Unexpected triaxial preferences in some all-syn 1,3,5-trifluorocyclohexanes

Cihang Yu, Bruno A. Piscelli, Nawaf Al Maharik, David B. Cordes, Alexandra M. Z. Slawin, Rodrigo A. Cormanich and David O'Hagan

Chem. Commun., 2022, 58, 12855
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The conformational preferences of polychlorocyclohexanes

Shida Gong, Yuan Chen, Qiong Luo and Henry F. Schaefer

New J. Chem., 2019, 43, 18546
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Janus all‐cis‐1,2,3,4,5,6‐Hexafluorocyclohexane: A Molecular Motif for Aggregation‐Induced Enhanced Polarization

Saied Md Pratik, Abdulrahiman Nijamudheen and Ayan Datta

ChemPhysChem, 2016, 17, 2373
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How strongly do Janus all-cis C6H6F6 and C6H6Cl6 bind ions in the gas-phase?

Berthelot Saïd Duvalier Ramlina Vamhindi, Chin-Hung Lai, Stève-Jonathan Koyambo-Konzapa and Mama Nsangou

Journal of Fluorine Chemistry, 2020, 236, 109575
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The Emergence and Properties of Selectively Fluorinated ‘Janus’ Cyclohexanes

David O'Hagan

The Chemical Record, 2023, 23
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Stepwise Preparation of All-cis 1,3,4-Trifluoro-2-phenylcyclohexane, Avoiding a Phenonium Intermediate

Alastair J. Durie, Tomoya Fujiwara, Nawaf Al-Maharik, Alexandra M. Z. Slawin and David O’Hagan

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Fluorinated Rings: Conformation and Application

Rajarshi Mondal, Mohamed Agbaria and Zackaria Nairoukh

Chemistry A European J, 2021, 27, 7193
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Computational study of inversion‐topomerization pathways in 1,3‐dimethylcyclohexane and 1,4‐dimethylcyclohexane: Ab initio conformational analysis

Huiting Bian, Yifan Zhang, Yongjin Wang, Jun Zhao, Xiaohui Ruan and Jing Li

Int J of Quantum Chemistry, 2021, 121
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London Dispersion Helps Refine Steric A-Values: The Halogens

Ephrath Solel, Marcel Ruth and Peter R. Schreiner

J. Org. Chem., 2021, 86, 7701
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Theoretical Exploitation of 1,2,3,4,5,6‐Hexachloro‐ and 1,2,3,4,5,6‐Hexafluorocyclohexane Isomers as Biologically Active Compounds

Francisco A. Martins and Matheus P. Freitas

ChemPhysChem, 2023, 24
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All-cis 1,2,3,4,5,6-hexafluorocyclohexane is a facially polarized cyclohexane

Neil S. Keddie, Alexandra M. Z. Slawin, Tomas Lebl, Douglas Philp and David O'Hagan

Nature Chem, 2015, 7, 483
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Polar Organofluorine Substituents: Multivicinal Fluorines on Alkyl Chains and Alicyclic Rings

David O'Hagan

Chemistry A European J, 2020, 26, 7981
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A Computational Study of Vicinal Fluorination in 2,3‐Difluorobutane: Implications for Conformational Control in Alkane Chains

Stephen J. Fox, Stephanie Gourdain, Anton Coulthurst, Clare Fox, Ilya Kuprov, Jonathan W. Essex, Chris‐Kriton Skylaris and Bruno Linclau

Chemistry A European J, 2015, 21, 1682
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Conformational inversion-topomerization processes of ethylcyclohexane and 1,2-dimethylcyclohexane: A computational investigation

Huiting Bian, Lili Ye, Wei Zhong and Jinhua Sun

Tetrahedron, 2019, 75, 449
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Janus Face All‐cis 1,2,4,5‐tetrakis(trifluoromethyl)‐ and All‐cis 1,2,3,4,5,6‐hexakis(trifluoromethyl)‐ Cyclohexanes

Cihang Yu, Agnes Kütt, Gerd‐Volker Röschenthaler, Tomas Lebl, David B. Cordes, Alexandra M. Z. Slawin, Michael Bühl and David O'Hagan

Angewandte Chemie, 2020, 132, 20077
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A -value revisited: ring flip energy of chair structures in halogenated cyclohexanes by quantum chemical methods

Sopanant Datta, Junming Ho, Taweetham Limpanuparb and Wanutcha Lorpaiboon

Molecular Physics, 2023, 121
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Dispersion and Halogen-Bonding Interactions: Binding of the Axial Conformers of Monohalo- and (±)-trans-1,2-Dihalocyclohexanes in Enantiopure Alleno-Acetylenic Cages

Cornelius Gropp, Tamara Husch, Nils Trapp, Markus Reiher and François Diederich

J. Am. Chem. Soc., 2017, 139, 12190
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Polarity Matters: Dielectric Relaxation in All-cis-Multifluorinated Cycloalkanes

Athanasios Theodoridis, George Papamokos, Mario P. Wiesenfeldt, Marco Wollenburg, Klaus Müllen, Frank Glorius and George Floudas

J. Phys. Chem. B, 2021, 125, 3700
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Theoretical Evidence for the Relevance of n(F) → σ*(C–X) (X = H, C, O, S) Stereoelectronic Interactions

Eusebio Juaristi and Rafael Notario

J. Org. Chem., 2016, 81, 1192
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Conformational Analysis Explores the Role of Electrostatic Nonclassical CF···HC Hydrogen Bonding Interactions in Selectively Halogenated Cyclohexanes

Mengfan He, Bruno A. Piscelli, Rodrigo A. Cormanich and David O’Hagan

J. Org. Chem., 2024, 89, 4009
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Janus Face All‐cis 1,2,4,5‐tetrakis(trifluoromethyl)‐ and All‐cis 1,2,3,4,5,6‐hexakis(trifluoromethyl)‐ Cyclohexanes

Cihang Yu, Agnes Kütt, Gerd‐Volker Röschenthaler, Tomas Lebl, David B. Cordes, Alexandra M. Z. Slawin, Michael Bühl and David O'Hagan

Angew Chem Int Ed, 2020, 59, 19905
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Selective Synthesis of Monofluorinated Compounds Applying Amine/HF Reagents

Günter Haufe

The Chemical Record, 2023, 23
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