PMO12@ZIF-8/ZnO-derived hierarchical porous molybdenum carbide as efficient electrocatalysts for hydrogen evolution

Jiao Li, Xiao Li, Jing Sun, Xiaoli Hu and Zhongmin Su

New J. Chem., 2021, 45, 9456
DOI: 10.1039/D1NJ01096D

Novel Co–Ni–graphene composite electrodes for hydrogen production

B. Subramanya, Y. Ullal, S. U. Shenoy, D. K. Bhat and A. C. Hegde

RSC Adv., 2015, 5, 47398
DOI: 10.1039/C5RA07627G

Photoinduced hydrogen evolution with new tetradentate cobalt(ii) complexes based on the TPMA ligand

Mirco Natali, Elena Badetti, Elisa Deponti, Marta Gamberoni, Francesca A. Scaramuzzo, Andrea Sartorel and Cristiano Zonta

Dalton Trans., 2016, 45, 14764
DOI: 10.1039/C6DT01705C

Metalloporphyrin-modified semiconductors for solar fuel production

D. Khusnutdinova, A. M. Beiler, B. L. Wadsworth, S. I. Jacob and G. F. Moore

Chem. Sci., 2017, 8, 253
DOI: 10.1039/C6SC02664H

Photoelectrochemical study of p-GaP(100)|ZnO|AuNP devices: strategies for enhanced electron transfer and aqueous catalysis

Owen M. Williams, Justin W. Shi and Michael J. Rose

Chem. Commun., 2016, 52, 9145
DOI: 10.1039/C6CC00703A

The effects of chelating N4 ligand coordination on Co(ii)-catalysed photochemical conversion of CO2 to CO: reaction mechanism and DFT calculations

Feng Wang, Bei Cao, Wai-Pong To, Chun-Wai Tse, Kai Li, Xiao-Yong Chang, Chao Zang, Sharon Lai-Fung Chan and Chi-Ming Che

Catal. Sci. Technol., 2016, 6, 7408
DOI: 10.1039/C6CY01265E

Hydrogen evolution driven by heteroatoms of bidentate N-heterocyclic ligands in iron(ii) complexes

Soma Keszei, Yiqing Wang, Haotian Zhou, Tamás Ollár, Éva Kováts, Krisztina Frey, Levente Tapasztó, Shaohua Shen and József Sándor Pap

Dalton Trans., 2024, 53, 14817
DOI: 10.1039/D4DT02081B

Enhanced catalysis of the electrochemical hydrogen evolution reaction using composites of molybdenum-based compounds, gold nanoparticles and carbon

Ubisha Joshi, Jing Lee, Cristina Giordano, Souradip Malkhandi and Boon Siang Yeo

Phys. Chem. Chem. Phys., 2016, 18, 21548
DOI: 10.1039/C6CP02828D

Ligand tunability versus condition optimization: a guide to the structure–activity/stability nexus and mechanistic insights into photoinduced hydrogen evolution using hexacoordinated cobalt complexes

Ibukun Oluwaseun Shotonwa, Emmanuel Aanu Bankole, Aminu Labaran Muhammad, Oluwatobiloba Emmanuel Ojomo, Emmanuel Anegbe, Peter Osaigie Ifagbuyi, Olubukola Anuoluwapo Alani, Simeon Okechukwu Eze, Busayo Christiana Akano, Tobiloba Mary Omifolajin, Segun Samuel Bamidele, Bakau Olanrewaju Ayoola, Kehinde Elizabeth Onasanya, Onome Ejeromedoghene, Winfried Plass, Adedoyin Oluseyi Adesoji and Sheriff Adewuyi

Catal. Sci. Technol., 2025, 15, 6271
DOI: 10.1039/D5CY00364D

Accelerated alkaline hydrogen evolution on M(OH)x/M-MoPOx (M = Ni, Co, Fe, Mn) electrocatalysts by coupling water dissociation and hydrogen ad-desorption steps

Lishan Peng, Mansheng Liao, Xingqun Zheng, Yao Nie, Ling Zhang, Minjie Wang, Rui Xiang, Jian Wang, Li Li and Zidong Wei

Chem. Sci., 2020, 11, 2487
DOI: 10.1039/C9SC04603H

Mapping free energy regimes in electrocatalytic reductions to screen transition metal-based catalysts

Srinivasan Ramakrishnan, Ross A. Moretti and Christopher E. D. Chidsey

Chem. Sci., 2019, 10, 7649
DOI: 10.1039/C9SC01766F

A high-performance metal-free hydrogen-evolution reaction electrocatalyst from bacterium derived carbon

Li Wei, Huseyin Enis Karahan, Kunli Goh, Wenchao Jiang, Dingshan Yu, Özgür Birer, Rongrong Jiang and Yuan Chen

J. Mater. Chem. A, 2015, 3, 7210
DOI: 10.1039/C5TA00966A

Hydrogen evolution reaction mediated by an all-sulfur trinuclear nickel complex

Cyril Pieri, Anirban Bhattacharjee, Alexandre Barrozo, Bruno Faure, Michel Giorgi, Jennifer Fize, Marius Réglier, Martin Field, Maylis Orio, Vincent Artero and Renaud Hardré

Chem. Commun., 2020, 56, 11106
DOI: 10.1039/D0CC04174B

High-efficiency electrochemical hydrogen evolution based on the intermetallic Pt2Si compound prepared by magnetron-sputtering

Yuchan Zhu, Min Yuan, Li Deng, Ruoxi Ming, Ailian Zhang, Ming Yang, Bo Chai and Zhandong Ren

RSC Adv., 2017, 7, 1553
DOI: 10.1039/C6RA24754G

Rational inert-basal-plane activating design of ultrathin 1T′ phase MoS2 with a MoO3 heterostructure for enhancing hydrogen evolution performances

Xiaoyi Xue, Jianan Zhang, Ibrahim Amiinu Saana, Jian Sun, Qun Xu and Shichun Mu

Nanoscale, 2018, 10, 16531
DOI: 10.1039/C8NR05270K

MoS2 nanotubes loaded with TiO2 nanoparticles for enhanced electrocatalytic hydrogen evolution

Bo Feng, Chuntao Liu, Weiyi Yan, Jianxin Geng and Guimin Wang

RSC Adv., 2019, 9, 26487
DOI: 10.1039/C9RA05041H

Vapor-fed electrolysis of water using earth-abundant catalysts in Nafion or in bipolar Nafion/poly(benzimidazolium) membranes

Patrick K. Giesbrecht, Astrid M. Müller, Carlos G. Read, Steven Holdcroft, Nathan S. Lewis and Michael S. Freund

Sustainable Energy Fuels, 2019, 3, 3611
DOI: 10.1039/C9SE00672A

Electrochemical Ni–H catalysis for selective tail-to-tail reductive dimerization of terminal alkynes to access 2,3-dibranched butadienes

Shide Lv, Mingming Yu, Yinglong Ni, Tiantian Huang, Hong Yi and Aiwen Lei

Green Chem., 2025, 27, 8549
DOI: 10.1039/D5GC02238J

A dinuclear porphyrin-macrocycle as efficient catalyst for the hydrogen evolution reaction

Julia Jökel, Fabian Schwer, Max von Delius and Ulf-Peter Apfel

Chem. Commun., 2020, 56, 14179
DOI: 10.1039/D0CC05229A

A mechanism study on the hydrogen evolution reaction catalyzed by molybdenum disulfide complexes

Ti-Long Yang, Shao-Fei Ni, Peng Qin and Li Dang

Chem. Commun., 2018, 54, 1113
DOI: 10.1039/C7CC08632F

Unravelling the pH-dependence of a molecular photocatalytic system for hydrogen production

Anna Reynal, Ernest Pastor, Manuela A. Gross, Shababa Selim, Erwin Reisner and James R. Durrant

Chem. Sci., 2015, 6, 4855
DOI: 10.1039/C5SC01349F

Electrochemical hydrogenation of a homogeneous nickel complex to form a surface adsorbed hydrogen-evolving species

Daniel J. Martin, Brian D. McCarthy, Carrie L. Donley and Jillian L. Dempsey

Chem. Commun., 2015, 51, 5290
DOI: 10.1039/C4CC08662G

Noncovalent immobilization of Co(ii)porphyrin through axial coordination as an enhanced electrocatalyst on carbon electrodes for oxygen reduction and evolution

Isaac Kwaku Attatsi, Weihua Zhu and Xu Liang

New J. Chem., 2020, 44, 4340
DOI: 10.1039/C9NJ02408E

Pt-like catalytic behavior of MoNi decorated CoMoO3cuboid arrays for the hydrogen evolution reaction

Dewen Wang, Ce Han, Zhicai Xing, Qun Li and Xiurong Yang

J. Mater. Chem. A, 2018, 6, 15558
DOI: 10.1039/C8TA04391D

Increasing the rate of hydrogen oxidation without increasing the overpotential: a bio-inspired iron molecular electrocatalyst with an outer coordination sphere proton relay

Jonathan M. Darmon, Neeraj Kumar, Elliott B. Hulley, Charles J. Weiss, Simone Raugei, R. Morris Bullock and Monte L. Helm

Chem. Sci., 2015, 6, 2737
DOI: 10.1039/C5SC00398A

Evaluation of the coordination preferences and catalytic pathways of heteroaxial cobalt oximes towards hydrogen generation

Debashis Basu, Shivnath Mazumder, Jens Niklas, Habib Baydoun, Dakshika Wanniarachchi, Xuetao Shi, Richard J. Staples, Oleg Poluektov, H. Bernhard Schlegel and Cláudio N. Verani

Chem. Sci., 2016, 7, 3264
DOI: 10.1039/C5SC04214C

Decorating mesoporous silicon with amorphous metal–phosphorous-derived nanocatalysts towards enhanced photoelectrochemical water reduction

Hefeng Zhang, Ailong Li, Zhiliang Wang, Weiguang Ma, Deng Li, Xu Zong and Can Li

J. Mater. Chem. A, 2016, 4, 14960
DOI: 10.1039/C6TA05725J

Beaded stream-like CoSe2 nanoneedle array for efficient hydrogen evolution electrocatalysis

Chuan-Pei Lee, Wei-Fu Chen, Tadesse Billo, Yan-Gu Lin, Fang-Yu Fu, Satyanarayana Samireddi, Chih-Hao Lee, Jih-Shang Hwang, Kuei-Hsien Chen and Li-Chyong Chen

J. Mater. Chem. A, 2016, 4, 4553
DOI: 10.1039/C6TA00464D

An inclusive review and perspective on Cu-based materials for electrochemical water splitting

Abdul Shakoor Sabir, Erum Pervaiz, Rafiq Khosa and Umair Sohail

RSC Adv., 2023, 13, 4963
DOI: 10.1039/D2RA07901A

Neutral nickel complexes with tetradentate N-heterocyclic carbene amidate ligands for electrocatalytic hydrogen evolution

Si Si, Wenxun Song, Jie Chen, Weimin Zhang, Wenhua Ji, Wonwoo Nam and Bin Wang

Dalton Trans., 2024, 53, 19088
DOI: 10.1039/D4DT02746A

Kinetics of furfural electrochemical hydrogenation and hydrogenolysis in acidic media on copper

Andrew S. May, Steven M. Watt and Elizabeth J. Biddinger

React. Chem. Eng., 2021, 6, 2075
DOI: 10.1039/D1RE00216C

Hydride & dihydrogen complexes of earth abundant metals: structure, reactivity, and applications to catalysis

S. J. Connelly Robinson and D. M. Heinekey

Chem. Commun., 2017, 53, 669
DOI: 10.1039/C6CC07529K

Insights into N, P, S multi-doped Mo2C/C composites as highly efficient hydrogen evolution reaction catalysts

Jieyu Xu, Lin Ge, Yajun Zhou, Guangyu Jiang, Liang Li, Yunheng Li and Yongsheng Li

Nanoscale Adv., 2020, 2, 3334
DOI: 10.1039/D0NA00335B

Recent advances in metal sulfides: from controlled fabrication to electrocatalytic, photocatalytic and photoelectrochemical water splitting and beyond

Sundaram Chandrasekaran, Lei Yao, Libo Deng, Chris Bowen, Yan Zhang, Sanming Chen, Zhiqun Lin, Feng Peng and Peixin Zhang

Chem. Soc. Rev., 2019, 48, 4178
DOI: 10.1039/C8CS00664D

Electrocatalytic proton reduction by mononuclear cobalt complexes of bis(benzimidazolyl)pyridine ligands: experimental and theoretical study

Sahanwaj Khan, Swaraj Sengupta, Md. Adnan Khan, Narayan Ch. Jana, Bidraha Bagh and Subhendu Naskar

New J. Chem., 2025, 49, 16134
DOI: 10.1039/D5NJ01975C

Electrode initiated proton-coupled electron transfer to promote degradation of a nickel(ii) coordination complex

Brian D. McCarthy, Carrie L. Donley and Jillian L. Dempsey

Chem. Sci., 2015, 6, 2827
DOI: 10.1039/C5SC00476D

Electronic transitions of SWCNTs in comparison to GO on Mn3O4/TiO2nanocomposites for hydrogen energy generation and solar photocatalysis

Saima Noor, Shamaila Sajjad, Sajjad Ahmed Khan Leghari, Cristina Flox, Tanja Kallio, Esko. I. Kauppinen and Saeed Ahmad

New J. Chem., 2021, 45, 2431
DOI: 10.1039/D0NJ05120A

H2 evolution by a cobalt selenolate electrocatalyst and related mechanistic studies

Courtney A. Downes, Joseph W. Yoo, Nicholas M. Orchanian, Ralf Haiges and Smaranda C. Marinescu

Chem. Commun., 2017, 53, 7306
DOI: 10.1039/C7CC02473H

Consecutive ligand-based PCET processes affording a doubly reduced nickel pyrazinedithiolate which transforms into a metal hydride required to evolve H2

Keita Koshiba, Kosei Yamauchi and Ken Sakai

Dalton Trans., 2019, 48, 635
DOI: 10.1039/C8DT04497J

Application of the energetic span model to the electrochemical catalysis of proton reduction by a diiron azadithiolate complex

Marc Bourrez and Frederic Gloaguen

New J. Chem., 2015, 39, 8073
DOI: 10.1039/C5NJ00770D

Hydrogen evolution by cobalt hangman porphyrins under operating conditions studied by vibrational spectro-electrochemistry

Patrycja Kielb, Marius Horch, Pierre Wrzolek, Robert Goetz, Khoa H. Ly, Jacek Kozuch, Matthias Schwalbe and Inez M. Weidinger

Catal. Sci. Technol., 2018, 8, 1849
DOI: 10.1039/C7CY02253K

Heteronanowires of MoC–Mo2C as efficient electrocatalysts for hydrogen evolution reaction

Huanlei Lin, Zhangping Shi, Sina He, Xiang Yu, Sinong Wang, Qingsheng Gao and Yi Tang

Chem. Sci., 2016, 7, 3399
DOI: 10.1039/C6SC00077K

Molecular engineered nanomaterials for catalytic hydrogen evolution and oxidation

Nathan Coutard, Nicolas Kaeffer and Vincent Artero

Chem. Commun., 2016, 52, 13728
DOI: 10.1039/C6CC06311J

Production of hydrogen by electrocatalysis: making the H–H bond by combining protons and hydrides

R. Morris Bullock, Aaron M. Appel and Monte L. Helm

Chem. Commun., 2014, 50, 3125
DOI: 10.1039/C3CC46135A

Understanding light-driven H2 evolution through the electronic tuning of aminopyridine cobalt complexes

Arnau Call, Federico Franco, Noufal Kandoth, Sergio Fernández, María González-Béjar, Julia Pérez-Prieto, Josep M. Luis and Julio Lloret-Fillol

Chem. Sci., 2018, 9, 2609
DOI: 10.1039/C7SC04328G

Electrocatalytic hydrogen production activity with a copper(ii)-dipyridylamine complex in acidic water

Nilankar Diyali, Meena Chettri, Subhajit Saha, Ankita Saha, Subhankar Kundu, Debasish Mondal, Debasis Dhak and Bhaskar Biswas

CrystEngComm, 2023, 25, 6837
DOI: 10.1039/D3CE00996C

Copper-based electrocatalyst for hydrogen evolution in water

Abdullah M. Abudayyeh, Michael S. Bennington, Johan Hamonnet, Aaron T. Marshall and Sally Brooker

Dalton Trans., 2024, 53, 6207
DOI: 10.1039/D4DT00224E

Understanding the role of co-catalysts on silicon photocathodes using intensity modulated photocurrent spectroscopy

James E. Thorne, Yanyan Zhao, Da He, Shizhao Fan, Srinivas Vanka, Zetian Mi and Dunwei Wang

Phys. Chem. Chem. Phys., 2017, 19, 29653
DOI: 10.1039/C7CP06533G

Structural and chemical properties of half-sandwich rhodium complexes supported by the bis(2-pyridyl)methane ligand

Davide Lionetti, Victor W. Day and James D. Blakemore

Dalton Trans., 2019, 48, 12396
DOI: 10.1039/C9DT01821B

Electrosynthesis of NiPx nanospheres for electrocatalytic hydrogen evolution from a neutral aqueous solution

Mingxing Chen, Jing Qi, Wei Zhang and Rui Cao

Chem. Commun., 2017, 53, 5507
DOI: 10.1039/C7CC01584D

Supramolecular assembly of cobaloxime on nanoring-coated carbon nanotubes: addressing the stability of the pyridine–cobalt linkage under hydrogen evolution turnover conditions

Simon Donck, Jennifer Fize, Edmond Gravel, Eric Doris and Vincent Artero

Chem. Commun., 2016, 52, 11783
DOI: 10.1039/C6CC06059E

Flower-like CdSe ultrathin nanosheet assemblies for enhanced visible-light-driven photocatalytic H2 production

Yong Peng, Lu Shang, Tong Bian, Yufei Zhao, Chao Zhou, Huijun Yu, Li-Zhu Wu, Chen-Ho Tung and Tierui Zhang

Chem. Commun., 2015, 51, 4677
DOI: 10.1039/C5CC00136F

pH-Modulated activation of a pendant amine leading to rapid electrocatalytic H2 production by a molecular copper complex in acidic water

Naseer Ahmed Shah, Thinles Dolkar, Suhana Karim, Jumana Ishrat, Chandan Das, Srewashi Das, Aritro Sinha Roy, Kalishankar Bhattacharyya and Arnab Dutta

Inorg. Chem. Front., 2025, 12, 6178
DOI: 10.1039/D5QI00963D

CoSe2 necklace-like nanowires supported by carbon fiber paper: a 3D integrated electrode for the hydrogen evolution reaction

Ke Wang, Dan Xi, Chongjian Zhou, Zhongqi Shi, Hongyan Xia, Guiwu Liu and Guanjun Qiao

J. Mater. Chem. A, 2015, 3, 9415
DOI: 10.1039/C5TA01143D

Cobalt-based molecular electrocatalysis of nitrile reduction: evolving sustainability beyond hydrogen

Simon N. Child, Radoslav Raychev, Nathan Moss, Benjamin Howchen, Peter N. Horton, Christopher C. Prior, Vasily S. Oganesyan and John Fielden

Dalton Trans., 2019, 48, 9576
DOI: 10.1039/C9DT00773C

Electroreduction of a CoIIcoordination complex producing a metal–organic film with high performance toward electrocatalytic hydrogen evolution

Leticia S. Bezerra, Persiely P. Rosa, Guilherme V. Fortunato, Lucas Pizzuti, Gleison A. Casagrande and Gilberto Maia

J. Mater. Chem. A, 2018, 6, 19590
DOI: 10.1039/C8TA07340F

Artificial photosynthesis: opportunities and challenges of molecular catalysts

Biaobiao Zhang and Licheng Sun

Chem. Soc. Rev., 2019, 48, 2216
DOI: 10.1039/C8CS00897C

Recent advances in metal–organic frameworks for electrocatalytic hydrogen evolution and overall water splitting reactions

Yulia H. Budnikova

Dalton Trans., 2020, 49, 12483
DOI: 10.1039/D0DT01741H

Electrocatalytic hydrogen evolution using hybrid electrodes based on single-walled carbon nanohorns and cobalt(ii) polypyridine complexes

Elisabetta Benazzi, Federico Begato, Alessandro Niorettini, Lorenza Destro, Klaus Wurst, Giulia Licini, Stefano Agnoli, Cristiano Zonta and Mirco Natali

J. Mater. Chem. A, 2021, 9, 20032
DOI: 10.1039/D1TA03645A

Dual cobalt–copper light-driven catalytic reduction of aldehydes and aromatic ketones in aqueous media

Arnau Call, Carla Casadevall, Ferran Acuña-Parés, Alicia Casitas and Julio Lloret-Fillol

Chem. Sci., 2017, 8, 4739
DOI: 10.1039/C7SC01276D

Anion-exchange membranes in electrochemical energy systems

John R. Varcoe, Plamen Atanassov, Dario R. Dekel, Andrew M. Herring, Michael A. Hickner, Paul. A. Kohl, Anthony R. Kucernak, William E. Mustain, Kitty Nijmeijer, Keith Scott, Tongwen Xu and Lin Zhuang

Energy Environ. Sci., 2014, 7, 3135
DOI: 10.1039/C4EE01303D

The application of CeO2-based materials in electrocatalysis

Jianda Wang, Xiao Xiao, Yong Liu, Kunming Pan, Huan Pang and Shizhong Wei

J. Mater. Chem. A, 2019, 7, 17675
DOI: 10.1039/C9TA04804A

One-step synthesis of cubic pyrite-type CoSe2at low temperature for efficient hydrogen evolution reaction

Hongxiu Zhang, Lecheng Lei and Xingwang Zhang

RSC Adv., 2014, 4, 54344
DOI: 10.1039/C4RA07876D

Recent progress in ligand-centered homogeneous electrocatalysts for hydrogen evolution reaction

Geng-Geng Luo, Hai-Lin Zhang, Yun-Wen Tao, Qiao-Yu Wu, Dan Tian and Qichun Zhang

Inorg. Chem. Front., 2019, 6, 343
DOI: 10.1039/C8QI01220B

Engineering cobalt oxide by interfaces and pore architectures for enhanced electrocatalytic performance for overall water splitting

Lin-Fei Gu, Jun-Jia Chen, Tao Zhou, Xue-Feng Lu and Gao-Ren Li

Nanoscale, 2020, 12, 11201
DOI: 10.1039/D0NR02030C

A facile approach to fabricate free-standing hydrogen evolution electrodes: riveting tungsten carbide nanocrystals to graphite felt fabrics by carbon nanosheets

Yi Shen, Ling Li, Jingyu Xi and Xinping Qiu

J. Mater. Chem. A, 2016, 4, 5817
DOI: 10.1039/C6TA01236A

Investigating synergistic interactions of group 4, 5 and 6 metals with gold nanoparticles for the catalysis of the electrochemical hydrogen evolution reaction

Ubisha Joshi, Souradip Malkhandi and Boon Siang Yeo

Phys. Chem. Chem. Phys., 2017, 19, 20861
DOI: 10.1039/C7CP03188B

Tuning the electronic structure of Co@N–C hybrids via metal-doping for efficient electrocatalytic hydrogen evolution reaction

Peiyun Zhou, Linmeng Wang, Junjun Lv, Rushuo Li, Fengyu Gao, Xiubing Huang, Yunfeng Lu and Ge Wang

J. Mater. Chem. A, 2022, 10, 4981
DOI: 10.1039/D1TA08226D

Mo-Doped NiCu as an efficient and stable electrocatalyst for the hydrogen evolution reaction

Zhengnan Wang, Xingbo Ge, Zhihao Li, Jing Wu, Zihao Liang and Shuang Wang

New J. Chem., 2019, 43, 9652
DOI: 10.1039/C9NJ01263J

Ru-tweaking of non-precious materials: the tale of a strategy that ensures both cost and energy efficiency in electrocatalytic water splitting

S. Anantharaj

J. Mater. Chem. A, 2021, 9, 6710
DOI: 10.1039/D0TA12424A

Exploring the effect of a pendent amine group poised over the secondary coordination sphere of a cobalt complex on the electrocatalytic hydrogen evolution reaction

Afsar Ali, Rajaneesh Kumar Verma, Avijit Das and Sayantan Paria

Dalton Trans., 2024, 53, 8289
DOI: 10.1039/D4DT00009A

Synthesis of an imine-type nickel complex and investigation of its electrocatalytic activity for H2 evolution

Lan H. Le, Ngoc H. Pham, Phong D. Tran and Tung H. To

RSC Adv., 2025, 15, 2430
DOI: 10.1039/D4RA08116A

IrO2–TiO2 electrocatalysts for the hydrogen evolution reaction in acidic water electrolysis without activation

Min Yuan, Yuchan Zhu, Li Deng, Ruoxi Ming, Ailian Zhang, Wenyang Li, Bo Chai and Zhandong Ren

New J. Chem., 2017, 41, 6152
DOI: 10.1039/C7NJ00756F

Preparation of electrocatalysts using a thiol–amine solution processing method

Carrie L. McCarthy and Richard L. Brutchey

Dalton Trans., 2018, 47, 5137
DOI: 10.1039/C8DT00442K

Simplifying levulinic acid conversion towards a sustainable biomass valorisation

Chiara Defilippi, Daily Rodríguez-Padrón, Rafael Luque and Cristina Giordano

Green Chem., 2020, 22, 2929
DOI: 10.1039/C9GC04306C

Facile electrodeposition of cauliflower-like S-doped nickel microsphere films as highly active catalysts for electrochemical hydrogen evolution

J. R. Zeng, M. Y. Gao, Q. B. Zhang, C. Yang, X. T. Li, W. Q. Yang, Y. X. Hua, C. Y. Xu and Y. Li

J. Mater. Chem. A, 2017, 5, 15056
DOI: 10.1039/C7TA04559J

Cobaloxime anchored MoS2 nanosheets as electrocatalysts for the hydrogen evolution reaction

Ming Cai, Fan Zhang, Chao Zhang, Chenbao Lu, Yafei He, Yang Qu, Hao Tian, Xinliang Feng and Xiaodong Zhuang

J. Mater. Chem. A, 2018, 6, 138
DOI: 10.1039/C7TA08684A

Ligand-based electronic effects on the electrocatalytic hydrogen production by thiosemicarbazone nickel complexes

Michael Papadakis, Alexandre Barrozo, Tatiana Straistari, Nicolas Queyriaux, Anisa Putri, Jennifer Fize, Michel Giorgi, Marius Réglier, Julien Massin, Renaud Hardré and Maylis Orio

Dalton Trans., 2020, 49, 5064
DOI: 10.1039/C9DT04775A

Anode co-valorization for scalable and sustainable electrolysis

Joshua Jack, Wenjin Zhu, José L. Avalos, Jinlong Gong and Zhiyong Jason Ren

Green Chem., 2021, 23, 7917
DOI: 10.1039/D1GC02094C

A macrocyclic ‘Co0’ complex: the relevance of ligand non-innocence to reactivity

Manuel Kaspar, Philipp J. Altmann, Alexander Pöthig, Stephen Sproules and Corinna R. Hess

Chem. Commun., 2017, 53, 7282
DOI: 10.1039/C7CC02239E

Advanced hydrogen evolution electrocatalysts promising sustainable hydrogen and chlor-alkali co-production

Lu-Nan Zhang, Rui Li, Hong-Ying Zang, Hua-Qiao Tan, Zhen-Hui Kang, Yong-Hui Wang and Yang-Guang Li

Energy Environ. Sci., 2021, 14, 6191
DOI: 10.1039/D1EE02798K

Hierarchical CoS/MoS2 and Co3S4/MoS2/Ni2P nanotubes for efficient electrocatalytic hydrogen evolution in alkaline media

Haifeng Lin, Haoyi Li, Yanyan Li, Junli Liu, Xun Wang and Lei Wang

J. Mater. Chem. A, 2017, 5, 25410
DOI: 10.1039/C7TA08760H

Targeted design of organic Janus particles for improved photocatalytic hydrogen evolution

Khaoula Missaoui, Guillaume Wantz, Thierry Toupance, Sylvain Chambon and Alexander Kuhn

Chem. Sci., 2025, 16, 10691
DOI: 10.1039/D5SC00802F

Earth-abundant inorganic electrocatalysts and their nanostructures for energy conversion applications

Matthew S. Faber and Song Jin

Energy Environ. Sci., 2014, 7, 3519
DOI: 10.1039/C4EE01760A

Bioinspired metal complexes for energy-related photocatalytic small molecule transformation

Hao-Lin Wu, Xu-Bing Li, Chen-Ho Tung and Li-Zhu Wu

Chem. Commun., 2020, 56, 15496
DOI: 10.1039/D0CC05870J

Hydrogen evolution reaction (HER) on Au@Ag ultrananoclusters as electro-catalysts

Le Chang, Daojian Cheng, Luca Sementa and Alessandro Fortunelli

Nanoscale, 2018, 10, 17730
DOI: 10.1039/C8NR06105J

Catalytic and mechanistic studies of a highly active and E-selective Co(ii) PNNH pincer catalyst system for transfer-semihydrogenation of internal alkynes

David Decker, Zhihong Wei, Jabor Rabeah, Hans-Joachim Drexler, Angelika Brückner, Haijun Jiao and Torsten Beweries

Inorg. Chem. Front., 2022, 9, 761
DOI: 10.1039/D1QI00998B

Self-supporting FeCoMoP nanosheets for efficient overall water splitting

Hongxi Xiong, Shuihua Tang, Mingjie Xu, Zelong Yu, Yuhang Xie, Shaoxiong Zhang, Xiaohan Wang, Yonglin Chen and Lei Zhang

New J. Chem., 2024, 48, 2679
DOI: 10.1039/D3NJ05592B

Functional integration of Ni–Mo electrocatalysts with Si microwire array photocathodes to simultaneously achieve high fill factors and light-limited photocurrent densities for solar-driven hydrogen evolution

Matthew R. Shaner, James R. McKone, Harry B. Gray and Nathan S. Lewis

Energy Environ. Sci., 2015, 8, 2977
DOI: 10.1039/C5EE01076D

Light-driven hydrogen evolution catalyzed by a cobaloxime catalyst incorporated in a MIL-101(Cr) metal–organic framework

Souvik Roy, Asamanjoy Bhunia, Nils Schuth, Michael Haumann and Sascha Ott

Sustainable Energy Fuels, 2018, 2, 1148
DOI: 10.1039/C8SE00072G

Water electrolysis: from textbook knowledge to the latest scientific strategies and industrial developments

Marian Chatenet, Bruno G. Pollet, Dario R. Dekel, Fabio Dionigi, Jonathan Deseure, Pierre Millet, Richard D. Braatz, Martin Z. Bazant, Michael Eikerling, Iain Staffell, Paul Balcombe, Yang Shao-Horn and Helmut Schäfer

Chem. Soc. Rev., 2022, 51, 4583
DOI: 10.1039/D0CS01079K

Toward the rational benchmarking of homogeneous H2-evolving catalysts

Vincent Artero and Jean-Michel Saveant

Energy Environ. Sci., 2014, 7, 3808
DOI: 10.1039/C4EE01709A

Driving electrocatalytic activity by interface electronic structure control in a metalloprotein hybrid catalyst for efficient hydrogen evolution

Sushant Kumar Behera, Pritam Deb and Arghya Ghosh

Phys. Chem. Chem. Phys., 2016, 18, 23220
DOI: 10.1039/C6CP03964B

Successes, challenges, and opportunities for quantum chemistry in understanding metalloenzymes for solar fuels research

Maylis Orio and Dimitrios A. Pantazis

Chem. Commun., 2021, 57, 3952
DOI: 10.1039/D1CC00705J

Exfoliated semiconducting pure 2H-MoS2 and 2H-WS2 assisted by chlorosulfonic acid

Georgia Pagona, Carla Bittencourt, Raul Arenal and Nikos Tagmatarchis

Chem. Commun., 2015, 51, 12950
DOI: 10.1039/C5CC04689K

Synthetic styrene-based bioinspired model of the [FeFe]-hydrogenase active site for electrocatalytic hydrogen evolution

Afridi Zamader, Bertrand Reuillard, Julien Pérard, Laurent Billon, Gustav Berggren and Vincent Artero

Sustainable Energy Fuels, 2023, 7, 4967
DOI: 10.1039/D3SE00409K

Recent advances in the mechanisms of the hydrogen evolution reaction by non-innocent sulfur-coordinating metal complexes

Maria Drosou, Fotios Kamatsos and Christiana A. Mitsopoulou

Inorg. Chem. Front., 2020, 7, 37
DOI: 10.1039/C9QI01113G

Hydrogen adsorption trends on two metal-doped Ni2P surfaces for optimal catalyst design

Lauri Partanen, Simon Alberti and Kari Laasonen

Phys. Chem. Chem. Phys., 2021, 23, 11538
DOI: 10.1039/D1CP00684C

Recent advances in heterogeneous electrocatalysts for the hydrogen evolution reaction

Min Zeng and Yanguang Li

J. Mater. Chem. A, 2015, 3, 14942
DOI: 10.1039/C5TA02974K

Nickel nitride as an efficient electrocatalyst for water splitting

Menny Shalom, Debora Ressnig, Xiaofei Yang, Guylhaine Clavel, Tim Patrick Fellinger and Markus Antonietti

J. Mater. Chem. A, 2015, 3, 8171
DOI: 10.1039/C5TA00078E

A MnCo2S4nanowire array as an earth-abundant electrocatalyst for an efficient oxygen evolution reaction under alkaline conditions

Xiaoping Zhang, Chongdian Si, Xiaoxi Guo, Rongmei Kong and Fengli Qu

J. Mater. Chem. A, 2017, 5, 17211
DOI: 10.1039/C7TA04804A

Mononuclear Mn complexes featuring N,S-/N,N-donor and 1,3,5-triaza-7-phosphaadamantane ligands: synthesis and electrocatalytic properties

Vishakha Kaim and Sandeep Kaur-Ghumaan

New J. Chem., 2021, 45, 20272
DOI: 10.1039/D1NJ02104D

One dimensional metal dithiolene (M = Ni, Fe, Zn) coordination polymers for the hydrogen evolution reaction

Courtney A. Downes and Smaranda C. Marinescu

Dalton Trans., 2016, 45, 19311
DOI: 10.1039/C6DT03257E

Polymeric coatings for applications in electrocatalytic and photoelectrosynthetic fuel production

B. L. Wadsworth, D. Khusnutdinova and G. F. Moore

J. Mater. Chem. A, 2018, 6, 21654
DOI: 10.1039/C8TA05805A

Photocatalytic hydrogen evolution with ruthenium polypyridine sensitizers: unveiling the key factors to improve efficiencies

Elisa Deponti and Mirco Natali

Dalton Trans., 2016, 45, 9136
DOI: 10.1039/C6DT01221C

Mn-modified nickel oxide for selective methanol oxidation: a route toward integrated formate electrosynthesis and hydrogen generation

Ning Jian, Yi Ma, Huan Ge, Yong Zhang, Jiwei Hu, Yun Ke, Chaochao Li, Jing Yu, Jordi Arbiol, Junfeng Liu, Andreu Cabot and Junshan Li

J. Mater. Chem. A, 2025, 13, 34772
DOI: 10.1039/D5TA05348J

Facile synthesis of iron phosphide nanorods for efficient and durable electrochemical oxygen evolution

Dehua Xiong, Xiaoguang Wang, Wei Li and Lifeng Liu

Chem. Commun., 2016, 52, 8711
DOI: 10.1039/C6CC04151E

Water-assisted proton delivery and removal in bio-inspired hydrogen production catalysts

Ming-Hsun Ho, Molly O'Hagan, Michel Dupuis, Daniel L. DuBois, R. Morris Bullock, Wendy J. Shaw and Simone Raugei

Dalton Trans., 2015, 44, 10969
DOI: 10.1039/C5DT00782H

Perspectives on metal–organic frameworks with intrinsic electrocatalytic activity

Marcello B. Solomon, Tamara L. Church and Deanna M. D'Alessandro

CrystEngComm, 2017, 19, 4049
DOI: 10.1039/C7CE00215G

Oxygen-tolerant hydrogen evolution in water using Schiff base copper complexes with tuneable secondary coordination environments

Santanu Ghorai, Gulafshan, Sukanta Saha, Abhishek Saini, Chandan Das, Yashwant Pratap Kharwar, Aritro Sinha Roy and Arnab Dutta

Dalton Trans., 2025, 54, 14505
DOI: 10.1039/D5DT01278C

Reaction mechanism of the selective reduction of CO2 to CO by a tetraaza [CoIIN4H]2+ complex in the presence of protons

Alejandro J. Garza, Srimanta Pakhira, Alexis T. Bell, Jose L. Mendoza-Cortes and Martin Head-Gordon

Phys. Chem. Chem. Phys., 2018, 20, 24058
DOI: 10.1039/C8CP01963K

Rational design of an efficient descriptor for single-atom catalysts in the hydrogen evolution reaction

Hai-Cai Huang, Yang Zhao, Jing Wang, Jun Li, Jing Chen, Qiang Fu, Yu-Xiang Bu and Shi-Bo Cheng

J. Mater. Chem. A, 2020, 8, 9202
DOI: 10.1039/D0TA01500H

Polyoxometalate-based metal–organic framework-derived hybrid electrocatalysts for highly efficient hydrogen evolution reaction

Ji-Sen Li, Yu-Jia Tang, Chun-Hui Liu, Shun-Li Li, Run-Han Li, Long-Zhang Dong, Zhi-Hui Dai, Jian-Chun Bao and Ya-Qian Lan

J. Mater. Chem. A, 2016, 4, 1202
DOI: 10.1039/C5TA09743F

Oxide-derived nanostructured metallic-glass electrodes for efficient electrochemical hydrogen generation

Shenghan Gao, Jili Jia, Shuangqin Chen, Hengwei Luan, Yang Shao and Kefu Yao

RSC Adv., 2017, 7, 27058
DOI: 10.1039/C7RA02954C

Au@Co2P core/shell nanoparticles as a nano-electrocatalyst for enhancing the oxygen evolution reaction

Xiaofang Zhang, Aixian Shan, Sibin Duan, Haofei Zhao, Rongming Wang and Woon-Ming Lau

RSC Adv., 2019, 9, 40811
DOI: 10.1039/C9RA07535F

A tricarboxylated PtCl(terpyridine) derivative exhibiting pH-dependent photocatalytic activity for H2 evolution from water

Kosei Yamauchi and Ken Sakai

Dalton Trans., 2015, 44, 8685
DOI: 10.1039/C5DT00425J

Efficient hydrogen evolution reaction catalyzed by molybdenum carbide and molybdenum nitride nanocatalysts synthesized via the urea glass route

Liang Ma, Louisa Rui Lin Ting, Valerio Molinari, Cristina Giordano and Boon Siang Yeo

J. Mater. Chem. A, 2015, 3, 8361
DOI: 10.1039/C5TA00139K

Precision and correctness in the evaluation of electrocatalytic water splitting: revisiting activity parameters with a critical assessment

S. Anantharaj, S. R. Ede, K. Karthick, S. Sam Sankar, K. Sangeetha, P. E. Karthik and Subrata Kundu

Energy Environ. Sci., 2018, 11, 744
DOI: 10.1039/C7EE03457A

Electrodeposition behavior of homoleptic transition metal acetonitrile complexes interrogated with piezoelectric gravimetry

David J. Sconyers and James D. Blakemore

Analyst, 2020, 145, 466
DOI: 10.1039/C9AN01952A

Boosting hydrogen evolution by using covalent frameworks of fluorinated cobalt porphyrins supported on carbon nanotubes

Gelun Xu, Haitao Lei, Guojun Zhou, Chaochao Zhang, Lisi Xie, Wei Zhang and Rui Cao

Chem. Commun., 2019, 55, 12647
DOI: 10.1039/C9CC06916J

Atomic-layer-deposited ultrafine MoS2nanocrystals on cobalt foam for efficient and stable electrochemical oxygen evolution

Dehua Xiong, Qingqing Zhang, Wei Li, Junjie Li, Xiuli Fu, M. F. Cerqueira, Pedro Alpuim and Lifeng Liu

Nanoscale, 2017, 9, 2711
DOI: 10.1039/C7NR00140A

Enhancing the reactivity of nickel(ii) in hydrogen evolution reactions (HERs) by β-hydrogenation of porphyrinoid ligands

Zhuo-Yan Wu, Teng Wang, Yin-Shan Meng, Yu Rao, Bing-Wu Wang, Jie Zheng, Song Gao and Jun-Long Zhang

Chem. Sci., 2017, 8, 5953
DOI: 10.1039/C7SC02073B

Electrocatalytic reduction of protons to dihydrogen by the cobalt tetraazamacrocyclic complex [Co(N4H)Cl2]+: mechanism and benchmarking of performances

Cheng-Bo Li, Andrew J. Bagnall, Dongyue Sun, Julia Rendon, Matthieu Koepf, Serge Gambarelli, Jean-Marie Mouesca, Murielle Chavarot-Kerlidou and Vincent Artero

Sustainable Energy Fuels, 2022, 6, 143
DOI: 10.1039/D1SE01267C

Highly active MoS2/carbon electrocatalysts for the hydrogen evolution reaction – insight into the effect of the internal resistance and roughness factor on the Tafel slope

Arun Prasad Murthy, Jayaraman Theerthagiri, Jagannathan Madhavan and Kadarkarai Murugan

Phys. Chem. Chem. Phys., 2017, 19, 1988
DOI: 10.1039/C6CP07416B

Exploring ligand-centered electrocatalytic H2O reduction: hydrogen generation with a soluble Ni(ii) octabutoxyphthalocyanine complex

Josh Brown and Darrin Richeson

Dalton Trans., 2024, 53, 14587
DOI: 10.1039/D4DT01419G

Highly functionalizable penta-coordinate iron hydrogen production catalysts with low overpotentials

Shawn C. Eady, Tanya Breault, Levi Thompson and Nicolai Lehnert

Dalton Trans., 2016, 45, 1138
DOI: 10.1039/C5DT03744A

Cobalt, nickel, and iron complexes of 8-hydroxyquinoline-di(2-picolyl)amine for light-driven hydrogen evolution

Nadia Alessandra Carmo dos Santos, Mirco Natali, Elena Badetti, Klaus Wurst, Giulia Licini and Cristiano Zonta

Dalton Trans., 2017, 46, 16455
DOI: 10.1039/C7DT02666H

Synthesis and characterization of an IrO2–Fe2O3 electrocatalyst for the hydrogen evolution reaction in acidic water electrolysis

Xian Yang, Yande Li, Li Deng, Wenyang Li, Zhandong Ren, Ming Yang, Xiaohong Yang and Yuchan Zhu

RSC Adv., 2017, 7, 20252
DOI: 10.1039/C7RA01533J

Cobalt corroles with phosphonic acid pendants as catalysts for oxygen and hydrogen evolution from neutral aqueous solution

Huiling Sun, Yongzhen Han, Haitao Lei, Mingxing Chen and Rui Cao

Chem. Commun., 2017, 53, 6195
DOI: 10.1039/C7CC02400B

Photocatalytic H2 production under visible-light irradiation based on covalent attachment of manganese phthalocyanine to graphene

Dandan Wang, Jie Huang, Xia Li, Ping Yang, Yukou Du, Cynthia M. Goh and Cheng Lu

J. Mater. Chem. A, 2015, 3, 4195
DOI: 10.1039/C4TA05721J

A noble metal-free photocatalytic system based on a novel cobalt tetrapyridyl catalyst for hydrogen production in fully aqueous medium

N. Queyriaux, E. Giannoudis, C. D. Windle, S. Roy, J. Pécaut, A. G. Coutsolelos, V. Artero and M. Chavarot-Kerlidou

Sustainable Energy Fuels, 2018, 2, 553
DOI: 10.1039/C7SE00428A

Electrocatalysis of the hydrogen-evolution reaction by electrodeposited amorphous cobalt selenide films

Azhar I. Carim, Fadl H. Saadi, Manuel P. Soriaga and Nathan S. Lewis

J. Mater. Chem. A, 2014, 2, 13835
DOI: 10.1039/C4TA02611J

Distinguishing deposition, corrosion, and stripping of transient heterogeneous materials during molecular electrocatalysis

David J. Sconyers and James D. Blakemore

Dalton Trans., 2019, 48, 6372
DOI: 10.1039/C9DT00584F

Multimetallic Ni–Mo/Cu nanowires as nonprecious and efficient full water splitting catalyst

Shunan Zhao, Jianfei Huang, Yanyan Liu, Jianhua Shen, Hao Wang, Xiaoling Yang, Yihua Zhu and Chunzhong Li

J. Mater. Chem. A, 2017, 5, 4207
DOI: 10.1039/C6TA10749D

Diethylenetriamine-mediated self-assembly of three-dimensional hierarchical nanoporous CoP nanoflowers/pristine graphene interconnected networks as efficient electrocatalysts toward hydrogen evolution

Xiuling Fan, Xiaoyan Wang, Weiyong Yuan and Chang Ming Li

Sustainable Energy Fuels, 2017, 1, 2172
DOI: 10.1039/C7SE00454K

2H → 1T phase transition and hydrogen evolution activity of MoS2, MoSe2, WS2 and WSe2 strongly depends on the MX2 composition

Adriano Ambrosi, Zdeněk Sofer and Martin Pumera

Chem. Commun., 2015, 51, 8450
DOI: 10.1039/C5CC00803D

Controllable Co@N-doped graphene anchored onto the NRGO toward electrocatalytic hydrogen evolution at all pH values

Lijuan Jiang, Lijun Qiu, Tianlun Cen, Yi-Yi Liu, Xiaomin Peng, Zhifeng Ye and Dingsheng Yuan

Chem. Commun., 2020, 56, 567
DOI: 10.1039/C9CC07994G

Large changes in hydricity as a function of charge and not metal in (PNP)M–H (de)hydrogenation catalysts that undergo metal–ligand cooperativity

Kevin Schlenker, Lillee K. Casselman, Ryan T. VanderLinden and Caroline T. Saouma

Catal. Sci. Technol., 2023, 13, 1358
DOI: 10.1039/D2CY01349E

Electrocatalytic hydrogen evolution reaction by a Ni(N2O2) complex based on 2,2′-bipyridine

Julia M. Dressel, Emma N. Cook, Shelby L. Hooe, Juan J. Moreno, Diane A. Dickie and Charles W. Machan

Inorg. Chem. Front., 2023, 10, 972
DOI: 10.1039/D2QI01928K

Mechanisms of catalytic reduction of CO2 with heme and nonheme metal complexes

Shunichi Fukuzumi, Yong-Min Lee, Hyun S. Ahn and Wonwoo Nam

Chem. Sci., 2018, 9, 6017
DOI: 10.1039/C8SC02220H

Structural characterization and proton reduction electrocatalysis of thiolate-bridged bimetallic (CoCo and CoFe) complexes

Peng Tong, Wenjie Xie, Dawei Yang, Baomin Wang, Xiaoxiao Ji, Jianzhe Li and Jingping Qu

Dalton Trans., 2016, 45, 18559
DOI: 10.1039/C6DT03275C

In-situ hydrothermal synthesis of Ni–MoO2 heterostructure on porous bulk NiMo alloy for efficient hydrogen evolution reaction

Jian TANG, Ji-lin XU, Liang-liang LI, Yong-cun MA, Zhi-guo YE, Hong-yu LUO and Jun-ming LUO

Transactions of Nonferrous Metals Society of China, 2022, 32, 1598
DOI: 10.1016/S1003-6326(22)65896-5

Developments and Perspectives in 3d Transition‐Metal‐Based Electrocatalysts for Neutral and Near‐Neutral Water Electrolysis

Sengeni Anantharaj and Vanchiappan Aravindan

Advanced Energy Materials, 2020, 10
DOI: 10.1002/aenm.201902666

Blending Cr2O3 into a NiO–Ni Electrocatalyst for Sustained Water Splitting

Ming Gong, Wu Zhou, Michael James Kenney, Rich Kapusta, Sam Cowley, Yingpeng Wu, Bingan Lu, Meng‐Chang Lin, Di‐Yan Wang, Jiang Yang, Bing‐Joe Hwang and Hongjie Dai

Angew Chem Int Ed, 2015, 54, 11989
DOI: 10.1002/anie.201504815

Activating Hydrogen Evolution Reaction on Carbon Nanotube via Aryl Functionalisation: The Role of Hybrid sp2–sp3 Interface and Curvature

Muhammad Ahmed, Gurpreet Kour, Ziqi Sun, Aijun Du and Xin Mao

Nanomaterials, 2023, 13, 2122
DOI: 10.3390/nano13142122

Design and synthesis of heteroleptic Ni(II) dipyrrin complexes for electrochemical proton reduction reactions: Cyclic voltammetric and theoretical studies

Rajendra Prasad Paitandi, Indranil Mondal, Yogesh Kumar, Nikhil Kumar Singh and Daya Shankar Pandey

Inorganica Chimica Acta, 2024, 569, 122113
DOI: 10.1016/j.ica.2024.122113

Advanced heterostructures as bifunctional electrocatalysts for overall water splitting - a review

Nihila Rahamathulla and Arun Prasad Murthy

Journal of Energy Storage, 2023, 73, 109127
DOI: 10.1016/j.est.2023.109127

Role of Oxidized Mo Species on the Active Surface of Ni–Mo Electrocatalysts for Hydrogen Evolution under Alkaline Conditions

Jeremy A. Bau, Sergey M. Kozlov, Luis Miguel Azofra, Samy Ould-Chikh, Abdul-Hamid Emwas, Hicham Idriss, Luigi Cavallo and Kazuhiro Takanabe

ACS Catal., 2020, 10, 12858
DOI: 10.1021/acscatal.0c02743

CO2 to CO Electroreduction, Electrocatalytic H2 Evolution, and Catalytic Degradation of Organic Dyes Using a Co(II) meso-Tetraarylporphyrin

Mouhieddinne Guergueb, Frédérique Loiseau, Florian Molton, Habib Nasri and Axel Klein

Molecules, 2022, 27, 1705
DOI: 10.3390/molecules27051705

Molecular-Modified Photocathodes for Applications in Artificial Photosynthesis and Solar-to-Fuel Technologies

Edgar A. Reyes Cruz, Daiki Nishiori, Brian L. Wadsworth, Nghi P. Nguyen, Lillian K. Hensleigh, Diana Khusnutdinova, Anna M. Beiler and G. F. Moore

Chem. Rev., 2022, 122, 16051
DOI: 10.1021/acs.chemrev.2c00200

Electro‐Oxidation of Ni42 Steel: A Highly Active Bifunctional Electrocatalyst

Helmut Schäfer, Daniel M. Chevrier, Peng Zhang, Johannes Stangl, Klaus Müller‐Buschbaum, Jörg D. Hardege, Karsten Kuepper, Joachim Wollschläger, Ulrich Krupp, Simon Dühnen, Martin Steinhart, Lorenz Walder, Shamaila Sadaf and Mercedes Schmidt

Adv Funct Materials, 2016, 26, 6402
DOI: 10.1002/adfm.201601581

A new catalyst based on a nickel(II) complex of diiminodiphosphine for hydrogen evolution and oxidation

Chun-Li Wang, Hao Yang, Juan Du and Shu-Zhong Zhan

International Journal of Hydrogen Energy, 2021, 46, 32480
DOI: 10.1016/j.ijhydene.2021.07.100

A new copper(I)–triazenido electro-catalyst for catalyzing hydrogen evolution from acetic acid and water

Ting Fang, Hai-Xia Lu, Jia-Xing Zhao, Shu-Zhong Zhan and Qi-Ying Lv

Journal of Molecular Catalysis A: Chemical, 2015, 396, 304
DOI: 10.1016/j.molcata.2014.10.008

Bimetallic [Co/K] hydrogen evolution catalyst for electrochemical terminal C-H functionalization

Sheng Zhang, Lei Hong, Jiayi Feng, Mohan Wang, Junyuan Hu, Ying Zhang and Man-Bo Li

Nat Commun, 2025, 16
DOI: 10.1038/s41467-025-63914-0

Elektrochemie der Wasserstoffentwicklungsreaktion: Optimierung durch Korrelation von Experiment und Theorie

Yao Zheng, Yan Jiao, Mietek Jaroniec and Shi Zhang Qiao

Angewandte Chemie, 2015, 127, 52
DOI: 10.1002/ange.201407031

Organic Electrochemical Cathodic Reduction of CO, CN, and NN

Bao‐Jie Wang, Jingye Fu, Zhihua Cai, Li‐Ming Zhang, Weisi Guo and Lin‐Bao Zhang

The Chemical Record, 2026
DOI: 10.1002/tcr.202500295

Reaction Parameters Influencing Cobalt Hydride Formation Kinetics: Implications for Benchmarking H2-Evolution Catalysts

Noémie Elgrishi, Daniel A. Kurtz and Jillian L. Dempsey

J. Am. Chem. Soc., 2017, 139, 239
DOI: 10.1021/jacs.6b10148

Engineering phase transformation of cobalt selenide in carbon cages and the phases’ bifunctional electrocatalytic activity for water splitting

Jiaojiao Gao, Li Liu, Hua-Jun Qiu and Yu Wang

Nanotechnology, 2017, 28, 315401
DOI: 10.1088/1361-6528/aa788b

Metal Doping and Ligand Engineering as Tools for Tailoring the Electronic Structure of Coordination Polymers and their Oxygen Evolution Electrocatalytic Activity

Gabriel Menendez Rodriguez and Alceo Macchioni

Eur J Inorg Chem, 2023, 26
DOI: 10.1002/ejic.202200625

Defects engineering of bimetallic Ni-based catalysts for electrochemical energy conversion

Lei Lei, Danlian Huang, Min Cheng, Rui Deng, Sha Chen, Yashi Chen and Wenjun Wang

Coordination Chemistry Reviews, 2020, 418, 213372
DOI: 10.1016/j.ccr.2020.213372

Tuning of Redox Energy of Transition-Metal Ions through the Utilization of Interlayer Potentials in Layered Perovskites: Development of a Titanium-Based Superior HER Catalyst in an Acidic Medium

Shraddha Jaiswal, Rakesh Mondal, Vishal Kushwaha, Asha Gupta and Preetam Singh

ACS Appl. Energy Mater., 2023, 6, 7323
DOI: 10.1021/acsaem.3c00361

General principles for designing supported catalysts for hydrogen evolution reaction based on conceptual Kinetic Monte Carlo modeling

Igor A. Pašti, Mikael Leetmaa and Natalia V. Skorodumova

International Journal of Hydrogen Energy, 2016, 41, 2526
DOI: 10.1016/j.ijhydene.2015.12.026

Hierarchical Transition‐Metal Dichalcogenide Nanosheets for Enhanced Electrocatalytic Hydrogen Evolution

Jian Zhang, Shaohua Liu, Haiwei Liang, Renhao Dong and Xinliang Feng

Advanced Materials, 2015, 27, 7426
DOI: 10.1002/adma.201502765

Electrocatalytic Hydrogen Evolution and Hydrogen Oxidation with a Ni(PS)2 Complex

Rahul Jain, Mark S. Mashuta, Robert M. Buchanan and Craig A. Grapperhaus

Eur J Inorg Chem, 2017, 2017, 3714
DOI: 10.1002/ejic.201700590

Oxygen deficient V2O3: A stable and efficient electrocatalyst for HER and high performance EDLCs

Shweta Chalotra, Rameez Ahmad Mir, Gurbinder Kaur and O.P. Pandey

Ceramics International, 2020, 46, 703
DOI: 10.1016/j.ceramint.2019.09.023

A coordinatively saturated cobalt complex as a new kind catalyst for efficient electro- and photo-catalytic hydrogen production in purely aqueous media

Qiu-Xia Peng, Dan Xue, Ling-Fen Yang and Shu-Zhong Zhan

International Journal of Hydrogen Energy, 2017, 42, 16428
DOI: 10.1016/j.ijhydene.2017.05.198

Atomic-Level Functionalized Graphdiyne for Electrocatalysis Applications

Xiaodong Qian, Yongshen Zheng, Songhua Chen and Jialiang Xu

Catalysts, 2020, 10, 929
DOI: 10.3390/catal10080929

Solar Hydrogen Production Using Molecular Catalysts Immobilized on Gallium Phosphide (111)A and (111)B Polymer-Modified Photocathodes

Anna M. Beiler, Diana Khusnutdinova, Samuel I. Jacob and Gary F. Moore

ACS Appl. Mater. Interfaces, 2016, 8, 10038
DOI: 10.1021/acsami.6b01557

Redox-Mediator-Assisted Electrocatalytic Hydrogen Evolution from Water by a Molybdenum Sulfide-Functionalized Metal–Organic Framework

Hyunho Noh, Chung-Wei Kung, Ken-ichi Otake, Aaron W. Peters, Zhanyong Li, Yijun Liao, Xinyi Gong, Omar K. Farha and Joseph T. Hupp

ACS Catal., 2018, 8, 9848
DOI: 10.1021/acscatal.8b02921

Electrocatalytic Proton Reduction by a Cobalt Complex Containing a Proton‐Responsive Bis(alkylimdazole)methane Ligand: Involvement of a C−H Bond in H2 Formation

Pradip Ghosh, Sander de Vos, Martin Lutz, Frederic Gloaguen, Philippe Schollhammer, Marc‐Etienne Moret and Robertus J. M. Klein Gebbink

Chemistry A European J, 2020, 26, 12560
DOI: 10.1002/chem.201905746

Branched nanostructures for photoelectrochemical water splitting

Yuanbing Mao

Nanomaterials and Energy, 2014, 3, 103
DOI: 10.1680/nme.14.00008

Oxygen vacancies and V co-doped Co3O4 prepared by ion implantation boosts oxygen evolution catalysis*

Bo Sun, Dong He, Hongbo Wang, Jiangchao Liu, Zunjian Ke, Li Cheng and Xiangheng Xiao

Chinese Phys. B, 2021, 30, 106102
DOI: 10.1088/1674-1056/ac1339

Green Rust: The Simple Organizing ‘Seed’ of All Life?

Michael J. Russell

Life, 2018, 8, 35
DOI: 10.3390/life8030035

Nickel–Copper Alloy Encapsulated in Graphitic Carbon Shells as Electrocatalysts for Hydrogen Evolution Reaction

Yi Shen, Yongfang Zhou, Duo Wang, Xi Wu, Jia Li and Jingyu Xi

Advanced Energy Materials, 2018, 8
DOI: 10.1002/aenm.201701759

Hydrogen Evolution, Oxygen Evolution, and Oxygen Reduction at Polarizable Liquid|Liquid Interfaces

Marcin Opallo, Katarzyna Dusilo, Magdalena Warczak and Justyna Kalisz

ChemElectroChem, 2022, 9
DOI: 10.1002/celc.202200513

The use of DES green solvents to produce electrocatalytically active Ni–Mo alloys. The insight into the role of surface chemistry and mechanism of HER

Anna Niciejewska, Grzegorz Dercz, Izabela Matuła, Andrzej Żak, Włodzimierz Tylus, Agnieszka Laszczyńska and Juliusz Winiarski

International Journal of Hydrogen Energy, 2024, 96, 21
DOI: 10.1016/j.ijhydene.2024.11.243

Covalent-Organic Frameworks Composed of Rhenium Bipyridine and Metal Porphyrins: Designing Heterobimetallic Frameworks with Two Distinct Metal Sites

Eric M. Johnson, Ralf Haiges and Smaranda C. Marinescu

ACS Appl. Mater. Interfaces, 2018, 10, 37919
DOI: 10.1021/acsami.8b07795

Electrocatalytic Proton Reduction by Dimeric Nickel Complex of a Sterically Demanding Pincer-type NS2 Aminobis(thiophenolate) Ligand

Alexander Mondragón, Marcos Flores-Alamo, Paulina R. Martínez-Alanis, Gabriel Aullón, Víctor M. Ugalde-Saldívar and Ivan Castillo

Inorg. Chem., 2015, 54, 619
DOI: 10.1021/ic502547y

Onsite Deposition of Self-Repairing Biomimetic Nanostructured Ni Catalysts with Improved Electrocatalysis toward Glycerol Oxidation for H 2 Production

Mingshu Xiao, Yuqing Miao, Weiwei Li, Yang Yang and Xiaocai Liang

Electrochimica Acta, 2015, 178, 209
DOI: 10.1016/j.electacta.2015.07.185

Switching Electrocatalytic Hydrogen Evolution Pathways through Electronic Tuning of Copper Porphyrins

Xinyang Peng, Mengchun Zhang, Haonan Qin, Jinxiu Han, Yuhan Xu, Wenzi Li, Xue‐Peng Zhang, Wei Zhang, Ulf‐Peter Apfel and Rui Cao

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202401074

Hydricity of Transition-Metal Hydrides: Thermodynamic Considerations for CO2 Reduction

Kate M. Waldie, Andrew L. Ostericher, Mark H. Reineke, Alissa F. Sasayama and Clifford P. Kubiak

ACS Catal., 2018, 8, 1313
DOI: 10.1021/acscatal.7b03396

Electrochemical reforming of ethanol with acetate Co-Production on nickel cobalt selenide nanoparticles

Junshan Li, Xiang Wang, Congcong Xing, Luming Li, Shijia Mu, Xu Han, Ren He, Zhifu Liang, Paulina Martinez, Yunan Yi, Qianbao Wu, Huiyan Pan, Jordi Arbiol, Chunhua Cui, Yu Zhang and Andreu Cabot

Chemical Engineering Journal, 2022, 440, 135817
DOI: 10.1016/j.cej.2022.135817

Reactivity of a Series of Isostructural Cobalt Pincer Complexes with CO2, CO, and H+

David W. Shaffer, Samantha I. Johnson, Arnold L. Rheingold, Joseph W. Ziller, William A. Goddard, Robert J. Nielsen and Jenny Y. Yang

Inorg. Chem., 2014, 53, 13031
DOI: 10.1021/ic5021725

A molecular molybdenum electrocatalyst for generating hydrogen from acetic acid or water

Jie-Ping Cao, Ling-Ling Zhou, Ling-Zhi Fu and Shuzhong Zhan

Journal of Power Sources, 2014, 272, 169
DOI: 10.1016/j.jpowsour.2014.08.078

Novel iron carbide based catalysts for biomass valorisation

Chiara Defilippi, Daily Rodríguez-Padrón, Rafael Luque, Louise Winchester and Cristina Giordano

Journal of Cleaner Production, 2022, 347, 131279
DOI: 10.1016/j.jclepro.2022.131279

Comparing electrocatalytic hydrogen and oxygen evolution activities of first-row transition metal complexes with similar coordination environments

Xiaotong Jin, Xialiang Li, Haitao Lei, Kai Guo, Bin Lv, Hongbo Guo, Dandan Chen, Wei Zhang and Rui Cao

Journal of Energy Chemistry, 2021, 63, 659
DOI: 10.1016/j.jechem.2021.08.068

Bifunctional CoFeVOx Catalyst for Solar Water Splitting by using Multijunction and Heterojunction Silicon Solar Cells

Minoh Lee, Xinyu Ding, Swarnendu Banerjee, Florian Krause, Vladimir Smirnov, Oleksandr Astakhov, Tsvetelina Merdzhanova, Benjamin Klingebiel, Thomas Kirchartz, Friedhelm Finger, Uwe Rau and Stefan Haas

Adv Materials Technologies, 2020, 5
DOI: 10.1002/admt.202000592

Improving and Understanding the Hydrogen Evolving Activity of a Cobalt Dithiolene Metal–Organic Framework

Keying Chen, Courtney A. Downes, Eugene Schneider, Jason D. Goodpaster and Smaranda C. Marinescu

ACS Appl. Mater. Interfaces, 2021, 13, 16384
DOI: 10.1021/acsami.1c01727

Ruthenium Complexes of Polyfluorocarbon Substituted Terpyridine and Mesoionic Carbene Ligands: An Interplay in CO2 Reduction

Felix Stein, Maite Nößler, Arijit Singha Hazari, Lisa Böser, Robert Walter, Hang Liu, Elias Klemm and Biprajit Sarkar

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202300405

Optimized hydrogen production through donor-assisted saline water splitting and its techno-economic feasibility

Shilpa Kumari, Aniruddha Pandit and Sadhana Rayalu

Sustainable Energy Technologies and Assessments, 2025, 76, 104302
DOI: 10.1016/j.seta.2025.104302

Triphos nickel(II) halide pincer complexes as robust proton reduction electrocatalysts

Chen Hu, Renta Jonathan Chew, Hui Min Tang, Sherzod Madrahimov, Ashfaq A. Bengali and Wai Yip Fan

Molecular Catalysis, 2020, 490, 110950
DOI: 10.1016/j.mcat.2020.110950

The Effect of Residual Palladium Catalyst Contamination on the Photocatalytic Hydrogen Evolution Activity of Conjugated Polymers

Jan Kosco, Michael Sachs, Robert Godin, Mindaugas Kirkus, Laia Francas, Matthew Bidwell, Muhammad Qureshi, Dalaver Anjum, James R. Durrant and Iain McCulloch

Advanced Energy Materials, 2018, 8
DOI: 10.1002/aenm.201802181

The rapid electrochemical activation of MoTe2 for the hydrogen evolution reaction

Jessica C. McGlynn, Torben Dankwort, Lorenz Kienle, Nuno A. G. Bandeira, James P. Fraser, Emma K. Gibson, Irene Cascallana-Matías, Katalin Kamarás, Mark D. Symes, Haralampos N. Miras and Alexey Y. Ganin

Nat Commun, 2019, 10
DOI: 10.1038/s41467-019-12831-0

Electrohydrogenation of Nitriles with Amines by Cobalt Catalysis

Tiantian Wang, Fangfang He, Wei Jiang and Jie Liu

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202316140

A cobalt complex, a highly efficient catalyst for electro- and photochemical driven hydrogen generation in purely aqueous media

Jia-Mei Lei, Su-Ping Luo and Shu-Zhong Zhan

Polyhedron, 2018, 154, 295
DOI: 10.1016/j.poly.2018.07.040

Synthetic models of hydrogenases based on framework structures containing coordinating P, N-atoms as hydrogen energy electrocatalysts – from molecules to materials

Yulia H. Budnikova and Vera V. Khrizanforova

Pure and Applied Chemistry, 2020, 92, 1305
DOI: 10.1515/pac-2019-1207

Enzyme Electrochemistry for Industrial Energy Applications—A Perspective on Future Areas of Focus

John C. Ruth and Alfred M. Spormann

ACS Catal., 2021, 11, 5951
DOI: 10.1021/acscatal.1c00708

Electrocatalytic H2 Evolution by Proton-Gated Hangman Iron Porphyrins

Daniel J. Graham and Daniel G. Nocera

Organometallics, 2014, 33, 4994
DOI: 10.1021/om500300e

One-pot synthesis of holey MoS2 nanostructures as efficient electrocatalysts for hydrogen evolution

Lanlan Wang, Xuan Li, Jian Zhang, Hongzhong Liu, Weitao Jiang and Hong Zhao

Applied Surface Science, 2017, 396, 1719
DOI: 10.1016/j.apsusc.2016.11.235

Direct Observation by Rapid-Scan FT-IR Spectroscopy of Two-Electron-Reduced Intermediate of Tetraaza Catalyst [CoIIN4H(MeCN)]2+ Converting CO2 to CO

Hua Sheng and Heinz Frei

J. Am. Chem. Soc., 2016, 138, 9959
DOI: 10.1021/jacs.6b05248

Structure Effects of Metal Corroles on Energy-Related Small Molecule Activation Reactions

Haitao Lei, Xialiang Li, Jia Meng, Haoquan Zheng, Wei Zhang and Rui Cao

ACS Catal., 2019, 9, 4320
DOI: 10.1021/acscatal.9b00310

Excited state electron transfer from cobalt coordination compounds anchored to TiO2

Erinn C. Brigham, Darren Achey and Gerald J. Meyer

Polyhedron, 2014, 82, 181
DOI: 10.1016/j.poly.2014.07.023

Electrochemistry of Polymeric Cobaloxime-Containing Assemblies in Organic and Aqueous Solvents

Brian L. Wadsworth, Daiki Nishiori, Nghi P. Nguyen, Edgar A. Reyes Cruz and Gary F. Moore

ECS J. Solid State Sci. Technol., 2020, 9, 061018
DOI: 10.1149/2162-8777/aba1ff

Phase-tunable cobalt borides with amorphous shell toward highly efficient oxygen evolution reaction

Yuxin Gao, Xiaowei Yang, Yuyang Zong, Lihong Bao, Ruguang Ma and Jijun Zhao

Journal of Power Sources, 2025, 631, 236255
DOI: 10.1016/j.jpowsour.2025.236255

Synthesis of First Antimony Porphycene and Electrocatalytic Hydrogen Evolution Driven by Ligand-Centered Reduction

Zhi Zhang, Taro Fujioka, Taro Koide, Yoshio Yano, Toshikazu Ono and Yoshio Hisaeda

Bulletin of the Chemical Society of Japan, 2021, 94, 2048
DOI: 10.1246/bcsj.20210177

Electrochemical performance of NiS/MoTe2 for efficient bifunctional catalyst in water splitting

Razan A. Alshgari, Syed Imran Abbas Shah, Karam Jabbour, Khadija Bibi, Nigarish Bano, Saikh Mohammad, Muhammad Fahad Ehsan and Mehar Un Nisa

International Journal of Hydrogen Energy, 2024, 91, 912
DOI: 10.1016/j.ijhydene.2024.10.186

One-step hydrothermal synthesis of few-layered and edge-abundant MoS2/C nanocomposites with enhanced electrocatalytic performance for hydrogen evolution reaction

Lin Ma, Xiaoping Zhou, Xuyao Xu, Limei Xu, Lingling Zhang and Weixiang Chen

Advanced Powder Technology, 2015, 26, 1273
DOI: 10.1016/j.apt.2015.06.010

Addressing the Origin of Photocurrents and Fuel Production Activities in Catalyst-Modified Semiconductor Electrodes

Brian L. Wadsworth, Nghi P. Nguyen, Daiki Nishiori, Anna M. Beiler and Gary F. Moore

ACS Appl. Energy Mater., 2020, 3, 7512
DOI: 10.1021/acsaem.0c00919

Enzymatic and Bioinspired Systems for Hydrogen Production

Linda Leone, Gianmattia Sgueglia, Salvatore La Gatta, Marco Chino, Flavia Nastri and Angela Lombardi

IJMS, 2023, 24, 8605
DOI: 10.3390/ijms24108605

Cobaltocene-Mediated Catalytic Hydride Transfer: Strategies for Electrocatalytic Hydrogenation

Daniel P. Marron, Conor M. Galvin, Julia M. Dressel and Robert M. Waymouth

J. Am. Chem. Soc., 2024, 146, 17075
DOI: 10.1021/jacs.4c02177

Metal-Assisted Ligand-Centered Electrocatalytic Hydrogen Evolution upon Reduction of a Bis(thiosemicarbazonato)Cu(II) Complex

Andrew Z. Haddad, Steve P. Cronin, Mark S. Mashuta, Robert M. Buchanan and Craig A. Grapperhaus

Inorg. Chem., 2017, 56, 11254
DOI: 10.1021/acs.inorgchem.7b01608

Theoretical screening of 2D materials supported transition-metal single atoms as efficient electrocatalysts for hydrogen evolution reaction

Feng Gao, Yuhua Wei, Jiguang Du and Gang Jiang

Materialia, 2021, 18, 101168
DOI: 10.1016/j.mtla.2021.101168

Electrodeposited Cobalt Stannide: A Highly Efficient Oxygen Evolution Reaction Catalyst

Shengsheng Cui, Yuna Zhang, Cuili Xue, Haisong Tan, Shanshan Fan, Yi Lu, Xinni Pan, Yanlei Liu and Daxiang Cui

J. Electrochem. Soc., 2021, 168, 096505
DOI: 10.1149/1945-7111/ac23a1

Energy-related catalysis

Salvatore Abate, Gabriele Centi and Siglinda Perathoner

National Science Review, 2015, 2, 143
DOI: 10.1093/nsr/nwv017

Developments of photo‐/electro‐catalysis based on covalent organic frameworks: A review

Guiping Yang, Qing Xu and Gaofeng Zeng

Electron, 2024, 2
DOI: 10.1002/elt2.39

Electrocatalytic CO2 Reduction with a Binuclear Bis‐Terpyridine Pyrazole‐Bridged Cobalt Complex**

Antoine Bohn, Juan José Moreno, Pierre Thuéry, Marc Robert and Orestes Rivada‐Wheelaghan

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202202361

Identification of an Electrode-Adsorbed Intermediate in the Catalytic Hydrogen Evolution Mechanism of a Cobalt Dithiolene Complex

Katherine J. Lee, Brian D. McCarthy, Eric S. Rountree and Jillian L. Dempsey

Inorg. Chem., 2017, 56, 1988
DOI: 10.1021/acs.inorgchem.6b02586

Molecular Electrocatalysts for the Hydrogen Evolution Reaction: Input from Quantum Chemistry

Alexandre Barrozo and Maylis Orio

ChemSusChem, 2019, 12, 4905
DOI: 10.1002/cssc.201901828

Recent Progress in the Development of Molecular Electrocatalysts for Formate Oxidation

Kate M. Waldie and Sriram Katipamula

Catal Res, 2022, 02, 1
DOI: 10.21926/cr.2201006

Synthesis and electrochemical characterization of a tridentate Schiff-base ligated Fe(II) complex

Daniel J. Martin, Brian D. McCarthy, Nicholas A. Piro and Jillian L. Dempsey

Polyhedron, 2016, 114, 200
DOI: 10.1016/j.poly.2015.12.003

A Hydrogen Evolution Catalyst [Co2O2] Metallacycle Enables Regioselective Allene C(sp2)‐H Functionalization

Yating Liang, Jiayi Feng, Huilong Li, Xiaoli Wang, Ying Zhang, Weigang Fan, Sheng Zhang and Man‐Bo Li

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202400938

Recent development on carbon based heterostructures for their applications in energy and environment: A review

Theerthagiri Jayaraman, Arun Prasad Murthy, Venugopal Elakkiya, Sivaraman Chandrasekaran, Palaniyandy Nithyadharseni, Ziyauddin Khan, Raja Arumugam Senthil, Ravi Shanker, Mitty Raghavender, Parasuraman Kuppusami, Madhavan Jagannathan and Muthupandian Ashokkumar

Journal of Industrial and Engineering Chemistry, 2018, 64, 16
DOI: 10.1016/j.jiec.2018.02.029

Effects of halogen ligands of complexes supported by bis(methylthioether)pyridine on catalytic activities for electrochemical and photochemical driven hydrogen evolution

Chun‐Li Wang, Hao Yang, Juan Du and Shu‐Zhong Zhan

Applied Organom Chemis, 2021, 35
DOI: 10.1002/aoc.6201

Noble metal-modified copper surfaces for alkaline condition hydrogen evolution reaction

Manman Liu, Xiaofeng Fan, Xiaoqiang Cui, Weitao Zheng and David J. Singh

Journal of Alloys and Compounds, 2024, 1005, 175966
DOI: 10.1016/j.jallcom.2024.175966

Electrochemically Synthesized Nanoporous Molybdenum Carbide as a Durable Electrocatalyst for Hydrogen Evolution Reaction

Jin Soo Kang, Jin Kim, Myeong Jae Lee, Yoon Jun Son, Dong Young Chung, Subin Park, Juwon Jeong, Ji Mun Yoo, Heejong Shin, Heeman Choe, Hyun S. Park and Yung‐Eun Sung

Advanced Science, 2018, 5
DOI: 10.1002/advs.201700601

Outer-coordination sphere in multi-H+/multi-e–molecular electrocatalysis

Soumalya Sinha, Caroline K. Williams and Jianbing “Jimmy” Jiang

iScience, 2022, 25, 103628
DOI: 10.1016/j.isci.2021.103628

Photoelectrochemistry of metalloporphyrin-modified GaP semiconductors

Daiki Nishiori, Brian L. Wadsworth, Edgar A. Reyes Cruz, Nghi P. Nguyen, Lillian K. Hensleigh, Timothy Karcher and Gary F. Moore

Photosynth Res, 2022, 151, 1
DOI: 10.1007/s11120-021-00834-2

Electrodeposition of sizeable and compositionally tunable rhodium-iron nanoparticles and their activity toward hydrogen evolution reaction

Irati Golvano-Escobal, Santiago Suriñach, Maria Dolors Baró, Salvador Pané, Jordi Sort and Eva Pellicer

Electrochimica Acta, 2016, 194, 263
DOI: 10.1016/j.electacta.2016.02.112

Beneficial Effects on the Cobalt-Catalyzed Hydrogen Evolution Reaction Induced by Corrole Chelation

Amit Kumar, Shachar Fite, Arik Raslin, Sachin Kumar, Amir Mizrahi, Atif Mahammed and Zeev Gross

ACS Catal., 2023, 13, 13344
DOI: 10.1021/acscatal.3c03021

Electrocatalytic Hydrogen Evolution with a Cobalt Complex Bearing Pendant Proton Relays: Acid Strength and Applied Potential Govern Mechanism and Stability

Nicolas Queyriaux, Dongyue Sun, Jennifer Fize, Jacques Pécaut, Martin J. Field, Murielle Chavarot-Kerlidou and Vincent Artero

J. Am. Chem. Soc., 2020, 142, 274
DOI: 10.1021/jacs.9b10407

Diiron Disulfide Methacrylate Metallopolymers as Sustainable Electrocatalysts for Water-Splitting and Molecular Hydrogen Production

Arthur C. Gibson, Richard S. Glass, Dennis L. Lichtenberger and Jeffrey Pyun

ACS Macro Lett., 2025, 14, 1504
DOI: 10.1021/acsmacrolett.5c00567

Kinetics of the Trans Effect in Ruthenium Complexes Provide Insight into the Factors That Control Activity and Stability in CO2 Electroreduction

Sergio Gonell, Eric A. Assaf, Kyle D. Duffee, Cynthia K. Schauer and Alexander J. M. Miller

J. Am. Chem. Soc., 2020, 142, 8980
DOI: 10.1021/jacs.0c02912

Sodium-ion electrochemical tuning of Prussian blue analog as an efficient oxygen evolution catalyst

S. Tang, L. Li, H. Ren, Q. Lv and R. Lv

Materials Today Chemistry, 2019, 12, 71
DOI: 10.1016/j.mtchem.2018.12.003

Recent progress on synthetic strategies and applications of transition metal phosphides in energy storage and conversion

Jayaraman Theerthagiri, Arun Prasad Murthy, Seung Jun Lee, K. Karuppasamy, Senthil Raja Arumugam, Yiseul Yu, Marlia M. Hanafiah, Hyun-Seok Kim, Vikas Mittal and Myong Yong Choi

Ceramics International, 2021, 47, 4404
DOI: 10.1016/j.ceramint.2020.10.098

Emerging opportunities for black phosphorus in energy applications

Shenghuang Lin, Yanyong Li, Jiasheng Qian and Shu Ping Lau

Materials Today Energy, 2019, 12, 1
DOI: 10.1016/j.mtener.2018.12.004

Catalytic Mechanism of Competing Proton Transfer Events from Water and Acetic Acid by [CoII(bpbH2)Cl2] for Water Splitting Processes

Koteswara Rao Gorantla and Bhabani S. Mallik

J. Phys. Chem. A, 2022, 126, 1321
DOI: 10.1021/acs.jpca.1c07353

Synthesis of Cobalt Phosphide Nanoparticles Supported on Pristine Graphene by Dynamically Self‐Assembled Graphene Quantum Dots for Hydrogen Evolution

Xiaoyan Wang, Weiyong Yuan, Yanan Yu and Chang Ming Li

ChemSusChem, 2017, 10, 1014
DOI: 10.1002/cssc.201601761

Nickel bis(dithiolene) complexes for electrocatalytic hydrogen evolution: A computational study

Zisheng Zhang, Tilong Yang, Peng Qin and Li Dang

Journal of Organometallic Chemistry, 2018, 864, 143
DOI: 10.1016/j.jorganchem.2018.03.007

Rational development of molecular earth-abundant metal complexes for electrocatalytic hydrogen production

John Daniel McCool, Shiyuan Zhang, Inen Cheng and Xuan Zhao

Chinese Journal of Catalysis, 2022, 43, 3019
DOI: 10.1016/S1872-2067(22)64150-0

Metal Organic Framework Derived Fe-Doped CoSe2 Incorporated in Nitrogen-Doped Carbon Hybrid for Efficient Hydrogen Evolution

Xiaolin Wu, Song Han, Denghong He, Chunlin Yu, Chaojun Lei, Wei Liu, Guokui Zheng, Xingwang Zhang and Lecheng Lei

ACS Sustainable Chem. Eng., 2018, 6, 8672
DOI: 10.1021/acssuschemeng.8b00968

Effective orientation control of photogenerated carrier separation via rational design of a Ti3C2(TiO2)@CdS/MoS2 photocatalytic system

Zizheng Ai, Yongliang Shao, Bin Chang, Baibiao Huang, Yongzhong Wu and Xiaopeng Hao

Applied Catalysis B: Environmental, 2019, 242, 202
DOI: 10.1016/j.apcatb.2018.09.101

Bifunctional electrocatalysts derived from cluster-based ternary sulfides for oxygen electrode reactions

Xiao-Li Wang, Zhou Wu, Xiang Wang, Chaozhuang Xue, Chengdong Liu, Jiaxu Zhang, Rui Zhou, Dong-Sheng Li and Tao Wu

Electrochimica Acta, 2021, 376, 138048
DOI: 10.1016/j.electacta.2021.138048

Switching Electrocatalytic Hydrogen Evolution Pathways through Electronic Tuning of Copper Porphyrins

Xinyang Peng, Mengchun Zhang, Haonan Qin, Jinxiu Han, Yuhan Xu, Wenzi Li, Xue‐Peng Zhang, Wei Zhang, Ulf‐Peter Apfel and Rui Cao

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202401074

[Fe(C5Ar5)(CO)2Br] complexes as hydrogenase mimics for the catalytic hydrogen evolution reaction

E.B. Hemming, B. Chan, P. Turner, L. Corcilius, J.R. Price, M.G. Gardiner, A.F. Masters and T. Maschmeyer

Applied Catalysis B: Environmental, 2018, 223, 234
DOI: 10.1016/j.apcatb.2017.04.053

Catalytic N2-to-NH3(or -N2H4) Conversion by Well-Defined Molecular Coordination Complexes

Matthew J. Chalkley, Marcus W. Drover and Jonas C. Peters

Chem. Rev., 2020, 120, 5582
DOI: 10.1021/acs.chemrev.9b00638

Synthesis of CoP nanoarrays by morphological engineering for efficient electrochemical hydrogen production

Peiyun Zhou, Rushuo Li, Junjun Lv, Xiubing Huang, Yunfeng Lu and Ge Wang

Electrochimica Acta, 2022, 426, 140768
DOI: 10.1016/j.electacta.2022.140768

Synthesis, crystal structure and electrocatalytic hydrogen evolution reaction studies of cobaloximes with diphenylglyoxime and carboxylic acid functionalized neutral bases

Subramanian Sowmya, Prince Makarios Paul, Sitheshwaran Boopalan, Angamuthu Abiram, François Michaud and Vijendran Vijaikanth

Polyhedron, 2023, 238, 116394
DOI: 10.1016/j.poly.2023.116394

The Future of Using Earth‐Abundant Elements in Counter Electrodes for Dye‐Sensitized Solar Cells

Joe Briscoe and Steve Dunn

Advanced Materials, 2016, 28, 3802
DOI: 10.1002/adma.201504085

Hydrogen production based on hexacoordinated cobalt scaffolds as electrocatalysts for acid-proton reduction: Electrochemistry and mechanisms

Ibukun O. Shotonwa, Onome Ejeromedoghene, Adedoyin O. Adesoji, Yakubu A. Alli, Caroline Akinremi and Sheriff Adewuyi

Journal of Electroanalytical Chemistry, 2024, 963, 118228
DOI: 10.1016/j.jelechem.2024.118228

H2-Evolving Dye-Sensitized Photocathode Based on a Ruthenium–Diacetylide/Cobaloxime Supramolecular Assembly

Siliu Lyu, Julien Massin, Michele Pavone, Ana B. Muñoz-García, Christine Labrugère, Thierry Toupance, Murielle Chavarot-Kerlidou, Vincent Artero and Céline Olivier

ACS Appl. Energy Mater., 2019, 2, 4971
DOI: 10.1021/acsaem.9b00652

PdCo alloys@N-doped porous carbon supported on reduced graphene oxide as a highly efficient electrocatalyst for hydrogen evolution reaction

Ming Zhong, Lingling Li, Kun Zhao, Fangzhen He, Bitao Su and Dahui Wang

J Mater Sci, 2021, 56, 14222
DOI: 10.1007/s10853-021-06212-6

Influence of the Metal Ion on the Electrocatalytic Hydrogen Production by a Thiosemicarbazone Palladium Complex

Tatiana Straistari, Renaud Hardré, Julien Massin, Mireille Attolini, Bruno Faure, Michel Giorgi, Marius Réglier and Maylis Orio

Eur J Inorg Chem, 2018, 2018, 2259
DOI: 10.1002/ejic.201800120

A Nickel Dithiolate Water Reduction Catalyst Providing Ligand‐Based Proton‐Coupled Electron‐Transfer Pathways

Keita Koshiba, Kosei Yamauchi and Ken Sakai

Angew Chem Int Ed, 2017, 56, 4247
DOI: 10.1002/anie.201700927

Vibrational Cooling Dynamics of a [FeFe]-Hydrogenase Mimic Probed by Time-Resolved Infrared Spectroscopy

Benjamin W. Caplins, Justin P. Lomont, Son C. Nguyen and Charles B. Harris

J. Phys. Chem. A, 2014, 118, 11529
DOI: 10.1021/jp510517z

Geometries and thermodynamic stability of [Mo3Se132-]@TM (TM = Sc-Ni) clusters: A theoretical investigation

Mai Nguyen, Phung Thi Thu, Ngo Thi Lan and Nguyen Thanh Tung

J. Mil. Sci. Technol., 2025, 101, 110
DOI: 10.54939/1859-1043.j.mst.101.2025.110-116

Theoretical Insights into the Hydrogen Evolution Reaction on the Ni3N Electrocatalyst

Russell W. Cross, Sachin R. Rondiya and Nelson Y. Dzade

Catalysts, 2021, 11, 716
DOI: 10.3390/catal11060716

Synthesis, structure, characterization and catalytic behavior of a bis(thiosemicarbazonato)-nickel complex

Hao Yang, Juan Du, Chun-Li Wang and Shu-Zhong Zhan

Journal of Coordination Chemistry, 2021, 74, 2274
DOI: 10.1080/00958972.2021.1943742

Electrochemical and electrocatalytic performance of single Au@Pt/Au bimetallic nanoparticles

Xia Qiu, Haifeng Wei, Renjia Li and Yongxin Li

Journal of Alloys and Compounds, 2023, 956, 170365
DOI: 10.1016/j.jallcom.2023.170365

Structural Design and Electronic Modulation of Transition‐Metal‐Carbide Electrocatalysts toward Efficient Hydrogen Evolution

Qingsheng Gao, Wenbiao Zhang, Zhangping Shi, Lichun Yang and Yi Tang

Advanced Materials, 2019, 31
DOI: 10.1002/adma.201802880

Directing the reactivity of metal hydrides for selective CO 2 reduction

Bianca M. Ceballos and Jenny Y. Yang

Proc. Natl. Acad. Sci. U.S.A., 2018, 115, 12686
DOI: 10.1073/pnas.1811396115

Synthetic strategy and evaluation of hierarchical nanoporous NiO/NiCoP microspheres as efficient electrocatalysts for hydrogen evolution reaction

Manman Guo, Yaohui Qu, Fanyan Zeng and Cailei Yuan

Electrochimica Acta, 2018, 292, 88
DOI: 10.1016/j.electacta.2018.09.159

PVP-assisted synthesis of porous CoO prisms with enhanced electrocatalytic oxygen evolution properties

Xueli Zhao, Wei Zhang and Rui Cao

Journal of Energy Chemistry, 2017, 26, 1210
DOI: 10.1016/j.jechem.2017.08.014

Dual properties of a hydrogen oxidation Ni-catalyst entrapped within a polymer promote self-defense against oxygen

Alaa A. Oughli, Adrian Ruff, Nilusha Priyadarshani Boralugodage, Patricia Rodríguez-Maciá, Nicolas Plumeré, Wolfgang Lubitz, Wendy J. Shaw, Wolfgang Schuhmann and Olaf Rüdiger

Nat Commun, 2018, 9
DOI: 10.1038/s41467-018-03011-7

Synthesis, crystal structure, characterization of pyrazine diaminotriazine based complexes and their systematic comparative study with pyridyl diaminotriazine based complexes for light-driven hydrogen production

Sanil Rajak, Olivier Schott, Prabhjyot Kaur, Thierry Maris, Garry S. Hanan and Adam Duong

Polyhedron, 2020, 180, 114412
DOI: 10.1016/j.poly.2020.114412

Visible Light-Driven Hydrogen Evolution Catalysis by Heteroleptic Ni(II) Complexes with Chelating Nitrogen Ligands: Probing Ligand Substituent Position and Photosensitizer Effects

Maria Kourmousi, Fotios Kamatsos and Christiana A. Mitsopoulou

Energies, 2024, 17, 2777
DOI: 10.3390/en17112777

CoP Nanoparticles in Situ Grown in Three-Dimensional Hierarchical Nanoporous Carbons as Superior Electrocatalysts for Hydrogen Evolution

Weiyong Yuan, Xiaoyan Wang, Xiaoling Zhong and Chang Ming Li

ACS Appl. Mater. Interfaces, 2016, 8, 20720
DOI: 10.1021/acsami.6b05304

Improved Electro- and Photocatalytic Water Reduction by Confined Cobalt Catalysts in Streptavidin

Arnau Call, Carla Casadevall, Adrian Romero-Rivera, Vlad Martin-Diaconescu, Dayn J. Sommer, Sílvia Osuna, Giovanna Ghirlanda and Julio Lloret-Fillol

ACS Catal., 2019, 9, 5837
DOI: 10.1021/acscatal.8b04981

V3+ Incorporated β-Co(OH)2: A Robust and Efficient Electrocatalyst for Water Oxidation

Sengeni Anantharaj, Kannimuthu Karthick, Palanichamy Murugan and Subrata Kundu

Inorg. Chem., 2020, 59, 730
DOI: 10.1021/acs.inorgchem.9b02977

First-row transition metal polypyridine complexes that catalyze proton to hydrogen reduction

Lianpeng Tong, Lele Duan, Aiju Zhou and Randolph P. Thummel

Coordination Chemistry Reviews, 2020, 402, 213079
DOI: 10.1016/j.ccr.2019.213079

Advances and Recent Trends in Heterogeneous Photo(Electro)-Catalysis for Solar Fuels and Chemicals

James Highfield

Molecules, 2015, 20, 6739
DOI: 10.3390/molecules20046739

Hybrid photocathodes for solar fuel production: coupling molecular fuel-production catalysts with solid-state light harvesting and conversion technologies

Diana Cedeno, Alexandra Krawicz and Gary F. Moore

Interface Focus, 2015, 5
DOI: 10.1098/rsfs.2014.0085

Valorization of lignin biowaste into Schiff base copper(II) complex as a magnetically reusable electrocatalyst for hydrogen evolution reaction

Mohaddeseh Sajjadi, Ali Ghaffarinejad, Hossein Ghafuri and Yahao Dong

International Journal of Biological Macromolecules, 2025, 314, 144249
DOI: 10.1016/j.ijbiomac.2025.144249

Homogeneous electrocatalytic hydrogen evolution by a N2P2Fe(II) complex: Structural characterization of iron-hydride intermediate

Danyang Huang, Bing He, Yipei Zhao, Mengqing Liu and Lianke Wang

Journal of Molecular Structure, 2025, 1325, 141021
DOI: 10.1016/j.molstruc.2024.141021

Expanding the Horizon of Bio‐Inspired Catalyst Design with Tactical Incorporation of Drug Molecules

Gul Afshan, Santanu Ghorai, Surabhi Rai, Aman Pandey, Piyali Majumder, G. Naresh Patwari and Arnab Dutta

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202203730

Studying the Mechanism of the Electrocatalyic Reaction for Producing Molecular Hydrogen Using the N-Methyl-2,4,6-triphenylpyridinyl Cation According to DFT

A. V. Dolganov, L. A. Klimaeva, E. E. Muryumin, A. D. Yudina, A. S. Zagorodnova, A. V. Tankova, T. V. Boikova, Yu. N. Kovaleva and A. V. Knyazev

Russian Journal of Physical Chemistry, 2023, 97, 1106
DOI: 10.31857/S004445372308006X

Mechanisms and Potential-Dependent Energy Barriers for Hydrogen Evolution on Supported MoS2 Catalysts

Charlie Ruffman, Calum K. Gordon, Egill Skúlason and Anna L. Garden

J. Phys. Chem. C, 2020, 124, 17015
DOI: 10.1021/acs.jpcc.0c04146

A cobalt mimochrome for photochemical hydrogen evolution from neutral water

Emily H. Edwards, Jennifer M. Le, Alison A. Salamatian, Noelle L. Peluso, Linda Leone, Angela Lombardi and Kara L. Bren

Journal of Inorganic Biochemistry, 2022, 230, 111753
DOI: 10.1016/j.jinorgbio.2022.111753

Pyridyl Aroyl Hydrazone-Based Metal Complexes Showing a Ligand-Centered Metal-Assisted Pathway for Electrocatalytic Hydrogen Evolution

Bharath M, Gargee Roy, Aryya Ghosh, Munmun Ghosh and Deepak Asthana

ACS Omega, 2025, 10, 3511
DOI: 10.1021/acsomega.4c07748

Hierarchical free-standing networks of MnCo2S4 as efficient Electrocatalyst for oxygen evolution reaction

Harsharaj S. Jadhav, Animesh Roy, Gaurav M. Thorat, Wook-Jin Chung and Jeong Gil Seo

Journal of Industrial and Engineering Chemistry, 2019, 71, 452
DOI: 10.1016/j.jiec.2018.12.002

Electrocatalytic Hydrogen Evolution and Oxidation with Rhenium Tris(thiolate) Complexes: A Competition between Rhenium and Sulfur for Electrons and Protons

Hao Tang, Edward N. Brothers, Craig A. Grapperhaus and Michael B. Hall

ACS Catal., 2020, 10, 3778
DOI: 10.1021/acscatal.9b04579

X-ray Absorption Spectroscopy and Theoretical Investigation of the Reductive Protonation of Cyclopentadienyl Cobalt Compounds

Elizabeth A. McLoughlin, Logan J. Giles, Robert M. Waymouth and Ritimukta Sarangi

Inorg. Chem., 2019, 58, 1167
DOI: 10.1021/acs.inorgchem.8b02475

Evaluation of the H2 Evolving Activity of Benzenehexathiolate Coordination Frameworks and the Effect of Film Thickness on H2 Production

Courtney A. Downes, Andrew J. Clough, Keying Chen, Joseph W. Yoo and Smaranda C. Marinescu

ACS Appl. Mater. Interfaces, 2018, 10, 1719
DOI: 10.1021/acsami.7b15969

Highly Water Dispersible Polymer Acid-Doped Polyanilines as Low-Cost, Nafion-Free Ionomers for Hydrogen Evolution Reaction

Arun Prasad Murthy, Jayaraman Theerthagiri and Jagannathan Madhavan

ACS Appl. Energy Mater., 2018, 1, 1512
DOI: 10.1021/acsaem.7b00315

Smart Designs of Mo Based Electrocatalysts for Hydrogen Evolution Reaction

Xingyuan Gao, Huilin Deng, Qiuping Dai, Quanlong Zeng, Shuxian Qiu and Xihong Lu

Catalysts, 2021, 12, 2
DOI: 10.3390/catal12010002

Coordination chemistry of ligands bearing heavy group 14 and 15 elements: Comparative analysis of their influence on transition metal chemistry

Yeong Jun Son, Dongyoung Kim, Jae Wan Park, Yeongjun Yu and Seung Jun Hwang

Coordination Chemistry Reviews, 2025, 526, 216317
DOI: 10.1016/j.ccr.2024.216317

Light‐driven catalysis with engineered enzymes and biomimetic systems

Emily H. Edwards and Kara L. Bren

Biotech and App Biochem, 2020, 67, 463
DOI: 10.1002/bab.1976

Effects of metal centers of complexes supported by S,S′‐bis(2‐pyridylmethyl)‐1,2‐thioethane on catalytic activities for electrochemical‐ and photochemical‐driven hydrogen production

Wei‐Xia Liu, Zhen‐Lang Xie, Chun‐Li Wang, Shu‐Zhong Zhan and Song‐Ping Wu

Applied Organom Chemis, 2020, 34
DOI: 10.1002/aoc.5776

Waste plastic derived carbon supported Mo2C composite catalysts for hydrogen production and energy storage applications

Rameez Ahmad Mir and O.P. Pandey

Journal of Cleaner Production, 2019, 218, 644
DOI: 10.1016/j.jclepro.2019.02.004

Tuning the reactivity of cobalt-based H2 production electrocatalysts via the incorporation of the peripheral basic functionalities

Dependu Dolui, Santanu Ghorai and Arnab Dutta

Coordination Chemistry Reviews, 2020, 416, 213335
DOI: 10.1016/j.ccr.2020.213335

Two-Electron-Induced Reorganization of Cobalt Coordination and Metal–Ligand Cooperative Redox Shifting Co(I) Reactivity toward CO2 Reduction

Seungjin Song, Wonjung Lee, Youngseob Lee, Kyung-Bin Cho, Junseong Lee and Junhyeok Seo

Inorg. Chem., 2023, 62, 2326
DOI: 10.1021/acs.inorgchem.2c04071

Cobalt Telluride: A Highly Efficient Trifunctional Electrocatalyst for Water Splitting and Oxygen Reduction

Manashi Nath, Umanga De Silva, Harish Singh, Matthew Perkins, Wipula P. R. Liyanage, Siddesh Umapathi, Shatadru Chakravarty and Jahangir Masud

ACS Appl. Energy Mater., 2021, 4, 8158
DOI: 10.1021/acsaem.1c01438

Probing the Dissolved Gas Concentration on the Electrode through Laser-Assisted Bubbles

Kota Ando, Yoshiharu Uchimoto and Takashi Nakajima

J. Phys. Chem. C, 2021, 125, 20952
DOI: 10.1021/acs.jpcc.1c06816

Dicationic Thiolate-Bridged Diruthenium Complexes for Catalytic Oxidation of Molecular Dihydrogen

Masahiro Yuki, Ken Sakata, Kazunari Nakajima, Syoma Kikuchi, Shinobu Sekine, Hiroyuki Kawai and Yoshiaki Nishibayashi

Organometallics, 2017, 36, 4499
DOI: 10.1021/acs.organomet.7b00764

Blending Cr2O3 into a NiO–Ni Electrocatalyst for Sustained Water Splitting

Ming Gong, Wu Zhou, Michael James Kenney, Rich Kapusta, Sam Cowley, Yingpeng Wu, Bingan Lu, Meng‐Chang Lin, Di‐Yan Wang, Jiang Yang, Bing‐Joe Hwang and Hongjie Dai

Angewandte Chemie, 2015, 127, 12157
DOI: 10.1002/ange.201504815

From Enzymes to Functional Materials—Towards Activation of Small Molecules

Frauke Möller, Stefan Piontek, Reece G. Miller and Ulf‐Peter Apfel

Chemistry A European J, 2018, 24, 1471
DOI: 10.1002/chem.201703451

Sustainable hydrogen production from water using tandem dye-sensitized photoelectrochemical cells

Benjamin D. Sherman, Nelli Klinova McMillan, Debora Willinger and Gyu Leem

Nano Convergence, 2021, 8
DOI: 10.1186/s40580-021-00257-8

Electrochemical and photocatalytic hydrogen evolution by an electron‐deficient cobalt tris(ethoxycarbonyl)corrole complex

Hui‐Qing Yuan, Hua‐Hua Wang, Jaipal Kandhadi, Hui Wang, Shu‐Zhong Zhan and Hai‐Yang Liu

Applied Organom Chemis, 2017, 31
DOI: 10.1002/aoc.3773

Multielectron Redox Chemistry of Transition Metal Complexes Supported by a Non‐Innocent N3P2 Ligand: Synthesis, Characterization, and Catalytic Properties

Denan Wang, Danushka M. Ekanayake, Sergey V. Lindeman, Cláudio N. Verani and Adam T. Fiedler

Eur J Inorg Chem, 2018, 2018, 4133
DOI: 10.1002/ejic.201800843

Theoretical and experimental investigations of vanadium pentoxide–based electrocatalysts for the hydrogen evolution reaction in alkaline media

Dima Abu Alhawa, Ahmed Badreldin, Abdellatif El-Ghenymy, Noor Hassan, Yiming Wubulikasimu, Khaled Elsaid and Ahmed Abdel-Wahab

emergent mater., 2024, 7, 1359
DOI: 10.1007/s42247-024-00679-0

A gas breathing hydrogen/air biofuel cell comprising a redox polymer/hydrogenase-based bioanode

Julian Szczesny, Nikola Marković, Felipe Conzuelo, Sónia Zacarias, Inês A. C. Pereira, Wolfgang Lubitz, Nicolas Plumeré, Wolfgang Schuhmann and Adrian Ruff

Nat Commun, 2018, 9
DOI: 10.1038/s41467-018-07137-6

Tungsten Carbide–Nitride on Graphene Nanoplatelets as a Durable Hydrogen Evolution Electrocatalyst

Wei‐Fu Chen, Jonathan M. Schneider, Kotaro Sasaki, Chiu‐Hui Wang, Jacob Schneider, Shilpa Iyer, Shweta Iyer, Yimei Zhu, James T. Muckerman and Etsuko Fujita

ChemSusChem, 2014, 7, 2414
DOI: 10.1002/cssc.201402454

The Impact of a Proton Relay in Binuclear α-Diimine-Mn(CO)3 Complexes on the CO2 Reduction Catalysis

Igor Fokin, Alisa Denisiuk, Christian Würtele and Inke Siewert

Inorg. Chem., 2019, 58, 10444
DOI: 10.1021/acs.inorgchem.9b00992

Non‐Covalent Integration of a [FeFe]‐Hydrogenase Mimic to Multiwalled Carbon Nanotubes for Electrocatalytic Hydrogen Evolution

Afridi Zamader, Bertrand Reuillard, Jacques Pécaut, Laurent Billon, Antoine Bousquet, Gustav Berggren and Vincent Artero

Chemistry A European J, 2022, 28
DOI: 10.1002/chem.202202260

Novel Ni(S0.49Se0.51)2 porous flakes array on carbon fiber cloth for efficient hydrogen evolution reaction

Bo Xu, Zhiming Chen, Haijing Zhang, Yiqiang Sun and Cuncheng Li

International Journal of Hydrogen Energy, 2017, 42, 30119
DOI: 10.1016/j.ijhydene.2017.10.081

Gd Active Sites Modulating the Intermediate Adsorption and Activation in Exfoliated Gadolinium Telluride for Oxygen Evolution and Reduction Reactions

Roshan Nazir, Partha Kumbhakar, Sakshi Agarwal, Arko Parui, Soumyabrata Roy, Pulickel M. Ajayan, AbhishekK. Singh, Sudhanshu Sharma and Chandra Sekhar Tiwary

ACS Appl. Eng. Mater., 2024, 2, 2302
DOI: 10.1021/acsaenm.4c00415

Electrochemical and spectroscopic methods for evaluating molecular electrocatalysts

Katherine J. Lee, Noémie Elgrishi, Banu Kandemir and Jillian L. Dempsey

Nat Rev Chem, 2017, 1
DOI: 10.1038/s41570-017-0039

Electrocatalytic activity of cobalt tris(4-nitrophenyl)corrole for hydrogen evolution from water

Hai Chen, Dong-Lan Huang, Md Sahadat Hossain, Guo-Tian Luo and Hai-Yang Liu

Journal of Coordination Chemistry, 2019, 72, 2791
DOI: 10.1080/00958972.2019.1671588

Impact of the Metal–Organic Frameworks Polymorphism on the Electrocatalytic Properties of CeO2 toward Oxygen Evolution

Nicolle Pauline de Araújo Mendes, Antonio Lopes de Souto Neto, Johnnys da Silva Hortêncio, André L. Menezes de Oliveira, Rafael A. Raimundo, Daniel Araújo Macedo and Fausthon Fred da Silva

ACS Omega, 2024, 9, 49913
DOI: 10.1021/acsomega.4c08837

Development of Cu3N electrocatalyst for hydrogen evolution reaction in alkaline medium

Aparna Sajeev, Aleena Mary Paul, Ravi Nivetha, Kannan Gothandapani, Tamil Selvi Gopal, George Jacob, Muthumareeswaran Muthuramamoorty, Saravanan Pandiaraj, Abdullah Alodhayb, Soo Young Kim, Quyet Van Le, Pau Loke Show, Soon Kwan Jeong and Andrews Nirmala Grace

Sci Rep, 2022, 12
DOI: 10.1038/s41598-022-05953-x

Encased Copper Boosts the Electrocatalytic Activity of N-Doped Carbon Nanotubes for Hydrogen Evolution

Yun Zhang, Yuling Ma, Yu-Yun Chen, Lu Zhao, Lin-Bo Huang, Hao Luo, Wen-Jie Jiang, Xing Zhang, Shuai Niu, Daojiang Gao, Jian Bi, Guangyin Fan and Jin-Song Hu

ACS Appl. Mater. Interfaces, 2017, 9, 36857
DOI: 10.1021/acsami.7b11748

Analysis of electrocatalytic metal-organic frameworks

Brian D. McCarthy, Anna M. Beiler, Ben A. Johnson, Timofey Liseev, Ashleigh T. Castner and Sascha Ott

Coordination Chemistry Reviews, 2020, 406, 213137
DOI: 10.1016/j.ccr.2019.213137

Mechanistic Insight into Electrocatalytic H2 Production by [Fe2(CN){μ-CN(Me)2}(μ-CO)(CO)(Cp)2]: Effects of Dithiolate Replacement in [FeFe] Hydrogenase Models

Federica Arrigoni, Luca Bertini, Luca De Gioia, Andrea Cingolani, Rita Mazzoni, Valerio Zanotti and Giuseppe Zampella

Inorg. Chem., 2017, 56, 13852
DOI: 10.1021/acs.inorgchem.7b01954

Unravelling the Mechanistic Pathway of the Hydrogen Evolution Reaction Driven by a Cobalt Catalyst

Bing Jiang, Marcos Gil‐Sepulcre, Pablo Garrido‐Barros, Carolina Gimbert‐Suriñach, Jia‐Wei Wang, Jordi Garcia‐Anton, Pau Nolis, Jordi Benet‐Buchholz, Nuria Romero, Xavier Sala and Antoni Llobet

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202209075

Heterogenization of a [NiFe] Hydrogenase Mimic through Simple and Efficient Encapsulation into a Mesoporous MOF

Davide Balestri, Yoann Roux, Monica Mattarozzi, Claudio Mucchino, Laurent Heux, Deborah Brazzolotto, Vincent Artero, Carole Duboc, Paolo Pelagatti, Luciano Marchiò and Marcello Gennari

Inorg. Chem., 2017, 56, 14801
DOI: 10.1021/acs.inorgchem.7b01824

Controlled Potential Electrolysis: Transition from Fast to Slow Regimes in Homogeneous Molecular Catalysis. Application to the Electroreduction of CO2 Catalyzed by Iron Porphyrin

Rana Deeba, Alexandra Collard, Camille Rollin, Florian Molton, Sylvie Chardon‐Noblat and Cyrille Costentin

ChemElectroChem, 2023, 10
DOI: 10.1002/celc.202300350

A molecular molybdenum–schiff base electro-catalyst for generating hydrogen from acetic acid or water

Jie-Ping Cao, Ting Fang, Ling-Ling Zhou, Ling-Zhi Fu and Shuzhong Zhan

Electrochimica Acta, 2014, 147, 129
DOI: 10.1016/j.electacta.2014.09.089

Investigation of Strain and Transition-Metal Doping Effect on Hydrogen Evolution Reaction Catalysts of Mo2C, MoP, and Ni2P

Feng Zhang, Lei He, Sen Lian, Mingyue Wang, Xue Chen, Jikang Yin, Huaqing Pan, Junfeng Ren and Meina Chen

J. Phys. Chem. C, 2021, 125, 19119
DOI: 10.1021/acs.jpcc.1c04745

Tuning redox potentials of CO2 reduction catalysts for carbon photofixation by Si nanowires

Rui Liu, Carolynn Stephani, Kian L. Tan and Dunwei Wang

Sci. China Mater., 2015, 58, 515
DOI: 10.1007/s40843-015-0068-8

Cobalt Molybdenum Oxide Derived High-Performance Electrocatalyst for the Hydrogen Evolution Reaction

Mingjie Zang, Ning Xu, Guoxuan Cao, Zhengjun Chen, Jie Cui, Liyong Gan, Hongbin Dai, Xianfeng Yang and Ping Wang

ACS Catal., 2018, 8, 5062
DOI: 10.1021/acscatal.8b00949

Electrocatalytic Metal–Organic Frameworks for Energy Applications

Courtney A. Downes and Smaranda C. Marinescu

ChemSusChem, 2017, 10, 4374
DOI: 10.1002/cssc.201701420

Phosphorus‐Doped MoS2 Nanosheets Supported on Carbon Cloths as Efficient Hydrogen‐Generation Electrocatalysts

Luozhen Bian, Wei Gao, Jiamin Sun, Mingming Han, Fulin Li, Zhaofeng Gao, Lei Shu, Ning Han, Zai‐xing Yang, Aimin Song, Yongquan Qu and Johnny C. Ho

ChemCatChem, 2018, 10, 1571
DOI: 10.1002/cctc.201701680

Cobalt hydride-mediated photocatalytic semihydrogenation of acetylene impurities for continuous-flow production of polymer-grade ethylene

Haojie Dai, Yuhan Wang, Kailin Wang, Hao Kang, Xiangyang Chen, Bei Ding, Xudan Chen, Ying Du, Lize Dong, Wen Zhong, Ning Sun, Pengyu Liu, Chunyang Yu, Jingyuan Ma, Fei Song, Yongfeng Hu, Shan Tang, Yannan Liu, Wenfeng Jiang, Yuanhai Su, Jun Li and Yongfeng Zhou

Nat Catal, 2025, 8, 645
DOI: 10.1038/s41929-025-01380-z

Porous NiCu alloy cathode with oriented pore structure for hydrogen evolution reaction by freeze casting

Jiahuan He, Liguo Zu, Xinli Liu, Lei Zhang and Bohua Duan

J Porous Mater, 2019, 26, 1533
DOI: 10.1007/s10934-019-00751-9

A review of alkaline solid polymer membrane in the application of AEM electrolyzer: Materials and characterization

Zulfirdaus Zakaria and Siti Kartom Kamarudin

Int J Energy Res, 2021, 45, 18337
DOI: 10.1002/er.6983

A Nickel Dithiolate Water Reduction Catalyst Providing Ligand‐Based Proton‐Coupled Electron‐Transfer Pathways

Keita Koshiba, Kosei Yamauchi and Ken Sakai

Angewandte Chemie, 2017, 129, 4311
DOI: 10.1002/ange.201700927

Active Electron Density Modulation of Co3O4‐Based Catalysts Enhances their Oxygen Evolution Performance

Dong He, Xianyin Song, Wenqing Li, Chongyang Tang, Jiangchao Liu, Zunjian Ke, Changzhong Jiang and Xiangheng Xiao

Angew Chem Int Ed, 2020, 59, 6929
DOI: 10.1002/anie.202001681

Hydrogen Evolution Reactions Catalyzed by a Bis(thiosemicarbazone) Cobalt Complex: An Experimental and Theoretical Study

Tatiana Straistari, Renaud Hardré, Jennifer Fize, Sergiu Shova, Michel Giorgi, Marius Réglier, Vincent Artero and Maylis Orio

Chemistry A European J, 2018, 24, 8779
DOI: 10.1002/chem.201801155

Molecular cathode and photocathode materials for hydrogen evolution in photoelectrochemical devices

Nicolas Queyriaux, Nicolas Kaeffer, Adina Morozan, Murielle Chavarot-Kerlidou and Vincent Artero

Journal of Photochemistry and Photobiology C: Photochemistry Reviews, 2015, 25, 90
DOI: 10.1016/j.jphotochemrev.2015.08.001

Electrocatalytic Dihydrogen Production by an Earth-Abundant Manganese Bipyridine Catalyst

Matthew D. Sampson and Clifford P. Kubiak

Inorg. Chem., 2015, 54, 6674
DOI: 10.1021/acs.inorgchem.5b01080

Insights into Formate Oxidation by a Series of Cobalt Piano-Stool Complexes Supported by Bis(phosphino)amine Ligands

Andrew W. Cook, Thomas J. Emge and Kate M. Waldie

Inorg. Chem., 2021, 60, 7372
DOI: 10.1021/acs.inorgchem.1c00563

NiMo@C3N5 heterostructures with multiple electronic transmission channels for highly efficient hydrogen evolution from alkaline electrolytes and seawater

Xiuming Bu, Xiongyi Liang, Yu Bu, Quan Quan, You Meng, Zhengxun Lai, Wei Wang, Chuntai Liu, Jian Lu, Chi-Man Lawrence Wu and Johnny C. Ho

Chemical Engineering Journal, 2022, 438, 135379
DOI: 10.1016/j.cej.2022.135379

Synthesis of Co9S8 nanoparticle embedded, N, S Co-doped mesoporous carbon with salts as templates for electrocatalytic hydrogen evolution

Huan Yu, Wenting Zhang, Sijia Miao, Yuhang Du, Yuan Huang, Duihai Tang, Zhen-An Qiao, Jianjun Wang and Zhen Zhao

Microporous and Mesoporous Materials, 2020, 302, 110235
DOI: 10.1016/j.micromeso.2020.110235

Vibrational structure analysis of cobalt fluoro-porphyrin surface coatings on gallium phosphide

Diana Khusnutdinova, Anna M. Beiler, Brian L. Wadsworth, Sylvia K. Nanyangwe and Gary F. Moore

J. Porphyrins Phthalocyanines, 2018, 22, 461
DOI: 10.1142/S1088424618500906

Monomeric MoS42–-Derived Polymeric Chains with Active Molecular Units for Efficient Hydrogen Evolution Reaction

Bora Seo, Gwan Yeong Jung, Se Jeong Lee, Du San Baek, Young Jin Sa, Hyeong Woo Ban, Jae Sung Son, Kiyoung Park, Sang Kyu Kwak and Sang Hoon Joo

ACS Catal., 2020, 10, 652
DOI: 10.1021/acscatal.9b02700

Doublet Ground State in a Vanadium(II) Complex: Redox and Coordinative Noninnocence of Tripodal Ligand Architecture

Justin P. Joyce, Romeo I. Portillo, Anthony K. Rappé and Matthew P. Shores

Inorg. Chem., 2022, 61, 6376
DOI: 10.1021/acs.inorgchem.1c03418

Enabling Silicon for Solar-Fuel Production

Ke Sun, Shaohua Shen, Yongqi Liang, Paul E. Burrows, Samuel S. Mao and Deli Wang

Chem. Rev., 2014, 114, 8662
DOI: 10.1021/cr300459q

Si-Based Water Oxidation Photoanodes Conjugated with Earth-Abundant Transition Metal-Based Catalysts

Sol A Lee, Seokhoon Choi, Changyeon Kim, Jin Wook Yang, Soo Young Kim and Ho Won Jang

ACS Materials Lett., 2020, 2, 107
DOI: 10.1021/acsmaterialslett.9b00422

Highly catalytic active PtNiCu nanochains for hydrogen evolution reaction

Xia Cao, Yu Han, Caizhen Gao, Ying Xu, Xiaomin Huang, Magnus Willander and Ning Wang

Nano Energy, 2014, 9, 301
DOI: 10.1016/j.nanoen.2014.08.008

Electrocatalytic Properties of Binuclear Cu(II) Fused Porphyrins for Hydrogen Evolution

Diana Khusnutdinova, Brian L. Wadsworth, Marco Flores, Anna M. Beiler, Edgar A. Reyes Cruz, Yegor Zenkov and Gary F. Moore

ACS Catal., 2018, 8, 9888
DOI: 10.1021/acscatal.8b01776

Organotrialkoxysilane-mediated synthesis of Ni–Pd nanocatalysts at lower concentrations of noble metal: Catalysts for faster hydrogen evolution kinetics

Prem C. Pandey, Shubhangi Shukla and Roger J. Narayan

Journal of Vacuum Science & Technology B, Nanotechnology and Microelectronics: Materials, Processing, Measurement, and Phenomena, 2021, 39
DOI: 10.1116/6.0000881

The bifunctional 3D-on-2D FeCo/Ni(OH)2 hierarchical nanocatalyst for industrial-level electrocatalytic water splitting

Shunshun Xu, Cong Chen, Junxia Shen, Zihao Xu, Yao Lu, Pengfei Song, Wen Dong, Ronglei Fan and Mingrong Shen

International Journal of Hydrogen Energy, 2023, 48, 17882
DOI: 10.1016/j.ijhydene.2023.01.289

Highly Efficient Molecular Cobalt Electrode for (Photo)electrochemical Hydrogen Evolution

Xuejiao Chen, Huan Ren, Wei Peng, Huiming Zhang, Juntao Lu and Lin Zhuang

J. Phys. Chem. C, 2014, 118, 20791
DOI: 10.1021/jp5061792

Cyclopentadienyl Cobalt Complexes as Precatalysts for Electrocatalytic Hydrogen Evolution

Kate M. Waldie, Sung‐Kwan Kim, Andrew J. Ingram and Robert M. Waymouth

Eur J Inorg Chem, 2017, 2017, 2755
DOI: 10.1002/ejic.201700188

Tunability of Nickel Benzenehexathiolate Electrocatalysts for the Hydrogen Evolution Reaction

Ashley Tu Anh Nguyen, Yashna Khakre, Amir Avishai, Maya Kawakami, Courtney Ennis and Smaranda C. Marinescu

ACS Appl. Mater. Interfaces, 2025, 17, 52090
DOI: 10.1021/acsami.5c11085

Evolution of unpredictable behaviour of a passivated stainless steel measured electrochemically

A.R. Moshaweh and G.T. Burstein

Corrosion Science, 2016, 113, 126
DOI: 10.1016/j.corsci.2016.10.013

Mechanism of the Electrocatalytic Reduction of Protons with Diaryldithiolene Cobalt Complexes

Christopher S. Letko, Julien A. Panetier, Martin Head-Gordon and T. Don Tilley

J. Am. Chem. Soc., 2014, 136, 9364
DOI: 10.1021/ja5019755

Analysis of Electrocatalytic Performance of Nanostructured MoS2 in Hydrogen Evolution Reaction

K. Nayana and A. P. Sunitha

CNANO, 2023, 19, 575
DOI: 10.2174/1573413718666220825163052

Electrochemical Strategy for Proton Relay Installation Enhances the Activity of a Hydrogen Evolution Electrocatalyst

Shaoyang Lin, Samragni Banerjee, Matthew T. Fortunato, Congcong Xue, Jie Huang, Alexander Yu. Sokolov and Claudia Turro

J. Am. Chem. Soc., 2022, 144, 20267
DOI: 10.1021/jacs.2c06011

Performance of cobalt doped two dimensional black phosphorus (Co-2D BP) for bifunctional hydrolysis in alkaline solution

Yue Yang, Haibo Li, Jianing Xu, Yu Shang, Lin Zhu, Yutong Jiang and Liuyu Song

Journal of Physics and Chemistry of Solids, 2024, 195, 112294
DOI: 10.1016/j.jpcs.2024.112294

A Bias‐Free, Stand‐Alone, and Scalable Photovoltaic–Electrochemical Device for Solar Hydrogen Production

Minoh Lee, Bugra Turan, Jan‐Philipp Becker, Katharina Welter, Benjamin Klingebiel, Elmar Neumann, Yoo Jung Sohn, Tsvetelina Merdzhanova, Thomas Kirchartz, Friedhelm Finger, Uwe Rau and Stefan Haas

Advanced Sustainable Systems, 2020, 4
DOI: 10.1002/adsu.202000070

Method for the Solution Deposition of Phase-Pure CoSe2 as an Efficient Hydrogen Evolution Reaction Electrocatalyst

Carrie L. McCarthy, Courtney A. Downes, Emily C. Schueller, Karla Abuyen and Richard L. Brutchey

ACS Energy Lett., 2016, 1, 607
DOI: 10.1021/acsenergylett.6b00246

Carbon‐Rich Nanomaterials: Fascinating Hydrogen and Oxygen Electrocatalysts

Jian Zhang, Guangbo Chen, Klaus Müllen and Xinliang Feng

Advanced Materials, 2018, 30
DOI: 10.1002/adma.201800528

Exploring single-atom catalysis for hydrogen evolution and storage: A DFT insight into first-row transition metal-porphyrin complexes (Porph@TMs)

Faheem Abbas, Saleem Nawaz Khan, Sadaf Bibi, Mariyum Yousaf, Francis Enujekwu, Muhammad Salman Khan, Sami Ullah and Mohammed Ali Assiri

Gas Science and Engineering, 2025, 139, 205646
DOI: 10.1016/j.jgsce.2025.205646

Two-phase model of hydrogen transport to optimize nanoparticle catalyst loading for hydrogen evolution reaction

Erno Kemppainen, Janne Halme, Ole Hansen, Brian Seger and Peter D. Lund

International Journal of Hydrogen Energy, 2016, 41, 7568
DOI: 10.1016/j.ijhydene.2015.12.207

Manganese Complexes: Hydrogen Generation and Oxidation

Vishakha Kaim and Sandeep Kaur‐Ghumaan

Eur J Inorg Chem, 2019, 2019, 5041
DOI: 10.1002/ejic.201900988

Electrochemical Hydrogen Evolution at Ordered Mo7Ni7

Peter M. Csernica, James R. McKone, Catherine R. Mulzer, William R. Dichtel, Héctor D. Abruña and Francis J. DiSalvo

ACS Catal., 2017, 7, 3375
DOI: 10.1021/acscatal.7b00344

Supramolecular Assembly Promotes the Electrocatalytic Reduction of Carbon Dioxide by Re(I) Bipyridine Catalysts at a Lower Overpotential

Charles W. Machan, Steven A. Chabolla, Jian Yin, Michael K. Gilson, F. Akif Tezcan and Clifford P. Kubiak

J. Am. Chem. Soc., 2014, 136, 14598
DOI: 10.1021/ja5085282

Hierarchical NiMo-based 3D electrocatalysts for highly-efficient hydrogen evolution in alkaline conditions

Ming Fang, Wei Gao, Guofa Dong, Zhaoming Xia, SenPo Yip, Yuanbin Qin, Yongquan Qu and Johnny C. Ho

Nano Energy, 2016, 27, 247
DOI: 10.1016/j.nanoen.2016.07.005

Rational design of freestanding MoS2 monolayers for hydrogen evolution reaction

Xiao Hai, Wei Zhou, Shengyao Wang, Hong Pang, Kun Chang, Fumihiko Ichihara and Jinhua Ye

Nano Energy, 2017, 39, 409
DOI: 10.1016/j.nanoen.2017.07.021

Dinuclear Manganese Carbonyl Complexes: Electrocatalytic Reduction of Protons to Dihydrogen

Vishakha Kaim, Mookan Natarajan and Sandeep Kaur‐Ghumaan

ChemistrySelect, 2019, 4, 1789
DOI: 10.1002/slct.201803754

Electrochemical Allene C─H Functionalization via Carbanion Sampling

Jiayi Feng, Yuhang Xia, Mingyu Shen, Junwei Wang, Weigang Fan, Sheng Zhang and Man‐Bo Li

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202508369

Microwave-Assisted Reactant-Protecting Strategy toward Efficient MoS2 Electrocatalysts in Hydrogen Evolution Reaction

Ning Liu, Yulin Guo, Xiaoyun Yang, Huanlei Lin, Lichun Yang, Zhangping Shi, Zhiwei Zhong, Sinong Wang, Yi Tang and Qingsheng Gao

ACS Appl. Mater. Interfaces, 2015, 7, 23741
DOI: 10.1021/acsami.5b08103

Enhanced photocatalytic hydrogen evolution from organic semiconductor heterojunction nanoparticles

Jan Kosco, Matthew Bidwell, Hyojung Cha, Tyler Martin, Calvyn T. Howells, Michael Sachs, Dalaver H. Anjum, Sandra Gonzalez Lopez, Lingyu Zou, Andrew Wadsworth, Weimin Zhang, Lisheng Zhang, James Tellam, Rachid Sougrat, Frédéric Laquai, Dean M. DeLongchamp, James R. Durrant and Iain McCulloch

Nat. Mater., 2020, 19, 559
DOI: 10.1038/s41563-019-0591-1

Photochemical hydrogen generation with porphyrin-based systems

Kalliopi Ladomenou, Mirco Natali, Elisabetta Iengo, Georgios Charalampidis, Franco Scandola and Athanassios G. Coutsolelos

Coordination Chemistry Reviews, 2015, 304-305, 38
DOI: 10.1016/j.ccr.2014.10.001

Chemistry at the Interface: Polymer-Functionalized GaP Semiconductors for Solar Hydrogen Production

Anna M. Beiler, Diana Khusnutdinova, Samuel I. Jacob and Gary F. Moore

Ind. Eng. Chem. Res., 2016, 55, 5306
DOI: 10.1021/acs.iecr.6b00478

Electrohydrogenation of Nitriles with Amines by Cobalt Catalysis

Tiantian Wang, Fangfang He, Wei Jiang and Jie Liu

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202316140

Expedited Proton Relay in Enzyme‐Inspired Cobaloximes Facilitate Organic Transformations

Subir Panja, Chandan Nandi, Somnath Guria, Avishek Pan, Chandan Das, Srewashi Das, Santanu Ghorai, Arnab Dutta and Debabrata Maiti

Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202401785

Electrocatalytic Hydrogen Production by [Ni(7PPh2NH)2]2+: Removing the Distinction Between Endo- and Exo-Protonation Sites

Houston J. S. Brown, Stefan Wiese, John A. S. Roberts, R. Morris Bullock and Monte L. Helm

ACS Catal., 2015, 5, 2116
DOI: 10.1021/cs502132y

Frontier Biological Electrodes for Cell Analysis

Yingying Huang and Bo Fang

Chem. Res. Chin. Univ., 2025, 41, 447
DOI: 10.1007/s40242-025-4243-5

Hydride Transfer Limits Hydrogen Evolution Efficiency With Zn Porphyrin Photocatalysts

Ouissam El Bakouri, Simon T. Clausing and Lluís Blancafort

Chemistry An Asian Journal, 2026, 21
DOI: 10.1002/asia.70665

Coupling Mo2C Nanoparticles with Graphite Nanosheets as Durable Electrocatalysts for Hydrogen Evolution Reaction

Yi Shen and Bin Gong

J. Electrochem. Soc., 2016, 163, H1060
DOI: 10.1149/2.0271613jes

Active Electron Density Modulation of Co3O4‐Based Catalysts Enhances their Oxygen Evolution Performance

Dong He, Xianyin Song, Wenqing Li, Chongyang Tang, Jiangchao Liu, Zunjian Ke, Changzhong Jiang and Xiangheng Xiao

Angewandte Chemie, 2020, 132, 6996
DOI: 10.1002/ange.202001681

The Dark Side of Molecular Catalysis: Diimine–Dioxime Cobalt Complexes Are Not the Actual Hydrogen Evolution Electrocatalyst in Acidic Aqueous Solutions

Nicolas Kaeffer, Adina Morozan, Jennifer Fize, Eugenie Martinez, Laure Guetaz and Vincent Artero

ACS Catal., 2016, 6, 3727
DOI: 10.1021/acscatal.6b00378

A Cu‐Based Nanoparticulate Film as Super‐Active and Robust Catalyst Surpasses Pt for Electrochemical H2 Production from Neutral and Weak Acidic Aqueous Solutions

Peili Zhang, Mei Wang, Hong Chen, Yongqi Liang, Junliang Sun and Licheng Sun

Advanced Energy Materials, 2016, 6
DOI: 10.1002/aenm.201502319

Introducing Water‐Network‐Assisted Proton Transfer for Boosted Electrocatalytic Hydrogen Evolution with Cobalt Corrole

Xialiang Li, Bin Lv, Xue‐Peng Zhang, Xiaotong Jin, Kai Guo, Dexia Zhou, Hongtao Bian, Wei Zhang, Ulf‐Peter Apfel and Rui Cao

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202114310

Evolution of layered double hydroxides (LDH) as high performance water oxidation electrocatalysts: A review with insights on structure, activity and mechanism

Sengeni Anantharaj, Kannimuthu Karthick and Subrata Kundu

Materials Today Energy, 2017, 6, 1
DOI: 10.1016/j.mtener.2017.07.016

Visible Light Sensitized CO2 Activation by the Tetraaza [CoIIN4H(MeCN)]2+ Complex Investigated by FT-IR Spectroscopy and DFT Calculations

M. Zhang, M. El-Roz, H. Frei, J. L. Mendoza-Cortes, M. Head-Gordon, David C. Lacy and Jonas C. Peters

J. Phys. Chem. C, 2015, 119, 4645
DOI: 10.1021/jp5127738

Singly versus Doubly Reduced Nickel Porphyrins for Proton Reduction: Experimental and Theoretical Evidence for a Homolytic Hydrogen‐Evolution Reaction

Yongzhen Han, Huayi Fang, Huize Jing, Huiling Sun, Haitao Lei, Wenzhen Lai and Rui Cao

Angew Chem Int Ed, 2016, 55, 5457
DOI: 10.1002/anie.201510001

Enhancing hydrogen evolution reaction using iridium atomic monolayer on conventional electrodes: A first-principles study

Abdul Ahad Mamun, Asif Billah and Muhammad Anisuzzaman Talukder

International Journal of Hydrogen Energy, 2024, 59, 982
DOI: 10.1016/j.ijhydene.2024.02.156

Highly active macrocyclic nickel(II) complex for hydrogen evolution reaction in neutral aqueous conditions

Hossain M. Shahadat, Nazir Ahmad, Zafar A.K. Khattak, Rahaman M. Abdur, Rashid Al-Hajri, Mohammed Al-Abri, Chih-Ming Kao, Hussein A. Younus and Francis Verpoort

International Journal of Hydrogen Energy, 2023, 48, 33927
DOI: 10.1016/j.ijhydene.2023.05.192

Triethylenetetramine-assisted hydrothermal synthesis of sulfur-doped few-layer MoSe 2 /nitrogenated graphene hybrids and their catalytic activity for hydrogen evolution reaction

Limei Xu, Xiaoping Zhou, Xuyao Xu, Lin Ma, Jin Luo and Lingling Zhang

Advanced Powder Technology, 2016, 27, 1560
DOI: 10.1016/j.apt.2016.05.019

Dimeric FeFe-hydrogenase mimics bearing carboxylic acids: Synthesis and electrochemical investigation

Benjamin R. Garrett, Amneh Awad, Mingfu He, Kevin A. Click, Christopher B. Durr, Judith C. Gallucci, Christopher M. Hadad and Yiying Wu

Polyhedron, 2016, 103, 21
DOI: 10.1016/j.poly.2015.08.019

Ultra-small freestanding amorphous molybdenum sulfide colloidal nanodots for highly efficient photocatalytic hydrogen evolution reaction

Kun Chang, Hong Pang, Xiao Hai, Guixia Zhao, Huabin Zhang, Li Shi, Fumihiko Ichihara and Jinhua Ye

Applied Catalysis B: Environmental, 2018, 232, 446
DOI: 10.1016/j.apcatb.2018.03.087

Electro- and Photocatalytic Hydrogen Production by Molecular Cobalt Complexes With Pentadentate Ligands

Xuan Zhao, Ping Wang and Melissa Long

Comments on Inorganic Chemistry, 2017, 37, 238
DOI: 10.1080/02603594.2016.1266618

Electrocatalytic Hydrogen Production by a Nickel Complex Containing a Tetradentate Phosphine Ligand

Christina M. Klug, William G. Dougherty, W. Scott Kassel and Eric S. Wiedner

Organometallics, 2019, 38, 1269
DOI: 10.1021/acs.organomet.8b00548

Catalytic Activity of Thiolate‐Bridged Diruthenium Complexes Bearing Pendent Ether Moieties in the Oxidation of Molecular Dihydrogen

Masahiro Yuki, Ken Sakata, Shoma Kikuchi, Hiroyuki Kawai, Tsuyoshi Takahashi, Masaki Ando, Kazunari Nakajima and Yoshiaki Nishibayashi

Chemistry A European J, 2017, 23, 1007
DOI: 10.1002/chem.201604974

Molybdenum Carbide‐Decorated Metallic Cobalt@Nitrogen‐Doped Carbon Polyhedrons for Enhanced Electrocatalytic Hydrogen Evolution

Can Wu, Dan Liu, Hui Li and Jinghong Li

Small, 2018, 14
DOI: 10.1002/smll.201704227

Dinitrosyl iron complexes: From molecular electrocatalysts to electrodeposited‐film electrodes for hydrogen evolution reaction

Shan Lu, Jin‐Cheng Chiang, Tzung‐Wen Chiou and Wen‐Feng Liaw

J Chinese Chemical Soc, 2019, 66, 1186
DOI: 10.1002/jccs.201900147

Hydrogen Bond‐Assisted PCET and Formation of WIII─OH in Bis(Dithiolene) Complex

Wonjung Lee, Daeyong Um, Yujin Baek, Sugyeong Hong, Youngseob Lee, Jaeheon Lee, Jin Kim, Sun Hee Kim, Kyung‐Bin Cho and Junhyeok Seo

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202506861

Density Functional Theory and Car–Parrinello Molecular Dynamics Study of the Hydrogen-Producing Mechanism of the Co(dmgBF2)2 and Co(dmgH)2 Cobaloxime Complexes in Acetonitrile–Water Solvent

Jinfan Chen and Patrick H.-L. Sit

J. Phys. Chem. A, 2017, 121, 3515
DOI: 10.1021/acs.jpca.7b00163

Reverse Electrodialysis-Assisted Solar Water Splitting

Jihye Lee, Jeongse Yun, Seung-Ryong Kwon, Woo Je Chang, Ki Tae Nam and Taek Dong Chung

Sci Rep, 2017, 7
DOI: 10.1038/s41598-017-12476-3

RETRACTED: Ammonia synthesis by N 2 and steam electrolysis in molten hydroxide suspensions of nanoscale Fe 2 O 3

Stuart Licht, Baochen Cui, Baohui Wang, Fang-Fang Li, Jason Lau and Shuzhi Liu

Science, 2014, 345, 637
DOI: 10.1126/science.1254234

Structure and electrochemical property of amorphous molybdenum selenide H2-evolving catalysts prepared by a solvothermal synthesis

Chuc T. Nguyen, Tuan M. Duong, Mai Nguyen, Quyen T. Nguyen, Anh D. Nguyen, Ung Thi Dieu Thuy, Quang Duc Truong, Tung T. Nguyen, Quang Liem Nguyen and Phong D. Tran

International Journal of Hydrogen Energy, 2019, 44, 13273
DOI: 10.1016/j.ijhydene.2019.03.186

Synthesis and studies of a molecular molybdenum–Schiff base electrocatalyst for generating hydrogen from organic acid or water

Ting Fang, Hai-Xia Lu, Jia-Xing Zhao and Shu-Zhong Zhan

Inorganic Chemistry Communications, 2015, 51, 66
DOI: 10.1016/j.inoche.2014.11.009

Ni-W nanostructure well-marked by Ni selective etching for enhanced hydrogen evolution reaction

P. Jameei Rad, M. Aliofkhazraei and Gh. Barati Darband

International Journal of Hydrogen Energy, 2019, 44, 880
DOI: 10.1016/j.ijhydene.2018.11.026

Synthesis of a molecular electrocatalyst based on an iron(III) complex supported by amine-bis(phenolate) ligand for water reduction

Ling-Ling Zhou, Ling-Zhi Tang, Yun-Xiao Zhang and Shu-Zhong Zhan

Polyhedron, 2015, 92, 124
DOI: 10.1016/j.poly.2015.03.013

New Tetracobalt Cluster Compounds for Electrocatalytic Proton Reduction: Syntheses, Structures, and Reactivity

Ping Li, Riccardo Zaffaroni, Bas de Bruin and Joost N. H. Reek

Chemistry A European J, 2015, 21, 4027
DOI: 10.1002/chem.201405052

Facile and large-scale preparation of Co/Ni-MoO2 composite as high-performance electrocatalyst for hydrogen evolution reaction

Bo Xu, Yiqiang Sun, Zhiming Chen, Shuying Zhao, Xiaodong Yang, Haijing Zhang and Cuncheng Li

International Journal of Hydrogen Energy, 2018, 43, 20721
DOI: 10.1016/j.ijhydene.2018.09.159

Amplifying Reactivity of Bio‐Inspired [FeFe]‐Hydrogenase Mimics by Organic Nanotubes

Md Estak Ahmed, Puspendu Das, Sk Mustak Ahamed, Samir Chattopadhyay, Abhijit Nayek, Mintu Mondal, Sudip Malik and Abhishek Dey

Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202403011

Graphene‐Supported Pyrene‐Modified Cobalt Corrole with Axial Triphenylphosphine for Enhanced Hydrogen Evolution in pH 0–14 Aqueous Solutions

Xialiang Li, Haitao Lei, Xiaojun Guo, Xueli Zhao, Shuping Ding, Xueqing Gao, Wei Zhang and Rui Cao

ChemSusChem, 2017, 10, 4632
DOI: 10.1002/cssc.201701196

Protonation/Reduction of Carbonyl-Rich Diiron Complexes and the Direct Observation of Triprotonated Species: Insights into the Electrocatalytic Mechanism of Hydrogen Formation

Yu-Chiao Liu, Kai-Ti Chu, Yi-Lan Huang, Cheng-Huey Hsu, Gene-Hsiang Lee, Mei-Chun Tseng and Ming-Hsi Chiang

ACS Catal., 2016, 6, 2559
DOI: 10.1021/acscatal.5b02646

Advancing the Electrochemistry of the Hydrogen‐Evolution Reaction through Combining Experiment and Theory

Yao Zheng, Yan Jiao, Mietek Jaroniec and Shi Zhang Qiao

Angew Chem Int Ed, 2015, 54, 52
DOI: 10.1002/anie.201407031

Electrocatalysis: From Planar Surfaces to Nanostructured Interfaces

Alasdair R. Fairhurst, Joshua Snyder, Chao Wang, Dusan Strmcnik and Vojislav R. Stamenkovic

Chem. Rev., 2025, 125, 1332
DOI: 10.1021/acs.chemrev.4c00133

Novel Amorphous Molybdenum Selenide as an Efficient Catalyst for Hydrogen Evolution Reaction

Quyen T. Nguyen, Phuc D. Nguyen, Duc N. Nguyen, Quang Duc Truong, Tran Thi Kim Chi, Thuy Thi Dieu Ung, Itaru Honma, Nguyen Quang Liem and Phong D. Tran

ACS Appl. Mater. Interfaces, 2018, 10, 8659
DOI: 10.1021/acsami.7b18675

Copper-promoted growth of hierarchical Cu–Co–Ni alloys on copper nanodendrites for enhanced hydrogen evolution in a wide pH range

Hussein A. Younus, Maimouna Al Hinai, Mohammed Al Abri and Rashid Al Hajri

International Journal of Hydrogen Energy, 2024, 92, 247
DOI: 10.1016/j.ijhydene.2024.10.139

Biopolymer-Inspired N-Doped Nanocarbon Using Carbonized Polydopamine: A High-Performance Electrocatalyst for Hydrogen-Evolution Reaction

Duong Nguyen Nguyen, Uk Sim and Jung Kyu Kim

Polymers, 2020, 12, 912
DOI: 10.3390/polym12040912

Dye-sensitized PS-b-P2VP-templated nickel oxide films for photoelectrochemical applications

Julien Massin, Maximilian Bräutigam, Nicolas Kaeffer, Nicolas Queyriaux, Martin J. Field, Felix H. Schacher, Jürgen Popp, Murielle Chavarot-Kerlidou, Benjamin Dietzek and Vincent Artero

Interface Focus, 2015, 5
DOI: 10.1098/rsfs.2014.0083

An Optically Transparent Iron Nickel Oxide Catalyst for Solar Water Splitting

Carlos G. Morales-Guio, Matthew T. Mayer, Aswani Yella, S. David Tilley, Michael Grätzel and Xile Hu

J. Am. Chem. Soc., 2015, 137, 9927
DOI: 10.1021/jacs.5b05544

Electrochemical-driven hydrogen evolution from acetic acid and water catalyzed by a mixed-valent CoII–CoI complex with high turnover frequency

Jie-Ping Cao, Ling-Zhi Fu, Ling-Ling Zhou and Shu-Zhong Zhan

Journal of Power Sources, 2015, 279, 107
DOI: 10.1016/j.jpowsour.2014.12.154

Ruthenium–Tungsten Composite Catalyst for the Efficient and Contamination-Resistant Electrochemical Evolution of Hydrogen

Ubisha Joshi, Souradip Malkhandi, Yi Ren, Teck Leong Tan, Sing Yang Chiam and Boon Siang Yeo

ACS Appl. Mater. Interfaces, 2018, 10, 6354
DOI: 10.1021/acsami.7b17970

The Holy Grail in Platinum‐Free Electrocatalytic Hydrogen Evolution: Molybdenum‐Based Catalysts and Recent Advances

Zechao Zhuang, Jiazhao Huang, Yong Li, Liang Zhou and Liqiang Mai

ChemElectroChem, 2019, 6, 3570
DOI: 10.1002/celc.201900143

Role of Ligand Protonation in Dihydrogen Evolution from a Pentamethylcyclopentadienyl Rhodium Catalyst

Samantha I. Johnson, Harry B. Gray, James D. Blakemore and William A. Goddard

Inorg. Chem., 2017, 56, 11375
DOI: 10.1021/acs.inorgchem.7b01698

Progress in Cobalt Complexes for Enabling Asymmetric Hydrogenation, H2 Production Catalysis and Alkene/Alkyne Hydro‐functionalization: A Review

Shalima Kumari, Maridula Thakur and Meena Kumari

ChemistrySelect, 2024, 9
DOI: 10.1002/slct.202303916

Singly versus Doubly Reduced Nickel Porphyrins for Proton Reduction: Experimental and Theoretical Evidence for a Homolytic Hydrogen‐Evolution Reaction

Yongzhen Han, Huayi Fang, Huize Jing, Huiling Sun, Haitao Lei, Wenzhen Lai and Rui Cao

Angewandte Chemie, 2016, 128, 5547
DOI: 10.1002/ange.201510001

Bioinspired Metal Selenolate Polymers with Tunable Mechanistic Pathways for Efficient H2 Evolution

Courtney A. Downes and Smaranda C. Marinescu

ACS Catal., 2017, 7, 848
DOI: 10.1021/acscatal.6b03161

MOF-Derived Ultrathin Cobalt Molybdenum Phosphide Nanosheets for Efficient Electrochemical Overall Water Splitting

Xiang Wang, Linlin Yang, Congcong Xing, Xu Han, Ruifeng Du, Ren He, Pablo Guardia, Jordi Arbiol and Andreu Cabot

Nanomaterials, 2022, 12, 1098
DOI: 10.3390/nano12071098

Surface Immobilization of Molecular Electrocatalysts for Energy Conversion

R. Morris Bullock, Atanu K. Das and Aaron M. Appel

Chemistry A European J, 2017, 23, 7626
DOI: 10.1002/chem.201605066

Electrochemical Detection of Transient Cobalt Hydride Intermediates of Electrocatalytic Hydrogen Production

Eric S. Wiedner and R. Morris Bullock

J. Am. Chem. Soc., 2016, 138, 8309
DOI: 10.1021/jacs.6b04779

Vertically Aligned Interlayer Expanded MoS2 Nanosheets on a Carbon Support for Hydrogen Evolution Electrocatalysis

Manjunath Chatti, Thomas Gengenbach, Russell King, Leone Spiccia and Alexandr N. Simonov

Chem. Mater., 2017, 29, 3092
DOI: 10.1021/acs.chemmater.7b00114

Fundamental aspects and recent advances in transition metal nitrides as electrocatalysts for hydrogen evolution reaction: A review

Jayaraman Theerthagiri, Seung Jun Lee, Arun Prasad Murthy, Jagannathan Madhavan and Myong Yong Choi

Current Opinion in Solid State and Materials Science, 2020, 24, 100805
DOI: 10.1016/j.cossms.2020.100805

MoS2 Nanosheets on MoNi4/MoO2 Nanorods for Hydrogen Evolution

Vivek Kumar Singh, Urwashi Gupta, Bratindranath Mukherjee, Sayan Chattopadhyay and Santanu Das

ACS Appl. Nano Mater., 2021, 4, 886
DOI: 10.1021/acsanm.0c03296

Efficient Electrochemical and Photoelectrochemical H2 Production from Water by a Cobalt Dithiolene One-Dimensional Metal–Organic Surface

Courtney A. Downes and Smaranda C. Marinescu

J. Am. Chem. Soc., 2015, 137, 13740
DOI: 10.1021/jacs.5b07020

Studying the Mechanism of the Electrocatalyic Reaction for Producing Molecular Hydrogen Using the N-Methyl-2,4,6-triphenylpyridinyl Cation According to DFT

A. V. Dolganov, L. A. Klimaeva, E. E. Muryumin, A. D. Yudina, A. S. Zagorodnova, A. V. Tankova, T. V. Boikova, Yu. N. Kovaleva and A. V. Knyazev

Russ. J. Phys. Chem., 2023, 97, 1665
DOI: 10.1134/S003602442308006X

Ligand steals spotlight from metal to orchestrate hydrogen production

Jillian L. Dempsey

Proc. Natl. Acad. Sci. U.S.A., 2016, 113, 478
DOI: 10.1073/pnas.1522759113

Electrocatalytic hydrogen evolution with cobalt–poly(4-vinylpyridine) metallopolymers

Zeynep Kap, Emine Ülker, Satya Vijaya Kumar Nune and Ferdi Karadas

J Appl Electrochem, 2018, 48, 201
DOI: 10.1007/s10800-018-1152-z

Spherical Ruthenium Disulfide-Sulfur-Doped Graphene Composite as an Efficient Hydrogen Evolution Electrocatalyst

Jie Yu, Yanan Guo, Shuanshuan Miao, Meng Ni, Wei Zhou and Zongping Shao

ACS Appl. Mater. Interfaces, 2018, 10, 34098
DOI: 10.1021/acsami.8b08239

Enhanced Homogeneous Photocatalytic Hydrogen Evolution in a Binuclear Bio‐Inspired Ni‐Ni Complex Bearing Phenanthroline and Sulfidophenolate Ligands

Fotios Kamatsos, Maria Drosou, Athanasios Zarkadoulas, Kostas Bethanis and Christiana A. Mitsopoulou

Chemistry A European J, 2025, 31
DOI: 10.1002/chem.202404396

Hollow Nano- and Microstructures as Catalysts

Gonzalo Prieto, Harun Tüysüz, Nicolas Duyckaerts, Johannes Knossalla, Guang-Hui Wang and Ferdi Schüth

Chem. Rev., 2016, 116, 14056
DOI: 10.1021/acs.chemrev.6b00374

Tetrahedral Cu(I) complexes as electrocatalysts for the reduction of protons to dihydrogen gas

Wen Liang James Loke, Chen Hu and Wai Yip Fan

Eur J Inorg Chem, 2021, 2021, 2499
DOI: 10.1002/ejic.202100295

Integration of amorphous/crystalline CoS/Co3B2 heterostructure with coupled electronic engineering toward efficient and stable oxygen evolution reaction

Yuxin Gao, Jing Zhao, Jiayu Xiao, Shuai Wan, Hao Wang, Xiaodong Lv and Lihong Bao

Journal of Alloys and Compounds, 2025, 1037, 182443
DOI: 10.1016/j.jallcom.2025.182443

Fe-Mediated Nitrogen Fixation with a Metallocene Mediator: Exploring pKaEffects and Demonstrating Electrocatalysis

Matthew J. Chalkley, Trevor J. Del Castillo, Benjamin D. Matson and Jonas C. Peters

J. Am. Chem. Soc., 2018, 140, 6122
DOI: 10.1021/jacs.8b02335

Ligand Substituents Govern the Efficiency and Mechanistic Path of Hydrogen Production with [Cp*Rh] Catalysts

Wade C. Henke, Davide Lionetti, William N. G. Moore, Julie A. Hopkins, Victor W. Day and James D. Blakemore

ChemSusChem, 2017, 10, 4589
DOI: 10.1002/cssc.201701416

Molybdenum nitrides from structures to industrial applications

Zainab N. Jaf, Hussein A. Miran, Zhong-Tao Jiang and Mohammednoor Altarawneh

Reviews in Chemical Engineering, 2023, 39, 329
DOI: 10.1515/revce-2021-0002

Synergistic effect of surface oxygen vacancies and hydroxyl groups on Cu-doped TiO2 photocatalyst for hydrogen evolution

Congcong Xing, Zhaofu Zhang, Yu Zhang, Xu Han, Linlin Yang, Junshan Li, Xiang Wang, Paulina Martinez, Muslum Demir, Laura Piveteau, Pierre Florian, Jordi Arbiol, Yuzheng Guo, Jordi Llorca and Andreu Cabot

Materials Today Nano, 2023, 24, 100435
DOI: 10.1016/j.mtnano.2023.100435

Cobalt Porphyrin–Polypyridyl Surface Coatings for Photoelectrosynthetic Hydrogen Production

A. M. Beiler, D. Khusnutdinova, B. L. Wadsworth and G. F. Moore

Inorg. Chem., 2017, 56, 12178
DOI: 10.1021/acs.inorgchem.7b01509

Bioelectrocatalysis as the basis for the design of enzyme-based biofuel cells and semi-artificial biophotoelectrodes

Adrian Ruff, Felipe Conzuelo and Wolfgang Schuhmann

Nat Catal, 2019, 3, 214
DOI: 10.1038/s41929-019-0381-9

Synthesis, Characterization, and Properties of Metal Phosphide Catalysts for the Hydrogen-Evolution Reaction

Juan F. Callejas, Carlos G. Read, Christopher W. Roske, Nathan S. Lewis and Raymond E. Schaak

Chem. Mater., 2016, 28, 6017
DOI: 10.1021/acs.chemmater.6b02148

Synergistic WO3·2H2O Nanoplates/WS2 Hybrid Catalysts for High-Efficiency Hydrogen Evolution

Lun Yang, Xiaobin Zhu, Shijie Xiong, Xinglong Wu, Yun Shan and Paul K. Chu

ACS Appl. Mater. Interfaces, 2016, 8, 13966
DOI: 10.1021/acsami.6b04045

Electrocatalytic Proton Reduction by a Cobalt(III) Hydride Complex with Phosphinopyridine PN Ligands

Khanittha Walaijai, Stuart A. Cavill, Adrian C. Whitwood, Richard E. Douthwaite and Robin N. Perutz

Inorg. Chem., 2020, 59, 18055
DOI: 10.1021/acs.inorgchem.0c02505

Unravelling the Mechanistic Pathway of the Hydrogen Evolution Reaction Driven by a Cobalt Catalyst

Bing Jiang, Marcos Gil‐Sepulcre, Pablo Garrido‐Barros, Carolina Gimbert‐Suriñach, Jia‐Wei Wang, Jordi Garcia‐Anton, Pau Nolis, Jordi Benet‐Buchholz, Nuria Romero, Xavier Sala and Antoni Llobet

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202209075

Synthesis of an electro-catalyst based on a cobalt(II) complex with dimethylaminoethylamino-N,N-bis(2-methylene-4-tert-butyl-6-methylphenol)

Ling-Ling Zhou, Ling-Zhi Fu, Qian-Nan Liang, Chang Fang and Shu-Zhong Zhan

Journal of Coordination Chemistry, 2016, 69, 628
DOI: 10.1080/00958972.2015.1134791

Ligand‐Based PCET Reduction in a Heteroleptic Ni(bpy)(dithiolene) Electrocatalyst Giving Rise to Higher Metal Basicity Required for Hydrogen Evolution

Keita Koshiba, Kosei Yamauchi and Ken Sakai

ChemElectroChem, 2019, 6, 2273
DOI: 10.1002/celc.201900400

First-row transition metal porphyrins for electrocatalytic hydrogen evolution — a SPP/JPP Young Investigator Award paper

Haitao Lei, Yabo Wang, Qingxin Zhang and Rui Cao

J. Porphyrins Phthalocyanines, 2020, 24, 1361
DOI: 10.1142/S1088424620500157

Artificial photosynthesis with metal and covalent organic frameworks (MOFs and COFs): challenges and prospects in fuel‐forming electrocatalysis

Nina Heidary, Tomos G.A.A. Harris, Khoa H. Ly and Nikolay Kornienko

Physiologia Plantarum, 2019, 166, 460
DOI: 10.1111/ppl.12935

Transition metal tetrapentafluorophenyl porphyrin catalyzed hydrogen evolution from acetic acid and water

Dong-Xu Zhang, Hui-Qing Yuan, Hua-Hua Wang, Atif Ali, Wei-Hong Wen, An-Na Xie, Shu-Zhong Zhan and Hai-Yang Liu

Transit Met Chem, 2017, 42, 773
DOI: 10.1007/s11243-017-0185-1

Insights on Tafel Constant in the Analysis of Hydrogen Evolution Reaction

Arun Prasad Murthy, Jayaraman Theerthagiri and Jagannathan Madhavan

J. Phys. Chem. C, 2018, 122, 23943
DOI: 10.1021/acs.jpcc.8b07763

MWCNT impregnated with [Fe3+-(5-Br-PADAP)] as an effective and stable nanocatalyst in acidic media for MOR and HER

Tahereh Rohani, Amirkhosro Beheshti-Marnani, Sayed Zia Mohammadi, Mohammad Bagher Askari and Behrouz Kurd-Sangani

Materials Chemistry and Physics, 2020, 254, 123568
DOI: 10.1016/j.matchemphys.2020.123568

Transition Metal Pyrithione Complexes (Ni, Mn, Fe, and Co) as Electrocatalysts for Proton Reduction of Acetic Acid

Hui Min Tang and Wai Yip Fan

ACS Omega, 2023, 8, 7234
DOI: 10.1021/acsomega.3c00412

Reactivity and Mechanism Studies of Hydrogen Evolution Catalyzed by Copper Corroles

Haitao Lei, Huayi Fang, Yongzhen Han, Wenzhen Lai, Xuefeng Fu and Rui Cao

ACS Catal., 2015, 5, 5145
DOI: 10.1021/acscatal.5b00666

Light-driven hydrogen production from Photosystem I-catalyst hybrids

Lisa M Utschig, Sarah R Soltau and David M Tiede

Current Opinion in Chemical Biology, 2015, 25, 1
DOI: 10.1016/j.cbpa.2014.11.019

Macroporous Array Induced Multiscale Modulation at the Surface/Interface of Co(OH)2/NiMo Self‐Supporting Electrode for Effective Overall Water Splitting

Qing Zhang, Wei Xiao, Wan Hui Guo, Yu Xian Yang, Jing Lei Lei, Hong Qun Luo and Nian Bing Li

Adv Funct Materials, 2021, 31
DOI: 10.1002/adfm.202102117

Covalent Attachment of Cobalt Bis(Benzylaminedithiolate) to Reduced Graphene Oxide as a Thin-Film Electrocatalyst for Hydrogen Production with Remarkable Dioxygen Tolerance

Virginia A. Larson and Nicolai Lehnert

ACS Catal., 2024, 14, 192
DOI: 10.1021/acscatal.3c03788

Engineered MoSe2‐Based Heterostructures for Efficient Electrochemical Hydrogen Evolution Reaction

Leyla Najafi, Sebastiano Bellani, Reinier Oropesa‐Nuñez, Alberto Ansaldo, Mirko Prato, Antonio Esau Del Rio Castillo and Francesco Bonaccorso

Advanced Energy Materials, 2018, 8
DOI: 10.1002/aenm.201703212

CoP aerogels assisted by selenite etching as high activity electrocatalysts for water splitting

Tao Wang, Xinyuan Liao, Ting Zhang, Minglan Dai and Hua Lin

Composites Part B: Engineering, 2023, 254, 110601
DOI: 10.1016/j.compositesb.2023.110601

Repurposing HER catalysis toward metal hydride-mediated electro-reductive transformations

Sheng Zhang and Man-Bo Li

Tetrahedron Chem, 2024, 11, 100080
DOI: 10.1016/j.tchem.2024.100080

Electrocatalytic H2 Evolution by the Co‐Mabiq Complex Requires Tempering of the Redox‐Active Ligand

G. Ceren Tok, Anna T. S. Freiberg, Hubert A. Gasteiger and Corinna R. Hess

ChemCatChem, 2019, 11, 3973
DOI: 10.1002/cctc.201900953

Circumventing Kinetic Barriers to Metal Hydride Formation with Metal–Ligand Cooperativity

Charlotte L. Montgomery, Mehmed Z. Ertem, Leo Chevalier and Jillian L. Dempsey

J. Am. Chem. Soc., 2024, 146, 30020
DOI: 10.1021/jacs.4c01716

Templating synthesis of porous carbons for energy-related applications: A review

Lu Guan, Han Hu, Xiao-ling Teng, Yi-fan Zhu, Yun-long Zhang, Hui-xia Chao, Hao Yang, Xiao-shan Wang and Ming-bo Wu

New Carbon Materials, 2022, 37, 25
DOI: 10.1016/S1872-5805(22)60574-2

Ultra-fast one-step electrochemical synthesize of Ni-Mn-P as an active and stable electrocatalyst for green hydrogen production

Ali Talebi and Ghasem Barati Darband

Fuel, 2025, 397, 135427
DOI: 10.1016/j.fuel.2025.135427

Recent advances in hydrogen evolution reaction catalysts on carbon/carbon-based supports in acid media

Arun Prasad Murthy, Jagannathan Madhavan and Kadarkarai Murugan

Journal of Power Sources, 2018, 398, 9
DOI: 10.1016/j.jpowsour.2018.07.040

Porphyrin-catalyzed electrochemical hydrogen evolution reaction. Metal-centered and ligand-centered mechanisms

Hiram M. Castro-Cruz and Norma A. Macías-Ruvalcaba

Coordination Chemistry Reviews, 2022, 458, 214430
DOI: 10.1016/j.ccr.2022.214430

Element-Specific Restructuring of Anion- and Cation-Substituted Cobalt Phosphide Nanoparticles under Electrochemical Water-Splitting Conditions

Zishan Wu, Ling Huang, Huan Liu and Hailiang Wang

ACS Catal., 2019, 9, 2956
DOI: 10.1021/acscatal.8b03835

Intramolecular Alkene Hydroamination with Hybrid Catalysts Consisting of a Metal Salt and a Neutral Organic Base

Philipp C. Stegner, Christian A. Fischer, D. Thao Nguyen, Andreas Rösch, Johanne Penafiel, Jens Langer, Michael Wiesinger and Sjoerd Harder

Eur J Inorg Chem, 2020, 2020, 3387
DOI: 10.1002/ejic.202000671

Nickel Complexes with Non‐innocent Ligands as Highly Active Electrocatalysts for Hydrogen Evolution

Zhixin Chen, Tao Wang, Tingting Sun, Zhiyong Chen, Tian Sheng, Yu‐Hao Hong, Zi‐Ang Nan, Jun Zhu, Zhi‐You Zhou, Haiping Xia and Shi‐Gang Sun

Chin. J. Chem., 2018, 36, 1161
DOI: 10.1002/cjoc.201800359

Eine Redoxpolymer‐basierte Gasdiffusions‐H2‐Oxidationsbioanode mit hoher Stromdichte unter Verwendung von [FeFe]‐Hydrogenase aus Desulfovibrio desulfuricans integriert in einer membranfreien Biobrennstoffzelle

Julian Szczesny, James A. Birrell, Felipe Conzuelo, Wolfgang Lubitz, Adrian Ruff and Wolfgang Schuhmann

Angewandte Chemie, 2020, 132, 16649
DOI: 10.1002/ange.202006824

Two‐Dimensional Polycyclic Photovoltaic Molecule with Low Trap Density for High‐Performance Photocatalytic Hydrogen Evolution

Zhenzhen Zhang, Wenqin Si, Baohua Wu, Wei Wang, Yawen Li, Wei Ma and Yuze Lin

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202114234

Precious metal-free approach to hydrogen electrocatalysis for energy conversion: From mechanism understanding to catalyst design

Tanyuan Wang, Huan Xie, Mengjie Chen, Alyssa D'Aloia, Jaephil Cho, Gang Wu and Qing Li

Nano Energy, 2017, 42, 69
DOI: 10.1016/j.nanoen.2017.10.045

Structural Engineering of Electrocatalysts for the Hydrogen Evolution Reaction: Order or Disorder?

Junfeng Xie and Yi Xie

ChemCatChem, 2015, 7, 2568
DOI: 10.1002/cctc.201500396

Tuning of metallic valence in CoMoP for promoting electrocatalytic hydrogen evolution

Dan Li, Dongyu Liu, Shuang Zhao, Shiyao Lu, Yaming Ma, Mingtao Li, Guangbo Chen, Yuankun Wang, Guoqing Zhou and Chunhui Xiao

International Journal of Hydrogen Energy, 2019, 44, 31072
DOI: 10.1016/j.ijhydene.2019.10.016

Electrochemistry, electrocatalysis, and mechanistic details into hydrogen evolution pathways of hexacoordinated iron scaffolds in hydrogenase mimics

Ibukun Oluwaseun Shotonwa, Onome Ejeromedoghene, Adedoyin Oluseyi Adesoji, Yakubu Adekunle Alli, Caroline Akinremi and Sheriff Adewuyi

Journal of Electroanalytical Chemistry, 2023, 938, 117446
DOI: 10.1016/j.jelechem.2023.117446

Highly Active Cobalt Sulfide/Carbon Nanotube Catalyst for Hydrogen Evolution at Soft Interfaces

Emre Aslan, Ilker Akin and Imren Hatay Patir

Chemistry A European J, 2016, 22, 5342
DOI: 10.1002/chem.201505048

Nickel complexes as molecular catalysts for water splitting and CO2 reduction

Jia-Wei Wang, Wen-Ju Liu, Di-Chang Zhong and Tong-Bu Lu

Coordination Chemistry Reviews, 2019, 378, 237
DOI: 10.1016/j.ccr.2017.12.009

Breaking the Correlation between Energy Costs and Kinetic Barriers in Hydrogen Evolution via a Cobalt Pyridine-Diimine-Dioxime Catalyst

Pengfei Huo, Christopher Uyeda, Jason D. Goodpaster, Jonas C. Peters and Thomas F. Miller

ACS Catal., 2016, 6, 6114
DOI: 10.1021/acscatal.6b01387

The striking influence of oxophilicity differences in heterometallic Mo–Mn oxide cluster reactions with water

Jarrett L. Mason, Ankur K. Gupta, Abbey J. McMahon, Carley N. Folluo, Krishnan Raghavachari and Caroline Chick Jarrold

The Journal of Chemical Physics, 2020, 152
DOI: 10.1063/1.5142398

Fuel from Water: The Photochemical Generation of Hydrogen from Water

Zhiji Han and Richard Eisenberg

Acc. Chem. Res., 2014, 47, 2537
DOI: 10.1021/ar5001605

Synthesis and studies of a molecular copper(I)-triazenido electrocatalyst for catalyzing hydrogen evolution from acetic acid and water

Ting Fang, Ling-Ling Zhou, Ling-Zhi Fu, Shu-Zhong Zhan and Qi-Ying Lv

Polyhedron, 2015, 85, 355
DOI: 10.1016/j.poly.2014.08.030

Iron incorporation affecting the structure and boosting catalytic activity of Cox-Fey-P for efficient hydrogen evolution

Man Li, Leiming Tao, Xin Xiao, Xingxing Jiang, Mingkui Wang and Yan Shen

Applied Surface Science, 2019, 478, 103
DOI: 10.1016/j.apsusc.2019.01.199

Thiolate-Bridged Dinuclear Ruthenium and Iron Complexes as Robust and Efficient Catalysts toward Oxidation of Molecular Dihydrogen in Protic Solvents

Masahiro Yuki, Ken Sakata, Yoshifumi Hirao, Nobuaki Nonoyama, Kazunari Nakajima and Yoshiaki Nishibayashi

J. Am. Chem. Soc., 2015, 137, 4173
DOI: 10.1021/jacs.5b00584

Iron(II) clathrochelates as electrocatalysts of hydrogen evolution reaction at low pH

A.V. Dolganov, O.V. Tarasova, A.Y. Ivleva, O.Y. Chernyaeva, K.A. Grigoryan and V.S. Ganz

International Journal of Hydrogen Energy, 2017, 42, 27084
DOI: 10.1016/j.ijhydene.2017.09.080

Microbial electrolysis cell (MEC): Strengths, weaknesses and research needs from electrochemical engineering standpoint

Raphaël Rousseau, Luc Etcheverry, Emma Roubaud, Régine Basséguy, Marie-Line Délia and Alain Bergel

Applied Energy, 2020, 257, 113938
DOI: 10.1016/j.apenergy.2019.113938

Chemoselective Electrochemical Hydrogenation of Ketones and Aldehydes with a Well‐Defined Base‐Metal Catalyst

Igor Fokin and Inke Siewert

Chemistry A European J, 2020, 26, 14137
DOI: 10.1002/chem.202002075

Synthesis and properties of a molybdenum Schiff base electrocatalyst for generating hydrogen from acetic acid

Jie-Ping Cao, Jia-Xing Zhao, Hai-Xia Lu and Shu-Zhong Zhan

Transition Met Chem, 2014, 39, 933
DOI: 10.1007/s11243-014-9878-x

Electrocatalytic Hydrogen Production with a Molecular Cobalt Complex in Aqueous Solution

Mona Wilken and Inke Siewert

ChemElectroChem, 2020, 7, 217
DOI: 10.1002/celc.201901913

From Monolayers to Nanotubes: Toward Catalytic Transition-Metal Dichalcogenides for Hydrogen Evolution Reaction

Günther Luft Cardoso, Paulo Cesar Piquini and Rajeev Ahuja

Energy Fuels, 2021, 35, 6282
DOI: 10.1021/acs.energyfuels.1c00462

Photoelectrochemical Hydrogen Production in Alkaline Solutions Using Cu2O Coated with Earth‐Abundant Hydrogen Evolution Catalysts

Carlos G. Morales‐Guio, Laurent Liardet, Matthew T. Mayer, S. David Tilley, Michael Grätzel and Xile Hu

Angewandte Chemie, 2015, 127, 674
DOI: 10.1002/ange.201410569

A Poly(cobaloxime)/Carbon Nanotube Electrode: Freestanding Buckypaper with Polymer‐Enhanced H2‐Evolution Performance

Bertrand Reuillard, Julien Warnan, Jane J. Leung, David W. Wakerley and Erwin Reisner

Angewandte Chemie, 2016, 128, 4020
DOI: 10.1002/ange.201511378

Photocatalytic Hydrogen Evolution Driven by [FeFe] Hydrogenase Models Tethered to Fluorene and Silafluorene Sensitizers

Roman Goy, Luca Bertini, Tobias Rudolph, Shu Lin, Martin Schulz, Giuseppe Zampella, Benjamin Dietzek, Felix H. Schacher, Luca De Gioia, Ken Sakai and Wolfgang Weigand

Chemistry A European J, 2017, 23, 334
DOI: 10.1002/chem.201603140

RETRACTED: Metallic Conductivity in a Two-Dimensional Cobalt Dithiolene Metal–Organic Framework

Andrew J. Clough, Jonathan M. Skelton, Courtney A. Downes, Ashley A. de la Rosa, Joseph W. Yoo, Aron Walsh, Brent C. Melot and Smaranda C. Marinescu

J. Am. Chem. Soc., 2017, 139, 10863
DOI: 10.1021/jacs.7b05742

Manganese-Based Molecular Electrocatalysts for Oxidation of Hydrogen

Elliott B. Hulley, Neeraj Kumar, Simone Raugei and R. Morris Bullock

ACS Catal., 2015, 5, 6838
DOI: 10.1021/acscatal.5b01751

Scanning Electrochemical Cell Microscopy Investigation of Single ZIF‐Derived Nanocomposite Particles as Electrocatalysts for Oxygen Evolution in Alkaline Media

Tsvetan Tarnev, Harshitha Barike Aiyappa, Alexander Botz, Thomas Erichsen, Andrzej Ernst, Corina Andronescu and Wolfgang Schuhmann

Angew Chem Int Ed, 2019, 58, 14265
DOI: 10.1002/anie.201908021

Mechanistic study on nickel-molybdenum based electrocatalysts for the hydrogen evolution reaction

Yongfang Zhou, Tingting Lin, Xuanli Luo, Zhibin Yan, Jin Wu, Jianshe Wang and Yi Shen

Journal of Catalysis, 2020, 388, 122
DOI: 10.1016/j.jcat.2020.05.011

RETRACTED: A new hyperbranched water-splitting technique based on Co3O4/MoS2 nano composite catalyst for High-Performance of hydrogen evolution reaction

Abdul Qayoom Mugheri, Muhammad Rafique Daudpoto, Ali Asghar Sangah, Nasrullah Mugheri, Zeinhom M. El-Bahy and Yaser A. El-Badry

International Journal of Hydrogen Energy, 2022, 47, 2124
DOI: 10.1016/j.ijhydene.2021.10.173

Nanoporous Metals Based on Metallic Glasses: Synthesis, Structure and Functional Applications

Jing Wang, Zhibin Li, Rui Li, Hui Wang, Yuan Wu, Xiongjun Liu and Zhaoping Lu

Acta Metall. Sin. (Engl. Lett.), 2023, 36, 1573
DOI: 10.1007/s40195-023-01597-6

Facile one-step electrodeposition preparation of porous NiMo film as electrocatalyst for hydrogen evolution reaction

Mingyong Wang, Zhi Wang, Xiangtao Yu and Zhancheng Guo

International Journal of Hydrogen Energy, 2015, 40, 2173
DOI: 10.1016/j.ijhydene.2014.12.022

Intercepting Hydrogen Evolution with Hydrogen-Atom Transfer: Electron-Initiated Hydrofunctionalization of Alkenes

Xiangyu Wu, Cara N. Gannett, Jinjian Liu, Rui Zeng, Luiz F. T. Novaes, Hongsen Wang, Héctor D. Abruña and Song Lin

J. Am. Chem. Soc., 2022, 144, 17783
DOI: 10.1021/jacs.2c08278

[FeFe]‐Hydrogenase Mimetic Metallopolymers with Enhanced Catalytic Activity for Hydrogen Production in Water

William P. Brezinski, Metin Karayilan, Kayla E. Clary, Nicholas G. Pavlopoulos, Sipei Li, Liye Fu, Krzysztof Matyjaszewski, Dennis H. Evans, Richard S. Glass, Dennis L. Lichtenberger and Jeffrey Pyun

Angew Chem Int Ed, 2018, 57, 11898
DOI: 10.1002/anie.201804661

Structure and Thermodynamic Hydricity in Cobalt(triphosphine)(monophosphine) Hydrides

Makenzie A. Kuehn, William Fernandez and Christopher M. Zall

Inorg. Chem., 2023, 62, 8505
DOI: 10.1021/acs.inorgchem.2c04124

Hydrogen Evolution by Ni2P Catalysts Derived from Phosphine MOFs

Oluwaniyi Mabayoje, Samuel G. Dunning, Kenta Kawashima, Bryan R. Wygant, Ryan A. Ciufo, Simon M. Humphrey and C. Buddie Mullins

ACS Appl. Energy Mater., 2020, 3, 176
DOI: 10.1021/acsaem.9b02109

Efficient Mn‐Ni‐Co nanocomposite–based electrocatalyst for oxygen evolution reaction in alkaline media

Abdul Qayoom Mugheri, Ali Asghar Sangah, Aijaz Ali otho, Shahzad Ahmed Memon, Khaled H. Mahmoud and Zeinhom M. El‐Bahy

J Chinese Chemical Soc, 2021, 68, 2254
DOI: 10.1002/jccs.202100386

A Cyanide-Based Coordination Polymer for Hydrogen Evolution Electrocatalysis

Elif Pınar Alsaç, Emine Ulker, Satya Vijaya Kumar Nune and Ferdi Karadas

Catal Lett, 2018, 148, 531
DOI: 10.1007/s10562-017-2271-6

Enhanced electrocatalytic methanol oxidation to formate on iron-substituted nickel oxide

Ning Jian, Yi Ma, Huan Ge, Jialing Tang, Jing Yu, Jordi Arbiol, Jiwei Hu, Yun Ke, Chaochao Li, Andreu Cabot and Junshan Li

Journal of Colloid and Interface Science, 2026, 710, 140014
DOI: 10.1016/j.jcis.2026.140014

Enhancing the Performance of Ni-Mo Alkaline Hydrogen Evolution Electrocatalysts with Carbon Supports

Rituja B. Patil, Aayush Mantri, Stephen D. House, Judith C. Yang and James R. McKone

ACS Appl. Energy Mater., 2019, 2, 2524
DOI: 10.1021/acsaem.8b02087

Nanostructured materials for water splitting - state of the art and future needs: A mini-review

Shuai Chen, Sapanbir S. Thind and Aicheng Chen

Electrochemistry Communications, 2016, 63, 10
DOI: 10.1016/j.elecom.2015.12.003

MoS2/Ti3C2 heterostructure for efficient visible-light photocatalytic hydrogen generation

Juhui Zhang, Chao Xing and Feng Shi

International Journal of Hydrogen Energy, 2020, 45, 6291
DOI: 10.1016/j.ijhydene.2019.12.109

Hydrogen Evolution Electrocatalysis with a Molecular Cobalt Bis(alkylimidazole)methane Complex in DMF: a Critical Activity Analysis

Sander D. de Vos, Maartje Otten, Tim Wissink, Daniël L. J. Broere, Emiel J. M. Hensen and Robertus J. M. Klein Gebbink

ChemSusChem, 2022, 15
DOI: 10.1002/cssc.202201308

Structural and Electronic Influences on Rates of Tertpyridine−Amine CoIII−H Formation During Catalytic H2 Evolution in an Aqueous Environment

Brian N. DiMarco, Dmitry E. Polyansky, David C. Grills, Ping Wang, Yutaka Kuwahara, Xuan Zhao and Etsuko Fujita

ChemPhysChem, 2021, 22, 1478
DOI: 10.1002/cphc.202100295

Carbon supported Ni3N/Ni heterostructure for hydrogen evolution reaction in both acid and alkaline media

Dhandapani Balaji, Jagannathan Madhavan, Mohamad S. AlSalhi, Mamduh J. Aljaafreh, Saradh Prasad and Pau Loke Show

International Journal of Hydrogen Energy, 2021, 46, 30739
DOI: 10.1016/j.ijhydene.2021.06.197

Merging Halogen-Atom Transfer (XAT) and Cobalt Catalysis to Override E2-Selectivity in the Elimination of Alkyl Halides: A Mild Route toward contra-Thermodynamic Olefins

Huaibo Zhao, Alastair J. McMillan, Timothée Constantin, Rory C. Mykura, Fabio Juliá and Daniele Leonori

J. Am. Chem. Soc., 2021, 143, 14806
DOI: 10.1021/jacs.1c06768

Introducing Water‐Network‐Assisted Proton Transfer for Boosted Electrocatalytic Hydrogen Evolution with Cobalt Corrole

Xialiang Li, Bin Lv, Xue‐Peng Zhang, Xiaotong Jin, Kai Guo, Dexia Zhou, Hongtao Bian, Wei Zhang, Ulf‐Peter Apfel and Rui Cao

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202114310

Understanding the Hydrogen Evolution Reaction Kinetics of Electrodeposited Nickel‐Molybdenum in Acidic, Near‐Neutral, and Alkaline Conditions

Fuxi Bao, Erno Kemppainen, Iris Dorbandt, Radu Bors, Fanxing Xi, Rutger Schlatmann, Roel van de Krol and Sonya Calnan

ChemElectroChem, 2021, 8, 195
DOI: 10.1002/celc.202001436

Defect-Induced Epitaxial Growth for Efficient Solar Hydrogen Production

Kan Zhang, Jung Kyu Kim, Bumsu Park, Shifeng Qian, Bingjun Jin, Xiaowei Sheng, Haibo Zeng, Hyunjung Shin, Sang Ho Oh, Chang-Lyoul Lee and Jong Hyeok Park

Nano Lett., 2017, 17, 6676
DOI: 10.1021/acs.nanolett.7b02622

RETRACTED: Meritorious spatially on hierarchically Co3O4/MoS2 phase nanocomposite synergistically a high-efficient electrocatalyst for hydrogen evolution reaction performance: Recent advances & future perspectives

Abdul Qayoom Mugheri, Aijaz Ali Otho and Arslan Ahmed Mugheri

International Journal of Hydrogen Energy, 2021, 46, 22707
DOI: 10.1016/j.ijhydene.2021.04.122

Exploring the Multifarious Role of the Ligand in Electrocatalytic Hydrogen Evolution Reaction Pathways

Pankaj Kumar, Vyom Prakash Tyagi and Munmun Ghosh

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202302195

A Poly(cobaloxime)/Carbon Nanotube Electrode: Freestanding Buckypaper with Polymer‐Enhanced H2‐Evolution Performance

Bertrand Reuillard, Julien Warnan, Jane J. Leung, David W. Wakerley and Erwin Reisner

Angew Chem Int Ed, 2016, 55, 3952
DOI: 10.1002/anie.201511378

Single-Step Electrodeposited Molybdenum Incorporated Nickel Sulfide Thin Films from Low-Cost Precursors as Highly Efficient Hydrogen Evolution Electrocatalysts in Acid Medium

Arun Prasad Murthy, Jayaraman Theerthagiri, Kumar Premnath, Jagannathan Madhavan and Kadarkarai Murugan

J. Phys. Chem. C, 2017, 121, 11108
DOI: 10.1021/acs.jpcc.7b02088

Co-Te-Se Nano-Compounds as Electrocatalysts for Hydrogen Evolution Reaction

Yanping Tian, Zhonghui Zhang and Yuqing Miao

J. Electrochem. Soc., 2016, 163, H625
DOI: 10.1149/2.0251608jes

X-ray Crystallographic, Multifrequency Electron Paramagnetic Resonance, and Density Functional Theory Characterization of the Ni(PCy2NtBu2)2n+Hydrogen Oxidation Catalyst in the Ni(I) Oxidation State

Jens Niklas, Mark Westwood, Kristy L. Mardis, Tiara L. Brown, Anthony M. Pitts-McCoy, Michael D. Hopkins and Oleg G. Poluektov

Inorg. Chem., 2015, 54, 6226
DOI: 10.1021/acs.inorgchem.5b00445

Efficient hydrogen production on MoNi4 electrocatalysts with fast water dissociation kinetics

Jian Zhang, Tao Wang, Pan Liu, Zhongquan Liao, Shaohua Liu, Xiaodong Zhuang, Mingwei Chen, Ehrenfried Zschech and Xinliang Feng

Nat Commun, 2017, 8
DOI: 10.1038/ncomms15437

Excellent Properties of Ni-15 wt.% W Alloy Electrodeposited from a Low-Temperature Pyrophosphate System

Changwei Su, Zhaoyao Sa, Yangyang Liu, Linfu Zhao, Fengjing Wu and Wei Bai

Coatings, 2021, 11, 1262
DOI: 10.3390/coatings11101262

Two‐Dimensional Polycyclic Photovoltaic Molecule with Low Trap Density for High‐Performance Photocatalytic Hydrogen Evolution

Zhenzhen Zhang, Wenqin Si, Baohua Wu, Wei Wang, Yawen Li, Wei Ma and Yuze Lin

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202114234

Ternary Platinum–Copper–Nickel Nanoparticles Anchored to Hierarchical Carbon Supports as Free-Standing Hydrogen Evolution Electrodes

Yi Shen, Aik Chong Lua, Jingyu Xi and Xinping Qiu

ACS Appl. Mater. Interfaces, 2016, 8, 3464
DOI: 10.1021/acsami.5b11966

Unraveling the Mechanism of the Zn-Improved Catalytic Activity of Pd-Based Catalysts for Water–Gas Shift Reaction

Jinhui Hu, Wenyue Guo, Zong-Huai Liu, Xiaoqing Lu, Houyu Zhu, Feng Shi, Junqing Yan and Ruibin Jiang

J. Phys. Chem. C, 2016, 120, 20181
DOI: 10.1021/acs.jpcc.6b07151

Electrochemical and photochemical-driven hydrogen evolution catalyzed by a dinuclear cobalt(II)–triazenido complex with high turnover number

Ling-Ling Zhou, Ling-Zhi Fu, Ling-Zhi Tang, Yun-Xiao Zhang and Shu-Zhong Zhan

International Journal of Hydrogen Energy, 2015, 40, 5099
DOI: 10.1016/j.ijhydene.2015.02.072

Electronic Structure of Molecular Cobalt Catalysts for H2 Production Revealed by Multifrequency EPR

Jens Niklas, Lars Kohler, Andrea M. Potocny, Kristy L. Mardis, Karen L. Mulfort and Oleg G. Poluektov

J. Phys. Chem. C, 2022, 126, 11889
DOI: 10.1021/acs.jpcc.2c02576

Potential Induced Protonation of the Second Coordination Sphere in a Hangman-type Iron Porphyrin Complex Promotes HER: Insights via in Situ Raman Spectroelectrochemistry

Anthony R. Ramuglia, Markus Göbel, Vishal Budhija, Matthias Werheid, Khoa H. Ly, Matthias Schwalbe and Inez M. Weidinger

Inorg. Chem., 2023, 62, 10232
DOI: 10.1021/acs.inorgchem.3c00946

Structure–Activity and Stability Relationships for Cobalt Polypyridyl‐Based Hydrogen‐Evolving Catalysts in Water

Stephan Schnidrig, Cyril Bachmann, Peter Müller, Nicola Weder, Bernhard Spingler, Evelyne Joliat‐Wick, Mathias Mosberger, Johannes Windisch, Roger Alberto and Benjamin Probst

ChemSusChem, 2017, 10, 4570
DOI: 10.1002/cssc.201701511

A Comprehensive Review of Bimetallic Nanoparticle–Graphene Oxide and Bimetallic Nanoparticle–Metal–Organic Framework Nanocomposites as Photo-, Electro-, and Photoelectrocatalysts for Hydrogen Evolution Reaction

Mogwasha Dapheny Makhafola, Sheriff Aweda Balogun and Kwena Desmond Modibane

Energies, 2024, 17, 1646
DOI: 10.3390/en17071646

A Highly Active and Robust Copper-Based Electrocatalyst toward Hydrogen Evolution Reaction with Low Overpotential in Neutral Solution

Jialei Du, Jianying Wang, Lvlv Ji, Xiaoxiang Xu and Zuofeng Chen

ACS Appl. Mater. Interfaces, 2016, 8, 30205
DOI: 10.1021/acsami.6b09975

ChemInform Abstract: Earth‐Abundant Hydrogen Evolution Electrocatalysts

James R. McKone, Smaranda C. Marinescu, Bruce S. Brunschwig, Jay R. Winkler and Harry B. Gray

ChemInform, 2014, 45
DOI: 10.1002/chin.201415267

Chemically Exfoliated MoS2 Nanosheets as an Efficient Catalyst for Reduction Reactions in the Aqueous Phase

Laura Guardia, Juan I. Paredes, José M. Munuera, Silvia Villar-Rodil, Miguel Ayán-Varela, Amelia Martínez-Alonso and Juan M. D. Tascón

ACS Appl. Mater. Interfaces, 2014, 6, 21702
DOI: 10.1021/am506922q

Proton Relay in Iron Porphyrins for Hydrogen Evolution Reaction

Sarmistha Bhunia, Atanu Rana, Shabnam Hematian, Kenneth D. Karlin and Abhishek Dey

Inorg. Chem., 2021, 60, 13876
DOI: 10.1021/acs.inorgchem.1c01079

H2 Evolution from a Thiolate-Bound Ni(III) Hydride

Nina X. Gu, Paul H. Oyala and Jonas C. Peters

J. Am. Chem. Soc., 2020, 142, 7827
DOI: 10.1021/jacs.0c00712

Co2N/Co2Mo3O8 Heterostructure as a Highly Active Electrocatalyst for an Alkaline Hydrogen Evolution Reaction

Wenjun Hu, Qing Shi, Zhengjun Chen, Hui Yin, Huafu Zhong and Ping Wang

ACS Appl. Mater. Interfaces, 2021, 13, 8337
DOI: 10.1021/acsami.0c20271

Ligand-Centered Photocatalytic Hydrogen Production in an Axially Capped Rh2(II,II) Paddlewheel Complex with Red Light

Matthew T. Fortunato, Curtis E. Moore and Claudia Turro

J. Am. Chem. Soc., 2023, 145, 27348
DOI: 10.1021/jacs.3c07532

Screening of electrocatalysts for hydrogen evolution reaction using bipolar electrodes fabricated by composition gradient magnetron sputtering

Vitalii Latyshev, Serhii Vorobiov, Oleg Shylenko and Vladimir Komanicky

Journal of Electroanalytical Chemistry, 2019, 854, 113562
DOI: 10.1016/j.jelechem.2019.113562

Nickel Phosphide Electrocatalysts for Hydrogen Evolution Reaction

Cun Hu, Chao Lv, Shuai Liu, Yan Shi, Jiangfeng Song, Zhi Zhang, Jinguang Cai and Akira Watanabe

Catalysts, 2020, 10, 188
DOI: 10.3390/catal10020188

Intermetallic Cu 5 Zr Clusters Anchored on Hierarchical Nanoporous Copper as Efficient Catalysts for Hydrogen Evolution Reaction

Hang Shi, Yi-Tong Zhou, Rui-Qi Yao, Wu-Bin Wan, Qing-Hua Zhang, Lin Gu, Zi Wen, Xing-You Lang and Qing Jiang

Research, 2020, 2020
DOI: 10.34133/2020/2987234

Electrochemical and photochemical-driven hydrogen evolution catalyzed by a dinuclear CoII–CoII complex

Ling-Zhi Fu, Ling-Ling Zhou, Ling-Zhi Tang, Yun-Xiao Zhang and Shu-Zhong Zhan

Journal of Power Sources, 2015, 280, 453
DOI: 10.1016/j.jpowsour.2015.01.121

Porous Molybdenum Carbide Nanostructures Synthesized on Carbon Cloth by CVD for Efficient Hydrogen Production

Mengci He, Hongyan Shi, Peng Wang, Xiudong Sun and Bo Gao

Chemistry A European J, 2019, 25, 16106
DOI: 10.1002/chem.201904100

Computational Characterization of Redox Non-Innocence in Cobalt-Bis(Diaryldithiolene)-Catalyzed Proton Reduction

Julien A. Panetier, Christopher S. Letko, T. Don Tilley and Martin Head-Gordon

J. Chem. Theory Comput., 2016, 12, 223
DOI: 10.1021/acs.jctc.5b00968

Lamellar structured CoSe 2 nanosheets directly arrayed on Ti plate as an efficient electrochemical catalyst for hydrogen evolution

Huaqing Xiao, Shutao Wang, Cong Wang, Yanyu Li, Hongrong Zhang, Zhaojie Wang, Yan Zhou, Changhua An and Jun Zhang

Electrochimica Acta, 2016, 217, 156
DOI: 10.1016/j.electacta.2016.09.043

Thermal and photocatalytic production of hydrogen with earth-abundant metal complexes

Shunichi Fukuzumi, Yong-Min Lee and Wonwoo Nam

Coordination Chemistry Reviews, 2018, 355, 54
DOI: 10.1016/j.ccr.2017.07.014

Efficient overall water splitting using nickel boride-based electrocatalysts

Jie Lao, Dong Li, Chunli Jiang, Rong Luo, Hui Peng, Ruijuan Qi, Hechun Lin, Rong Huang, Geoffrey I.N. Waterhouse and Chunhua Luo

International Journal of Hydrogen Energy, 2020, 45, 28616
DOI: 10.1016/j.ijhydene.2020.07.171

Precious Metal Free Hydrogen Evolution Catalyst Design and Application

Anders A. Feidenhans’l, Yagya N. Regmi, Chao Wei, Dong Xia, Jakob Kibsgaard and Laurie A. King

Chem. Rev., 2024, 124, 5617
DOI: 10.1021/acs.chemrev.3c00712

Stereochemical Tailoring of Nickel‐based Electrocatalysts for Hydrogen Evolution Reaction

Michael Papadakis, Jana Mehrez, Iris Wehrung, Léa Delmotte, Michel Giorgi, Renaud Hardré and Maylis Orio

ChemCatChem, 2024, 16
DOI: 10.1002/cctc.202400426

Polyethyleneimine-bound [FeFe]-hydrogenase mimics as bioinspired diiron electrocatalysts for hydrogen evolution reaction

Pei-Hua Zhao, Zhen Guo, Yu-Long Sun, Yan-Nan Liu, Xing-Bin Jing and Li Guo

Electrochimica Acta, 2026, 549, 148024
DOI: 10.1016/j.electacta.2025.148024

Single-Metal Atoms Supported on MBenes for Robust Electrochemical Hydrogen Evolution

Bing Li, Yang Wu, Neng Li, Xingzhu Chen, Xianbing Zeng, Arramel, Xiujian Zhao and Jizhou Jiang

ACS Appl. Mater. Interfaces, 2020, 12, 9261
DOI: 10.1021/acsami.9b20552

Redox and Acid–Base Properties of Binuclear 4‐Terphenyldithiophenolate Complexes of Nickel

Felix Koch, Andreas Berkefeld, Hartmut Schubert and Claudius Grauer

Chemistry A European J, 2016, 22, 14640
DOI: 10.1002/chem.201603060

Synthesizing Nanoparticles of Co-P-Se compounds as Electrocatalysts for the Hydrogen Evolution Reaction

Mingshu Xiao, Yuqing Miao, Yanping Tian and Yuhua Yan

Electrochimica Acta, 2015, 165, 206
DOI: 10.1016/j.electacta.2015.03.023

Conductive MOFs based on Thiol-functionalized Linkers: Challenges, Opportunities, and Recent Advances

Xiangling Deng, Sai-Li Zheng, Yuan-Hui Zhong, Jieying Hu, Lai-Hon Chung and Jun He

Coordination Chemistry Reviews, 2022, 450, 214235
DOI: 10.1016/j.ccr.2021.214235

Hydrogen Bond‐Assisted PCET and Formation of WIII─OH in Bis(Dithiolene) Complex

Wonjung Lee, Daeyong Um, Yujin Baek, Sugyeong Hong, Youngseob Lee, Jaeheon Lee, Jin Kim, Sun Hee Kim, Kyung‐Bin Cho and Junhyeok Seo

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202506861

Proton reduction using cobalt glyoximes with isothiocyanate and aniline axial ligands

Wai Yip Fan, Zi Bin Tan and Jingzhi Iris Koh

Polyhedron, 2015, 96, 38
DOI: 10.1016/j.poly.2015.04.030

A Smorgasbord of Carbon: Electrochemical Analysis of Cobalt–Bis(benzenedithiolate) Complex Adsorption and Electrocatalytic Activity on Diverse Graphitic Supports

Shawn C. Eady, Molly M. MacInnes and Nicolai Lehnert

ACS Appl. Mater. Interfaces, 2016, 8, 23624
DOI: 10.1021/acsami.6b05159

Constructing Ni-VN interfaces with superior electrocatalytic activity for alkaline hydrogen evolution reaction

Jiao Yang, Lishan Peng, Na Yang, Lianqiao Tan, Fangzheng Wang, Xinran Shen, Qingfei Liu and Zidong Wei

Journal of Colloid and Interface Science, 2022, 626, 486
DOI: 10.1016/j.jcis.2022.06.087

Bio-Inspired histidine-based copper complex: An efficient and robust electrocatalyst for electrochemical hydrogen evolution

Heba Emam, Rashid Al Hajri, Nazir Ahmad, Fatma M. Elantabli, M. El-Rabiei, Abdelwahab Hassan, Mohammed Al Abri and Hussein A. Younus

International Journal of Hydrogen Energy, 2025, 137, 976
DOI: 10.1016/j.ijhydene.2024.07.386

Ultrathin MoS2-coated carbon nanospheres as highly efficient electrocatalyts for hydrogen evolution reaction

Wen-Hui Hu, Guan-Qun Han, Yan-Ru Liu, Bin Dong, Yong-Ming Chai, Yun-Qi Liu and Chen-Guang Liu

International Journal of Hydrogen Energy, 2015, 40, 6552
DOI: 10.1016/j.ijhydene.2015.03.150

4, 4′-Bipyridine as a molecular catalyst for electrochemical hydrogen production

Taro Uchida, Yoichi Sasaki, Tamio Ikeshoji and Masatoshi Osawa

Electrochimica Acta, 2017, 248, 585
DOI: 10.1016/j.electacta.2017.07.101

A molecular iron(III) electrocatalyst supported by amine-bis(phenolate) ligand for water reduction

Ling-Zhi Fu, Ling-Ling Zhou, Ling-Zhi Tang, Yun-Xiao Zhang and Shu-Zhong Zhan

International Journal of Hydrogen Energy, 2015, 40, 8688
DOI: 10.1016/j.ijhydene.2015.05.026

Co–Fe–Se ultrathin nanosheet-fabricated microspheres for efficient electrocatalysis of hydrogen evolution

Mingshu Xiao, Zhonghui Zhang, Yanping Tian, Yuqing Miao and Jiahai Wang

J Appl Electrochem, 2017, 47, 361
DOI: 10.1007/s10800-016-1014-5

H2 Evolution from Electrocatalysts with Redox-Active Ligands: Mechanistic Insights from Theory and Experiment vis-à-vis Co-Mabiq

G. Ceren Tok, Sebastian Reiter, Anna T. S. Freiberg, Leonhard Reinschlüssel, Hubert A. Gasteiger, Regina de Vivie-Riedle and Corinna R. Hess

Inorg. Chem., 2021, 60, 13888
DOI: 10.1021/acs.inorgchem.1c01157

Operando Spectroscopic Analysis of CoP Films Electrocatalyzing the Hydrogen-Evolution Reaction

Fadl H. Saadi, Azhar I. Carim, Walter S. Drisdell, Sheraz Gul, Jack H. Baricuatro, Junko Yano, Manuel P. Soriaga and Nathan S. Lewis

J. Am. Chem. Soc., 2017, 139, 12927
DOI: 10.1021/jacs.7b07606

Synthesis, Isomerization and Electrocatalytic Properties of Thiolate‐Bridged Dicobalt Hydride Complexes with Different Substituents

Chunlong Wang, Jianzhe Li, Dawei Yang, Peng Tong, Puhua Sun, Baomin Wang and Jingping Qu

Eur J Inorg Chem, 2020, 2020, 2757
DOI: 10.1002/ejic.202000369

Proton Reduction by Amino Acid‐Based Iron Complexes: Impact of Proton Residue Concentration at Catalyst Sites

Srijit Sen, Pankaj Kumar, Santanu Pattanayak, Chandan Das, Arnab Dutta and Munmun Ghosh

Chemistry An Asian Journal, 2025, 20
DOI: 10.1002/asia.202500827

A 3D Nanoporous Ni–Mo Electrocatalyst with Negligible Overpotential for Alkaline Hydrogen Evolution

Yuhang Wang, Guoxin Zhang, Wenwen Xu, Pengbo Wan, Zhiyi Lu, Yaping Li and Xiaoming Sun

ChemElectroChem, 2014, 1, 1138
DOI: 10.1002/celc.201402089

Benchmarking Hydrogen Evolving Reaction and Oxygen Evolving Reaction Electrocatalysts for Solar Water Splitting Devices

Charles C. L. McCrory, Suho Jung, Ivonne M. Ferrer, Shawn M. Chatman, Jonas C. Peters and Thomas F. Jaramillo

J. Am. Chem. Soc., 2015, 137, 4347
DOI: 10.1021/ja510442p

One-step synthesis of Ni3S2 nanowires at low temperature as efficient electrocatalyst for hydrogen evolution reaction

Junjie Li, Pei Kang Shen and Zhiqun Tian

International Journal of Hydrogen Energy, 2017, 42, 7136
DOI: 10.1016/j.ijhydene.2016.03.068

Current progress and challenges in engineering viable artificial leaf for solar water splitting

Phuc D. Nguyen, Tuan M. Duong and Phong D. Tran

Journal of Science: Advanced Materials and Devices, 2017, 2, 399
DOI: 10.1016/j.jsamd.2017.08.006

Bacteriorhodopsin/Ag Nanoparticle-Based Hybrid Nano-Bio Electrocatalyst for Efficient and Robust H2 Evolution from Water

Zhenlu Zhao, Ping Wang, Xiaolong Xu, Mordechai Sheves and Yongdong Jin

J. Am. Chem. Soc., 2015, 137, 2840
DOI: 10.1021/jacs.5b00200

Synthesis of binder-free hybrid Ni-Co-Se@NiS2 nanostructures as highly active and durable electrocatalyst for hydrogen evolution reaction in alkaline media and Seawater

Sina Jamali, Mohammad Abedini Mohammadi, Morteza Saghafi Yazdi, Mohammad Talafi Noghani, Amirhossein Moghanian, Mohammad Rezayat and Miguel Morales

Journal of Electroanalytical Chemistry, 2024, 969, 118527
DOI: 10.1016/j.jelechem.2024.118527

Fluorination of porphyrin β-periphery boosts nickel(II)-catalyzed hydrogen evolution reaction

Haozong Xue, Zhuo-Yan Wu and Jun-Long Zhang

Journal of Inorganic Biochemistry, 2024, 254, 112516
DOI: 10.1016/j.jinorgbio.2024.112516

Semiconductor, molecular and hybrid systems for photoelectrochemical solar fuel production

Rosalba Passalacqua, Siglinda Perathoner and Gabriele Centi

Journal of Energy Chemistry, 2017, 26, 219
DOI: 10.1016/j.jechem.2017.03.004

High volume hydrogen evolution from KBH4 hydrolysis with palladium complex catalyst

Dilek Kilinc and Omer Sahin

Renewable Energy, 2020, 161, 257
DOI: 10.1016/j.renene.2020.06.035

Synthesis of Novel Heteroleptic Oxothiolate Ni(II) Complexes and Evaluation of Their Catalytic Activity for Hydrogen Evolution

Fotios Kamatsos, Kostas Bethanis and Christiana A. Mitsopoulou

Catalysts, 2021, 11, 401
DOI: 10.3390/catal11030401

A bioinspired cobalt catalyst based on a tripodal imidazole/pyridine platform capable of water reduction and oxidation

Krista M. Kulesa, Diego S. Padilha, Bishnu Thapa, Shivnath Mazumder, Yaroslav Losovyj, H. Bernhard Schlegel, Marciela Scarpellini and Cláudio N. Verani

Journal of Inorganic Biochemistry, 2023, 242, 112162
DOI: 10.1016/j.jinorgbio.2023.112162

Organic Photovoltaic Catalyst with Extended Exciton Diffusion for High-Performance Solar Hydrogen Evolution

Yufan Zhu, Zhenzhen Zhang, Wenqin Si, Qianlu Sun, Guilong Cai, Yawen Li, Yixiao Jia, Xinhui Lu, Weigao Xu, Shiming Zhang and Yuze Lin

J. Am. Chem. Soc., 2022, 144, 12747
DOI: 10.1021/jacs.2c03161

Hydrogen evolution catalyzed by a water-soluble cobalt(II) complex with picolinic acid ions

Ling-Zhi Fu, Ling-Zhi Tang, Yun-Xiao Zhang, Qian-Nan Liang, Chang Fang and Shu-Zhong Zhan

International Journal of Hydrogen Energy, 2016, 41, 249
DOI: 10.1016/j.ijhydene.2015.10.134

Semisynthetic and Biomolecular Hydrogen Evolution Catalysts

Banu Kandemir, Saikat Chakraborty, Yixing Guo and Kara L. Bren

Inorg. Chem., 2016, 55, 467
DOI: 10.1021/acs.inorgchem.5b02054

Neutral heteroleptic nickel complexes incorporating maleonitriledithiolate and bis(diphenylphosphanyl)amine as robust molecular electrocatalysts for hydrogen evolution

Wen-Yu Mou, Tao Li, Bin Xie, Dong-Liang Zhang, Chuan Lai, Cheng-Long Deng, Jia-Xi Cao, Xiao-Xue Bai and Xiao-Qiang Liu

Inorganica Chimica Acta, 2020, 507, 119587
DOI: 10.1016/j.ica.2020.119587

General Scheme for Oxidative Quenching of a Copper Bis‐Phenanthroline Photosensitizer for Light‐Driven Hydrogen Production

J. Windisch, M. Orazietti, P. Hamm, R. Alberto and B. Probst

ChemSusChem, 2016, 9, 1719
DOI: 10.1002/cssc.201600422

Hydrogen Evolution Reaction, Electrochemical CO2 Reduction, and Oxidative Photodegradation of Organic Dyes Catalyzed by Co(II) Trimethoxy-Meso-Arylporphyrin

Mouhieddinne Guergueb, Azhar Kechiche, Frédérique Loiseau, Florian Molton, Habib Nasri, Johannes Hohnsen and Axel Klein

Inorganics, 2022, 11, 6
DOI: 10.3390/inorganics11010006

Solar‐to‐Hydrogen Energy Conversion Based on Water Splitting

Jing Qi, Wei Zhang and Rui Cao

Advanced Energy Materials, 2018, 8
DOI: 10.1002/aenm.201701620

Synthesis, structure and electrocatalytic properties of a water‐soluble copper complex supported by 2‐ethyl‐2‐(2‐hydroxybenzylideneamino)propane‐1,3‐diol ligand

Dong Li, Ling‐Zhi Tang, Yan Liu and Shu‐Zhong Zhan

Applied Organom Chemis, 2017, 31
DOI: 10.1002/aoc.3797

A bis(thiosemicarbazonato)‐zinc complex, an electrocatalyst for hydrogen evolution and oxidation via ligand‐assisted metal‐centered reactivity

Juan Du, Hao Yang, Chun‐Li Wang and Shu‐Zhong Zhan

Applied Organom Chemis, 2022, 36
DOI: 10.1002/aoc.6572

Electrochemical Allene C─H Functionalization via Carbanion Sampling

Jiayi Feng, Yuhang Xia, Mingyu Shen, Junwei Wang, Weigang Fan, Sheng Zhang and Man‐Bo Li

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202508369

A Review of Phosphide‐Based Materials for Electrocatalytic Hydrogen Evolution

Peng Xiao, Wei Chen and Xin Wang

Advanced Energy Materials, 2015, 5
DOI: 10.1002/aenm.201500985

Importance of Ligand Exchange in the Modulation of Molecular Catalysis: Mechanism of the Electrochemical Reduction of Nitrous Oxide with Rhenium Bipyridyl Carbonyl Complexes

Rana Deeba, Sylvie Chardon-Noblat and Cyrille Costentin

ACS Catal., 2023, 13, 8262
DOI: 10.1021/acscatal.3c01495

Deciphering Electrocatalytic Hydrogen Production in Water Through a Bioinspired Water‐Stable Copper(II) Complex Adorned with (N2S2)‐Donor Sites

Sangharaj Diyali, Subhajit Saha, Nilankar Diyali, Avantika Bhattacharjee, Abhishek Mallick, Suraj Kumar Agrawalla, Chandra Shekhar Purohit and Bhaskar Biswas

ChemSusChem, 2025, 18
DOI: 10.1002/cssc.202401089

Ligand-Assisted Metal-Centered Electrocatalytic Hydrogen Evolution upon Reduction of a Bis(thiosemicarbazonato)Ni(II) Complex

Rahul Jain, Abdullah Al Mamun, Robert M. Buchanan, Pawel M. Kozlowski and Craig A. Grapperhaus

Inorg. Chem., 2018, 57, 13486
DOI: 10.1021/acs.inorgchem.8b02110

Direct Spectroscopic Detection of Key Intermediates and the Turnover Process in Catalytic H2 Formation by a Biomimetic Diiron Catalyst

Shihuai Wang, Sonja Pullen, Valentin Weippert, Tianfei Liu, Sascha Ott, Reiner Lomoth and Leif Hammarström

Chemistry A European J, 2019, 25, 11135
DOI: 10.1002/chem.201902100

MoS2 Nanosheets Supported on 3D Graphene Aerogel as a Highly Efficient Catalyst for Hydrogen Evolution

Yufei Zhao, Xiuqiang Xie, Jinqiang Zhang, Hao Liu, Hyo‐Jun Ahn, Kening Sun and Guoxiu Wang

Chemistry A European J, 2015, 21, 15908
DOI: 10.1002/chem.201501964

[FeFe]‐Hydrogenase Mimetic Metallopolymers with Enhanced Catalytic Activity for Hydrogen Production in Water

William P. Brezinski, Metin Karayilan, Kayla E. Clary, Nicholas G. Pavlopoulos, Sipei Li, Liye Fu, Krzysztof Matyjaszewski, Dennis H. Evans, Richard S. Glass, Dennis L. Lichtenberger and Jeffrey Pyun

Angewandte Chemie, 2018, 130, 12074
DOI: 10.1002/ange.201804661

Enzyme-Inspired Synthetic Proton Relays Generate Fast and Acid-Stable Cobalt-Based H2 Production Electrocatalysts

Dependu Dolui, Shikha Khandelwal, Althaf Shaik, Deepika Gaat, Vijay Thiruvenkatam and Arnab Dutta

ACS Catal., 2019, 9, 10115
DOI: 10.1021/acscatal.9b02953

Porous Ni3Si intermetallics as electrocatalysts for hydrogen evolution reaction

Liang Wu, Li Li, Hui Wang, Xinya Mo, Haihong Zhang, Qiankun Zhang, Yifeng Xiao, Jiangang Kang and Yuehui He

International Journal of Hydrogen Energy, 2024, 51, 806
DOI: 10.1016/j.ijhydene.2023.08.354

Elucidating Surface Restructuring-Induced Catalytic Reactivity of Cobalt Phosphide Nanoparticles under Electrochemical Conditions

Zishan Wu, Quan Gan, Xiaolin Li, Yiren Zhong and Hailiang Wang

J. Phys. Chem. C, 2018, 122, 2848
DOI: 10.1021/acs.jpcc.7b11843

Facile electrodeposition of ternary Ni-Fe-Co alloy nanostructure as a binder free, cost-effective and durable electrocatalyst for high-performance overall water splitting

Gh. Barati Darband, M. Aliofkhazraei and A. Sabour Rouhaghdam

Journal of Colloid and Interface Science, 2019, 547, 407
DOI: 10.1016/j.jcis.2019.03.098

Substrate Impact on the Structure and Electrocatalyst Properties of Molybdenum Disulfide for HER from Water

Arūnas Jagminas, Arnas Naujokaitis, Paulius Gaigalas, Simonas Ramanavičius, Marija Kurtinaitienė and Romualdas Trusovas

Metals, 2020, 10, 1251
DOI: 10.3390/met10091251

Conformational Effects of [Ni2(μ‐ArS)2] Cores on Their Electrocatalytic Activity

Alexander Mondragón‐Díaz, Elvis Robles‐Marín, Brenda A. Murueta‐Cruz, Juan C. Aquite, Paulina R. Martínez‐Alanis, Marcos Flores‐Alamo, Gabriel Aullón, Luis Norberto Benítez and Ivan Castillo

Chemistry An Asian Journal, 2019, 14, 3301
DOI: 10.1002/asia.201901037

Photoelectrochemical Hydrogen Production in Alkaline Solutions Using Cu2O Coated with Earth‐Abundant Hydrogen Evolution Catalysts

Carlos G. Morales‐Guio, Laurent Liardet, Matthew T. Mayer, S. David Tilley, Michael Grätzel and Xile Hu

Angew Chem Int Ed, 2015, 54, 664
DOI: 10.1002/anie.201410569

Redox−Acid/Base Phase Diagrams as an Entry to Computational Redox Chemistry

Patrick M. Becker, Katja Heinze, Biprajit Sarkar and Johannes Kästner

ChemElectroChem, 2024, 11
DOI: 10.1002/celc.202400301

Engineering Monolayer 1T-MoS2 into a Bifunctional Electrocatalyst via Sonochemical Doping of Isolated Transition Metal Atoms

Thomas H. M. Lau, Simson Wu, Ryuichi Kato, Tai-Sing Wu, Jiří Kulhavý, Jiaying Mo, Jianwei Zheng, John S. Foord, Yun-Liang Soo, Kazu Suenaga, Matthew T. Darby and S. C. Edman Tsang

ACS Catal., 2019, 9, 7527
DOI: 10.1021/acscatal.9b01503

Low-crystalline NiCuP with elemental synergy for hydrogen evolution reaction in proton exchange membrane water electrolyzer

Yeji Jun, Junhyeong Kim, Soo Young Kim and Sang Hyun Ahn

Fuel, 2023, 350, 128737
DOI: 10.1016/j.fuel.2023.128737

Time-resolved X-ray absorption spectroscopy for the study of molecular systems relevant for artificial photosynthesis

G. Smolentsev and V. Sundström

Coordination Chemistry Reviews, 2015, 304-305, 117
DOI: 10.1016/j.ccr.2015.03.001

A Copper Complex as Catalyst in Proton Reduction

Sebastian Nestke, Merle Kügler, Julius Scholz, Mona Wilken, Christian Jooss and Inke Siewert

Eur J Inorg Chem, 2017, 2017, 3376
DOI: 10.1002/ejic.201700154

Paired electrocatalysis unlocks cross-dehydrogenative coupling of C(sp3)-H bonds using a pentacoordinated cobalt-salen catalyst

Ke Liu, Mengna Lei, Xin Li, Xuemei Zhang, Ying Zhang, Weigang Fan, Man-Bo Li and Sheng Zhang

Nat Commun, 2024, 15
DOI: 10.1038/s41467-024-47220-9

A water soluble electro-catalyst for generating hydrogen based on a cobalt(III) complex supported by 1,10-phenanthroline

Qiu-Xia Peng, Ling-Zhi Tang, Shi-Tao Ren, Li-Ping Ye, Yuan-Fu Deng and Shu-Zhong Zhan

Chemical Physics Letters, 2016, 662, 152
DOI: 10.1016/j.cplett.2016.09.017

Parallels between enzyme catalysis, electrocatalysis, and photoelectrosynthesis

Daiki Nishiori, Brian L. Wadsworth and Gary F. Moore

Chem Catalysis, 2021, 1, 978
DOI: 10.1016/j.checat.2021.09.008

Microsecond X‐ray Absorption Spectroscopy Identification of CoI Intermediates in Cobaloxime‐Catalyzed Hydrogen Evolution

Grigory Smolentsev, Bianca Cecconi, Alexander Guda, Murielle Chavarot‐Kerlidou, Jeroen A. van Bokhoven, Maarten Nachtegaal and Vincent Artero

Chemistry A European J, 2015, 21, 15158
DOI: 10.1002/chem.201502900

Immobilized Cobalt Bis(benzenedithiolate) Complexes: Exceptionally Active Heterogeneous Electrocatalysts for Dihydrogen Production from Mildly Acidic Aqueous Solutions

Shawn C. Eady, Molly M. MacInnes and Nicolai Lehnert

Inorg. Chem., 2017, 56, 11654
DOI: 10.1021/acs.inorgchem.7b01589

Effect of Ligand Modification on the Mechanism of Electrocatalytic Hydrogen Production by Ni(pyridinethiolate)3– Derivatives

C. N. Virca, J. R. Lohmolder, J. B. Tsang, M. M. Davis and T. M. McCormick

J. Phys. Chem. A, 2018, 122, 3057
DOI: 10.1021/acs.jpca.7b11912

Acridinium salts as metal-free electrocatalyst for hydrogen evolution reaction

A.V. Dolganov, B.S. Tanaseichuk, D.N. Moiseeva, V.Y. Yurova, J.R. Sakanyan, N.S. Shmelkova and V.V. Lobanov

Electrochemistry Communications, 2016, 68, 59
DOI: 10.1016/j.elecom.2016.04.015

Using Molecular Design to Control the Performance of Hydrogen-Producing Polymer-Brush-Modified Photocathodes

Diana Cedeno, Alexandra Krawicz, Peter Doak, Min Yu, Jeffrey B. Neaton and Gary F. Moore

J. Phys. Chem. Lett., 2014, 5, 3222
DOI: 10.1021/jz5016394

An iron-iron hydrogenase mimic with appended electron reservoir for efficient proton reduction in aqueous media

René Becker, Saeed Amirjalayer, Ping Li, Sander Woutersen and Joost N. H. Reek

Sci. Adv., 2016, 2
DOI: 10.1126/sciadv.1501014

Electrospinning Hetero‐Nanofibers of Fe3C‐Mo2C/Nitrogen‐Doped‐Carbon as Efficient Electrocatalysts for Hydrogen Evolution

Huanlei Lin, Wenbiao Zhang, Zhangping Shi, Minwei Che, Xiang Yu, Yi Tang and Qingsheng Gao

ChemSusChem, 2017, 10, 2597
DOI: 10.1002/cssc.201700207

Advanced Electrocatalysts for Hydrogen Evolution Reaction Based on Core–Shell MoS2/TiO2 Nanostructures in Acidic and Alkaline Media

Aneela Tahira, Zafar Hussain Ibupoto, Raffaello Mazzaro, Shuji You, Vittorio Morandi, Marta Maria Natile, Mikhail Vagin and Alberto Vomiero

ACS Appl. Energy Mater., 2019, 2, 2053
DOI: 10.1021/acsaem.8b02119

Redox‐Polymer‐Based High‐Current‐Density Gas‐Diffusion H2‐Oxidation Bioanode Using [FeFe] Hydrogenase from Desulfovibrio desulfuricans in a Membrane‐free Biofuel Cell

Julian Szczesny, James A. Birrell, Felipe Conzuelo, Wolfgang Lubitz, Adrian Ruff and Wolfgang Schuhmann

Angew Chem Int Ed, 2020, 59, 16506
DOI: 10.1002/anie.202006824

Ab Initio-Based Kinetic Modeling for the Design of Molecular Catalysts: The Case of H2 Production Electrocatalysts

Ming-Hsun Ho, Roger Rousseau, John A. S. Roberts, Eric S. Wiedner, Michel Dupuis, Daniel L. DuBois, R. Morris Bullock and Simone Raugei

ACS Catal., 2015, 5, 5436
DOI: 10.1021/acscatal.5b01152

Synthesis of Metallopolymers via Atom Transfer Radical Polymerization from a [2Fe‐2S] Metalloinitiator: Molecular Weight Effects on Electrocatalytic Hydrogen Production

Metin Karayilan, Keelee Cathleen McCleary‐Petersen, Meghan O'Brien Hamilton, Liye Fu, Krzysztof Matyjaszewski, Richard S. Glass, Dennis L. Lichtenberger and Jeffrey Pyun

Macromol. Rapid Commun., 2020, 41
DOI: 10.1002/marc.201900424

How Metal Nuclearity Impacts Electrocatalytic H2 Production in Thiocarbohydrazone-Based Complexes

Michael Papadakis, Alexandre Barrozo, Léa Delmotte, Tatiana Straistari, Sergiu Shova, Marius Réglier, Vera Krewald, Sylvain Bertaina, Renaud Hardré and Maylis Orio

Inorganics, 2023, 11, 149
DOI: 10.3390/inorganics11040149

Electrocatalytic and Optical Properties of Cobaloxime Catalysts Immobilized at a Surface-Grafted Polymer Interface

Brian L. Wadsworth, Anna M. Beiler, Diana Khusnutdinova, Samuel I. Jacob and Gary F. Moore

ACS Catal., 2016, 6, 8048
DOI: 10.1021/acscatal.6b02194

Nickel-doped nanobelt structured molybdenum oxides as electrocatalysts for electrochemical hydrogen evolution reaction

Aruna Kalasapurayil Kunhiraman and Manoharan Ramasamy

J Nanopart Res, 2017, 19
DOI: 10.1007/s11051-017-3890-y

Oxygen Evolution Catalyzed by Nickel–Iron Oxide Nanocrystals with a Nonequilibrium Phase

Jeremy A. Bau, Erik J. Luber and Jillian M. Buriak

ACS Appl. Mater. Interfaces, 2015, 7, 19755
DOI: 10.1021/acsami.5b05594

Hydrogen production in a neutral aqueous solution with a water-soluble copper complex

Zhi-Juan Xin, Si Liu, Cheng-Bo Li, You-Jia Lei, Dong-Xu Xue, Xue-Wang Gao and Hong-Yan Wang

International Journal of Hydrogen Energy, 2017, 42, 4202
DOI: 10.1016/j.ijhydene.2016.11.103

UV/FeⅡNTA as a novel photoreductive system for the degradation of perfluorooctane sulfonate (PFOS) via a photoinduced intramolecular electron transfer mechanism

Zhuyu Sun, Chaojie Zhang, Jinchi Jiang, Jin Wen, Qi Zhou and Michael R. Hoffmann

Chemical Engineering Journal, 2022, 427, 130923
DOI: 10.1016/j.cej.2021.130923

Structure of the CoI Intermediate of a Cobalt Pentapyridyl Catalyst for Hydrogen Evolution Revealed by Time‐Resolved X‐ray Spectroscopy

Grigory Smolentsev, Mikhail A. Soldatov, Benjamin Probst, Cyril Bachmann, Nicolo Azzaroli, Roger Alberto, Maarten Nachtegaal and Jeroen A. van Bokhoven

ChemSusChem, 2018, 11, 3087
DOI: 10.1002/cssc.201801140

Electrochemical Properties of N-Methyl- and N-Phenyl-2,4,6-Triphenylpyridium Perchlorate

A. V. Dolganov, B. S. Tanaseichuk, O. V. Tarasova, O. Yu. Chernyaeva, Yu. M. Selivanova, A. D. Yudina, K. A. Grigor’yan, A. V. Balandina and V. Yu. Yurova

Russ J Electrochem, 2019, 55, 807
DOI: 10.1134/S1023193519080056

Electrochemical surface science twenty years later: Expeditions into the electrocatalysis of reactions at the core of artificial photosynthesis

Manuel P. Soriaga, Jack H. Baricuatro, Kyle D. Cummins, Youn-Geun Kim, Fadl H. Saadi, Guofeng Sun, Charles C.L. McCrory, James R. McKone, Jesus M. Velazquez, Ivonne M. Ferrer, Azhar I. Carim, Alnald Javier, Brian Chmielowiec, David C. Lacy, John M. Gregoire, Jean Sanabria-Chinchilla, Xenia Amashukeli, William J. Royea, Bruce S. Brunschwig, John C. Hemminger, Nathan S. Lewis and John L. Stickney

Surface Science, 2015, 631, 285
DOI: 10.1016/j.susc.2014.06.028

CO2 Hydrogenation to Formate and Methanol as an Alternative to Photo- and Electrochemical CO2 Reduction

Wan-Hui Wang, Yuichiro Himeda, James T. Muckerman, Gerald F. Manbeck and Etsuko Fujita

Chem. Rev., 2015, 115, 12936
DOI: 10.1021/acs.chemrev.5b00197

Photocatalytic hydrogen production based on a water-soluble porphyrin derivative as sensitizer and a series of Wilkinson type complexes as catalysts

Athanassios A. Panagiotopoulos, Efthymios G. Fasoulakis, Eleftheria E. Vardalachaki and Athanassios G. Coutsolelos

J. Porphyrins Phthalocyanines, 2016, 20, 1200
DOI: 10.1142/S1088424616500905

Nanosecond laser texturing of Ni electrodes as a high-speed and cost-effective technique for efficient hydrogen evolution reaction

Keisuke Sota, Siniya Mondal, Kota Ando, Yoshiharu Uchimoto and Takashi Nakajima

International Journal of Hydrogen Energy, 2024, 93, 1218
DOI: 10.1016/j.ijhydene.2024.10.389

Metal–Polypyridyl Catalysts for Electro- and Photochemical Reduction of Water to Hydrogen

David Z. Zee, Teera Chantarojsiri, Jeffrey R. Long and Christopher J. Chang

Acc. Chem. Res., 2015, 48, 2027
DOI: 10.1021/acs.accounts.5b00082

Pydridoxal (thio) Semicarbazone Ligands and Their Fe(III) Complexes as Potential Electrocatalysts for Hydrogen Evolution Raction

Violeta Jevtovic, Khalaf M. Alenezi, Hani El Moll, Ashanul Haque, Jamal Humaidi, Salma A. Al-Zahrani and Dragoslav Vidovic

International Journal of Electrochemical Science, 2021, 16, 210731
DOI: 10.20964/2021.07.61

A Thiosemicarbazone–Nickel(II) Complex as Efficient Electrocatalyst for Hydrogen Evolution

Tatiana Straistari, Jennifer Fize, Sergiu Shova, Marius Réglier, Vincent Artero and Maylis Orio

ChemCatChem, 2017, 9, 2262
DOI: 10.1002/cctc.201600967

Catalysis of Proton Reduction by a [BO4]-Bridged Dicobalt Glyoxime

Stephanie M. Laga, James D. Blakemore, Lawrence M. Henling, Bruce S. Brunschwig and Harry B. Gray

Inorg. Chem., 2014, 53, 12668
DOI: 10.1021/ic501804h

Recent Advances in Self-Supported Layered Double Hydroxides for Oxygen Evolution Reaction

Libo Wu, Luo Yu, Xin Xiao, Fanghao Zhang, Shaowei Song, Shuo Chen and Zhifeng Ren

Research, 2020, 2020
DOI: 10.34133/2020/3976278

Photoelectrochemical Performance of BiVO4 Photoanodes Integrated with [NiFe]‐Layered Double Hydroxide Nanocatalysts

Timothy S. Sinclair, Harry B. Gray and Astrid M. Müller

Eur J Inorg Chem, 2018, 2018, 1060
DOI: 10.1002/ejic.201701231

Translational Science for Energy and Beyond

James R. McKone, Debbie C. Crans, Cheryl Martin, John Turner, Anil R. Duggal and Harry B. Gray

Inorg. Chem., 2016, 55, 9131
DOI: 10.1021/acs.inorgchem.6b01097

Doping β-CoMoO4 Nanoplates with Phosphorus for Efficient Hydrogen Evolution Reaction in Alkaline Media

Shu Li, Nan Yang, Li Liao, Yanzhu Luo, Shengyao Wang, Feifei Cao, Wei Zhou, Dekang Huang and Hao Chen

ACS Appl. Mater. Interfaces, 2018, 10, 37038
DOI: 10.1021/acsami.8b13266

A Co2P/WC Nano‐Heterojunction Covered with N‐Doped Carbon as Highly Efficient Electrocatalyst for Hydrogen Evolution Reaction

Ya Gao, Zhongling Lang, Feiyang Yu, Huaqiao Tan, Gang Yan, Yonghui Wang, Yuanyuan Ma and Yangguang Li

ChemSusChem, 2018, 11, 1082
DOI: 10.1002/cssc.201702328

A Hydrogen Evolution Catalyst [Co2O2] Metallacycle Enables Regioselective Allene C(sp2)‐H Functionalization

Yating Liang, Jiayi Feng, Huilong Li, Xiaoli Wang, Ying Zhang, Weigang Fan, Sheng Zhang and Man‐Bo Li

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202400938

Function of 7,7,8,8-tetracyanoquinodimethane (TCNQ) on electrocatalytic hydrogen generation catalyzed by N,N′-benzene bis(salicylideniminato)nickel(II)

Dan Xue, Qi-Ying Lv, Chen-Neng Lin and Shu-Zhong Zhan

Polyhedron, 2016, 117, 300
DOI: 10.1016/j.poly.2016.05.064

Bio-inspired Cobalt Catalyst Enables Natural-Sunlight-Driven Hydrogen Production from Aerobic Neutral Aqueous Solution

Dependu Dolui, Srewashi Das, Jaya Bharti, Shivam Kumar, Pankaj Kumar and Arnab Dutta

Cell Reports Physical Science, 2020, 1, 100007
DOI: 10.1016/j.xcrp.2019.100007

A Supramolecular Porous Organic Cage Platform Promotes Electrochemical Hydrogen Evolution from Water Catalyzed by Cobalt Porphyrins

Peter T. Smith, Bahiru Punja Benke, Lun An, Younghoon Kim, Kimoon Kim and Christopher J. Chang

ChemElectroChem, 2021, 8, 1653
DOI: 10.1002/celc.202100331

Complexes of a Noncyclic Carbazole-based N5-donor Schiff base: Structures, Redox, EPR and Poor Activity as Hydrogen Evolution Electrocatalysts

Folaranmi S. Akogun, Martyna Judd, Alexandra G. C. Mort, Stuart J. Malthus, Matthew G. Robb, Nicholas Cox and Sally Brooker

Inorg. Chem., 2024, 63, 17014
DOI: 10.1021/acs.inorgchem.4c02657

Homogeneously Catalyzed Electroreduction of Carbon Dioxide—Methods, Mechanisms, and Catalysts

Robert Francke, Benjamin Schille and Michael Roemelt

Chem. Rev., 2018, 118, 4631
DOI: 10.1021/acs.chemrev.7b00459

Bimetallic polyoxometalate derived Co/WN composite as electrocatalyst for high-efficiency hydrogen evolution

Linglan Men, Tiancong Shi, Jiao Li, Xiao Li, Bo Sun, Qingqing Pan and Zhongmin Su

International Journal of Hydrogen Energy, 2022, 47, 27452
DOI: 10.1016/j.ijhydene.2022.06.061

Encapsulation of Ferrocene Methylamine in a Metal–Organic Framework for Enhanced Oxygen Evolution Reaction

Wuzhen Luo, Lin Tang, Xudong Wang, Shu-Juan Lin and Zhixiong Cai

ACS Appl. Nano Mater., 2023, 6, 22406
DOI: 10.1021/acsanm.3c04672

Hybrid bioinorganic approach to solar-to-chemical conversion

Eva M. Nichols, Joseph J. Gallagher, Chong Liu, Yude Su, Joaquin Resasco, Yi Yu, Yujie Sun, Peidong Yang, Michelle C. Y. Chang and Christopher J. Chang

Proc. Natl. Acad. Sci. U.S.A., 2015, 112, 11461
DOI: 10.1073/pnas.1508075112

A molybdenum–Schiff base complex, a new molecular electro-catalyst for generating hydrogen from acetic acid or water

Jie-Ping Cao, Ling-Ling Zhou, Ling-Zhi Fu, Jia-Xing Zhao, Hai-Xia Lu and Shu-Zhong Zhan

Catalysis Communications, 2014, 57, 1
DOI: 10.1016/j.catcom.2014.07.032

The Cobalt Hydride that Never Was: Revisiting Schrauzer’s “Hydridocobaloxime”

David C. Lacy, Gerri M. Roberts and Jonas C. Peters

J. Am. Chem. Soc., 2015, 137, 4860
DOI: 10.1021/jacs.5b01838

Multidisciplinary approaches to solar hydrogen

Kara L. Bren

Interface Focus, 2015, 5
DOI: 10.1098/rsfs.2014.0091

Direct Observation of an Iron-Bound Terminal Hydride in [FeFe]-Hydrogenase by Nuclear Resonance Vibrational Spectroscopy

Edward J. Reijerse, Cindy C. Pham, Vladimir Pelmenschikov, Ryan Gilbert-Wilson, Agnieszka Adamska-Venkatesh, Judith F. Siebel, Leland B. Gee, Yoshitaka Yoda, Kenji Tamasaku, Wolfgang Lubitz, Thomas B. Rauchfuss and Stephen P. Cramer

J. Am. Chem. Soc., 2017, 139, 4306
DOI: 10.1021/jacs.7b00686

Electrocatalytic Hydrogen Evolution by Water‐Soluble Cobalt (II), Copper (II) and Iron (III) meso‐Tetrakis(carboxyl)porphyrin

Xiao‐Wen Qi, Gang Yang, Xiao‐Shuang Guo, Li‐Ping Si, Hao Zhang and Hai‐Yang Liu

Eur J Inorg Chem, 2023, 26
DOI: 10.1002/ejic.202200613

Synthesis and electrocatalytic properties of a cobalt(II) complex supported by N,N-dimethylethylenediamino-N,N-bis(2-tert-butyl-4-ethylphenol)

Yun-Xiao Zhang, Chen-Neng Lin, Jing Liu, Shu-Zhong Zhan and Xiao-Hua Xie

Transit Met Chem, 2016, 41, 623
DOI: 10.1007/s11243-016-0061-4

Synthesis, Properties, and Electrochemical Proton Reduction of a Homoleptic Tetrathiolato Ni-Site Model of [NiFe]-Hydrogenase

Benjamin A. Yosen, Amelia G. Reid, Phan T. Truong, Tiara Hinton, Indranil Chakraborty, Marilyn M. Olmstead, Timothy L. Stemmler and Todd C. Harrop

Inorg. Chem., 2025, 64, 22308
DOI: 10.1021/acs.inorgchem.5c03077

Cobalt Complexes Containing Pendant Amines in the Second Coordination Sphere as Electrocatalysts for H2 Production

Ming Fang, Eric S. Wiedner, William G. Dougherty, W. Scott Kassel, Tianbiao Liu, Daniel L. DuBois and R. Morris Bullock

Organometallics, 2014, 33, 5820
DOI: 10.1021/om5004607

Small‐Sized Tungsten Nitride Particles Strongly Anchored on Carbon Nanotubes and their Use as Supports for Pt for Methanol Electro‐oxidation

Yuan Liu, Haijing Yan, Xiaoguang Zhou, Mingxia Li and Honggang Fu

Chemistry A European J, 2015, 21, 18345
DOI: 10.1002/chem.201503150

Impactful Role of Cocatalysts on Molecular Electrocatalytic Hydrogen Production

Charles G. Margarit, Naomi G. Asimow, Agnes E. Thorarinsdottir, Cyrille Costentin and Daniel G. Nocera

ACS Catal., 2021, 11, 4561
DOI: 10.1021/acscatal.1c00253

New Rh2(II,II) Architecture for the Catalytic Reduction of H+

Travis A. White, Suzanne E. Witt, Zhanyong Li, Kim R. Dunbar and Claudia Turro

Inorg. Chem., 2015, 54, 10042
DOI: 10.1021/acs.inorgchem.5b01823

Expanding the Redox Range of Surface-Immobilized Metallocomplexes Using Molecular Interfaces

Brian L. Wadsworth, Diana Khusnutdinova, Jennifer M. Urbine, Ahlea S. Reyes and Gary F. Moore

ACS Appl. Mater. Interfaces, 2020, 12, 3903
DOI: 10.1021/acsami.9b15286

Coordination polymer structure and revisited hydrogen evolution catalytic mechanism for amorphous molybdenum sulfide

Phong D. Tran, Thu V. Tran, Maylis Orio, Stephane Torelli, Quang Duc Truong, Keiichiro Nayuki, Yoshikazu Sasaki, Sing Yang Chiam, Ren Yi, Itaru Honma, James Barber and Vincent Artero

Nature Mater, 2016, 15, 640
DOI: 10.1038/nmat4588

Advanced catalysts for sustainable hydrogen generation and storage via hydrogen evolution and carbon dioxide/nitrogen reduction reactions

Kai-Hua Liu, Hai-Xia Zhong, Si-Jia Li, Yan-Xin Duan, Miao-Miao Shi, Xin-Bo Zhang, Jun-Min Yan and Qing Jiang

Progress in Materials Science, 2018, 92, 64
DOI: 10.1016/j.pmatsci.2017.09.001

Self-supported NiCoP/nanoporous copper as highly active electrodes for hydrogen evolution reaction

Z.B. Li, J. Wang, X.J. Liu, R. Li, H. Wang, Y. Wu, X.Z. Wang and Z.P. Lu

Scripta Materialia, 2019, 173, 51
DOI: 10.1016/j.scriptamat.2019.07.035

Metallic Cobalt@Nitrogen-Doped Carbon Nanocomposites: Carbon-Shell Regulation toward Efficient Bi-Functional Electrocatalysis

Qijie Mo, Nana Chen, Mengdie Deng, Lichun Yang and Qingsheng Gao

ACS Appl. Mater. Interfaces, 2017, 9, 37721
DOI: 10.1021/acsami.7b10853

Surface amorphized nickel hydroxy sulphide for efficient hydrogen evolution reaction in alkaline medium

Sengeni Anantharaj, Hisashi Sugime and Suguru Noda

Chemical Engineering Journal, 2021, 408, 127275
DOI: 10.1016/j.cej.2020.127275

Appropriate Use of Electrochemical Impedance Spectroscopy in Water Splitting Electrocatalysis

Sengeni Anantharaj and Suguru Noda

ChemElectroChem, 2020, 7, 2297
DOI: 10.1002/celc.202000515

Interplay between Light Flux, Quantum Efficiency, and Turnover Frequency in Molecular-Modified Photoelectrosynthetic Assemblies

Brian L. Wadsworth, Anna M. Beiler, Diana Khusnutdinova, Edgar A. Reyes Cruz and Gary F. Moore

J. Am. Chem. Soc., 2019, 141, 15932
DOI: 10.1021/jacs.9b07295

Controlled synthesis of self-supportive hydrangea shaped Ni based hydroxide/phosphide for efficient overall water splitting and full pH hydrogen evolution

Yatao Yan, Yang Chen, Mengting Shao, Jianhua Hou, Xing Chen, Lele Fan, Fanjie Kong and Ming Chen

Fuel, 2024, 367, 131551
DOI: 10.1016/j.fuel.2024.131551

Two-Dimensional Metal–Organic Surfaces for Efficient Hydrogen Evolution from Water

Andrew J. Clough, Joseph W. Yoo, Matthew H. Mecklenburg and Smaranda C. Marinescu

J. Am. Chem. Soc., 2015, 137, 118
DOI: 10.1021/ja5116937

Hydrothermal synthesis and water splitting application of d-Ti3C2 MXene/V2O5 hybrid nanostructures as an efficient bifunctional catalyst

Iffat Ashraf, Saba Ahmad, Farzana Nazir, Davoud Dastan, Zhicheng Shi, Hamid Garmestani and Mudassir Iqbal

International Journal of Hydrogen Energy, 2022, 47, 27383
DOI: 10.1016/j.ijhydene.2022.06.095

Carboxylate pentapyridines: Pathway to surface modification and tuneable catalytic proton reduction

Marissa K. Melvin, Paul K. Eggers and Colin L. Raston

Polyhedron, 2022, 228, 116177
DOI: 10.1016/j.poly.2022.116177

The Key Role of Proton‐Responsive Groups in Electrochemical Hydrogen Evolution Reaction

Sanajit Kumar Mandal, Saswati Ray and Joyanta Choudhury

ChemCatChem, 2024, 16
DOI: 10.1002/cctc.202401149

Mimicking of Tunichlorin: Deciphering the Importance of a β-Hydroxyl Substituent on Boosting the Hydrogen Evolution Reaction

Zhuo-Yan Wu, Haozong Xue, Teng Wang, Yanru Guo, Yin-Shan Meng, Xingguo Li, Jie Zheng, Christian Brückner, Guodong Rao, R. David Britt and Jun-Long Zhang

ACS Catal., 2020, 10, 2177
DOI: 10.1021/acscatal.9b03985

Co3O4@Cu‐Based Conductive Metal–Organic Framework Core–Shell Nanowire Electrocatalysts Enable Efficient Low‐Overall‐Potential Water Splitting

Lei Hu, Tuzhi Xiong, Ran Liu, Yuwen Hu, Yanchao Mao, M.‐Sadeeq (Jie Tang) Balogun and Yexiang Tong

Chemistry A European J, 2019, 25, 6575
DOI: 10.1002/chem.201900045

Nitrogen-doped graphite encapsulating RuCo nanoparticles toward high-activity catalysis of water oxidation and reduction

Mengtian Zhang, Hao Li, Junxiang Chen, Luocai Yi, Ping Shao, Cheng-Yan Xu and Zhenhai Wen

Chemical Engineering Journal, 2021, 422, 130077
DOI: 10.1016/j.cej.2021.130077

Ultrafine Ru nanoparticles confined in 3D nitrogen-doped porous carbon nanosheet networks for alkali-acid Zn-H2 hybrid battery

Hao Li, Mengtian Zhang, Luocai Yi, Yangjie Liu, Kai Chen, Ping Shao and Zhenhai Wen

Applied Catalysis B: Environmental, 2021, 280, 119412
DOI: 10.1016/j.apcatb.2020.119412

Design of macrocycles mono- and multinuclear nickel complexes based 1,4,7,10-tetraazacyclododecane and electrocatalytic activities for hydrogen evolution

Yan Zhang, Xiao-Fang Qi, Sheng-Qiao Guan and Shu-Zhong Zhan

Inorganic Chemistry Communications, 2023, 156, 111150
DOI: 10.1016/j.inoche.2023.111150

Rapid Characterization of Multi-Metallic Electrocatalysts for the Water Splitting Reactions Utilizing Printed Microelectrodes on a Chip

Timothy D. McDonald, Cal Bayer, Anne Marie DeLee, Ed Atchison, Danny Widrig, Brennan Hutchens and Kevin C. Leonard

J. Electrochem. Soc., 2016, 163, H359
DOI: 10.1149/2.1141605jes

Heterostructured MoC-MoP/N-doped carbon nanofibers as efficient electrocatalysts for hydrogen evolution reaction

NaNa Chen, Qijie Mo, Liuqing He, Xiaoqing Huang, Lichun Yang, Jiachang Zeng and Qingsheng Gao

Electrochimica Acta, 2019, 299, 708
DOI: 10.1016/j.electacta.2019.01.054

Elektrochemische Rasterzellmikroskopie einzelner ZIF‐basierter Nanokompositpartikel als Elektrokatalysatoren für die Sauerstoffentwicklung in alkalischen Medien

Tsvetan Tarnev, Harshitha Barike Aiyappa, Alexander Botz, Thomas Erichsen, Andrzej Ernst, Corina Andronescu and Wolfgang Schuhmann

Angewandte Chemie, 2019, 131, 14403
DOI: 10.1002/ange.201908021

Electrochemical-driven water reduction and oxidation catalyzed by an iron(III) complex supported by a N2O2 ligand

Jie-Jie Tan, Xia-Xing Sun, Chun-Li Wang and Shu-Zhong Zhan

Journal of Electroanalytical Chemistry, 2022, 906, 115895
DOI: 10.1016/j.jelechem.2021.115895

Electrochemically Generated Carbanions Enable Isomerizing Allylation and Allenylation of Aldehydes with Alkenes and Alkynes

Sheng Zhang, Yating Liang, Ke Liu, Xuan Zhan, Weigang Fan, Man-Bo Li and Michael Findlater

J. Am. Chem. Soc., 2023, 145, 14143
DOI: 10.1021/jacs.3c04864