4‐Selective Functionalization of Pyridinium Salts with Cyclopropanols

Mari Vellakkaran, Taehwan Kim and Sungwoo Hong

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202113658

Selective Radical N−H Activation: the Unprecedented Harnessing of Formamide with S8 for N−S−N Bonds Construction

Xiang Yu, Yu Chen, Qian Luo, Yufei Li, Peng Dai, Qing Xia, Fang Liu and Wei‐Hua Zhang

Asian J Org Chem, 2021, 10, 771
DOI: 10.1002/ajoc.202000692

Copper‐Catalyzed Radical Cross‐Coupling of Redox‐Active Oxime Esters, Styrenes, and Boronic Acids

Xiao‐Ye Yu, Quan‐Qing Zhao, Jun Chen, Jia‐Rong Chen and Wen‐Jing Xiao

Angew Chem Int Ed, 2018, 57, 15505
DOI: 10.1002/anie.201809820

DFT Mechanistic Account for the Site Selectivity of Electron-Rich C(sp3)–H Bond in the Manganese-Catalyzed Aminations

Zheyuan Liu, Yu Lu, Jiandong Guo, Wenping Hu, Yanfeng Dang and Zhi-Xiang Wang

Org. Lett., 2020, 22, 453
DOI: 10.1021/acs.orglett.9b04215

Cobalt-Catalyzed Divergent Aminofluorination and Diamination of Styrenes with N-Fluorosulfonamides

Peng Guo, Jun-Fa Han, Guo-Cai Yuan, Lin Chen, Jia-Bin Liao and Ke-Yin Ye

Org. Lett., 2021, 23, 4067
DOI: 10.1021/acs.orglett.1c01308

Chemistry with Electrochemically Generated N-Centered Radicals

Peng Xiong and Hai-Chao Xu

Acc. Chem. Res., 2019, 52, 3339
DOI: 10.1021/acs.accounts.9b00472

ChemInform Abstract: New Amination Strategies Based on Nitrogen‐Centered Radical Chemistry

Tao Xiong and Qian Zhang

ChemInform, 2016, 47
DOI: 10.1002/chin.201630264

Radical philicity and its role in selective organic transformations

Faeze Parsaee, Milinda C. Senarathna, Prashansa B. Kannangara, Shevon N. Alexander, Phillip Damien E. Arche and Eric R. Welin

Nat Rev Chem, 2021, 5, 486
DOI: 10.1038/s41570-021-00284-3

Recent advances in amidyl radical-mediated photocatalytic direct intermolecular hydrogen atom transfer

Hao-Sen Wang, Lin Li, Xin Chen, Jian-Li Wu, Kai Sun, Xiao-Lan Chen, Ling-Bo Qu and Bing Yu

Beilstein J. Org. Chem., 2025, 21, 1306
DOI: 10.3762/bjoc.21.100

Visible‐Light‐Mediated Nitrogen‐Centered Radical Strategy: Preparation of 3‐Acylated Spiro[4,5]trienones

Pu Chen, Jun Xie, Zan Chen, Bi‐Quan Xiong, Yu Liu, Chang‐An Yang and Ke‐Wen Tang

Adv Synth Catal, 2021, 363, 4440
DOI: 10.1002/adsc.202100852

Visible‐Light‐Catalyzed N‐Radical‐Enabled Cyclization of Alkenes for the Synthesis of Five‐Membered N‐Heterocycles

Hui‐Zhi Wang, Jiao‐Zhe Li, Zhiyong Guo, Hongxing Zheng and Wen‐Ting Wei

ChemSusChem, 2021, 14, 4658
DOI: 10.1002/cssc.202101586

Copper-catalyzed amination of phenylboronic acids with benzofurazan 1-oxides

Manman Wang, Yunyun Li, Fen Wang and Xingwei Li

Chinese Journal of Catalysis, 2017, 38, 1842
DOI: 10.1016/S1872-2067(17)62914-0

Copper-Catalyzed Aerobic 6-Endo-Trig Cyclization of β,γ-Unsaturated Hydrazones for the Divergent Synthesis of Dihydropyridazines and Pyridazines

Zhenwei Fan, Zhangjin Pan, Liangsen Huang and Jiajia Cheng

J. Org. Chem., 2019, 84, 4236
DOI: 10.1021/acs.joc.9b00228

Copper‐Catalyzed Modular Access to N‐Fused Polycyclic Indoles and 5‐Aroyl‐pyrrol‐2‐ones via Intramolecular N—H/C—H Annulation with Alkynes: Scope and Mechanism Probes

Yan‐Hua Liu, Hong Song, Chi Zhang, Yue‐Jin Liu and Bing‐Feng Shi

Chin. J. Chem., 2020, 38, 1545
DOI: 10.1002/cjoc.202000246

Merging photoredox catalysis with transition metal catalysis: Direct C4-H amination of 8-hydroxyquinoline derivatives

Yueyue Ma, Yaqi Shi, Fan Yang, Yusheng Wu and Yangjie Wu

Tetrahedron, 2019, 75, 3904
DOI: 10.1016/j.tet.2019.06.006

Regioselective Intramolecular Allene Amidation Enabled by an EDA Complex**

Lu Liu, Robert M. Ward and Jennifer M. Schomaker

Chemistry A European J, 2020, 26, 13783
DOI: 10.1002/chem.202002533

Photoredox Radical Cascade Cyclization of 2‐Alkynylarylnitriles in Visible Light: Direct Access to 3‐Amino‐1‐indenones

Shruti Rajput, Dikshita Garg and Nidhi Jain

Adv Synth Catal, 2024, 366, 2072
DOI: 10.1002/adsc.202400026

Organophotoredox-Catalyzed Direct C–H Amination of 2H-Indazoles with Amines

Sukanya Neogi, Asim Kumar Ghosh, Koushik Majhi, Sadhanendu Samanta, Golam Kibriya and Alakananda Hajra

Org. Lett., 2020, 22, 5605
DOI: 10.1021/acs.orglett.0c01973

Regioselective Radical Amino-Functionalizations of Allyl Alcohols via Dual Catalytic Cross-Coupling

Zuxiao Zhang, Duong T. Ngo and David A. Nagib

ACS Catal., 2021, 11, 3473
DOI: 10.1021/acscatal.1c00404

Amine-Controlled, Transition-Metal-Catalyzed Hydrodefluorination and Defluoroamination of Fluoroarenes with 8-Aminoquinoline as a Directing Group

Anjun Ding, Xiaoyong Liu, Ziyue Xu, Shiyu Lei, Wen Liu, Jie Jiang, Shunxin Li, Zhengjiang Fu, Shengmei Guo and Hu Cai

J. Org. Chem., 2025, 90, 9697
DOI: 10.1021/acs.joc.5c00361

Copper‐Catalyzed Arylation of Remote C(sp3)−H Bonds in Carboxamides and Sulfonamides

Zhaodong Li, Qian Wang and Jieping Zhu

Angew Chem Int Ed, 2018, 57, 13288
DOI: 10.1002/anie.201807623

Construction of Functional Superhydrophobic Biochars as Hydrogen Transfer Catalysts for Dehydrogenation of N-Heterocycles

Shaofeng Pang, Fangfang Liu, Yujing Zhang, Zhaowen Dong, Qiong Su, Wenfang Wang, Zhenhua Li, Feng Zhou and Yanbin Wang

ACS Sustainable Chem. Eng., 2021, 9, 9062
DOI: 10.1021/acssuschemeng.1c02322

Metallaphotoredox-enabled aminocarboxylation of alkenes with CO2

Jun-Ping Yue, Jin-Cheng Xu, Hai-Tian Luo, Xiao-Wang Chen, He-Xin Song, Yu Deng, Lihua Yuan, Jian-Heng Ye and Da-Gang Yu

Nat Catal, 2023, 6, 959
DOI: 10.1038/s41929-023-01029-9

(Diacetoxy)iodobenzene-Mediated Oxidative C–H Amination of Imidazopyridines at Ambient Temperature

Susmita Mondal, Sadhanendu Samanta, Sourav Jana and Alakananda Hajra

J. Org. Chem., 2017, 82, 4504
DOI: 10.1021/acs.joc.7b00564

Iron‐catalyzed C‐7 Selective NH2 Amination of Indoles

Zhan‐Lin Wang, Jin‐Kai Cheng and Fei Wang

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202412103

Detection of the Elusive Nitrogen‐Centered Radicals from Catalytic Hofmann–Löffler Reactions

Alexandra E. Bosnidou, Thomas Duhamel and Kilian Muñiz

Eur J Org Chem, 2020, 2020, 6361
DOI: 10.1002/ejoc.201900497

Expedient Access to Structural Complexity via Radical β-Fragmentation of N–O Bonds

Xingheng Yang, Chi Zhang, Cheng-Qiang Wang and Chao Feng

Synlett, 2025, 36, 1135
DOI: 10.1055/a-2504-3639

Photoinduced α‐C−H Amination of Cyclic Amine Scaffolds Enabled by Polar‐Radical Relay

Wongyu Lee, Dongwook Kim, Sangwon Seo and Sukbok Chang

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202202971

Photocatalysis with organic dyes: facile access to reactive intermediates for synthesis

Stephanie G E Amos, Marion Garreau, Luca Buzzetti and Jerome Waser

Beilstein J. Org. Chem., 2020, 16, 1163
DOI: 10.3762/bjoc.16.103

Introducing Phenalenyl-Based Organic Lewis Acid as a Photocatalyst to Facilitate Oxidative Azolation of Unactivated Arenes

Partha Pratim Sen and Sudipta Raha Roy

Org. Lett., 2023, 25, 1895
DOI: 10.1021/acs.orglett.3c00409

Three-component aminofluorination of alkenes with electronically rich amino sources

Yang Li, Jiamin Bao, Yu Zhang, Xue Peng, Weijie Yu, Tao Wang, Dengtao Yang, Qun Liu, Qian Zhang and Junkai Fu

Chem, 2022, 8, 1147
DOI: 10.1016/j.chempr.2022.02.014

Copper-Catalyzed Amide Radical-Directed Cyanation of Unactivated Csp3–H Bonds

Hongwei Zhang, Yulu Zhou, Peiyuan Tian and Cuiyu Jiang

Org. Lett., 2019, 21, 1921
DOI: 10.1021/acs.orglett.9b00553

Visible-Light-Promoted Xanthate-Transfer Cyclization Reactions of Unactivated Olefins under Photocatalyst- and Additive-Free Conditions

Tongyao Zhou, Hang Chen, Yang Liu, Haifeng Wang, Qiongjiao Yan, Wei Wang and Fener Chen

J. Org. Chem., 2022, 87, 15582
DOI: 10.1021/acs.joc.2c02113

Amidyl Radicals by Oxidation of α‐Amido‐oxy Acids: Transition‐Metal‐Free Amidofluorination of Unactivated Alkenes

Heng Jiang and Armido Studer

Angewandte Chemie, 2018, 130, 10867
DOI: 10.1002/ange.201804966

Enantioconvergent Radical–Radical Cross-Coupling via Magnesium-Mediated Charge-Transfer Photocatalysis

Lei Yan, Hui-Qing Yang, Wan-Lei Yu, Xu-Gang Zhang and Peng-Fei Xu

J. Am. Chem. Soc., 2025, 147, 25264
DOI: 10.1021/jacs.5c03154

Electrochemically Enabled Intramolecular Aminooxygenation of Alkynes via Amidyl Radical Cyclization

Zhong‐Wei Hou and Hai‐Chao Xu

Chin. J. Chem., 2020, 38, 394
DOI: 10.1002/cjoc.201900500

Coordinatively Unsaturated Amidotitanocene Cations with Inverted σ and π Bond Strengths: Controlled Release of Aminyl Radicals and Hydrogenation/Dehydrogenation Catalysis

Quentin Bonnin, Tereza Edlová, E. Daiann Sosa Carrizo, Paul Fleurat‐Lessard, Stéphane Brandès, Hélène Cattey, Philippe Richard, Pierre Le Gendre and Adrien T. Normand

Chemistry A European J, 2021, 27, 18175
DOI: 10.1002/chem.202103487

Electrochemical C−H Amidation of Heteroarenes with N‐Alkyl Sulfonamides in Aqueous Medium

Yan Zhang, Zhipeng Lin and Lutz Ackermann

Chemistry A European J, 2021, 27, 242
DOI: 10.1002/chem.202004229

N-Chloro-N-sodio-carbamates as a Practical Amidating Reagent for Scalable and Sustainable Amidation of Aldehydes under Visible Light

Hyun Ji Jeon, Wongyu Lee, Sangwon Seo and Sukbok Chang

Org. Process Res. Dev., 2021, 25, 1176
DOI: 10.1021/acs.oprd.1c00054

A Visible‐Light‐Driven Iminyl Radical‐Mediated C−C Single Bond Cleavage/Radical Addition Cascade of Oxime Esters

Xiao‐Ye Yu, Jia‐Rong Chen, Peng‐Zi Wang, Meng‐Nan Yang, Dong Liang and Wen‐Jing Xiao

Angew Chem Int Ed, 2018, 57, 738
DOI: 10.1002/anie.201710618

An Expanded SET Model Associated with the Functional Hindrance Dominates the Amide-Directed Distal sp3 C–H Functionalization

Juanjuan Wang, Wei-Hai Fang, Ling-Bo Qu, Lin Shen, Feliu Maseras and Xuebo Chen

J. Am. Chem. Soc., 2021, 143, 19406
DOI: 10.1021/jacs.1c07983

Preparation of Oxindoles via Visible‐Light‐Induced Amination/Cyclization of Arylacrylamides with Alkyl Amines

Yu‐Zhao Wang, Wu‐Jie Lin, Jian‐Yu Zou, Wei Yu and Xue‐Yuan Liu

Adv Synth Catal, 2020, 362, 3116
DOI: 10.1002/adsc.202000609

When Light Meets Nitrogen-Centered Radicals: From Reagents to Catalysts

Xiao-Ye Yu, Quan-Qing Zhao, Jun Chen, Wen-Jing Xiao and Jia-Rong Chen

Acc. Chem. Res., 2020, 53, 1066
DOI: 10.1021/acs.accounts.0c00090

Photochemical Generation of Nitrogen-Centered Amidyl, Hydrazonyl, and Imidyl Radicals: Methodology Developments and Catalytic Applications

Markus D. Kärkäs

ACS Catal., 2017, 7, 4999
DOI: 10.1021/acscatal.7b01385

Synthesis of Hypervalent Iodine(III) Reagents Containing a Transferable (Diarylmethylene)amino Group and Their Use in the Oxidative Amination of Silyl Ketene Acetals

Kensuke Kiyokawa, Daichi Okumatsu and Satoshi Minakata

Angewandte Chemie, 2019, 131, 8999
DOI: 10.1002/ange.201904971

Highly regioselective electrochemical oxidative 2,1-azolization of alkenes with azoles and nucleophiles

Yaqi Deng, Jian Xue, Xiang Wu and Shunying Liu

Chinese Chemical Letters, 2025, 36, 110822
DOI: 10.1016/j.cclet.2025.110822

Visible-Light-Driven Nitrogen Radical-Catalyzed [3 + 2] Cyclization of Vinylcyclopropanes and N-Tosyl Vinylaziridines with Alkenes

Quan-Qing Zhao, Xue-Song Zhou, Shuang-Hua Xu, Ya-Li Wu, Wen-Jing Xiao and Jia-Rong Chen

Org. Lett., 2020, 22, 2470
DOI: 10.1021/acs.orglett.0c00712

Microwave- and Thermally Promoted Iminyl Radical Cyclizations: A Versatile Method for the Synthesis of Functionalized Pyrrolines

Jatinder Singh, Tanner J. Nelson, Samuel A. Mansfield, Garrison A. Nickel, Yu Cai, Dakota D. Jones, Jeshurun E. Small, Daniel H. Ess and Steven L. Castle

J. Org. Chem., 2022, 87, 16250
DOI: 10.1021/acs.joc.2c01806

Synthesis of Phenanthridines through Iodine-Supported Intramolecular C–H Amination and Oxidation under Visible Light

Yan Gao, Yi Jing, Lixin Li, Jie Zhang, Xuenian Chen and Yan-Na Ma

J. Org. Chem., 2020, 85, 12187
DOI: 10.1021/acs.joc.0c01390

Solvent Controlled Transformation between Sulfonyl Hydrazides and Alkynes: Divergent Synthesis of Benzo[b]thiophene‐1,1‐dioxides and (E)‐β‐iodo Vinylsulfones

Yue Ma, Kun Wang, Dong Zhang and Peng Sun

Adv Synth Catal, 2019, 361, 597
DOI: 10.1002/adsc.201801258

Exploiting Imine Photochemistry for Masked N‐Centered Radical Reactivity

Daryl Staveness, James L. Collins, Rory C. McAtee and Corey R. J. Stephenson

Angewandte Chemie, 2019, 131, 19176
DOI: 10.1002/ange.201909492

Copper Promoted Regio‐ and Stereoselective Aminochlorination of Alkynes and Alkenes with NFSI

Weilin Wang, Lingyan Liu, Weixing Chang and Jing Li

Chemistry A European J, 2018, 24, 8542
DOI: 10.1002/chem.201801262

Kooperative Licht‐aktivierte Iod‐ und Photoredox‐Katalyse zur Aminierung von C‐H‐Bindungen

Peter Becker, Thomas Duhamel, Christopher J. Stein, Markus Reiher and Kilian Muñiz

Angewandte Chemie, 2017, 129, 8117
DOI: 10.1002/ange.201703611

Copper-Mediated Radical Fluorine-Atom Transfer to Sulfonyl Radical: A Dramatic 4-Methoxypyridine 1-Oxide Ligand Effect

Hongwei Zhang, Xiaoxiao Sun, Cheng Ma, Chuang Li, Yuanyuan Ni, Ying Yu, Yuan-Qing Xu, Shao-Fei Ni and Zhong-Yan Cao

ACS Catal., 2024, 14, 3115
DOI: 10.1021/acscatal.3c05154

Electrochemical oxidation induced intermolecular aromatic C-H imidation

Xia Hu, Guoting Zhang, Lei Nie, Taige Kong and Aiwen Lei

Nat Commun, 2019, 10
DOI: 10.1038/s41467-019-13524-4

Pyridyl Radical Cation for C−H Amination of Arenes

Simon L. Rössler, Benson J. Jelier, Pascal F. Tripet, Andrej Shemet, Gunnar Jeschke, Antonio Togni and Erick M. Carreira

Angew Chem Int Ed, 2019, 58, 526
DOI: 10.1002/anie.201810261

Iodonitrene in Action: Direct Transformation of Amino Acids into Terminal Diazirines and 15N2-Diazirines and Their Application as Hyperpolarized Markers

Thomas Glachet, Hamid Marzag, Nathalie Saraiva Rosa, Johannes F. P. Colell, Guannan Zhang, Warren S. Warren, Xavier Franck, Thomas Theis and Vincent Reboul

J. Am. Chem. Soc., 2019, 141, 13689
DOI: 10.1021/jacs.9b07035

Radical Bicyclization of 2‐Cyanoaryl Acrylamides with Dicumyl Peroxide

Tai‐Gang Fan, Xue‐Ling Ding, Bo‐Xun Sun, Yu‐Jian Hou, Bo Jiang, Xu‐Nan Wang and Ya‐Min Li

Adv Synth Catal, 2023, 365, 579
DOI: 10.1002/adsc.202201368

Brønsted Base Assisted Photoredox Catalysis: Proton Coupled Electron Transfer for Remote C−C Bond Formation via Amidyl Radicals

Jiaqi Jia, Yee Ann Ho, Raoul F. Bülow and Magnus Rueping

Chemistry A European J, 2018, 24, 14054
DOI: 10.1002/chem.201802907

Eosin Y-Catalyzed Synthesis of 3-Aminoimidazo[1,2-a]Pyridines via the HAT Process under Visible Light through Formation of the C–N Bond

Himanshu Kumar Singh, Arsala Kamal, Savita Kumari, Dhirendra Kumar, Suresh Kumar Maury, Vandana Srivastava and Sundaram Singh

ACS Omega, 2020, 5, 29854
DOI: 10.1021/acsomega.0c03941

Visible-Light Photoredox-Catalyzed Formal [5 + 1] Cycloaddition of N-Tosyl Vinylaziridines with Difluoroalkyl Halides

Yantao Liu, Wen Luo, Zhenjie Wang, Yuxin Zhao, Jingjing Zhao, Xuejun Xu, Chaojie Wang and Pan Li

Org. Lett., 2020, 22, 9658
DOI: 10.1021/acs.orglett.0c03718

Cross‐Coupling of C−H and N−H Bonds: A Hydrogen Evolution Strategy for the Construction of C−N Bonds

Lekkala Ravindar, Siti Aishah Hasbullah, Nurul Izzaty Hassan and Hua‐Li Qin

Eur J Org Chem, 2022, 2022
DOI: 10.1002/ejoc.202200596

Visible-Light-Mediated Construction of Pyrroloindolines via an Amidyl Radical Cyclization/Carbon Radical Addition Cascade: Rapid Synthesis of (±)-Flustramide B

Kui Wu, Yuliu Du and Ting Wang

Org. Lett., 2017, 19, 5669
DOI: 10.1021/acs.orglett.7b02837

Silver-Mediated Indole (4 + 2) Dearomative Annulation with N-Radicals: A Strategy To Construct Heterocycle-Fused Indolines

Lin-Bao Zhang, Ming-Hui Zhu, Shao-Fei Ni, Li-Rong Wen and Ming Li

ACS Catal., 2019, 9, 1680
DOI: 10.1021/acscatal.8b04933

Direct C(sp3)–N Radical Coupling: Photocatalytic C–H Functionalization by Unconventional Intermolecular Hydrogen Atom Transfer to Aryl Radical

Jihee Kang, Ho Seong Hwang, Vineet Kumar Soni and Eun Jin Cho

Org. Lett., 2020, 22, 6112
DOI: 10.1021/acs.orglett.0c02179

A Visible‐Light‐Driven Iminyl Radical‐Mediated C−C Single Bond Cleavage/Radical Addition Cascade of Oxime Esters

Xiao‐Ye Yu, Jia‐Rong Chen, Peng‐Zi Wang, Meng‐Nan Yang, Dong Liang and Wen‐Jing Xiao

Angewandte Chemie, 2018, 130, 746
DOI: 10.1002/ange.201710618

Copper-Catalyzed Selective Amino-alkoxycarbonylation of Unactivated Alkenes with CO

Si-Shun Yan, Ralf Jackstell and Matthias Beller

J. Am. Chem. Soc., 2025, 147, 6464
DOI: 10.1021/jacs.4c13723

Transition-metal free trifluoromethylimination of alkenes enabled by direct activation of N-unprotected ketimines

Boqiang Wang, Yongzhuo Xu, Jiajia Wang, Muyang Yang, Guo-Jun Deng and Wen Shao

Chinese Chemical Letters, 2024, 35, 109502
DOI: 10.1016/j.cclet.2024.109502

N-Radical enabled cyclization of 1,n-enynes

Wen-Ting Wei, Qiang Li, Ming-Zhong Zhang and Wei-Min He

Chinese Journal of Catalysis, 2021, 42, 731
DOI: 10.1016/S1872-2067(20)63702-0

Photocatalysis in Dual Catalysis Systems for Carbon‐Nitrogen Bond Formation

Swati Singh, Vishal Jyoti Roy, Neha Dagar, Partha Pratim Sen and Sudipta Raha Roy

Adv Synth Catal, 2021, 363, 937
DOI: 10.1002/adsc.202001176

Comparative Nitrene-Transfer Chemistry to Olefinic Substrates Mediated by a Library of Anionic Mn(II) Triphenylamido-Amine Reagents and M(II) Congeners (M = Fe, Co, Ni) Favoring Aromatic over Aliphatic Alkenes

Vivek Bagchi, Anshika Kalra, Purak Das, Patrina Paraskevopoulou, Saidulu Gorla, Lin Ai, Qiuwen Wang, Sudip Mohapatra, Amitava Choudhury, Zhicheng Sun, Thomas R. Cundari and Pericles Stavropoulos

ACS Catal., 2018, 8, 9183
DOI: 10.1021/acscatal.8b01941

N-Radical Initiated Aminosulfonylation of Unactivated C(sp3)–H Bond through Insertion of Sulfur Dioxide

Yuewen Li, Runyu Mao and Jie Wu

Org. Lett., 2017, 19, 4472
DOI: 10.1021/acs.orglett.7b02010

Synthesis of Functionalized Nitriles by Microwave‐Promoted Fragmentations of Cyclic Iminyl Radicals

Mary M. Jackman, Siyeon Im, Seth R. Bohman, Concordia C. L. Lo, Amanda L. Garrity and Steven L. Castle

Chemistry A European J, 2018, 24, 594
DOI: 10.1002/chem.201705728

Chemistry With N-Centered Radicals Generated by Single-Electron Transfer-Oxidation Using Photoredox Catalysis

Heng Jiang and Armido Studer

CCS Chem, 2019, 1, 38
DOI: 10.31635/ccschem.019.20180026

Cooperative Light‐Activated Iodine and Photoredox Catalysis for the Amination of C−H Bonds

Peter Becker, Thomas Duhamel, Christopher J. Stein, Markus Reiher and Kilian Muñiz

Angew Chem Int Ed, 2017, 56, 8004
DOI: 10.1002/anie.201703611

De Novo Synthesis of Highly Functionalized Benzimidazolones and Benzoxazolones through an Electrochemical Dehydrogenative Cyclization Cascade

Fan Xu, Hao Long, Jinshuai Song and Hai‐Chao Xu

Angew Chem Int Ed, 2019, 58, 9017
DOI: 10.1002/anie.201904931

Coupling of N2 and O2 in the Gas Phase to Synthesize Nitric Oxide at Room Temperature: A Zeldovich-Like Strategy

Yong-Qi Ding, Zhi-Ying Chen, Feng-Xiang Zhang and Jia-Bi Ma

J. Phys. Chem. Lett., 2023, 14, 7597
DOI: 10.1021/acs.jpclett.3c01675

Photoredox‐Initiated 1,2‐Difunctionalization of Alkenes with N‐Chloro S‐Fluoroalkyl Sulfoximines

Alexis Prieto, Patrick Diter, Martial Toffano, Jérôme Hannedouche and Emmanuel Magnier

Adv Synth Catal, 2019, 361, 436
DOI: 10.1002/adsc.201801207

Generation of N-Centered Radicals via a Photocatalytic Energy Transfer: Remote Double Functionalization of Arenes Facilitated by Singlet Oxygen

Vineet Kumar Soni, Ho Seong Hwang, Yu Kyung Moon, Sung-Woo Park, Youngmin You and Eun Jin Cho

J. Am. Chem. Soc., 2019, 141, 10538
DOI: 10.1021/jacs.9b05572

Controllable synthesis of benzoxazinones and 2-hydroxy-3-indolinones by visible-light-promoted 5-endo-dig N-radical cyclization cascade

Tong-De Tan, Tong-Yi Zhai, Bin-Yang Liu, Long Li, Peng-Cheng Qian, Qing Sun, Jin-Mei Zhou and Long-Wu Ye

Cell Reports Physical Science, 2021, 2, 100577
DOI: 10.1016/j.xcrp.2021.100577

Visible-light-driven cyanoalkylation of quinoxalinones using cyclobutanone oxime esters as the radical precursors

Bin Zhao, Xianqiang Kong and Bo Xu

Tetrahedron Letters, 2019, 60, 2063
DOI: 10.1016/j.tetlet.2019.06.059

Pyridyl Radical Cation for C−H Amination of Arenes

Simon L. Rössler, Benson J. Jelier, Pascal F. Tripet, Andrej Shemet, Gunnar Jeschke, Antonio Togni and Erick M. Carreira

Angewandte Chemie, 2019, 131, 536
DOI: 10.1002/ange.201810261

Sulfoximidations of Benzylic C−H bonds by Photocatalysis

Han Wang, Duo Zhang and Carsten Bolm

Angew Chem Int Ed, 2018, 57, 5863
DOI: 10.1002/anie.201801660

Photolysis of N-chlorourea and its effect on urea removal in a combined pre-chlorination and UV254 process

Qian Yang, Yang Guo, Jie Xu, Xingyi Wu, Bingying He, Ernest R. Blatchley and Jing Li

Journal of Hazardous Materials, 2021, 411, 125111
DOI: 10.1016/j.jhazmat.2021.125111

Visible‐Light‐Induced 1,3‐Aminopyridylation of [1.1.1]Propellane with N‐Aminopyridinium Salts

Sanghoon Shin, Seojin Lee, Wonjun Choi, Namhoon Kim and Sungwoo Hong

Angew Chem Int Ed, 2021, 60, 7873
DOI: 10.1002/anie.202016156

Electronic and Structural Comparisons between Iron(II/III) and Ruthenium(II/III) Imide Analogs

Kelly E. Aldrich, B. Scott Fales, Amrendra K. Singh, Richard J. Staples, Benjamin G. Levine, John McCracken, Milton R. Smith and Aaron L. Odom

Inorg. Chem., 2019, 58, 11699
DOI: 10.1021/acs.inorgchem.9b01672

Generation of Aromatic N‐Heterocyclic Radicals for Functionalization of Unactivated Alkenes

Lu Wang, Minxu Shi, Xiaoping Chen, Nicholas Su, Weili Luo and Xiaheng Zhang

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202314312

Radical Alkene-Trifluoromethylation-Triggered Nitrile Insertion/Remote Functionalization Relay Processes: Diverse Synthesis of Trifluoromethylated Azaheterocycles Enabled by Copper Catalysis

Ji-Ming Xi, Yun-Hai Sun, Wen-Cheng Li, Yu-Heng Wu, Zhong-Lin Wei and Wei-Wei Liao

Org. Lett., 2022, 24, 1110
DOI: 10.1021/acs.orglett.2c00083

Facial Syntheses of Bromobenzothiazines via Catalyst-Free Tandem C–H Amination/Bromination in Water

Lixin Li, Yong Li, Zhengguang Zhao, Haotian Luo and Yan-Na Ma

Org. Lett., 2019, 21, 5995
DOI: 10.1021/acs.orglett.9b02131

Functionalization of C-H Bonds by Photoredox Catalysis

Qixue Qin, Heng Jiang, Zhentao Hu, Daan Ren and Shouyun Yu

Chem. Rec., 2017, 17, 754
DOI: 10.1002/tcr.201600125