Electro-oxidative depolymerisation of technical lignin in water using platinum, nickel oxide hydroxide and graphite electrodes

Nicola Di Fidio, Johan W. Timmermans, Claudia Antonetti, Anna Maria Raspolli Galletti, Richard J. A. Gosselink, Roel J. M. Bisselink and Ted M. Slaghek

New J. Chem., 2021, 45, 9647
DOI: 10.1039/D1NJ01037A

Overcoming lignin heterogeneity: reliably characterizing the cleavage of technical lignin

S. Stiefel, C. Marks, T. Schmidt, S. Hanisch, G. Spalding and M. Wessling

Green Chem., 2016, 18, 531
DOI: 10.1039/C5GC01506E

Liquid/liquid extraction of biomass-derived lignin from lignocellulosic pretreatments

Serafin Stiefel, Davide Di Marino, Armin Eggert, Ivo Robert Kühnrich, Markus Schmidt, Philipp M. Grande, Walter Leitner, Andreas Jupke and Matthias Wessling

Green Chem., 2017, 19, 93
DOI: 10.1039/C6GC02270G

Electrochemical oxidation mechanisms for selective products due to C–O and C–C cleavages of β-O-4 linkages in lignin model compounds

Jing Chen, Hanling Yang, Hongquan Fu, Hongyan He, Qiang Zeng and Xuehui Li

Phys. Chem. Chem. Phys., 2020, 22, 11508
DOI: 10.1039/D0CP01091J

Solvent free depolymerization of Kraft lignin to alkyl-phenolics using supported NiMo and CoMo catalysts

Chowdari Ramesh Kumar, Narani Anand, Arjan Kloekhorst, Catia Cannilla, Giuseppe Bonura, Francesco Frusteri, Katalin Barta and Hero Jan Heeres

Green Chem., 2015, 17, 4921
DOI: 10.1039/C5GC01641J

An integrated electrochemical process to convert lignin to value-added products under mild conditions

Serafin Stiefel, Annika Schmitz, Jens Peters, Davide Di Marino and Matthias Wessling

Green Chem., 2016, 18, 4999
DOI: 10.1039/C6GC00878J

One-pot synthesis of β-O-4 lignin modelsviathe insertion of stable 2-diazo-1,3-dicarbonyls into O–H bonds

Rafael Mafra P. Dias, Gabriela P. de Oliveira and Antonio C. B. Burtoloso

Org. Biomol. Chem., 2020, 18, 4815
DOI: 10.1039/D0OB00800A

Study on the cleavage of alkyl-O-aryl bonds by in situ generated hydroxyl radicals on an ORR cathode

Lei Wang, Yongmei Chen, Shuangyan Liu, Haomin Jiang, Linan Wang, Yanzhi Sun and Pingyu Wan

RSC Adv., 2017, 7, 51419
DOI: 10.1039/C7RA11236J

Enhanced ORR performance to electrochemical lignin valorization in a mixture of ionic liquid/organic solvent binary electrolytes

Haomin Jiang, Ang Li, Yanzhi Sun, Lei Wang and Yongmei Chen

New J. Chem., 2023, 47, 18682
DOI: 10.1039/D3NJ03967F

Electrochemical depolymerization of lignin into renewable aromatic compounds in a non-diaphragm electrolytic cell

Haibin Zhu, Lei Wang, Yongmei Chen, Gaiyun Li, Huan Li, Yang Tang and Pingyu Wan

RSC Adv., 2014, 4, 29917
DOI: 10.1039/C4RA03793F

Electro-organic synthesis – a 21stcentury technique

Dennis Pollok and Siegfried R. Waldvogel

Chem. Sci., 2020, 11, 12386
DOI: 10.1039/D0SC01848A

Electro-oxidative depolymerization of lignin for production of value-added chemicals

Daihong Gao, Denghao Ouyang and Xuebing Zhao

Green Chem., 2022, 24, 8585
DOI: 10.1039/D2GC02660K

Preparation and characterization of flame retardant polyurethane foams containing phosphorus–nitrogen-functionalized lignin

Haibin Zhu, Zumao Peng, Yongmei Chen, Gaiyun Li, Lei Wang, Yang Tang, Ran Pang, Zia Ul Haq Khan and Pingyu Wan

RSC Adv., 2014, 4, 55271
DOI: 10.1039/C4RA08429B

Comprehensive valorisation of technically relevant organosolv lignins via anodic oxidation

Manuel Breiner, Michael Zirbes and Siegfried R. Waldvogel

Green Chem., 2021, 23, 6449
DOI: 10.1039/D1GC01995C

Rapid room temperature solubilization and depolymerization of polymeric lignin at high loadings

Jian Sun, Tanmoy Dutta, Ramakrishnan Parthasarathi, Kwang Ho Kim, Nikola Tolic, Rosalie K. Chu, Nancy G. Isern, John R. Cort, Blake A. Simmons and Seema Singh

Green Chem., 2016, 18, 6012
DOI: 10.1039/C6GC02258H

Recent advances in the electrocatalytic oxidative upgrading of lignocellulosic biomass

Yufeng Qi, Hairui Guo, Junting Li, Li Ma, Yang Xu, Huiling Liu, Cheng Wang and Zhicheng Zhang

ChemPhysMater, 2024, 3, 157
DOI: 10.1016/j.chphma.2024.02.001

Hydrotreatment of Kraft Lignin to Alkylphenolics and Aromatics Using Ni, Mo, and W Phosphides Supported on Activated Carbon

Ramesh Kumar Chowdari, Shilpa Agarwal and Hero Jan Heeres

ACS Sustainable Chem. Eng., 2019, 7, 2044
DOI: 10.1021/acssuschemeng.8b04411

Development of a Method for Anodic Degradation of Lignin for the Analysis of Paleo‐Vegetation Proxies in Speleothems

Julia Homann, Michael Zirbes, Meiko Arndt‐Engelbart, Denis Scholz, Siegfried R. Waldvogel and Thorsten Hoffmann

ChemElectroChem, 2022, 9
DOI: 10.1002/celc.202101312

An approach for in situ qualitative and quantitative analysis of moisture adsorption in nanogram-scaled lignin by using micro-FTIR spectroscopy and partial least squares regression

Teng Xiao, Hanmeng Yuan, Qiang Ma, Xin Guo and Yiqiang Wu

International Journal of Biological Macromolecules, 2019, 132, 1106
DOI: 10.1016/j.ijbiomac.2019.04.043

Lignin Valorization: Two Hybrid Biochemical Routes for the Conversion of Polymeric Lignin into Value-added Chemicals

Weihua Wu, Tanmoy Dutta, Arul M. Varman, Aymerick Eudes, Bianca Manalansan, Dominique Loqué and Seema Singh

Sci Rep, 2017, 7
DOI: 10.1038/s41598-017-07895-1

Moderne Aspekte der Elektrochemie zur Synthese hochwertiger organischer Produkte

Sabine Möhle, Michael Zirbes, Eduardo Rodrigo, Tile Gieshoff, Anton Wiebe and Siegfried R. Waldvogel

Angewandte Chemie, 2018, 130, 6124
DOI: 10.1002/ange.201712732

Improved Oxidative Cleavage of Lignin Model Compound by ORR in Protic Ionic Liquid

Haomin Jiang, Lei Wang, Lingling Qiao, Aiguo Xue, Yujuan Cheng, Yueying Chen, Yuan Ren, Yongmei Chen and Pingyu Wan

International Journal of Electrochemical Science, 2019, 14, 2645
DOI: 10.20964/2019.03.10

Electrochemical removal of carbamazepine in water with Ti/PbO2 cylindrical mesh anode

J. D. García-Espinoza, P. Gortáres-Moroyoqui, M. T. Orta-Ledesma, P. Drogui and P. Mijaylova-Nacheva

Water Science and Technology, 2016, 73, 1155
DOI: 10.2166/wst.2015.591

Electro-conversion as sustainable method for the fine chemical production from the biopolymer lignin

Michael Zirbes and Siegfried R. Waldvogel

Current Opinion in Green and Sustainable Chemistry, 2018, 14, 19
DOI: 10.1016/j.cogsc.2018.05.001

Ionic liquid-trimetallic electrocatalytic system for C-O bond cleavage in lignin model compounds and lignin under ambient conditions

Guangyong Liu, Yumiao Lu, JunFeng Lu, Yanlei Wang, Shijing Liang, Hongyan He and Lilong Jiang

Nano Res., 2024, 17, 2420
DOI: 10.1007/s12274-023-6086-z

Crosslinking of renewable polyesters with epoxides to form bio-based epoxy thermosets

Kalin G. Hanson, Ching-Hsuan Lin and Mahdi M. Abu-Omar

Polymer, 2022, 238, 124363
DOI: 10.1016/j.polymer.2021.124363

Electrochemical Degradation of Lignin by ROS

Haomin Jiang, Aiguo Xue, Zhaohui Wang, Ruyue Xia, Lei Wang, Yang Tang, Pingyu Wan and Yongmei Chen

Sustainable Chemistry, 2020, 1, 345
DOI: 10.3390/suschem1030023

High temperature, flame-retardant, and transparent epoxy thermosets prepared from an acetovanillone-based hydroxyl poly(ether sulfone) and commercial epoxy resins

Ching Hsuan Lin, Yu Chun Chou, Wei Feng Shiao and Meng Wei Wang

Polymer, 2016, 97, 300
DOI: 10.1016/j.polymer.2016.05.035

Review on Catalytic Cracking of Lignin for the Production of Fuels and High-Value-Added Chemicals: Advances, Challenges, Opportunities, and Outlook

Liying Shen, Xiang Xue, Meng Wang, Yuxian Fan, Di Gu, Lingyue Zhu, Tingting Jiang, Dandan Yuan, Hongjun Wu and Baohui Wang

Energy Fuels, 2023, 37, 15309
DOI: 10.1021/acs.energyfuels.3c01878

Isolation and characterization of Burkholderia sp. strain CCA53 exhibiting ligninolytic potential

Hironaga Akita, Zen-ichiro Kimura, Mohd Zulkhairi Mohd Yusoff, Nobutaka Nakashima and Tamotsu Hoshino

SpringerPlus, 2016, 5
DOI: 10.1186/s40064-016-2237-y

Progress and prospects of catalysts for electrocatalytic lignin depolymerization

Yujing Li, Yanxia Wang, Wei Liu, Lingmin Sun, Tengfei Guo, Jiangshan Zhao, Danyang Li, Xiang Li and Zhigang Wang

Applied Catalysis A: General, 2026, 710, 120667
DOI: 10.1016/j.apcata.2025.120667

Biogene Produkte: Guter Geschmack aus Holz

Siegfried R. Waldvogel and Manuel Breiner

Nachr Chem, 2020, 68, 42
DOI: 10.1002/nadc.20204100604

Atomically Dispersed Pt–N3C1 Sites Enabling Efficient and Selective Electrocatalytic C–C Bond Cleavage in Lignin Models under Ambient Conditions

Tingting Cui, Lina Ma, Shibin Wang, Chenliang Ye, Xiao Liang, Zedong Zhang, Ge Meng, Lirong Zheng, Han-Shi Hu, Jiangwei Zhang, Haohong Duan, Dingsheng Wang and Yadong Li

J. Am. Chem. Soc., 2021, 143, 9429
DOI: 10.1021/jacs.1c02328

Modern Electrochemical Aspects for the Synthesis of Value‐Added Organic Products

Sabine Möhle, Michael Zirbes, Eduardo Rodrigo, Tile Gieshoff, Anton Wiebe and Siegfried R. Waldvogel

Angew Chem Int Ed, 2018, 57, 6018
DOI: 10.1002/anie.201712732

Peroxodicarbonate as a Green Oxidizer for the Selective Degradation of Kraft Lignin into Vanillin

Michael Zirbes, Tobias Graßl, Rieke Neuber and Siegfried R. Waldvogel

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202219217

Electrochemical Generation of ROS in Ionic Liquid for the Degradation of Lignin Model Compound

Lei Wang, Shuangyan Liu, Haomin Jiang, Yueying Chen, Linan Wang, Guoyi Duan, Yanzhi Sun, Yongmei Chen and Pingyu Wan

J. Electrochem. Soc., 2018, 165, H705
DOI: 10.1149/2.0801811jes

Application of Generalized Standard Addition Method and Ultraviolet Spectroscopy to Quantify Electrolytic Depolymerization of Lignin

Zewei Chen, Mahtab NaderiNasrabadi, John A. Staser and Peter B. Harrington

J. Anal. Test., 2020, 4, 35
DOI: 10.1007/s41664-020-00119-y

Catalytic Transformation of Lignin for the Production of Chemicals and Fuels

Changzhi Li, Xiaochen Zhao, Aiqin Wang, George W. Huber and Tao Zhang

Chem. Rev., 2015, 115, 11559
DOI: 10.1021/acs.chemrev.5b00155

Peroxodicarbonat als grünes Oxidationsmittel für den selektiven Abbau von Kraft‐Lignin zu Vanillin

Michael Zirbes, Tobias Graßl, Rieke Neuber and Siegfried R. Waldvogel

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202219217

A comprehensive analysis of the production of H2 and value-added chemicals from the electrolysis of biomass and derived feedstocks

Ali Gunerhan, Onder Altuntas and Emin Açıkkalp

Biomass and Bioenergy, 2025, 192, 107510
DOI: 10.1016/j.biombioe.2024.107510

Energy-saving cathodic H2 production enabled by non-oxygen evolution anodic reactions: A critical review on fundamental principles and applications

Wei Zhou, Shuai Chen, Xiaoxiao Meng, Jingyu Li and Jihui Gao

International Journal of Hydrogen Energy, 2023, 48, 15748
DOI: 10.1016/j.ijhydene.2023.01.063

Towards a sustainable technology for H2 production: Direct lignin electrolysis in a continuous-flow Polymer Electrolyte Membrane reactor

Angel Caravaca, Wendy Eunice Garcia-Lorefice, Sonia Gil, Antonio de Lucas-Consuegra and Philippe Vernoux

Electrochemistry Communications, 2019, 100, 43
DOI: 10.1016/j.elecom.2019.01.016

Oxidative Depolymerisation of Kraft Lignin: From Fabrication of Multi‐Metal‐Modified Electrodes For Vanillin Electrogeneration via Pulse Electrolysis To High‐Throughput Screening of Multi‐Metal Composites

Ann Cathrin Brix, Olga A. Krysiak, Ieva A. Cechanaviciutè, Gal Bjelovučić, Lars Banko, Alfred Ludwig and Wolfgang Schuhmann

ChemElectroChem, 2024, 11
DOI: 10.1002/celc.202300483

MnO2 oxidative degradation of lignin and electrochemical recovery study

Xiuyuan Ma, Jiayue Ma, Mengzhu Li, Yuanxin Gu and Ting Wang

Polymer Degradation and Stability, 2022, 204, 110091
DOI: 10.1016/j.polymdegradstab.2022.110091

On the electrooxidation of kraft black liquor on boron-doped diamond

Raisa C.P. Oliveira, Josephus G. Buijnsters, Maria M. Mateus, João C.M. Bordado and Diogo M.F. Santos

Journal of Electroanalytical Chemistry, 2022, 909, 116151
DOI: 10.1016/j.jelechem.2022.116151

High-Value Chemicals from Electrocatalytic Depolymerization of Lignin: Challenges and Opportunities

Rabia Ayub and Ahmad Raheel

IJMS, 2022, 23, 3767
DOI: 10.3390/ijms23073767

Alkali lignin depolymerization under eco-friendly and cost-effective NaOH/urea aqueous solution for fast curing bio-based phenolic resin

Jiongjiong Li, Jizhi Zhang, Shifeng Zhang, Qiang Gao, Jianzhang Li and Wei Zhang

Industrial Crops and Products, 2018, 120, 25
DOI: 10.1016/j.indcrop.2018.04.027

Promising Techniques for Depolymerization of Lignin into Value‐added Chemicals

Tianyu Ren, Wei Qi, Rongxin Su and Zhimin He

ChemCatChem, 2019, 11, 639
DOI: 10.1002/cctc.201801428

Recent Progress in Electrochemical Conversion from Biomass Derivatives into High‐Value‐Added Chemicals

Yao Sun, Jiaming Miao, Xinyi Fan, Kan Zhang and Tierui Zhang

Small Structures, 2024, 5
DOI: 10.1002/sstr.202300576

The driving force of biomass value-addition: Selective catalytic depolymerization of lignin to high-value chemicals

Quyang Tian, Piao Xu, Danlian Huang, Han Wang, Ziwei Wang, Hong Qin, Yangzhuo He, Ruijin Li, Lingshi Yin, Sha Chen and Yin Zhao

Journal of Environmental Chemical Engineering, 2023, 11, 109719
DOI: 10.1016/j.jece.2023.109719

Selective electrocatalytic upgrading of lignin to aryl aldehydes and carboxylic acids over dodecyl sulfate-intercalated CoS nanocones

Zhiyong Fang, Fuhua Li, Mei Wang, Fusheng Li, Xiujuan Wu, Ke Fan, Qing Tang, Licheng Sun and Peili Zhang

Applied Catalysis B: Environmental, 2023, 323, 122149
DOI: 10.1016/j.apcatb.2022.122149

Oxidative electrochemical depolymerization of lignin using highly active self-standing electrocatalysts prepared by electrospinning of lignin

M. García-Rollán, M. Toscano-de los Riscos, R. Ruiz-Rosas, J.M. Rosas, J. Rodríguez-Mirasol and T. Cordero

Biomass and Bioenergy, 2025, 193, 107560
DOI: 10.1016/j.biombioe.2024.107560

Electrochemical Routes for the Valorization of Biomass-Derived Feedstocks: From Chemistry to Application

Francisco W. S. Lucas, R. Gary Grim, Sean A. Tacey, Courtney A. Downes, Joseph Hasse, Alex M. Roman, Carrie A. Farberow, Joshua A. Schaidle and Adam Holewinski

ACS Energy Lett., 2021, 1205
DOI: 10.1021/acsenergylett.0c02692

Electrocatalytic Lignin Valorization via Enhanced H₂O₂ Generation Using a MWNCT‐Modified Gas Diffusion Electrode

Lei Wang, Shuangyan Liu, Jinyou Meng, Meng Song, Mingli Jiao, Haomin Jiang and Yongmei Chen

ChemPlusChem, 2025, 90
DOI: 10.1002/cplu.202400769

Selective oxidative cleavage of lignin through tailored reactive oxygen species

Ying He, Rongji Li, Mingyang Hu and Yun Liu

Tetrahedron Green Chem, 2026, 7, 100090
DOI: 10.1016/j.tgchem.2025.100090

High-Temperature Electrolysis of Kraft Lignin for Selective Vanillin Formation

Michael Zirbes, Lorenzo L. Quadri, Manuel Breiner, Andreas Stenglein, Alexander Bomm, Wolfgang Schade and Siegfried R. Waldvogel

ACS Sustainable Chem. Eng., 2020, 8, 7300
DOI: 10.1021/acssuschemeng.0c00162

H2O2 generated through ORR on cathode in a protic ionic liquid and its utilization in lignin valorization

Zhiwei Han, Haomin Jiang, Aiguo Xue, Gaoguo Ni, Yanzhi Sun, Yang Tang, Pingyu Wan and Yongmei Chen

Journal of Electroanalytical Chemistry, 2022, 923, 116814
DOI: 10.1016/j.jelechem.2022.116814

A Short Review of Second-Generation Isobutanol Production by SHF and SSF

Hironaga Akita and Akinori Matsushika

Applied Biosciences, 2024, 3, 296
DOI: 10.3390/applbiosci3030020

Electrochemical Lignin Conversion

Xu Du, Haichuan Zhang, Kevin P. Sullivan, Parikshit Gogoi and Yulin Deng

ChemSusChem, 2020, 13, 4318
DOI: 10.1002/cssc.202001187

From monomers to polymers from renewable resources: Recent advances

Alessandro Gandini and Talita M. Lacerda

Progress in Polymer Science, 2015, 48, 1
DOI: 10.1016/j.progpolymsci.2014.11.002

Metallo‐Deuteroporphyrin as a Biomimetic Catalyst for the Catalytic Oxidation of Lignin to Aromatics

Chenjie Zhu, Weiwei Ding, Tao Shen, Chenglun Tang, Chenguo Sun, Shichao Xu, Yong Chen, Jinglan Wu and Hanjie Ying

ChemSusChem, 2015, 8, 1768
DOI: 10.1002/cssc.201500048

Thermal Liquefaction of Lignin to Aromatics: Efficiency, Selectivity, and Product Analysis

Evguenii I. Kozliak, Alena Kubátová, Anastasia A. Artemyeva, Eric Nagel, Cheng Zhang, Rudresh B. Rajappagowda and Alevtina L. Smirnova

ACS Sustainable Chem. Eng., 2016, 4, 5106
DOI: 10.1021/acssuschemeng.6b01046

Greener Routes to Biomass Waste Valorization: Lignin Transformation Through Electrocatalysis for Renewable Chemicals and Fuels Production

Mahlet Garedew, Fang Lin, Bing Song, Tamara M. DeWinter, James E. Jackson, Christopher M. Saffron, Chun Ho Lam and Paul T. Anastas

ChemSusChem, 2020, 13, 4214
DOI: 10.1002/cssc.202000987