Kinetic investigation of photoiniferter-RAFT polymerization in continuous flow using inline NMR analysis

Magdalena A. Bereś, Bo Zhang, Tanja Junkers and Sébastien Perrier

Polym. Chem., 2024, 15, 3166
DOI: 10.1039/D4PY00409D

Efficiency assessment of single unit monomer insertion reactions for monomer sequence control: kinetic simulations and experimental observations

Joris J. Haven, Joke Vandenbergh, Rafael Kurita, Jonas Gruber and Tanja Junkers

Polym. Chem., 2015, 6, 5752
DOI: 10.1039/C5PY00485C

Propagation rate coefficients of 2-(dimethylamino)ethyl methacrylate radical polymerization in bulk, alcohols and alcohol/water solutions determined by PLP-SEC

Opeyemi J. Ajogbeje, Igor Lacík and Robin A. Hutchinson

Polym. Chem., 2024, 15, 2094
DOI: 10.1039/D4PY00331D

A self-crosslinking monomer, α-pinene methacrylate: understanding and exploiting hydrogen abstraction

Olivia R. Monaghan, Stephen T. Skowron, Jonathan C. Moore, María Pin-Nó, Kristoffer Kortsen, Rachel L. Atkinson, Eduards Krumins, Joachim C. Lentz, Fabricio Machado, Zeynep Onat, Adam Brookfield, David Collison, Andrei N. Khlobystov, Davide De Focatiis, Derek J. Irvine, Vincenzo Taresco, Robert A. Stockman and Steven M. Howdle

Polym. Chem., 2022, 13, 5557
DOI: 10.1039/D2PY00878E

Impact of side reactions on molar mass distribution, unsaturation level and branching density in solution free radical polymerization of n-butyl acrylate under well-defined lab-scale reactor conditions

Mariya Edeleva, Yoshi W. Marien, Paul H. M. Van Steenberge and Dagmar R. D'hooge

Polym. Chem., 2021, 12, 2095
DOI: 10.1039/D1PY00151E

A comparison of the solution radical propagation kinetics of partially water-miscible non-functional acrylates to acrylic acid

Maryam Agboluaje, Ibrahim Refai, Henry H. Manston, Robin A. Hutchinson, Eva Dušička, Anna Urbanová and Igor Lacík

Polym. Chem., 2020, 11, 7104
DOI: 10.1039/D0PY01356K

A well-defined, versatile photoinitiator (salen)Co–CO2CH3 for visible light-initiated living/controlled radical polymerization

Yaguang Zhao, Mengmeng Yu, Shuailin Zhang, Zhenqiang Wu, Yuchu Liu, Chi-How Peng and Xuefeng Fu

Chem. Sci., 2015, 6, 2979
DOI: 10.1039/C5SC00477B

Investigating the propagation kinetics of a novel class of nitrogen-containing methacrylates via PLP-SEC

Katrin B. Kockler, Friederike Fleischhaker and Christopher Barner-Kowollik

Polym. Chem., 2016, 7, 4342
DOI: 10.1039/C6PY00867D

Model-based design of the polymer microstructure: bridging the gap between polymer chemistry and engineering

Dagmar R. D'hooge, Paul H. M. Van Steenberge, Pieter Derboven, Marie-Françoise Reyniers and Guy B. Marin

Polym. Chem., 2015, 6, 7081
DOI: 10.1039/C5PY01069A

Hydrogen bonding in radical solution copolymerization kinetics of acrylates and methacrylates: a comparison of hydroxy- and methoxy-functionality

Jan E. S. Schier, David Cohen-Sacal and Robin A. Hutchinson

Polym. Chem., 2017, 8, 1943
DOI: 10.1039/C7PY00185A

Radical copolymerization kinetics of N-tert-butyl acrylamide and methyl acrylate in polar media

Ibrahim Refai, Maryam Agboluaje and Robin A. Hutchinson

Polym. Chem., 2022, 13, 2036
DOI: 10.1039/D2PY00087C

Update and critical reanalysis of IUPAC benchmark propagation rate coefficient data

Sabine Beuermann, Simon Harrisson, Robin A. Hutchinson, Tanja Junkers and Gregory T. Russell

Polym. Chem., 2022, 13, 1891
DOI: 10.1039/D2PY00147K

Two-compartment kinetic Monte Carlo modelling of electrochemically mediated ATRP

Dagmar R. D'hooge, Marco Fantin, Andrew J. D. Magenau, Dominik Konkolewicz and Krzysztof Matyjaszewski

React. Chem. Eng., 2018, 3, 866
DOI: 10.1039/C8RE00156A

Pulsed laser polymerization to retrieve kinetic parameters for a propagated mid-chain radical in poly(n-butyl acrylate) synthesis: a combined DFT and kinetic Monte Carlo study

F. A. Lugo, L. Trossaert, Y. W. Marien, M. K. Sabbe, M. Edeleva, D. R. D'hooge and P. H. M. Van Steenberge

Polym. Chem., 2025, 16, 3496
DOI: 10.1039/D5PY00343A

The influence of hydrogen bonding on radical chain-growth parameters for butyl methacrylate/2-hydroxyethyl acrylate solution copolymerization

Jan E. S. Schier and Robin A. Hutchinson

Polym. Chem., 2016, 7, 4567
DOI: 10.1039/C6PY00834H

Access to the β-scission rate coefficient in acrylate radical polymerization by careful scanning of pulse laser frequencies at elevated temperature

Anil B. Vir, Y. W. Marien, Paul H. M. Van Steenberge, Christopher Barner-Kowollik, Marie-Françoise Reyniers, Guy B. Marin and Dagmar R. D'hooge

React. Chem. Eng., 2018, 3, 807
DOI: 10.1039/C8RE00171E

Mechanism of supplemental activator and reducing agent atom transfer radical polymerization mediated by inorganic sulfites: experimental measurements and kinetic simulations

Pawel Krys, Marco Fantin, Patrícia V. Mendonça, Carlos M. R. Abreu, Tamaz Guliashvili, Jaquelino Rosa, Lino O. Santos, Arménio C. Serra, Krzysztof Matyjaszewski and Jorge F. J. Coelho

Polym. Chem., 2017, 8, 6506
DOI: 10.1039/C7PY01319A

Under pressure: electrochemically-mediated atom transfer radical polymerization of vinyl chloride

Francesco De Bon, Diana C. M. Ribeiro, Carlos M. R. Abreu, Rafael A. C. Rebelo, Abdirisak A. Isse, Arménio C. Serra, Armando Gennaro, Krzysztof Matyjaszewski and Jorge F. J. Coelho

Polym. Chem., 2020, 11, 6745
DOI: 10.1039/D0PY00995D

Identification of β scission products from free radical polymerizations of butyl acrylate at high temperature

Marco Drache, Maria Stehle, Jonas Mätzig, Katrin Brandl, Marcel Jungbluth, Jan C. Namyslo, Andreas Schmidt and Sabine Beuermann

Polym. Chem., 2019, 10, 1956
DOI: 10.1039/C9PY00103D

The effects of Lewis acid complexation on type I radical photoinitiators and implications for pulsed laser polymerization

Benjamin B. Noble, Adam C. Mater, Leesa M. Smith and Michelle L. Coote

Polym. Chem., 2016, 7, 6400
DOI: 10.1039/C6PY01445C

Connecting polymer synthesis and chemical recycling on a chain-by-chain basis: a unified matrix-based kinetic Monte Carlo strategy

Kyann De Smit, Yoshi W. Marien, Kevin M. Van Geem, Paul H. M. Van Steenberge and Dagmar R. D'hooge

React. Chem. Eng., 2020, 5, 1909
DOI: 10.1039/D0RE00266F

Jacket temperature regulation allowing well-defined non-adiabatic lab-scale solution free radical polymerization of acrylates

Mariya Edeleva, Yoshi W. Marien, Paul H. M. Van Steenberge and Dagmar R. D'hooge

React. Chem. Eng., 2021, 6, 1053
DOI: 10.1039/D1RE00099C

An alternative method to estimate the bulk backbiting rate coefficient in acrylate radical polymerization

Yoshi W. Marien, Paul H. M. Van Steenberge, Katrin B. Kockler, Christopher Barner-Kowollik, Marie-Françoise Reyniers, Dagmar R. D'hooge and Guy B. Marin

Polym. Chem., 2016, 7, 6521
DOI: 10.1039/C6PY01468B

Quasi-monodisperse polymer libraries via flash column chromatography: correlating dispersity with glass transition

Joris J. Haven and Tanja Junkers

Polym. Chem., 2019, 10, 679
DOI: 10.1039/C8PY01603H

Photo-induced copper-mediated polymerization of methyl acrylate in continuous flow reactors

Benjamin Wenn, Matthias Conradi, Andre Demetrio Carreiras, David M. Haddleton and Tanja Junkers

Polym. Chem., 2014, 5, 3053
DOI: 10.1039/C3PY01762A

Chain-length dependence of the propagation rate coefficient for methyl acrylate polymerization at 25 °C investigated by the PLP-SEC method

Anatoly N. Nikitin, Eva Dušička, Igor Lacík and Robin A. Hutchinson

Polym. Chem., 2022, 13, 3053
DOI: 10.1039/D2PY00225F

From n-butyl acrylate Arrhenius parameters for backbiting and tertiary propagation to β-scission via stepwise pulsed laser polymerization

Anil B. Vir, Yoshi W. Marien, Paul H. M. Van Steenberge, Christopher Barner-Kowollik, Marie-Françoise Reyniers, Guy B. Marin and Dagmar R. D'hooge

Polym. Chem., 2019, 10, 4116
DOI: 10.1039/C9PY00623K

Pulsed laser polymerization–size exclusion chromatography investigations into backbiting in ethylhexyl acrylate polymerization

Greg Quintens and Tanja Junkers

Polym. Chem., 2022, 13, 2019
DOI: 10.1039/D1PY01533H

A complete kinetic study of a versatile functional monomer: acetoacetoxyethyl methacrylate (AAEMA)

Alexander Zoller, Katrin B. Kockler, Marion Rollet, Catherine Lefay, Didier Gigmes, Christopher Barner-Kowollik and Yohann Guillaneuf

Polym. Chem., 2016, 7, 5518
DOI: 10.1039/C6PY01115B

Propagation rate coefficient for acrylic acid polymerization in bulk and in propionic acid by the PLP–SEC method: experiment and 3D simulation

Eva Dušička, Anatoly N. Nikitin and Igor Lacík

Polym. Chem., 2019, 10, 5870
DOI: 10.1039/C9PY01188A

Online tracing of molecular weight evolution during radical polymerization via high-resolution FlowNMR spectroscopy

Jeroen H. Vrijsen, Isabel A. Thomlinson, Martin E. Levere, Catherine L. Lyall, Matthew G. Davidson, Ulrich Hintermair and Tanja Junkers

Polym. Chem., 2020, 11, 3546
DOI: 10.1039/D0PY00475H

A machine-readable online database for rate coefficients in radical polymerization

Joren Van Herck, Simon Harrisson, Robin A. Hutchinson, Gregory T. Russell and Tanja Junkers

Polym. Chem., 2021, 12, 3688
DOI: 10.1039/D1PY00544H

A Predictive machine-learning model for propagation rate coefficients in radical polymerization

Emma Van de Reydt, Noam Marom, James Saunderson, Mario Boley and Tanja Junkers

Polym. Chem., 2023, 14, 1622
DOI: 10.1039/D2PY01531E

Acrylate Network Formation by Free‐Radical Polymerization Modeled Using Random Graphs

Verena Schamboeck, Ivan Kryven and Pieter D. Iedema

Macro Theory & Simulations, 2017, 26
DOI: 10.1002/mats.201700047

Kinetics of Atom Transfer Radical Polymerization

Pawel Krys and Krzysztof Matyjaszewski

European Polymer Journal, 2017, 89, 482
DOI: 10.1016/j.eurpolymj.2017.02.034

Random and block architectures of N-arylitaconimide monomers with methyl methacrylate

Chetana Deoghare

Physical Sciences Reviews, 2024, 9, 2097
DOI: 10.1515/psr-2022-0327

Experimental and Mechanistic Modeling Study of Self-Initiated High-Temperature Polymerization of Ethyl Acrylate

Saeed Laki, Ahmad A. Shamsabadi, Hossein Riazi, Michael C. Grady, Andrew M. Rappe and Masoud Soroush

Ind. Eng. Chem. Res., 2020, 59, 2621
DOI: 10.1021/acs.iecr.9b05050

No Apparent Correlation of kp with Steric Hindrance for Branched Acrylates

Katrin B. Kockler, Alexander P. Haehnel, Friederike Fleischhaker, Maria Schneider‐Baumann, Andrea M. Misske and Christopher Barner‐Kowollik

Macro Chemistry & Physics, 2015, 216, 1573
DOI: 10.1002/macp.201500140

The effect of hydrogen bonding on the copolymerization kinetics of 2‐methoxyethyl acrylate with 2‐hydroxyethyl methacrylate in alcohol and aqueous solutions

Maryam Agboluaje and Robin A. Hutchinson

Can J Chem Eng, 2022, 100, 689
DOI: 10.1002/cjce.24226

Radical Polymerization of Acrylates, Methacrylates, and Styrene: Biobased Approaches, Mechanism, Kinetics, Secondary Reactions, and Modeling

T. Pirman, M. Ocepek and B. Likozar

Ind. Eng. Chem. Res., 2021, 60, 9347
DOI: 10.1021/acs.iecr.1c01649

Determination of Propagation Rate Coefficient for the Polymerization of N-Vinylpyrrolidone in Aqueous Solution by Pulsed Electron Polymerization and Size Exclusion Chromatography

Nina Bartoszek, Piotr Sawicki, Sławomir Kadłubowski, Piotr Ulański and Janusz M. Rosiak

ACS Macro Lett., 2014, 3, 639
DOI: 10.1021/mz500294c

SEC Analysis of Poly(Acrylic Acid) and Poly(Methacrylic Acid)

Igor Lacík, Marek Stach, Peter Kasák, Vladislav Semak, Lucia Uhelská, Anna Chovancová, Günter Reinhold, Peter Kilz, Guillaume Delaittre, Bernadette Charleux, Isabelle Chaduc, Franck D'Agosto, Muriel Lansalot, Marianne Gaborieau, Patrice Castignolles, Robert G. Gilbert, Zachary Szablan, Christopher Barner‐Kowollik, Pascal Hesse and Michael Buback

Macro Chemistry & Physics, 2015, 216, 23
DOI: 10.1002/macp.201400339

Branch-Controlled ATRP Via Sulfoxide Chemistry

Dongwoo Kim, Juhyuk Do, Kyungho Kim, Yeonji Kim, Hana Lee, Bongkuk Seo, Wonjoo Lee, Heung Bae Jeon, Hong Y. Cho and Hyun-jong Paik

Macromolecules, 2021, 54, 7716
DOI: 10.1021/acs.macromol.1c00968

Synthesis and Characterization of the Most Active Copper ATRP Catalyst Based on Tris[(4-dimethylaminopyridyl)methyl]amine

Thomas G. Ribelli, Marco Fantin, Jean-Claude Daran, Kyle F. Augustine, Rinaldo Poli and Krzysztof Matyjaszewski

J. Am. Chem. Soc., 2018, 140, 1525
DOI: 10.1021/jacs.7b12180

Method of Moments Applied to Most-Likely High-Temperature Free-Radical Polymerization Reactions

Hossein Riazi, Ahmad Arabi Shamsabadi, Michael Grady, Andrew Rappe and Masoud Soroush

Processes, 2019, 7, 656
DOI: 10.3390/pr7100656

Advances in continuous polymer analysis in flow with application towards biopolymers

Samuel B. H. Patterson, Raymond Wong, Graeme Barker and Filipe Vilela

J Flow Chem, 2023, 13, 103
DOI: 10.1007/s41981-023-00268-y

Measurement and Modeling of Semi-Batch Solution Radical Copolymerization of N-tert-Butyl Acrylamide with Methyl Acrylate in Ethanol/Water

Gagandeep Kaur, Maryam Agboluaje and Robin A. Hutchinson

Polymers, 2022, 15, 215
DOI: 10.3390/polym15010215

Experimental and Theoretical Study of the Self-Initiation Reaction of Methyl Acrylate in Free-Radical Polymerization

Hossein Riazi, Ahmad A. Shamsabadi, Michael C. Grady, Andrew M. Rappe and Masoud Soroush

Ind. Eng. Chem. Res., 2018, 57, 532
DOI: 10.1021/acs.iecr.7b04648

Suspension Photopolymerization of Methyl Methacrylate and ATRP Grafting of Thermo‐Responsive Polymers Using a Perylediimide Derivative Photoinitiator

Aurel Diacon, Florica Rizea, Alexandra Mocanu, Adrian Dinescu, Cristina Stavarache, Luiza Izabela Jinga, Cristian N. Mihăilescu and Edina Rusen

Macro Materials & Eng, 2024, 309
DOI: 10.1002/mame.202300274

Detection of PLP Structure for Accurate Determination of Propagation Rate Coefficients over an Enhanced Range of PLP-SEC Conditions

Anatoly N. Nikitin, Igor Lacık, Robin A. Hutchinson, Michael Buback and Gregory T. Russell

Macromolecules, 2019, 52, 55
DOI: 10.1021/acs.macromol.8b01943

Radical polymerization kinetics of water-soluble monomers

Michael Buback, Robin A. Hutchinson and Igor Lacík

Progress in Polymer Science, 2023, 138, 101645
DOI: 10.1016/j.progpolymsci.2022.101645

Free Radical Propagation Rate Coefficients of N-Containing Methacrylates: Are We Family?

Katrin B. Kockler, Friederike Fleischhaker and Christopher Barner-Kowollik

Macromolecules, 2016, 49, 8572
DOI: 10.1021/acs.macromol.6b01957

Flexible material formulations for 3D printing of ordered porous beds with applications in bioprocess engineering

Simone Dimartino, Giuseppe Rafael Galindo-Rodriguez, Ursula Simon, Mariachiara Conti, M. Sulaiman Sarwar, Selva Manikandan Athi Narayanan, Qihao Jiang and Nick Christofi

Bioresour. Bioprocess., 2022, 9
DOI: 10.1186/s40643-022-00511-9

Measurement and Modeling of N‐tert‐butyl Acrylamide Radical Homo‐ and Copolymerization with Methyl Acrylate in Ethanol/Water

Maryam Agboluaje, Gagandeep Kaur and Robin A. Hutchinson

Macro Reaction Engineering, 2022, 16
DOI: 10.1002/mren.202200026

Radical polymerization of acrylic monomers: An overview

Nicholas Ballard and Jose M. Asua

Progress in Polymer Science, 2018, 79, 40
DOI: 10.1016/j.progpolymsci.2017.11.002

Photo-Induced Copper-Mediated Acrylate Polymerization in Continuous-Flow Reactors

Svitlana Railian, Benjamin Wenn and Tanja Junkers

J Flow Chem, 2016, 6, 260
DOI: 10.1556/1846.2016.00018

Effects of Chain Transfer Agent and Temperature on Branching and β‐Scission in Radical Polymerization of 2‐Ethylhexyl Acrylate

Jean‐Baptiste Lena, Michaël Deschamps, Natasha F. Sciortino, Sarah L. Masters, Marie A. Squire and Gregory T. Russell

Macro Chemistry & Physics, 2018, 219
DOI: 10.1002/macp.201700579

Determination of Head‐Addition Incidence of Methyl Acrylate and Temperature Dependence in Radical Polymerization by Coupling Reversible Addition‐Fragmentation Chain Transfer Block Polymerization Derivatization and Gradient Polymer Elution Chromatography

Mengyuan Zhang, Yang Xue, Shixian Zhang, Jianhua Zhang and Ruiwei Guo

Macro Chemistry & Physics, 2020, 221
DOI: 10.1002/macp.202000148

Critically evaluated propagation rate coefficients for radical polymerizations: acrylates and vinyl acetate in bulk (IUPAC Technical Report)

Robin A. Hutchinson and Sabine Beuermann

Pure and Applied Chemistry, 2019, 91, 1883
DOI: 10.1515/pac-2018-1108

On the Use of Quantum Chemistry for the Determination of Propagation, Copolymerization, and Secondary Reaction Kinetics in Free Radical Polymerization

Evangelos Mavroudakis, Danilo Cuccato and Davide Moscatelli

Polymers, 2015, 7, 1789
DOI: 10.3390/polym7091483

Exploring solution ICAR ATRP of methyl acrylate with AIBN as azo initiator: a kinetic modeling and simulation study

Guilherme C.L. Faria and Emerson P. Lyra

Results in Materials, 2022, 15, 100313
DOI: 10.1016/j.rinma.2022.100313

Secondary reactions during acrylate radical polymerization: Determining their rate coefficients

Fernando A. Lugo, Mariya Edeleva, Paul H.M. Van Steenberge and Maarten K. Sabbe

Polymer, 2024, 300, 126938
DOI: 10.1016/j.polymer.2024.126938

Frontal Polymerizations: From Chemical Perspectives to Macroscopic Properties and Applications

Benjamin A. Suslick, Julie Hemmer, Brecklyn R. Groce, Katherine J. Stawiasz, Philippe H. Geubelle, Giulio Malucelli, Alberto Mariani, Jeffrey S. Moore, John A. Pojman and Nancy R. Sottos

Chem. Rev., 2023, 123, 3237
DOI: 10.1021/acs.chemrev.2c00686

Effect of side-group structure and temperature on chain transfer to polymer and branching in acrylate homopolymerizations

Ian Gray, Frank Heatley and Peter Alfred Lovell

Colloid Polym Sci, 2022, 300, 445
DOI: 10.1007/s00396-021-04935-1

Global Trends for kp? The Influence of Ester Side Chain Topography in Alkyl (Meth)Acrylates − Completing the Data Base

Alexander P. Haehnel, Maria Schneider-Baumann, Lukas Arens, Andrea M. Misske, Friederike Fleischhaker and Christopher Barner-Kowollik

Macromolecules, 2014, 47, 3483
DOI: 10.1021/ma500304f

Free‐radical propagation rate coefficients

Michael Buback

Can J Chem Eng, 2023, 101, 5087
DOI: 10.1002/cjce.24885

Atom Transfer Radical Polymerization: A Mechanistic Perspective

Francesca Lorandi, Marco Fantin and Krzysztof Matyjaszewski

J. Am. Chem. Soc., 2022, 144, 15413
DOI: 10.1021/jacs.2c05364

Predictive Model for the Design of Zwitterionic Polymer Brushes: A Statistical Design of Experiments Approach

Ramya Kumar and Joerg Lahann

ACS Appl. Mater. Interfaces, 2016, 8, 16595
DOI: 10.1021/acsami.6b04370

A Critical Assessment of the Kinetics and Mechanism of Initiation of Radical Polymerization with Commercially Available Dialkyldiazene Initiators

Graeme Moad

Progress in Polymer Science, 2019, 88, 130
DOI: 10.1016/j.progpolymsci.2018.08.003

Modeling of Semibatch Solution Radical Copolymerization of Butyl Methacrylate and 2‐Hydroxyethyl Acrylate

Jan E. S. Schier, Min Zhang, Michael C. Grady and Robin A. Hutchinson

Macro Reaction Engineering, 2018, 12
DOI: 10.1002/mren.201800008

A systematic study of tert‐butylacrylamide‐methyl acrylate‐acrylic acid radical solution terpolymerization

Maryam Agboluaje, Gagandeep Kaur, Eva Dušička, Anna Urbanová, Mohammad Pishnamazi, Branislav Horváth, Miroslav Janata, Vladimír Raus, Igor Lacík and Robin A. Hutchinson

Can J Chem Eng, 2023, 101, 5300
DOI: 10.1002/cjce.24947

On the Activation Energy of Termination in Radical Polymerization, as Studied at Low Conversion

Majed M. Alghamdi and Gregory T. Russell

Polymers, 2024, 16, 3225
DOI: 10.3390/polym16223225

Vinyl pivalate Propagation Kinetics in Radical Polymerization

Otlaatla Monyatsi and Robin A. Hutchinson

Macro Chemistry & Physics, 2016, 217, 51
DOI: 10.1002/macp.201500285

Determining Free‐Radical Propagation Rate Coefficients with High‐Frequency Lasers: Current Status and Future Perspectives

Katrin B. Kockler, Alexander P. Haehnel, Tanja Junkers and Christopher Barner‐Kowollik

Macromol. Rapid Commun., 2016, 37, 123
DOI: 10.1002/marc.201500503

The strength of multi-scale modeling to unveil the complexity of radical polymerization

Dagmar R. D’hooge, Paul H.M. Van Steenberge, Marie-Françoise Reyniers and Guy B. Marin

Progress in Polymer Science, 2016, 58, 59
DOI: 10.1016/j.progpolymsci.2016.04.002

Radical Polymerization of Alkyl 2-Cyanoacrylates

Cormac Duffy, Per B. Zetterlund and Fawaz Aldabbagh

Molecules, 2018, 23, 465
DOI: 10.3390/molecules23020465

Effect of transfer agent, temperature and initial monomer concentration on branching in poly(acrylic acid): A study by 13 C NMR spectroscopy and capillary electrophoresis

Jean-Baptiste Lena, Alexander K. Goroncy, Joel J. Thevarajah, Alison R. Maniego, Gregory T. Russell, Patrice Castignolles and Marianne Gaborieau

Polymer, 2017, 114, 209
DOI: 10.1016/j.polymer.2017.01.030

Temperature Effects in Conventional and RAFT Photopolymerization

Tochukwu Nwoko, Bo Zhang, Taylor Vargo, Tanja Junkers and Dominik Konkolewicz

Macromolecules, 2025, 58, 488
DOI: 10.1021/acs.macromol.4c02001

Kinetic Monte Carlo Modeling Extracts Information on Chain Initiation and Termination from Complete PLP-SEC Traces

Yoshi W. Marien, Paul H. M. Van Steenberge, Christopher Barner-Kowollik, Marie-Françoise Reyniers, Guy B. Marin and Dagmar R. D’hooge

Macromolecules, 2017, 50, 1371
DOI: 10.1021/acs.macromol.6b02627

Exploiting (Multicomponent) Semibatch and Jacket Temperature Procedures to Safely Tune Molecular Properties for Solution Free Radical Polymerization of n‐Butyl Acrylate

Mariya Edeleva, Yoshi W. Marien, Dagmar R. D'hooge and Paul H. M. Van Steenberge

Macro Theory & Simulations, 2021, 30
DOI: 10.1002/mats.202100024

Gas-permeable templates using cellulose derivatives with acrylate and methacrylate groups for reducing in void defect density in ultraviolet nanoimprint lithography

Shinya Nakajima, Satoshi Takei, Soichiro Takamatsu, Kento Mizui, Toshitaka Oka, Yoko Matsumoto, Atsushi Sekiguchi and Makoto Hanabata

Jpn. J. Appl. Phys., 2018, 57, 086503
DOI: 10.7567/JJAP.57.086503

UV-Curable Polymer Nanocomposites Based on Poly(dimethylsiloxane) and Zirconia Nanoparticles: Reactive versus Passive Nanofillers

Ria D. Corder, Joseph C. Tilly, Wade F. Ingram, Sangchul Roh, Richard J. Spontak and Saad A. Khan

ACS Appl. Polym. Mater., 2020, 2, 394
DOI: 10.1021/acsapm.9b00855

Synergistic approach of type I hybrid complexes for highly efficient metal-based initiating strategies: Toward low energy-consuming polymerization for thermoplastic composite implementation

Marie Le Dot, Nicolas Giacoletto, Fabrice Morlet-Savary, Bernadette Graff, Valérie Monnier, Didier Gigmes, Malek Nechab, Frédéric Dumur, Pierre Gerard and Jacques Lalevée

European Polymer Journal, 2023, 186, 111871
DOI: 10.1016/j.eurpolymj.2023.111871

Improved Approach for ab Initio Calculations of Rate Coefficients for Secondary Reactions in Acrylate Free-Radical Polymerization

Fernando A. Lugo, Mariya Edeleva, Paul H. M. Van Steenberge and Maarten K. Sabbe

Polymers, 2024, 16, 872
DOI: 10.3390/polym16070872

Propagation Kinetics of Isoprene Radical Homopolymerization Derived from Pulsed Laser Initiated Polymerizations

Brian van Büren, Florian Brandl and Sabine Beuermann

Macro Reaction Engineering, 2020, 14
DOI: 10.1002/mren.201900030

Tin(II) 2-ethylhexanoate and ascorbic acid as reducing agents in solution ARGET ATRP: A kinetic study approach by mathematical modeling and simulation

Emerson P. Lyra, Cesar L. Petzhold and Liliane M.F. Lona

Chemical Engineering Journal, 2019, 364, 186
DOI: 10.1016/j.cej.2019.01.123

Solvent Effects on Acrylate kp in Organic Media?—A Systematic PLP–SEC Study

Alexander P. Haehnel, Benjamin Wenn, Katrin Kockler, Tobias Bantle, Andrea M. Misske, Friederike Fleischhaker, Tanja Junkers and Christopher Barner‐Kowollik

Macromol. Rapid Commun., 2014, 35, 2029
DOI: 10.1002/marc.201400479

DFT Investigation of Polyethylene-co-vinyl Acetate: Kinetics of Initiation and Propagation, Copolymer Composition, and Unit Sequence Distribution

Minhua Zhang, Suocheng Chi and Yingzhe Yu

Ind. Eng. Chem. Res., 2022, 61, 10775
DOI: 10.1021/acs.iecr.2c01401

Controversies on the mechanism and kinetics of emulsion polymerization: An updated critical review

Jorge Herrera-Ordonez

Advances in Colloid and Interface Science, 2023, 320, 103005
DOI: 10.1016/j.cis.2023.103005

Kilohertz Pulsed‐Laser‐Polymerization: Simultaneous Determination of Backbiting, Secondary, and Tertiary Radical Propagation Rate Coefficients for tert‐Butyl Acrylate

Benjamin Wenn and Tanja Junkers

Macromol. Rapid Commun., 2016, 37, 781
DOI: 10.1002/marc.201600011

Critically Evaluated Rate Coefficients in Radical Polymerization – 8. Propagation Rate Coefficients for Vinyl Acetate in Bulk

Christopher Barner‐Kowollik, Sabine Beuermann, Michael Buback, Robin A. Hutchinson, Tanja Junkers, Hendrik Kattner, Bart Manders, Anatoly N. Nikitin, Gregory T. Russell and Alex M. van Herk

Macro Chemistry & Physics, 2017, 218
DOI: 10.1002/macp.201600357

One‐Pot Synthesis of Block Copolymers by a Combination of Living Cationic and Controlled Radical Polymerization

Anne‐Kristin Trützschler, Meike N. Leiske, Maria Strumpf, Johannes C. Brendel and Ulrich S. Schubert

Macromol. Rapid Commun., 2019, 40
DOI: 10.1002/marc.201800398

An old kinetic method for a new polymerization mechanism: Toward photochemically mediated ATRP

Yin‐Ning Zhou and Zheng‐Hong Luo

AIChE Journal, 2015, 61, 1947
DOI: 10.1002/aic.14792

Theoretical Study of Chain Transfer to Solvent Reactions of Alkyl Acrylates

Nazanin Moghadam, Sriraj Srinivasan, Michael C. Grady, Andrew M. Rappe and Masoud Soroush

J. Phys. Chem. A, 2014, 118, 5474
DOI: 10.1021/jp5020669

Measurement and Modeling of Methyl Acrylate Radical Polymerization in Polar and Nonpolar Solvents

Maryam Agboluaje and Robin A. Hutchinson

Ind. Eng. Chem. Res., 2022, 61, 6398
DOI: 10.1021/acs.iecr.2c00677

Electrochemically mediated ATRP process intensified by ionic liquid: A “flash” polymerization of methyl acrylate

Jun-Kang Guo, Yin-Ning Zhou and Zheng-Hong Luo

Chemical Engineering Journal, 2019, 372, 163
DOI: 10.1016/j.cej.2019.04.110

Polymer Colloids: Current Challenges, Emerging Applications, and New Developments

Miren Aguirre, Nicholas Ballard, Edurne Gonzalez, Shaghayegh Hamzehlou, Haritz Sardon, Marcelo Calderon, Maria Paulis, Radmila Tomovska, Damien Dupin, Ren H. Bean, Timothy E. Long, Jose R. Leiza and José M. Asua

Macromolecules, 2023, 56, 2579
DOI: 10.1021/acs.macromol.3c00108

Propagation Rate Coefficients for Vinylidene Fluoride Homopolymerizations

Rebekka Siegmann, Marco Drache and Sabine Beuermann

Macromolecules, 2013, 46, 9507
DOI: 10.1021/ma401830a

Miniemulsion polymerization via membrane emulsification: Exploring system feasibility for different monomers

Nida Nauman, Cyrille Boyer and Per B. Zetterlund

Colloid Polym Sci, 2022, 300, 309
DOI: 10.1007/s00396-021-04918-2

PLP-SEC Investigation of the Influence of Electrostatic Interactions on the Radical Propagation Rate Coefficients of Cationic Monomers TMAEMC and MAPTAC

Anna Urbanová, Ikenna H. Ezenwajiaku, Anatoly. N. Nikitin, Marián Sedlák, Hugo M. Vale, Robin A. Hutchinson and Igor Lacík

Macromolecules, 2021, 54, 3204
DOI: 10.1021/acs.macromol.1c00263

Solvent Effects on Radical Copolymerization Kinetics of 2-Hydroxyethyl Methacrylate and Butyl Methacrylate

Loretta A. Idowu and Robin A. Hutchinson

Polymers, 2019, 11, 487
DOI: 10.3390/polym11030487

Synthesis of Micrometer-Sized Poly(methyl acrylate) by Temperature-Step Microsuspension Polymerization with Iodoform Based on the “Radical Exit Depression” Effect§

Chujuan Huang, Hideto Minami and Masayoshi Okubo

Langmuir, 2021, 37, 3158
DOI: 10.1021/acs.langmuir.1c00008

Benchmark Cases and Guidelines for Kinetic Monte Carlo Simulations with Linear Polymers

Tomás Romero Pietrafesa, Alessandro D. Trigilio, Yoshi W. Marien, Pablo Reyes, Mariya Edeleva, Mariano Asteasuain, Paul H. M. Van Steenberge and Dagmar R. D’hooge

Ind. Eng. Chem. Res., 2025, 64, 9974
DOI: 10.1021/acs.iecr.5c00639

SP–PLP–EPR Measurement of CuII-Mediated ATRP Deactivation and CuI-Mediated Organometallic Reactions in Butyl Acrylate Polymerization

Nicolai Soerensen, Hendrik Schroeder and Michael Buback

Macromolecules, 2016, 49, 4732
DOI: 10.1021/acs.macromol.6b00760

Dependence of Propagation Rate Coefficients in Radical Polymerization on Solution Properties

Peter Deglmann, Klaus‐Dieter Hungenberg and Hugo M. Vale

Macro Reaction Engineering, 2017, 11
DOI: 10.1002/mren.201600037

A 3D Simulation Investigation of the Influence of Temperature Increases on the Accuracy of Propagation Rate Coefficients Determined by Pulsed-Laser Polymerization

Anatoly N. Nikitin, Igor Lacík and Robin A. Hutchinson

Macromolecules, 2016, 49, 9320
DOI: 10.1021/acs.macromol.6b02336

Modeling of Branching Distributions in Butyl Acrylate Polymerization Applying Monte Carlo Methods

Marco Drache, Benjamin Hosemann, Tetyana Laba and Sabine Beuermann