Fátima Lucas, Esteban D. Babot, Marina Cañellas, José C. del Río, Lisbeth Kalum, René Ullrich, Martin Hofrichter, Victor Guallar, Angel T. Martínez and Ana Gutiérrez

Catal. Sci. Technol., 2016, 6, 288
DOI: 10.1039/C5CY00427F

Fatty acid epoxidation byCollariella virescensperoxygenase and heme-channel variants

Alejandro González-Benjumea, Juan Carro, Chantal Renau-Mínguez, Dolores Linde, Elena Fernández-Fueyo, Ana Gutiérrez and Angel T. Martínez

Catal. Sci. Technol., 2020, 10, 717
DOI: 10.1039/C9CY02332A

Scalable biocatalytic C–H oxyfunctionalization reactions

Suman Chakrabarty, Ye Wang, Jonathan C. Perkins and Alison R. H. Narayan

Chem. Soc. Rev., 2020, 49, 8137
DOI: 10.1039/D0CS00440E

Simultaneous screening of multiple substrates with an unspecific peroxygenase enabled modified alkane and alkene oxyfunctionalisations

Anja Knorrscheidt, Jordi Soler, Nicole Hünecke, Pascal Püllmann, Marc Garcia-Borràs and Martin J. Weissenborn

Catal. Sci. Technol., 2021, 11, 6058
DOI: 10.1039/D0CY02457K

Nonconventional regeneration of redox enzymes – a practical approach for organic synthesis?

Wuyuan Zhang and Frank Hollmann

Chem. Commun., 2018, 54, 7281
DOI: 10.1039/C8CC02219D

Enzymatic strategies for asymmetric synthesis

Mélanie Hall

RSC Chem. Biol., 2021, 2, 958
DOI: 10.1039/D1CB00080B

Enzymatic Oxidation of Butane to 2‐Butanol in a Bubble Column

Frederic Perz, Sebastian Bormann, Roland Ulber, Miguel Alcalde, Paul Bubenheim, Frank Hollmann, Dirk Holtmann and Andreas Liese

ChemCatChem, 2020, 12, 3666
DOI: 10.1002/cctc.202000431

Robust Light Driven Enzymatic Oxyfunctionalization via Immobilization of Unspecific Peroxygenase

Piera De Santis, Deborah Wegstein, Bastien O. Burek, Jacqueline Patzsch, Miguel Alcalde, Wolfgang Kroutil, Jonathan Z. Bloh and Selin Kara

ChemSusChem, 2023, 16
DOI: 10.1002/cssc.202300613

In Situ O2 Generation for Biocatalytic Oxyfunctionalization Reactions

Anna Hoschek, Andreas Schmid and Bruno Bühler

ChemCatChem, 2018, 10, 5366
DOI: 10.1002/cctc.201801262

Recent Advances in Biocatalytic Preparation of Chiral Sulfoxides

Yawen Song, Yifang Wang, Bochen Pan, Xiaoling Cheng, Jiawei Yang and Yongzheng Chen

Asian J Org Chem, 2025
DOI: 10.1002/ajoc.202400708

Energising the E-factor: The E+-factor

Florian Tieves, Fabio Tonin, Elena Fernández-Fueyo, John M. Robbins, Bettina Bommarius, Andreas S. Bommarius, Miguel Alcalde and Frank Hollmann

Tetrahedron, 2019, 75, 1311
DOI: 10.1016/j.tet.2019.01.065

A simplified process design for P450 driven hydroxylation based on surface displayed enzymes

Frank W. Ströhle, Eva Kranen, Jens Schrader, Ruth Maas and Dirk Holtmann

Biotech & Bioengineering, 2016, 113, 1225
DOI: 10.1002/bit.25885

Application of the all-in-one electrode for in situ H2O2 generation in hydroxylation catalyzed by unspecific peroxygenase from Agrocybe aegerita

Giovanni V. Sayoga, Victoria S. Bueschler, Hubert Beisch, Dirk Holtmann, An-Ping Zeng, Bodo Fiedler, Daniel Ohde and Andreas Liese

Molecular Catalysis, 2023, 547, 113325
DOI: 10.1016/j.mcat.2023.113325

Multienzymatic in situ hydrogen peroxide generation cascade for peroxygenase-catalysed oxyfunctionalisation reactions

Milja Pesic, Sébastien Jean-Paul Willot, Elena Fernández-Fueyo, Florian Tieves, Miguel Alcalde and Frank Hollmann

Zeitschrift für Naturforschung C, 2019, 74, 101
DOI: 10.1515/znc-2018-0137

Biocatalytic synthesis of the Green Note trans-2-hexenal in a continuous-flow microreactor

Morten M C H van Schie, Tiago Pedroso de Almeida, Gabriele Laudadio, Florian Tieves, Elena Fernández-Fueyo, Timothy Noël, Isabel W C E Arends and Frank Hollmann

Beilstein J. Org. Chem., 2018, 14, 697
DOI: 10.3762/bjoc.14.58

Shuffling the Neutral Drift of Unspecific Peroxygenase in Saccharomyces cerevisiae

Javier Martin-Diaz, Carmen Paret, Eva García-Ruiz, Patricia Molina-Espeja, Miguel Alcalde and Janet L. Schottel

Appl Environ Microbiol, 2018, 84
DOI: 10.1128/AEM.00808-18

Chromoselective Photocatalysis Enables Stereocomplementary Biocatalytic Pathways**

Luca Schmermund, Susanne Reischauer, Sarah Bierbaumer, Christoph K. Winkler, Alba Diaz‐Rodriguez, Lee J. Edwards, Selin Kara, Tamara Mielke, Jared Cartwright, Gideon Grogan, Bartholomäus Pieber and Wolfgang Kroutil

Angewandte Chemie, 2021, 133, 7041
DOI: 10.1002/ange.202100164

Photobiokatalyse: Aktivierung von Redoxenzymen durch direkten oder indirekten Transfer photoinduzierter Elektronen

Sahng Ha Lee, Da Som Choi, Su Keun Kuk and Chan Beum Park

Angewandte Chemie, 2018, 130, 8086
DOI: 10.1002/ange.201710070

Microscale Atmospheric Pressure Plasma Jet as a Source for Plasma‐Driven Biocatalysis

Abdulkadir Yayci, Tim Dirks, Friederike Kogelheide, Miguel Alcalde, Frank Hollmann, Peter Awakowicz and Julia E. Bandow

ChemCatChem, 2020, 12, 5893
DOI: 10.1002/cctc.202001225

An Inexpensive, Efficient Alternative to NADPH to Support Catalysis by Thermostable Cytochrome P450 Enzymes

Silja J. Strohmaier, Jong Min Baek, James J. De Voss, Ulrik Jurva, Shalini Andersson and Elizabeth M. J. Gillam

ChemCatChem, 2020, 12, 1750
DOI: 10.1002/cctc.201902235

Immobilization of unspecific peroxygenase expressed in Pichia pastoris by metal affinity binding

Sebastian Bormann, Bastien Oliver Burek, Roland Ulber and Dirk Holtmann

Molecular Catalysis, 2020, 492, 110999
DOI: 10.1016/j.mcat.2020.110999

Enzymatic Oxy‐ and Amino‐Functionalization in Biocatalytic Cascade Synthesis: Recent Advances and Future Perspectives

Eleonora Grandi, Fatma Feyza Özgen, Sandy Schmidt and Gerrit J. Poelarends

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202309012

Ru(II)-diimine complexes and cytochrome P450 working hand-in-hand

Celine Eidenschenk and Lionel Cheruzel

Journal of Inorganic Biochemistry, 2020, 213, 111254
DOI: 10.1016/j.jinorgbio.2020.111254

Visible-light-driven photobiocatalytic synthesis of chiral sulfoxides over immobilized chloroperoxidase on magnetic yolk–shell Fe3O4@Cu-H-TiO2 photocatalyst

Xiaoyang Yue, Yuying Hou, Cuiyao Cao, Xue Cao, Haolei Song, Yanjun Jiang, Liya Zhou, Ying He, Xiaobing Zheng, Li Ma and Shijie Li

Journal of Cleaner Production, 2024, 478, 143992
DOI: 10.1016/j.jclepro.2024.143992

Solar‐Powered Whole‐Cell P450 Catalytic Platform for C‐Hydroxylation Reactions

Thien‐Kim Le, Jinhyun Kim, Ngoc Anh Nguyen, Thi Huong Ha Nguyen, Eun‐Gene Sun, Su‐Min Yee, Hyung‐Sik Kang, Soo‐Jin Yeom, Chan Beum Park and Chul‐Ho Yun

ChemSusChem, 2021, 14, 3054
DOI: 10.1002/cssc.202100944

A Horseradish Peroxidase–Mediator System for Benzylic C–H Activation

Mario A. Cribari, Maxwell J. Unger and Jeffrey D. Martell

ACS Catal., 2022, 12, 12246
DOI: 10.1021/acscatal.2c03424

Revisiting strategies and their combinatorial effect for introducing peroxygenase activity in CYP102A1 (P450BM3)

Jasmin C. Aschenbrenner, Ana C. Ebrecht, Martha S. Smit and Diederik J. Opperman

Molecular Catalysis, 2024, 557, 113953
DOI: 10.1016/j.mcat.2024.113953

Peroxide-Mediated Oxygenation of Organic Compounds by Fungal Peroxygenases

Martin Hofrichter, Harald Kellner, Robert Herzog, Alexander Karich, Jan Kiebist, Katrin Scheibner and René Ullrich

Antioxidants, 2022, 11, 163
DOI: 10.3390/antiox11010163

Selective Oxidations of Toluenes and Benzyl Alcohols by an Unspecific Peroxygenase (UPO)

Balázs Pogrányi, Tamara Mielke, Jared Cartwright, William P. Unsworth and Gideon Grogan

ChemCatChem, 2024, 16
DOI: 10.1002/cctc.202400702

A novel insight of enhancing the hydrogen peroxide tolerance of unspecific peroxygenase from Daldinia caldariorum based on structure

Tiantian Li, Ruochen Jin, Bin Wu, Dongming Lan, Yunjian Ma and Yonghua Wang

Chinese Chemical Letters, 2024, 35, 108701
DOI: 10.1016/j.cclet.2023.108701

A novel system comprising metalloporphyrins and cyclohexene for the biomimetic aerobic oxidation of toluene

Hong-Yu Chen, Meng Lv, Xian-Tai Zhou, Jie-Xiang Wang, Qi Han and Hong-Bing Ji

Catalysis Communications, 2018, 109, 76
DOI: 10.1016/j.catcom.2018.02.020

Selective Oxyfunctionalisation Reactions Driven by Sulfite Oxidase‐Catalysed In Situ Generation of H2O2

Morten M. C. H. van Schie, Alexander T. Kaczmarek, Florian Tieves, Patricia Gomez de Santos, Caroline E. Paul, Isabel W. C. E. Arends, Miguel Alcalde, Günter Schwarz and Frank Hollmann

ChemCatChem, 2020, 12, 3186
DOI: 10.1002/cctc.201902297

Homogeneous Oxygenase Catalysis

Yujie Liang, Jialiang Wei, Xu Qiu and Ning Jiao

Chem. Rev., 2018, 118, 4912
DOI: 10.1021/acs.chemrev.7b00193

Current state and future perspectives of engineered and artificial peroxygenases for the oxyfunctionalization of organic molecules

Marie-Cathérine Sigmund and Gerrit J. Poelarends

Nat Catal, 2020, 3, 690
DOI: 10.1038/s41929-020-00507-8

Selektive C‐H‐Bindungsaktivierung durch eine Kaskade aus Photochemie und Biokatalyse

Wuyuan Zhang, Bastien O. Burek, Elena Fernández‐Fueyo, Miguel Alcalde, Jonathan Z. Bloh and Frank Hollmann

Angewandte Chemie, 2017, 129, 15654
DOI: 10.1002/ange.201708668

Versatile Biocatalytic C(sp3)−H Oxyfunctionalization for the Site‐ Selective and Stereodivergent Synthesis of α‐ and β‐Hydroxy Acids

Yingle Mao, Weijie Zhang, Zunyun Fu, Yanqiong Liu, Lin Chen, Xin Lian, Dan Zhuo, Jiewei Wu, Mingyue Zheng and Cangsong Liao

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202305250

A novel unspecific peroxygenase from Agaricus bisporus var. bisporus for biocatalytic oxyfunctionalisation reactions

Tiantian Li, Hongjing Liang, Bin Wu, Dongming Lan, Yunjian Ma, Frank Hollmann and Yonghua Wang

Molecular Catalysis, 2023, 546, 113275
DOI: 10.1016/j.mcat.2023.113275

P450DA Monooxygenase-Catalyzed Chemoselective and Enantiodivergent Epoxidation of Unactivated Alkenes

Jia-Jing Li, Xiao-Jian Zhou, Juan Ao, Jin-Tao Gao, An-Ni Wang, Zhuang-Lin Shen, Yang Gu, Jia-Hai Zhou and Yong-Zheng Chen

ACS Catal., 2024, 14, 16175
DOI: 10.1021/acscatal.4c04941

Photoelectroenzymatic Oxyfunctionalization on Flavin-Hybridized Carbon Nanotube Electrode Platform

Da Som Choi, Yan Ni, Elena Fernández-Fueyo, Minah Lee, Frank Hollmann and Chan Beum Park

ACS Catal., 2017, 7, 1563
DOI: 10.1021/acscatal.6b03453

Engineering Collariella virescens Peroxygenase for Epoxides Production from Vegetable Oil

Dolores Linde, Alejandro González-Benjumea, Carmen Aranda, Juan Carro, Ana Gutiérrez and Angel T. Martínez

Antioxidants, 2022, 11, 915
DOI: 10.3390/antiox11050915

Structural Insights into the Substrate Promiscuity of a Laboratory-Evolved Peroxygenase

Mercedes Ramirez-Escudero, Patricia Molina-Espeja, Patricia Gomez de Santos, Martin Hofrichter, Julia Sanz-Aparicio and Miguel Alcalde

ACS Chem. Biol., 2018, 13, 3259
DOI: 10.1021/acschembio.8b00500

A Biocatalytic Aza-Achmatowicz Reaction

Elena Fernández-Fueyo, Sabry H. H. Younes, Stefan van Rootselaar, René W. M. Aben, Rokus Renirie, Ron Wever, Dirk Holtmann, Floris P. J. T. Rutjes and Frank Hollmann

ACS Catal., 2016, 6, 5904
DOI: 10.1021/acscatal.6b01636

Chiral Nanozymes for Enantioselective Biological Catalysis

Kai Dong, Chen Xu, Jinsong Ren and Xiaogang Qu

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202208757

Enantioselectivity in Vanadium-Dependent Haloperoxidases of Different Marine Sources for Sulfide Oxidation to Sulfoxides

Yun-Han Zhang, Ya-Ting Zou, Yong-Yi Zeng, Lan Liu and Bi-Shuang Chen

Marine Drugs, 2024, 22, 419
DOI: 10.3390/md22090419

Dehaloperoxidase: An enzymatic Swiss army knife

Talita Malewschik and Reza A. Ghiladi

Coordination Chemistry Reviews, 2021, 441, 213976
DOI: 10.1016/j.ccr.2021.213976

Sustainable Approach for Peroxygenase-Catalyzed Oxidation Reactions Using Hydrogen Peroxide Generated from Spent Coffee Grounds and Tea Leaf Residues

Hideaki Kawana, Toru Miwa, Yuki Honda and Toshiki Furuya

ACS Omega, 2022, 7, 20259
DOI: 10.1021/acsomega.2c02186

Retracted: Combined Photoredox/Enzymatic C−H Benzylic Hydroxylations

Rick C. Betori, Catherine M. May and Karl A. Scheidt

Angewandte Chemie, 2019, 131, 16642
DOI: 10.1002/ange.201909426

Synthesis of Enantioenriched Sulfoxides by an Oxidation‐Reduction Enzymatic Cascade

Peipei Wang, Xiaofeng Han, Xinqi Liu, Richen Lin, Yongzheng Chen, Zhoutong Sun and Wuyuan Zhang

Chemistry A European J, 2022, 28
DOI: 10.1002/chem.202201997

Evolved Peroxygenase–Aryl Alcohol Oxidase Fusions for Self-Sufficient Oxyfunctionalization Reactions

Patricia Gomez de Santos, Sofia Lazaro, Javier Viña-Gonzalez, Manh Dat Hoang, Israel Sánchez-Moreno, Anton Glieder, Frank Hollmann and Miguel Alcalde

ACS Catal., 2020, 10, 13524
DOI: 10.1021/acscatal.0c03029

Studies on Biosynthesis of Chiral Sulfoxides by Using P450 119 Peroxygenase and Its Mutants

Qin Wang, Xin‐Meng Jiang, Yan‐Ping Gao, Li‐Ping Yin, Xiao‐Yao Wei, Kai Guo, Xiao‐Wei Gao, Li Wang and Chun Zhang

ChemistrySelect, 2022, 7
DOI: 10.1002/slct.202204031

Selective Synthesis of the Human Drug Metabolite 5′-Hydroxypropranolol by an Evolved Self-Sufficient Peroxygenase

Patricia Gomez de Santos, Marina Cañellas, Florian Tieves, Sabry H. H. Younes, Patricia Molina-Espeja, Martin Hofrichter, Frank Hollmann, Victor Guallar and Miguel Alcalde

ACS Catal., 2018, 8, 4789
DOI: 10.1021/acscatal.8b01004

Enzymatic Oxy‐ and Amino‐Functionalization in Biocatalytic Cascade Synthesis: Recent Advances and Future Perspectives

Eleonora Grandi, Fatma Feyza Özgen, Sandy Schmidt and Gerrit J. Poelarends

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202309012

Identification and Expression of New Unspecific Peroxygenases – Recent Advances, Challenges and Opportunities

Alina Kinner, Katrin Rosenthal and Stephan Lütz

Front. Bioeng. Biotechnol., 2021, 9
DOI: 10.3389/fbioe.2021.705630

Photoenzymatic Hydroxylation of Ethylbenzene Catalyzed by Unspecific Peroxygenase: Origin of Enzyme Inactivation and the Impact of Light Intensity and Temperature

Bastien O. Burek, Sabrina R. de Boer, Florian Tieves, Wuyuan Zhang, Morten van Schie, Sebastian Bormann, Miguel Alcalde, Dirk Holtmann, Frank Hollmann, Detlef W. Bahnemann and Jonathan Z. Bloh

ChemCatChem, 2019, 11, 3093
DOI: 10.1002/cctc.201900610

Mesoporous Encapsulated Chiral Nanogold for Use in Enantioselective Reactions

Ya Zhou, Hanjun Sun, Hongcheng Xu, Silvina Matysiak, Jinsong Ren and Xiaogang Qu

Angewandte Chemie, 2018, 130, 17033
DOI: 10.1002/ange.201811118

Towards preparative peroxygenase-catalyzed oxyfunctionalization reactions in organic media

Elena Fernández-Fueyo, Yan Ni, Alvaro Gomez Baraibar, Miguel Alcalde, Lukas M. van Langen and Frank Hollmann

Journal of Molecular Catalysis B: Enzymatic, 2016, 134, 347
DOI: 10.1016/j.molcatb.2016.09.013

Directed evolution of carbon–hydrogen bond activating enzymes

Raphael Frey, Takahiro Hayashi and Rebecca M Buller

Current Opinion in Biotechnology, 2019, 60, 29
DOI: 10.1016/j.copbio.2018.12.004

Versatile Biocatalytic C(sp3)−H Oxyfunctionalization for the Site‐ Selective and Stereodivergent Synthesis of α‐ and β‐Hydroxy Acids

Yingle Mao, Weijie Zhang, Zunyun Fu, Yanqiong Liu, Lin Chen, Xin Lian, Dan Zhuo, Jiewei Wu, Mingyue Zheng and Cangsong Liao

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202305250

Recent progress in enzymatic functionalization of carbon-hydrogen bonds for the green synthesis of chemicals

Zheyu Wang, Yupei Jian, Yilei Han, Zhongwang Fu, Diannan Lu, Jianzhong Wu and Zheng Liu

Chinese Journal of Chemical Engineering, 2020, 28, 2499
DOI: 10.1016/j.cjche.2020.06.040

Halogenation in Fungi: What Do We Know and What Remains to Be Discovered?

Bastien Cochereau, Laurence Meslet-Cladière, Yves François Pouchus, Olivier Grovel and Catherine Roullier

Molecules, 2022, 27, 3157
DOI: 10.3390/molecules27103157

Selective Activation of C−H Bonds in a Cascade Process Combining Photochemistry and Biocatalysis

Wuyuan Zhang, Bastien O. Burek, Elena Fernández‐Fueyo, Miguel Alcalde, Jonathan Z. Bloh and Frank Hollmann

Angew Chem Int Ed, 2017, 56, 15451
DOI: 10.1002/anie.201708668

Research Progress of Peroxygenase-Catalyzed Reactions Driven by in-situ Generation of H 2 O 2

Kexin Li, Qingyuan Yang, Pengpeng Zhang and Wuyuan Zhang

Chinese Journal of Organic Chemistry, 2022, 42, 732
DOI: 10.6023/cjoc202108052

Structural and Biochemical Studies Enlighten the Unspecific Peroxygenase from Hypoxylon sp. EC38 as an Efficient Oxidative Biocatalyst

Laura Rotilio, Alexander Swoboda, Katharina Ebner, Claudia Rinnofner, Anton Glieder, Wolfgang Kroutil and Andrea Mattevi

ACS Catal., 2021, 11, 11511
DOI: 10.1021/acscatal.1c03065

Mesoporous Encapsulated Chiral Nanogold for Use in Enantioselective Reactions

Ya Zhou, Hanjun Sun, Hongcheng Xu, Silvina Matysiak, Jinsong Ren and Xiaogang Qu

Angew Chem Int Ed, 2018, 57, 16791
DOI: 10.1002/anie.201811118

Shortening Synthetic Routes to Small Molecule Active Pharmaceutical Ingredients Employing Biocatalytic Methods

Stefan Simić, Erna Zukić, Luca Schmermund, Kurt Faber, Christoph K. Winkler and Wolfgang Kroutil

Chem. Rev., 2022, 122, 1052
DOI: 10.1021/acs.chemrev.1c00574

Mapping Potential Determinants of Peroxidative Activity in an Evolved Fungal Peroxygenase from Agrocybe aegerita

Patricia Molina-Espeja, Alejandro Beltran-Nogal, Maria Alejandra Alfuzzi, Victor Guallar and Miguel Alcalde

Front. Bioeng. Biotechnol., 2021, 9
DOI: 10.3389/fbioe.2021.741282

Immobilization of Enzymes on Cyclodextrin-Anchored Dehiscent Mesoporous TiO2 for Efficient Photoenzymatic Hydroxylation

Feifei Jia, Yunting Liu, Xuewu Deng, Xue Cao, Xiaobing Zheng, Liya Zhou, Jing Gao and Yanjun Jiang

ACS Appl. Mater. Interfaces, 2023, 15, 7928
DOI: 10.1021/acsami.2c17971

Electro-enzymatic hydroxylation of ethylbenzene by the evolved unspecific peroxygenase of Agrocybe aegerita

A.E.W. Horst, S. Bormann, J. Meyer, M. Steinhagen, R. Ludwig, A. Drews, M. Ansorge-Schumacher and D. Holtmann

Journal of Molecular Catalysis B: Enzymatic, 2016, 133, S137
DOI: 10.1016/j.molcatb.2016.12.008

Design and biocatalytic applications of genetically fused multifunctional enzymes

Dianelis T. Monterrey, Iván Ayuso-Fernández, Isabel Oroz-Guinea and Eduardo García-Junceda

Biotechnology Advances, 2022, 60, 108016
DOI: 10.1016/j.biotechadv.2022.108016

Metalloporphyrin-mediated aerobic oxidation of hydrocarbons in cumene: Co-substrate specificity and mechanistic consideration

Jun Jiang, Rongchang Luo, Xiantai Zhou, Fenfen Wang and Hongbing Ji

Molecular Catalysis, 2017, 440, 36
DOI: 10.1016/j.mcat.2017.07.007

Recent developments in the use of peroxygenases – Exploring their high potential in selective oxyfunctionalisations

Markus Hobisch, Dirk Holtmann, Patricia Gomez de Santos, Miguel Alcalde, Frank Hollmann and Selin Kara

Biotechnology Advances, 2021, 51, 107615
DOI: 10.1016/j.biotechadv.2020.107615

Photocatalyst-enzyme hybrid systems for light-driven biotransformation

Nan Yang, Yao Tian, Mai Zhang, Xiting Peng, Feng Li, Jianxun Li, Yi Li, Bei Fan, Fengzhong Wang and Hao Song

Biotechnology Advances, 2022, 54, 107808
DOI: 10.1016/j.biotechadv.2021.107808

Broadening the Scope of Biocatalysis in Sustainable Organic Synthesis

Roger A. Sheldon and Dean Brady

ChemSusChem, 2019, 12, 2859
DOI: 10.1002/cssc.201900351

Photobiocatalysis: Activating Redox Enzymes by Direct or Indirect Transfer of Photoinduced Electrons

Sahng Ha Lee, Da Som Choi, Su Keun Kuk and Chan Beum Park

Angew Chem Int Ed, 2018, 57, 7958
DOI: 10.1002/anie.201710070

Engineering of Unspecific Peroxygenases Using a Superfolder-Green-Fluorescent-Protein-Mediated Secretion System in Escherichia coli

Xingyu Yan, Xiaodong Zhang, Haoran Li, Di Deng, Zhiyong Guo, Lixin Kang and Aitao Li

JACS Au, 2024, 4, 1654
DOI: 10.1021/jacsau.4c00129

Peroxygenases en route to becoming dream catalysts. What are the opportunities and challenges?

Yonghua Wang, Dongming Lan, Rabia Durrani and Frank Hollmann

Current Opinion in Chemical Biology, 2017, 37, 1
DOI: 10.1016/j.cbpa.2016.10.007

Highly Efficient Access to (S)‐Sulfoxides Utilizing a Promiscuous Flavoprotein Monooxygenase in a Whole‐Cell Biocatalyst Format

Christian Willrodt, Janosch A. D. Gröning, Philipp Nerke, Rainhard Koch, Anika Scholtissek, Thomas Heine, Andreas Schmid, Bruno Bühler and Dirk Tischler

ChemCatChem, 2020, 12, 4664
DOI: 10.1002/cctc.201901894

Keeping the spotlight on cytochrome P450

Hadil Shalan, Mallory Kato and Lionel Cheruzel

Biochimica et Biophysica Acta (BBA) - Proteins and Proteomics, 2018, 1866, 80
DOI: 10.1016/j.bbapap.2017.06.002

Protection strategies for biocatalytic proteins under plasma treatment

Abdulkadir Yayci, Tim Dirks, Friederike Kogelheide, Miguel Alcalde, Frank Hollmann, Peter Awakowicz and Julia E Bandow

J. Phys. D: Appl. Phys., 2021, 54, 035204
DOI: 10.1088/1361-6463/abb979

The Oxygen Dilemma: A Severe Challenge for the Application of Monooxygenases?

Dirk Holtmann and Frank Hollmann

ChemBioChem, 2016, 17, 1391
DOI: 10.1002/cbic.201600176

Chromoselective Photocatalysis Enables Stereocomplementary Biocatalytic Pathways**

Luca Schmermund, Susanne Reischauer, Sarah Bierbaumer, Christoph K. Winkler, Alba Diaz‐Rodriguez, Lee J. Edwards, Selin Kara, Tamara Mielke, Jared Cartwright, Gideon Grogan, Bartholomäus Pieber and Wolfgang Kroutil

Angew Chem Int Ed, 2021, 60, 6965
DOI: 10.1002/anie.202100164

Modularization of Immobilized Multienzyme Cascades for Continuous‐Flow Enantioselective C−H Amination

Weixi Kong, Chen Huang, Liya Zhou, Jing Gao, Li Ma, Yunting Liu and Yanjun Jiang

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202407778

Surfing the wave of oxyfunctionalization chemistry by engineering fungal unspecific peroxygenases

Alejandro Beltrán-Nogal, Israel Sánchez-Moreno, Daniel Méndez-Sánchez, Patricia Gómez de Santos, Frank Hollmann and Miguel Alcalde

Current Opinion in Structural Biology, 2022, 73, 102342
DOI: 10.1016/j.sbi.2022.102342

Asymmetric Bio‐epoxidation of Unactivated Alkenes

Jiajing Li, Wenjing Gu, Zhongqiang Wang, Xiaojian Zhou and Yongzheng Chen

ChemBioChem, 2023, 24
DOI: 10.1002/cbic.202200719

Fatty Acid Chain Shortening by a Fungal Peroxygenase

Andrés Olmedo, José C. del Río, Jan Kiebist, René Ullrich, Martin Hofrichter, Katrin Scheibner, Angel T. Martínez and Ana Gutiérrez

Chemistry A European J, 2017, 23, 16985
DOI: 10.1002/chem.201704773

Engineering carboxylic acid reductases and unspecific peroxygenases for flavor and fragrance biosynthesis

Alejandra Agosto-Maldonado, Jiantao Guo and Wei Niu

Journal of Biotechnology, 2024, 385, 1
DOI: 10.1016/j.jbiotec.2024.02.013

Enzymatic Nitrogen Incorporation Using Hydroxylamine

Shilong Gao, Anuvab Das, Edwin Alfonzo, Kathleen M. Sicinski, Dominic Rieger and Frances H. Arnold

J. Am. Chem. Soc., 2023, 145, 20196
DOI: 10.1021/jacs.3c08053

Peroxygenase‐katalysierte Oxyfunktionalisierung angetrieben durch Methanoloxidation

Yan Ni, Elena Fernández‐Fueyo, Alvaro Gomez Baraibar, René Ullrich, Martin Hofrichter, Hideshi Yanase, Miguel Alcalde, Willem J. H. van Berkel and Frank Hollmann

Angewandte Chemie, 2016, 128, 809
DOI: 10.1002/ange.201507881

Retracted: Combined Photoredox/Enzymatic C−H Benzylic Hydroxylations

Rick C. Betori, Catherine M. May and Karl A. Scheidt

Angew Chem Int Ed, 2019, 58, 16490
DOI: 10.1002/anie.201909426

Accessing Chemo- and Regioselective Benzylic and Aromatic Oxidations by Protein Engineering of an Unspecific Peroxygenase

Anja Knorrscheidt, Jordi Soler, Nicole Hünecke, Pascal Püllmann, Marc Garcia-Borràs and Martin J. Weissenborn

ACS Catal., 2021, 11, 7327
DOI: 10.1021/acscatal.1c00847

Whole-cell biocatalysis using the Acidovorax sp. CHX100 Δ6HX for the production of ω-hydroxycarboxylic acids from cycloalkanes

Diego Salamanca, Katja Bühler, Karl-Heinrich Engesser, Andreas Schmid and Rohan Karande

New Biotechnology, 2021, 60, 200
DOI: 10.1016/j.nbt.2020.10.009

Bias-Free In Situ H2O2 Generation in a Photovoltaic-Photoelectrochemical Tandem Cell for Biocatalytic Oxyfunctionalization

Da Som Choi, Hojin Lee, Florian Tieves, Yang Woo Lee, Eun Jin Son, Wuyuan Zhang, Byungha Shin, Frank Hollmann and Chan Beum Park

ACS Catal., 2019, 9, 10562
DOI: 10.1021/acscatal.9b04454

Oxidoreductases on their way to industrial biotransformations

Angel T. Martínez, Francisco J. Ruiz-Dueñas, Susana Camarero, Ana Serrano, Dolores Linde, Henrik Lund, Jesper Vind, Morten Tovborg, Owik M. Herold-Majumdar, Martin Hofrichter, Christiane Liers, René Ullrich, Katrin Scheibner, Giovanni Sannia, Alessandra Piscitelli, Cinzia Pezzella, Mehmet E. Sener, Sibel Kılıç, Willem J.H. van Berkel, Victor Guallar, Maria Fátima Lucas, Ralf Zuhse, Roland Ludwig, Frank Hollmann, Elena Fernández-Fueyo, Eric Record, Craig B. Faulds, Marta Tortajada, Ib Winckelmann, Jo-Anne Rasmussen, Mirjana Gelo-Pujic, Ana Gutiérrez, José C. del Río, Jorge Rencoret and Miguel Alcalde

Biotechnology Advances, 2017, 35, 815
DOI: 10.1016/j.biotechadv.2017.06.003

Cross-linked cytochrome P450 BM3 aggregates promoted by Ru(II)-diimine complexes bearing aldehyde groups

Minh Quan Do, Evelynn Henry, Mallory Kato and Lionel Cheruzel

Journal of Inorganic Biochemistry, 2018, 186, 130
DOI: 10.1016/j.jinorgbio.2018.06.001

Process intensification using immobilized enzymes

Sera Bolat, Raphael Greifenstein, Matthias Franzreb and Dirk Holtmann

Physical Sciences Reviews, 2024, 9, 2737
DOI: 10.1515/psr-2022-0110

Valorization of Small Alkanes by Biocatalytic Oxyfunctionalization

Durga Mahor, Zhiqi Cong, Martin J. Weissenborn, Frank Hollmann and Wuyuan Zhang

ChemSusChem, 2022, 15
DOI: 10.1002/cssc.202101116

Reductants fuel lytic polysaccharide monooxygenase activity in a pH‐dependent manner

Ole Golten, Iván Ayuso‐Fernández, Kelsi R. Hall, Anton A. Stepnov, Morten Sørlie, Åsmund Kjendseth Røhr and Vincent G. H. Eijsink

FEBS Letters, 2023, 597, 1363
DOI: 10.1002/1873-3468.14629

Piezobiocatalysis: Ultrasound-Driven Enzymatic Oxyfunctionalization of C–H Bonds

Jaeho Yoon, Jinhyun Kim, Florian Tieves, Wuyuan Zhang, Miguel Alcalde, Frank Hollmann and Chan Beum Park

ACS Catal., 2020, 10, 5236
DOI: 10.1021/acscatal.0c00188

Chiral Nanozymes for Enantioselective Biological Catalysis

Kai Dong, Chen Xu, Jinsong Ren and Xiaogang Qu

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202208757

Yeast Surface Display Enables One‐Step Production and Immobilization of Unspecific Peroxygenases

Niklas Teetz, Selina Lang, Andreas Liese and Dirk Holtmann

ChemCatChem, 2024, 16
DOI: 10.1002/cctc.202400908

Comparing the Catalytic and Structural Characteristics of a ‘Short’ Unspecific Peroxygenase (UPO) Expressed in Pichia pastoris and Escherichia coli

Wendy X. Q. Robinson, Tamara Mielke, Benjamin Melling, Anibal Cuetos, Alison Parkin, William P. Unsworth, Jared Cartwright and Gideon Grogan

ChemBioChem, 2023, 24
DOI: 10.1002/cbic.202200558

H2O2 Production at Low Overpotentials for Electroenzymatic Halogenation Reactions

Sebastian Bormann, Morten M. C. H. van Schie, Tiago Pedroso De Almeida, Wuyuan Zhang, Markus Stöckl, Roland Ulber, Frank Hollmann and Dirk Holtmann

ChemSusChem, 2019, 12, 4759
DOI: 10.1002/cssc.201902326

Modularization of Immobilized Multienzyme Cascades for Continuous‐Flow Enantioselective C−H Amination

Weixi Kong, Chen Huang, Liya Zhou, Jing Gao, Li Ma, Yunting Liu and Yanjun Jiang

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202407778

A Unique P450 Peroxygenase System Facilitated by a Dual-Functional Small Molecule: Concept, Application, and Perspective

Siyu Di, Shengxian Fan, Fengjie Jiang and Zhiqi Cong

Antioxidants, 2022, 11, 529
DOI: 10.3390/antiox11030529

Oxidoreductases and Reactive Oxygen Species in Conversion of Lignocellulosic Biomass

Bastien Bissaro, Anikó Várnai, Åsmund K. Røhr and Vincent G. H. Eijsink

Microbiol Mol Biol Rev, 2018, 82
DOI: 10.1128/MMBR.00029-18

Biocatalytic regio- and stereoselective access to ω-3 endocannabinoid epoxides with peroxygenase from oat flour

Claudia Sanfilippo and Angela Patti

Bioorganic Chemistry, 2021, 113, 105014
DOI: 10.1016/j.bioorg.2021.105014

Peroxygenase‐Catalyzed Oxyfunctionalization Reactions Promoted by the Complete Oxidation of Methanol

Yan Ni, Elena Fernández‐Fueyo, Alvaro Gomez Baraibar, René Ullrich, Martin Hofrichter, Hideshi Yanase, Miguel Alcalde, Willem J. H. van Berkel and Frank Hollmann

Angew Chem Int Ed, 2016, 55, 798
DOI: 10.1002/anie.201507881

Modeling and simulation‐based design of electroenzymatic batch processes catalyzed by unspecific peroxygenase from A. aegerita

Sebastian Bormann, Dominik Hertweck, Sabrina Schneider, Jonathan Z. Bloh, Roland Ulber, Antje C. Spiess and Dirk Holtmann

Biotech & Bioengineering, 2021, 118, 7
DOI: 10.1002/bit.27545

Selective Epoxidation of Fatty Acids and Fatty Acid Methyl Esters by Fungal Peroxygenases

Carmen Aranda, Andrés Olmedo, Jan Kiebist, Katrin Scheibner, José C. del Río, Angel T. Martínez and Ana Gutiérrez

ChemCatChem, 2018, 10, 3964
DOI: 10.1002/cctc.201800849

Peroxygenase‐Catalyzed Enantioselective Sulfoxidations

Ivan Bassanini, Erica Elisa Ferrandi, Marta Vanoni, Gianluca Ottolina, Sergio Riva, Michele Crotti, Elisabetta Brenna and Daniela Monti

Eur J Org Chem, 2017, 2017, 7186
DOI: 10.1002/ejoc.201701390