Dinitrogen activation by a penta-pyridyl molybdenum complex

Jeongmin Cha, Hyunchul Kwon, Hayoung Song and Eunsung Lee

Dalton Trans., 2020, 49, 12945
DOI: 10.1039/D0DT02692A

Recent advancement in the electrocatalytic synthesis of ammonia

Xudong Wen and Jingqi Guan

Nanoscale, 2020, 12, 8065
DOI: 10.1039/D0NR01359E

Single-atom molybdenum immobilized on photoactive carbon nitride as efficient photocatalysts for ambient nitrogen fixation in pure water

Xiang-Wei Guo, Shuang-Ming Chen, Hong-Juan Wang, Zhi-Ming Zhang, Hong Lin, Li Song and Tong-Bu Lu

J. Mater. Chem. A, 2019, 7, 19831
DOI: 10.1039/C9TA06653E

Engineering photocatalytic ammonia synthesis

Yonghui Shi, Zhanfeng Zhao, Dong Yang, Jiangdan Tan, Xin Xin, Yongqi Liu and Zhongyi Jiang

Chem. Soc. Rev., 2023, 52, 6938
DOI: 10.1039/D2CS00797E

Retrosynthetic approach to the design of molybdenum–magnesium oxoalkoxides

Denis A. Kuznetsov, Ivan V. Fedyanin, Konstantin A. Lyssenko and Tamara A. Bazhenova

Dalton Trans., 2014, 43, 12876
DOI: 10.1039/C4DT01035C

Facile N-functionalization and strong magnetic communication in a diuranium(v) bis-nitride complex

Luciano Barluzzi, Lucile Chatelain, Farzaneh Fadaei-Tirani, Ivica Zivkovic and Marinella Mazzanti

Chem. Sci., 2019, 10, 3543
DOI: 10.1039/C8SC05721D

Direct and indirect hyperpolarisation of amines using parahydrogen

Wissam Iali, Peter J. Rayner, Adel Alshehri, A. Jonathan. Holmes, Amy J. Ruddlesden and Simon B. Duckett

Chem. Sci., 2018, 9, 3677
DOI: 10.1039/C8SC00526E

B4C nanosheets decorated within situ-derived boron-doped graphene quantum dots for high-efficiency ambient N2fixation

Wei-Bin Qiu, Yu-Xi Luo, Ru-Ping Liang, Jian-Ding Qiu and Xing-Hua Xia

Chem. Commun., 2019, 55, 7406
DOI: 10.1039/C9CC03413G

Cation assisted binding and cleavage of dinitrogen by uranium complexes

Nadir Jori, Thayalan Rajeshkumar, Rosario Scopelliti, Ivica Z̆ivković, Andrzej Sienkiewicz, Laurent Maron and Marinella Mazzanti

Chem. Sci., 2022, 13, 9232
DOI: 10.1039/D2SC02530B

Site-exposed Ti3C2 MXene anchored in N-defect g-C3N4 heterostructure nanosheets for efficient photocatalytic N2 fixation

Cong Sun, Zhiqiang Chen, Jian Cui, Kang Li, Hongxia Qu, Huifang Xie and Qin Zhong

Catal. Sci. Technol., 2021, 11, 1027
DOI: 10.1039/D0CY01955K

Nitrogen reduction reaction under ambient conditions by K3Ti8O17 nanorod electrocatalyst

Meera Sebastian, Subrata Das and Nishanth Karimbintherikkal Gopalan

Sustainable Energy Fuels, 2022, 6, 1519
DOI: 10.1039/D1SE01932E

Progress of electrocatalytic urea synthesis: strategic design, reactor engineering, mechanistic details and techno-commercial study

Sourav Paul, Ashadul Adalder and Uttam Kumar Ghorai

Mater. Chem. Front., 2023, 7, 3820
DOI: 10.1039/D3QM00433C

A tuned Lewis acidic catalyst guided by hard–soft acid–base theory to promote N2 electroreduction

Yongwen Ren, Chang Yu, Xuedan Song, Fengyi Zhou, Xinyi Tan, Yiwang Ding, Qianbing Wei, Jiafu Hong and Jieshan Qiu

J. Mater. Chem. A, 2021, 9, 13036
DOI: 10.1039/D1TA02681J

Simultaneous enzymatic activity modulation and rapid determination of enzyme kinetics by highly crystalline graphite dots

Rui Shi, Hao Li, Enhui Wu, Lipeng Xiong, Rui Lv, Ruochen Guo, Yang Liu, Guoqiang Xu, Zhenhui Kang and Jian Liu

Nanoscale, 2017, 9, 8410
DOI: 10.1039/C7NR02285A

Computational screening of a single transition metal atom supported on the C2N monolayer for electrochemical ammonia synthesis

Zhongxu Wang, Zhigang Yu and Jingxiang Zhao

Phys. Chem. Chem. Phys., 2018, 20, 12835
DOI: 10.1039/C8CP01215F

Activation of the N2 molecule by means of low-valence complexes of calcium and magnesium

Anna Rovaletti, Luca De Gioia, Claudio Greco and Federica Arrigoni

Dalton Trans., 2023, 52, 7966
DOI: 10.1039/D3DT00945A

Teaching old compounds new tricks: efficient N2 fixation by simple Fe(N2)(diphosphine)2 complexes

Laurence R. Doyle, Peter J. Hill, Gregory G. Wildgoose and Andrew E. Ashley

Dalton Trans., 2016, 45, 7550
DOI: 10.1039/C6DT00884D

Computational investigation of single and multiple boron atom doped WS2 monolayers for superior electrocatalytic reduction of nitrogen

Zehong Yin, Jingeng Cao, Xiuyuan Li and Nan Li

Phys. Chem. Chem. Phys., 2024, 26, 7674
DOI: 10.1039/D3CP05648A

An MnO2–Ti3C2Tx MXene nanohybrid: an efficient and durable electrocatalyst toward artificial N2 fixation to NH3 under ambient conditions

Wenhan Kong, Feng (Frank) Gong, Qiang Zhou, Guangsen Yu, Lei Ji, Xuping Sun, Abdullah M. Asiri, Ting Wang, Yonglan Luo and Yuanhong Xu

J. Mater. Chem. A, 2019, 7, 18823
DOI: 10.1039/C9TA04902A

Dinitrogen-derived (diarylboryl)diazenido complexes with differing coordination to the thallium cation

Amal Bouammali, Anaïs Coffinet, Laure Vendier and Antoine Simonneau

Dalton Trans., 2022, 51, 10697
DOI: 10.1039/D1DT03905A

NaCl template-assisted construction of a CoP–MoP heterostructured electrocatalyst for electrocatalytic nitrogen reduction

Yunni Liu, Yinghao Tao, Zhaobing Lu, Jing Teng, Weiju Hao, Jun Lin and Guisheng Li

Dalton Trans., 2023, 52, 11631
DOI: 10.1039/D3DT00686G

Efficient nitric oxide electroreduction toward ambient ammonia synthesis catalyzed by a CoP nanoarray

Jie Liang, Wen-Feng Hu, Bingyi Song, Ting Mou, Longcheng Zhang, Yongsong Luo, Qian Liu, Abdulmohsen Ali Alshehri, Mohamed S. Hamdy, Li-Ming Yang and Xuping Sun

Inorg. Chem. Front., 2022, 9, 1366
DOI: 10.1039/D2QI00002D

A CeP nanoparticle-reduced graphene oxide hybrid: an efficient electrocatalyst for the NH3 synthesis under ambient conditions

Yuyao Ji, Lei Li, Wendong Cheng, Yu Xiao, Chengbo Li and Xingquan Liu

Inorg. Chem. Front., 2021, 8, 2103
DOI: 10.1039/D0QI01511C

Metal-free boron nanosheet as “buffer electron pool” for urea and ethanol synthesis via C–N and C–C coupling

Yongyong Cao, Yuxiao Meng, Yuting Wu, Hongjie Huang, Weichan Zhong, Zhangfeng Shen, Qineng Xia, Yangang Wang and Xi Li

J. Mater. Chem. A, 2022, 10, 23843
DOI: 10.1039/D2TA06739K

Observing C–N bond formation in plasma: a case study of benzene and dinitrogen coupling via an arylnitrenium ion intermediate

Wen Liu and Yonghui Tian

Phys. Chem. Chem. Phys., 2024, 26, 18016
DOI: 10.1039/D4CP01594K

On the binding modes of metal NHC complexes with DNA secondary structures: implications for therapy and imaging

Özden Karaca, Samuel M. Meier-Menches, Angela Casini and Fritz E. Kühn

Chem. Commun., 2017, 53, 8249
DOI: 10.1039/C7CC03074F

Single-metal atom sandwiched by graphdiyne and BN-doped graphdiyne sheets as an electrocatalyst for nitrogen reduction: a first-principles study

Manqi Li, Zhenhua Liu, Tian Gao, Shiyao Liu, Hong Yu, Zhao Wang and Hao Sun

Phys. Chem. Chem. Phys., 2023, 25, 4803
DOI: 10.1039/D2CP04898A

Vanadium-doped NiS2 porous nanospheres with high selectivity and stability for the electroreduction of nitrogen to ammonia

Mingzhu Zhao, Chengying Guo, Lingfeng Gao, Xuan Kuang, Hua Yang, Xiaojing Ma, Chengqing Liu, Xuejing Liu, Xu Sun and Qin Wei

Inorg. Chem. Front., 2021, 8, 3266
DOI: 10.1039/D1QI00328C

Facet-dependent solar ammonia synthesis of BiOCl nanosheets via a proton-assisted electron transfer pathway

Hao Li, Jian Shang, Jingu Shi, Kun Zhao and Lizhi Zhang

Nanoscale, 2016, 8, 1986
DOI: 10.1039/C5NR07380D

Harnessing halogen bond donors for enhanced nitrogen reduction: a case study on metal-free boron nitride single-atom catalysts

Venkata Surya Kumar Choutipalli and Venkatesan Subramanian

Phys. Chem. Chem. Phys., 2024, 26, 12495
DOI: 10.1039/D4CP00076E

P- or S-Doped graphdiyne as a superior metal-free electrocatalyst for the hydrogen evolution reaction: a computational study

Siyao Wang, Dongxu Jiao, Jingwei Liu, Yongchen Shang and Jingxiang Zhao

New J. Chem., 2021, 45, 8101
DOI: 10.1039/D1NJ00652E

Ambient dinitrogen electrocatalytic reduction for ammonia synthesis

Aling Chen and Bao Yu Xia

J. Mater. Chem. A, 2019, 7, 23416
DOI: 10.1039/C9TA05505C

N-Heterocyclic carbenes as supporting ligands in transition metal complexes of N2

Yasuhiro Ohki and Hidetake Seino

Dalton Trans., 2016, 45, 874
DOI: 10.1039/C5DT04298D

Charge transfer and reaction coordinate construction based theoretical investigation of the eNRR and HER on cuboidal silver phosphate: a tale of two competing mechanisms

Prajna Parimita Mohanty, Tisita Das, Rajeev Ahuja and Sudip Chakraborty

Sustainable Energy Fuels, 2025, 9, 2333
DOI: 10.1039/D4SE01614A

Construction of PdO–Pd interfaces assisted by laser irradiation for enhanced electrocatalytic N2 reduction reaction

Jiali Lv, Shouliang Wu, Zhenfei Tian, Yixing Ye, Jun Liu and Changhao Liang

J. Mater. Chem. A, 2019, 7, 12627
DOI: 10.1039/C9TA02045D

Coupling denitrification and ammonia synthesis via selective electrochemical reduction of nitric oxide over Fe2O3 nanorods

Jie Liang, Hongyu Chen, Ting Mou, Longcheng Zhang, Yiting Lin, Luchao Yue, Yongsong Luo, Qian Liu, Na Li, Abdulmohsen Ali Alshehri, Imran Shakir, Philips O. Agboola, Yuanyuan Wang, Bo Tang, Dongwei Ma and Xuping Sun

J. Mater. Chem. A, 2022, 10, 6454
DOI: 10.1039/D2TA00744D

Plasmonic gold nanocrystals simulated efficient photocatalytic nitrogen fixation over Mo doped W18O49nanowires

Peng Qiu, Cong Huang, Gang Dong, Feiyang Chen, Feifan Zhao, Yongsheng Yu, Xueqin Liu, Zhen Li and Yang Wang

J. Mater. Chem. A, 2021, 9, 14459
DOI: 10.1039/D1TA03339E

Screening of transition metal single-atom catalysts supported by a WS2 monolayer for electrocatalytic nitrogen reduction reaction: insights from activity trend and descriptor

Renyi Li and Wei Guo

Phys. Chem. Chem. Phys., 2022, 24, 13384
DOI: 10.1039/D2CP01446G

Electrochemical C–N coupling with perovskite hybrids toward efficient urea synthesis

Menglei Yuan, Junwu Chen, Yiling Bai, Zhanjun Liu, Jingxian Zhang, Tongkun Zhao, Qiaona Shi, Shuwei Li, Xi Wang and Guangjin Zhang

Chem. Sci., 2021, 12, 6048
DOI: 10.1039/D1SC01467F

A cobalt-based metal–organic framework as a sustainable catalyst for base-free transfer hydrogenation of biomass-derived carbonyl compounds

Aashish, Ruchika Gupta and Rajeev Gupta

RSC Sustainability, 2024, 2, 3409
DOI: 10.1039/D4SU00368C

A magnetron sputtered Mo3Si thin film: an efficient electrocatalyst for N2 reduction under ambient conditions

Ting Wang, Qian Liu, Tingshuai Li, Siyu Lu, Guang Chen, Xifeng Shi, Abdullah M. Asiri, Yonglan Luo, Dongwei Ma and Xuping Sun

J. Mater. Chem. A, 2021, 9, 884
DOI: 10.1039/D0TA11231C

Recent progress in electrochemical synthesis of ammonia from nitrogen: strategies to improve the catalytic activity and selectivity

Bing Yang, Weilu Ding, Honghua Zhang and Suojiang Zhang

Energy Environ. Sci., 2021, 14, 672
DOI: 10.1039/D0EE02263B

A bioinspired sulfur-surrounded iron catalyst for ammonia synthesis

Na Zhang, Yubing Si, Qiang Fu and Xing Chen

J. Mater. Chem. A, 2024, 12, 11602
DOI: 10.1039/D4TA00710G

Catalytic conversion of nitrogen molecule into ammonia using molybdenum complexes under ambient reaction conditions

Yuya Ashida and Yoshiaki Nishibayashi

Chem. Commun., 2021, 57, 1176
DOI: 10.1039/D0CC07146C

Spherical micro-heterostructured Bi2MoO6/Mo–Bi2O3 with interfacial oxygen vacancies enabling efficient photocatalytic NH3 production from N2 and H2O

Dan Wu, Lu Hong, Xin Gu, Yanan Liu, Haohong Li, Jinni Shen, Yingshu Wang, Huidong Zheng and Xuxu Wang

Catal. Sci. Technol., 2025
DOI: 10.1039/D5CY00505A

Recent advances in photocatalytic nitrogen fixation: from active sites to ammonia quantification methods

Rong Huang, Xiaoman Li, Wanguo Gao, Xu Zhang, Sen Liang and Min Luo

RSC Adv., 2021, 11, 14844
DOI: 10.1039/D0RA10439F

A roadmap for ammonia synthesis via electrocatalytic reduction of nitric oxide

Haoxuan Jiang, Adel Rezaeimotlagh, Sahar Nazari, Renwu Zhou, Tianyu Li, Jingwen Huang, Dorna Esrafilzadeh and Ali R. Jalili

Energy Environ. Sci., 2025
DOI: 10.1039/D5EE03443D

Ambient electrochemical NH3 synthesis from N2 and water enabled by ZrO2 nanoparticles

Tong Xu, Dongwei Ma, Chengbo Li, Qian Liu, Siyu Lu, Abdullah M. Asiri, Chun Yang and Xuping Sun

Chem. Commun., 2020, 56, 3673
DOI: 10.1039/C9CC10087C

Anchoring ultrafine CdS nanoparticles in TpPa-1-COF: a type II heterojunction for enhanced photocatalytic N2 fixation

Chunqiang Wang, Songhu Shi, Fang Duan, Shuanglong Lu, Han Zhu, Mingliang Du, Xin Chen and Mingqing Chen

J. Mater. Chem. A, 2022, 10, 16524
DOI: 10.1039/D2TA03461A

Revisiting group 4–7 transition metals for heterogeneous ammonia synthesis

Wenbo Gao, Yawei Wang, Qianru Wang, Zhaolong Sun, Jianping Guo and Ping Chen

EES Catal., 2024, 2, 780
DOI: 10.1039/D3EY00301A

Theoretical study of ammonia synthesis catalysed by trimetallic clusters with or without a sumanene support

Xiao-Meng Huang, Zhi-Wen Ji, Xun-Lei Ding, Yan Chen, Wei Li, Jiao-Jiao Chen, Shao-Peng Xu and Lin-Lin Li

Phys. Chem. Chem. Phys., 2025, 27, 10259
DOI: 10.1039/D5CP00926J

Photocatalytic fixation of nitrogen to ammonia: state-of-the-art advancements and future prospects

Xingzhu Chen, Neng Li, Zhouzhou Kong, Wee-Jun Ong and Xiujian Zhao

Mater. Horiz., 2018, 5, 9
DOI: 10.1039/C7MH00557A

Defect induced nitrogen reduction reaction of carbon nanomaterials

Reen Maria Lawrence and Sreekuttan M. Unni

Sustainable Energy Fuels, 2021, 5, 3765
DOI: 10.1039/D1SE00644D

Fe-doped phosphorene for the nitrogen reduction reaction

Zengxi Wei, Yuefeng Zhang, Shuangyin Wang, Caiyun Wang and Jianmin Ma

J. Mater. Chem. A, 2018, 6, 13790
DOI: 10.1039/C8TA03989E

Constructing a tunable defect structure in TiO2 for photocatalytic nitrogen fixation

Guoqiang Zhang, Xun Yang, Chuanxin He, Peixin Zhang and Hongwei Mi

J. Mater. Chem. A, 2020, 8, 334
DOI: 10.1039/C9TA10471B

Progress and challenges in photocatalytic ammonia synthesis

Qing Han, Haimiao Jiao, Lunqiao Xiong and Junwang Tang

Mater. Adv., 2021, 2, 564
DOI: 10.1039/D0MA00590H

Plasmon-enabled N2 photofixation on partially reduced Ti3C2 MXene

Binbin Chang, Yanzhen Guo, Donghai Wu, Li Li, Baocheng Yang and Jianfang Wang

Chem. Sci., 2021, 12, 11213
DOI: 10.1039/D1SC02772G

A review on catalysts for electrocatalytic and photocatalytic reduction of N2to ammonia

Shanshan Lin, Xinghua Zhang, Lungang Chen, Qi Zhang, Longlong Ma and Jianguo Liu

Green Chem., 2022, 24, 9003
DOI: 10.1039/D2GC03174D

High yield selective electrochemical conversion of N2 to NH3via morphology controlled silver phosphate under ambient conditions

Divyani Gupta, Alankar Kafle, Sukhjot Kaur, Prajna Parimita Mohanty, Tisita Das, Sudip Chakraborty, Rajeev Ahuja and Tharamani C. Nagaiah

J. Mater. Chem. A, 2022, 10, 20616
DOI: 10.1039/D2TA04155C

(Plasmonic gold core)@(ultrathin ruthenium shell) nanostructures as antenna-reactor photocatalysts toward nitrogen photofixation

Henglei Jia, Yuanyuan Yang, Yanrong Dou, Fan Li, Mengxuan Zhao and Chun-yang Zhang

Chem. Commun., 2022, 58, 1013
DOI: 10.1039/D1CC06014G

Small molecule activation by boron-containing heterocycles

Yuanting Su and Rei Kinjo

Chem. Soc. Rev., 2019, 48, 3613
DOI: 10.1039/C9CS00072K

Modulation strategies of Cu-based electrocatalysts for efficient nitrogen reduction

Hangyan Zhou, Bingyan Xiong, Lisong Chen and Jianlin Shi

J. Mater. Chem. A, 2020, 8, 20286
DOI: 10.1039/D0TA06776H

A polyoxometalate cluster-based single-atom catalyst for NH3 synthesis via an enzymatic mechanism

Shamraiz Hussain Talib, Xiaohu Yu, Zhansheng Lu, Khalil Ahmad, Tongtong Yang, Hai Xiao and Jun Li

J. Mater. Chem. A, 2022, 10, 6165
DOI: 10.1039/D1TA07903D

Synthesis, characterization, DFT calculations, and reactivity study of a nitrido-bridged dimeric vanadium(iv) complex

Adriana Lugosan, Thomas Cundari, Kristin Fleming, Diane A. Dickie, Matthias Zeller, Jack Ghannam and Wei-Tsung Lee

Dalton Trans., 2020, 49, 1200
DOI: 10.1039/C9DT04544A

New opportunities for efficient N2 fixation by nanosheet photocatalysts

Hao Li, Chengliang Mao, Huan Shang, Zhiping Yang, Zhihui Ai and Lizhi Zhang

Nanoscale, 2018, 10, 15429
DOI: 10.1039/C8NR04277B

Defective ZrO2−x supported Ru nanoparticles as a Mott–Schottky photocatalyst for efficient ammonia synthesis under ambient conditions

Rong Fu, Yan Wang, Guangming Wang, Qingyun Zhan, Lili Zhang and Le Liu

Green Chem., 2023, 25, 8531
DOI: 10.1039/D3GC02130K

Towards H2O catalyzed N2-fixation over TiO2 doped Run clusters (n = 5, 6): a mechanistic and kinetic approach

Sourav Ghoshal, Anup Pramanik and Pranab Sarkar

Phys. Chem. Chem. Phys., 2021, 23, 1527
DOI: 10.1039/D0CP03507F

Oxygen-regulated carbon quantum dots as an efficient metal-free electrocatalyst for nitrogen reduction

Yaqian Han, Xiaoteng Ding, Jingrui Han, Yanfeng Fang, Zhaoyong Jin, Wenhan Kong and Chuangwei Liu

Nanoscale, 2022, 14, 9893
DOI: 10.1039/D2NR01551J

Deep eutectic-solvothermal synthesis of nanostructured Fe3S4 for electrochemical N2 fixation under ambient conditions

Xinhui Zhao, Xue Lan, Dongkun Yu, Hui Fu, Zhimin Liu and Tiancheng Mu

Chem. Commun., 2018, 54, 13010
DOI: 10.1039/C8CC08045C

Heterojunction-based photocatalytic nitrogen fixation: principles and current progress

Hassan Ali, Milan Masar, Ali Can Guler, Michal Urbanek, Michal Machovsky and Ivo Kuritka

Nanoscale Adv., 2021, 3, 6358
DOI: 10.1039/D1NA00565K

The effect of Ni(i)–N active sites on the photocatalytic H2O2 production ability over nickel doped graphitic carbon nitride nanofibers

Guang Wu, Shaozheng Hu, Zheng Han, Chuntao Liu and Qiang Li

New J. Chem., 2017, 41, 15289
DOI: 10.1039/C7NJ03298F

Boosting electrochemical nitrogen reduction reaction performance of two-dimensional Mo porphyrin monolayers via turning the coordination environment

Shiqiang Liu, Zhiwen Cheng, Yawei Liu, Xiaoping Gao, Yujia Tan, Yuanyang Ren and Zhemin Shen

Phys. Chem. Chem. Phys., 2021, 23, 4178
DOI: 10.1039/D0CP06036D

Anion (O, N, C, and S) vacancies promoted photocatalytic nitrogen fixation

Chengliang Mao, Jiaxian Wang, Yunjie Zou, Hao Li, Guangming Zhan, Jie Li, Jincai Zhao and Lizhi Zhang

Green Chem., 2019, 21, 2852
DOI: 10.1039/C9GC01010F

Regulation of the electronic structure of perovskites to improve the electrocatalytic performance for the nitrogen-reduction reaction

Yan Zhang, Jia-Zhi Wang, Kai Li, Miao-Miao Shi, Zi Wen, Meng-Gai Jiao and Di Bao

J. Mater. Chem. A, 2022, 10, 2819
DOI: 10.1039/D1TA10534E

Trimetallic clusters in the sumanene bowl for dinitrogen activation

Ya-Ya Wang, Xun-Lei Ding, Yan Chen, Meng-Meng Wang, Wei Li and Xin Wang

Phys. Chem. Chem. Phys., 2022, 24, 23265
DOI: 10.1039/D2CP03346A

Heterojunction photocatalysts for artificial nitrogen fixation: fundamentals, latest advances and future perspectives

Jiale Lee, Lling-Lling Tan and Siang-Piao Chai

Nanoscale, 2021, 13, 7011
DOI: 10.1039/D1NR00783A

Electrocatalytic nitrogen cycle: mechanism, materials, and momentum

Laiquan Li, Linyuan Xu, Hanyun Wang, Haohong Wei, Cheng Tang, Guisheng Li, Yuhai Dou, Hua Kun Liu and Shi Xue Dou

Energy Environ. Sci., 2024, 17, 9027
DOI: 10.1039/D4EE03156C

Insight into the surface property modification-enhanced C3N4 performance of photocatalytic nitrogen fixation

Wei Cai, Jian Cui, Kang Li, Zhicheng Zhang, Huifang Xie, Qin Zhong and Hongxia Qu

Chem. Commun., 2022, 58, 6502
DOI: 10.1039/D2CC01602H

Preparation and reactivity of iron complexes bearing anionic carbazole-based PNP-type pincer ligands toward catalytic nitrogen fixation

Junichi Higuchi, Shogo Kuriyama, Aya Eizawa, Kazuya Arashiba, Kazunari Nakajima and Yoshiaki Nishibayashi

Dalton Trans., 2018, 47, 1117
DOI: 10.1039/C7DT04327A

Au nanoparticle-embedded, nitrogen-deficient hollow mesoporous carbon nitride spheres for nitrogen photofixation

Yanzhen Guo, Jianhua Yang, Donghai Wu, Haoyuan Bai, Zhi Yang, Jianfang Wang and Baocheng Yang

J. Mater. Chem. A, 2020, 8, 16218
DOI: 10.1039/D0TA03793A

Pt-embedded in monolayer g-C3N4as a promising single-atom electrocatalyst for ammonia synthesis

Hui Yin, Shu-Long Li, Li-Yong Gan and Ping Wang

J. Mater. Chem. A, 2019, 7, 11908
DOI: 10.1039/C9TA01624D

Bonding and stability of dinitrogen-bonded donor base-stabilized Si(0)/Ge(0) species [(cAACMe–Si/Ge)2(N2)]: EDA-NOCV analysis

Harsha S. Karnamkkott, Sai Manoj N. V. T. Gorantla, Kavita Devi, Geetika Tiwari and Kartik Chandra Mondal

RSC Adv., 2022, 12, 4081
DOI: 10.1039/D1RA07714G

Fe3O4 nanostructure films as solar-thermal conversion materials for ammonia synthesis

Rong Fu, Di Lei, Zhenlu Li, Hangjian Zhang, Xiaofei Zhao and Shuo Tao

Chem. Commun., 2024, 60, 13055
DOI: 10.1039/D4CC04112G

Nitrogen fixation catalyzed by ferrocene-substituted dinitrogen-bridged dimolybdenum–dinitrogen complexes: unique behavior of ferrocene moiety as redox active site

Shogo Kuriyama, Kazuya Arashiba, Kazunari Nakajima, Hiromasa Tanaka, Kazunari Yoshizawa and Yoshiaki Nishibayashi

Chem. Sci., 2015, 6, 3940
DOI: 10.1039/C5SC00545K

Ti3C2Tx(T = F, OH) MXene nanosheets: conductive 2D catalysts for ambient electrohydrogenation of N2to NH3

Jinxiu Zhao, Lei Zhang, Xiao-Ying Xie, Xianghong Li, Yongjun Ma, Qian Liu, Wei-Hai Fang, Xifeng Shi, Ganglong Cui and Xuping Sun

J. Mater. Chem. A, 2018, 6, 24031
DOI: 10.1039/C8TA09840A

Theoretical and experimental progress of metal electrocatalysts for the nitrogen reduction reaction

Shishi Zhang, Xiaoxue Zhang, Chengguang Liu, Lun Pan, Chengxiang Shi, Xiangwen Zhang, Zhen-Feng Huang and Ji-Jun Zou

Mater. Chem. Front., 2023, 7, 643
DOI: 10.1039/D2QM01061E

Single transition metal atom embedded into a MoS2 nanosheet as a promising catalyst for electrochemical ammonia synthesis

Jia Zhao, Jingxiang Zhao and Qinghai Cai

Phys. Chem. Chem. Phys., 2018, 20, 9248
DOI: 10.1039/C7CP08626A

A comparative study on the reactivity of ditantalum deuteride cluster anions Ta2D2− and Ta2D4− toward N2

Xin Cheng, Zi-Yu Li, Li-Hui Mou, Qing-Yu Liu and Sheng-Gui He

Phys. Chem. Chem. Phys., 2022, 24, 24950
DOI: 10.1039/D2CP02248F

Ag nanoparticles modified hollow tubular In2O3 for enhanced photocatalytic nitrogen reduction to ammonia

Yang Yang, Mengyao Tan, Xiaoman Li and Min Luo

New J. Chem., 2025, 49, 4580
DOI: 10.1039/D4NJ05447D

Recent advances in material design and reactor engineering for electrocatalytic ambient nitrogen fixation

Tariq Ali, Niaz Muhammad, Yijin Qian, Sisi Liu, Sai Wang, Mengfan Wang, Tao Qian and Chenglin Yan

Mater. Chem. Front., 2022, 6, 843
DOI: 10.1039/D1QM01620B

Challenges in reduction of dinitrogen by proton and electron transfer

Cornelis J. M. van der Ham, Marc T. M. Koper and Dennis G. H. Hetterscheid

Chem. Soc. Rev., 2014, 43, 5183
DOI: 10.1039/C4CS00085D

Reactivity of hydride bridges in a high-spin [Fe3(μ-H)3]3+ cluster: reversible H2/CO exchange and Fe–H/B–F bond metathesis

Kevin J. Anderton, Brian J. Knight, Arnold L. Rheingold, Khalil A. Abboud, Ricardo García-Serres and Leslie J. Murray

Chem. Sci., 2017, 8, 4123
DOI: 10.1039/C6SC05583D

W supported on g-CN manifests high activity and selectivity for N2electroreduction to NH3

Shuhua Wang, Wei Wei, Xingshuai Lv, Baibiao Huang and Ying Dai

J. Mater. Chem. A, 2020, 8, 1378
DOI: 10.1039/C9TA10935H

An arene-tethered silylene ligand enabling reversible dinitrogen binding to iron and catalytic silylation

Yunping Bai, Jianying Zhang and Chunming Cui

Chem. Commun., 2018, 54, 8124
DOI: 10.1039/C8CC03734E

Insights on hydrogen spillover on carbonaceous supports

Adi M. Moyal, Ofra Paz-Tal, Eyal Ben-Yehuda, Pietro Moretto, Marek Bielewski, Emilio Napolitano, Michael Gozin and Svetlana Pevzner

Nanoscale, 2022, 14, 9068
DOI: 10.1039/D2NR02067J

Performance of the nitrogen reduction reaction on metal bound g-C6N6: a combined approach of machine learning and DFT

Moumita Mukherjee, Sayan Dutta, Madhusudan Ghosh, Partha Basuchowdhuri and Ayan Datta

Phys. Chem. Chem. Phys., 2022, 24, 17050
DOI: 10.1039/D2CP01901A

Atomic Ru clusters supported on CeO2(110) for effectively catalyzing the electrochemical N2 reduction reaction: insights from density functional theory

Heng Cao and Shulan Zhou

New J. Chem., 2024, 48, 5919
DOI: 10.1039/D4NJ00210E

Ambient electrochemical N2 reduction to NH3 under alkaline conditions enabled by a layered K2Ti4O9 nanobelt

Dan Wu, Huanbo Wang, Hong Huang, Rong Zhang, Lei Ji, Hongyu Chen, Yonglan Luo, Jinmao You, Dianping Tang, Zhonghai Zhang and Xuping Sun

Chem. Commun., 2019, 55, 7546
DOI: 10.1039/C9CC02409C

Coupling of terminal iridium nitrido complexes

Josh Abbenseth, Markus Finger, Christian Würtele, Müge Kasanmascheff and Sven Schneider

Inorg. Chem. Front., 2016, 3, 469
DOI: 10.1039/C5QI00267B

A perspective on the future of electrochemical ammonia synthesis: aqueous or non-aqueous?

Divyani Gupta, Alankar Kafle, Sukhjot Kaur and Tharamani C. Nagaiah

J. Mater. Chem. A, 2023, 11, 22132
DOI: 10.1039/D3TA05136F

Correlation between the structural features and intrinsic activity trend of Fe surfaces for ammonia synthesis

Jianfu Chen, Ye Chen, Haifeng Wang and P. Hu

Catal. Sci. Technol., 2023, 13, 5237
DOI: 10.1039/D3CY00462G

Photocatalytic reaction mechanisms at the gas–solid interface for environmental and energy applications

Lei Xiao, Peng Chen, Weiping Yang, Xiaoli Zhao and Fan Dong

Catal. Sci. Technol., 2021, 11, 7807
DOI: 10.1039/D1CY01776D

Efficient photocatalytic nitrogen fixation under ambient conditions enabled by the heterojunctions of n-type Bi2MoO6 and oxygen-vacancy-rich p-type BiOBr

Xiaolan Xue, Renpeng Chen, Changzeng Yan, Yi Hu, Wenjun Zhang, Songyuan Yang, Lianbo Ma, Guoyin Zhu and Zhong Jin

Nanoscale, 2019, 11, 10439
DOI: 10.1039/C9NR02279A

Electron repulsion tuned electronic structure of TiO2 by fluorination for efficient and selective photocatalytic ammonia generation

Huiling Zhu, Xiangran Xu, Yongchao Wang, Jian Ding, Xinru Yu, Xiaoyi Liu, Zhaowu Zeng, Huan Wang, Zhen Li and Yang Wang

Nanoscale, 2024, 16, 12992
DOI: 10.1039/D4NR01787K

Effect of substituents on molybdenum triiodide complexes bearing PNP-type pincer ligands toward catalytic nitrogen fixation

Takayuki Itabashi, Ikki Mori, Kazuya Arashiba, Aya Eizawa, Kazunari Nakajima and Yoshiaki Nishibayashi

Dalton Trans., 2019, 48, 3182
DOI: 10.1039/C8DT04975K

Strategies to activate inert nitrogen molecules for efficient ammonia electrosynthesis: current status, challenges, and perspectives

Yongwen Ren, Chang Yu, Xinyi Tan, Qianbing Wei, Zhao Wang, Lin Ni, Linshan Wang and Jieshan Qiu

Energy Environ. Sci., 2022, 15, 2776
DOI: 10.1039/D2EE00358A

Electrocatalytic nitrogen reduction: mechanisms, system-level optimization, and future perspectives

Zichao Chen, Xueyao Meng, Guanze Su, Ning Wang, Li-Li Zhang, Hao Wan, Renzhi Ma, Wei Ma and Zhen Zhou

Nanoscale, 2025, 17, 16100
DOI: 10.1039/D5NR01582K

Comprehensive insights into synthetic nitrogen fixation assisted by molecular catalysts under ambient or mild conditions

Yoshiaki Tanabe and Yoshiaki Nishibayashi

Chem. Soc. Rev., 2021, 50, 5201
DOI: 10.1039/D0CS01341B

Photofixation of N2 to ammonia utilizing Ni@TPP–HPA nanocomposite under visible-light illumination

Shahrbanoo Rostami, Reza Tayebee and Behnam Mahdavi

RSC Adv., 2023, 13, 31303
DOI: 10.1039/D3RA03921H

Rational design of electrocatalysts and photo(electro)catalysts for nitrogen reduction to ammonia (NH3) under ambient conditions

Chunxian Guo, Jingrun Ran, Anthony Vasileff and Shi-Zhang Qiao

Energy Environ. Sci., 2018, 11, 45
DOI: 10.1039/C7EE02220D

Synthesis and reactivity of titanium- and zirconium-dinitrogen complexes bearing anionic pyrrole-based PNP-type pincer ligands

Yoshiya Sekiguchi, Fanqiang Meng, Hiromasa Tanaka, Aya Eizawa, Kazuya Arashiba, Kazunari Nakajima, Kazunari Yoshizawa and Yoshiaki Nishibayashi

Dalton Trans., 2018, 47, 11322
DOI: 10.1039/C8DT02739K

Light-driven nitrogen fixation routes for green ammonia production

Laura Collado, Alejandro H. Pizarro, Mariam Barawi, Miguel García-Tecedor, Marta Liras and Víctor A. de la Peña O'Shea

Chem. Soc. Rev., 2024, 53, 11334
DOI: 10.1039/D3CS01075A

Electrochemical C–N coupling of CO2and nitrogenous small molecules for the electrosynthesis of organonitrogen compounds

Xianyun Peng, Libin Zeng, Dashuai Wang, Zhibin Liu, Yan Li, Zhongjian Li, Bin Yang, Lecheng Lei, Liming Dai and Yang Hou

Chem. Soc. Rev., 2023, 52, 2193
DOI: 10.1039/D2CS00381C

Adsorption mechanism of the N2 and NRR intermediates on oxygen modified MnN4–graphene layers – a single atom catalysis perspective

A. E. Genç and I. C. Tranca

Phys. Chem. Chem. Phys., 2023, 25, 18465
DOI: 10.1039/D2CP05491D

Inorganic clusters with a [Fe2MoOS3] core—a functional model for acetylene reduction by nitrogenases

Koji Yoshimoto, Takeshi Yatabe, Takahiro Matsumoto, Viet-Ha Tran, Andrew Robertson, Hidetaka Nakai, Koichiro Asazawa, Hirohisa Tanaka and Seiji Ogo

Dalton Trans., 2016, 45, 14620
DOI: 10.1039/C6DT01655C

Photoredox catalysis over graphene aerogel-supported composites

Kang-Qiang Lu, Xin Xin, Nan Zhang, Zi-Rong Tang and Yi-Jun Xu

J. Mater. Chem. A, 2018, 6, 4590
DOI: 10.1039/C8TA00728D

Electrochemical N2 fixation to NH3 under ambient conditions: porous LiFe5O8 nanoparticle–reduced graphene oxide as a highly efficient and selective catalyst

Yuyao Ji, Lei Li, Wendong Cheng, Yu Xiao, Chengbo Li and Xingquan Liu

Inorg. Chem. Front., 2021, 8, 3156
DOI: 10.1039/D1QI00419K

When iron met phosphines: a happy marriage for reduction catalysis

Luis C. Misal Castro, Haoquan Li, Jean-Baptiste Sortais and Christophe Darcel

Green Chem., 2015, 17, 2283
DOI: 10.1039/C4GC01866D

Synthesis and reactivity of iron–dinitrogen complexes bearing anionic methyl- and phenyl-substituted pyrrole-based PNP-type pincer ligands toward catalytic nitrogen fixation

Yoshiya Sekiguchi, Shogo Kuriyama, Aya Eizawa, Kazuya Arashiba, Kazunari Nakajima and Yoshiaki Nishibayashi

Chem. Commun., 2017, 53, 12040
DOI: 10.1039/C7CC06987A

Electrochemical ammonia synthesis: fundamental practices and recent developments in transition metal boride, carbide and nitride-class of catalysts

Ashmita Biswas, Sakshi Bhardwaj, Tribani Boruah and Ramendra Sundar Dey

Mater. Adv., 2022, 3, 5207
DOI: 10.1039/D2MA00279E

Insights into small molecule activation by multinuclear first-row transition metal cyclophanates

David M. Ermert and Leslie J. Murray

Dalton Trans., 2016, 45, 14499
DOI: 10.1039/C6DT01857B

The journey of iron-based electrocatalytic materials for nitrogen reduction reaction: from current status to future prospects

Yi-Han Wang, Ji-Hong Dong, Zhenquan Tan, Xiao-Feng Wang and Xue-Zhi Song

J. Mater. Chem. A, 2023, 11, 11048
DOI: 10.1039/D3TA01548C

Structural characterization of molybdenum–dinitrogen complex as key species toward ammonia formation by dispersive XAFS spectroscopy

Akira Yamamoto, Kazuya Arashiba, Shimpei Naniwa, Kazuo Kato, Hiromasa Tanaka, Kazunari Yoshizawa, Yoshiaki Nishibayashi and Hisao Yoshida

Phys. Chem. Chem. Phys., 2020, 22, 12368
DOI: 10.1039/C9CP06761B

Synthesis of highly twinned ZnSe nanorods for enhancing N2electrochemical conversion to NH3

Kangwen Qiu, Yuning Han, Wenbo Guo, Licun Wang, Jinbing Cheng and Yongsong Luo

Chem. Commun., 2023, 59, 2465
DOI: 10.1039/D2CC06776E

Dinitrogen functionalization at a ditantalum center. Balancing N2displacement and N2functionalization in the reaction of coordinated N2with CS2

Richard J. Burford, Ludovic Castro, Laurent Maron, Jason E. Hein and Michael D. Fryzuk

Dalton Trans., 2018, 47, 7983
DOI: 10.1039/C8DT01615A

Modulating oxygen vacancies of CeO2 nanospheres by Zn-doping: an efficient electrocatalyst for N2 reduction under ambient conditions

Yuyao Ji, Mingyu Yang, Wendong Cheng, Chengbo Li and Xingquan Liu

Energy Adv., 2022, 1, 868
DOI: 10.1039/D2YA00241H

Emerging two-dimensional nanomaterials for electrochemical nitrogen reduction

Yingping Pang, Chao Su, Guohua Jia, Liqiang Xu and Zongping Shao

Chem. Soc. Rev., 2021, 50, 12744
DOI: 10.1039/D1CS00120E

Single-atom and cluster catalysts for thermocatalytic ammonia synthesis at mild conditions

Xuanbei Peng, Mingyuan Zhang, Tianhua Zhang, Yanliang Zhou, Jun Ni, Xiuyun Wang and Lilong Jiang

Chem. Sci., 2024, 15, 5897
DOI: 10.1039/D3SC06998B

Advancements in dinitrogen activation for catalytic breakthroughs

Vamsi Vikram Gande, Nishithan C. Kani, Ishita Goyal, Rohit Chauhan, Yancun Qi, Samuel A. Olusegun, Joseph A. Gauthier and Meenesh R. Singh

EES Catal., 2025, 3, 883
DOI: 10.1039/D5EY00033E

AB5-type intermetallic compounds as catalysts for ammonia synthesis

Xi Chen, Yichen Duan, Jing Wang, Xinhai Yuan, Lili Liu, Yuhui Chen, Lijun Fu and Yuping Wu

J. Mater. Chem. A, 2025, 13, 24824
DOI: 10.1039/D5TA02005K

High-efficiency electrocatalyst for N2 conversion to NH3 based on Au nanoparticles loaded on defective WO3−x

Youzeng Li, Pengfei Yan, Jun Chen, Yumei Ren, Yannan Zhou, Tianpei Ge, Jun Chen and Qun Xu

Chem. Commun., 2019, 55, 13307
DOI: 10.1039/C9CC06550D

High Néel temperature and magnetism modulation in 2D pentagon-based XN2 (X = B, Al, and Ga) structures with spin-polarized non-metallic atoms

Zhenyu Wu and Hong Zhang

Phys. Chem. Chem. Phys., 2025, 27, 2968
DOI: 10.1039/D4CP04582C

Support effect boosting the electrocatalytic N2 reduction activity of Ni2P/N,P-codoped carbon nanosheet hybrids

Menglei Yuan, Honghua Zhang, Denglei Gao, Hongyan He, Yu Sun, Peilong Lu, Sobia Dipazir, Qiongguang Li, Le Zhou, Shuwei Li, Zhanjun Liu, Junhan Yang, Yongbing Xie, He Zhao and Guangjin Zhang

J. Mater. Chem. A, 2020, 8, 2691
DOI: 10.1039/C9TA09920D

Plasma-promoted reactions of the heterobimetallic anions CuNb− with dinitrogen and subsequent reactions with carbon dioxide: formation of C–N bonds

Lan-Ye Chu, Yong-Qi Ding, Ming Wang and Jia-Bi Ma

Phys. Chem. Chem. Phys., 2022, 24, 14333
DOI: 10.1039/D2CP01817A

Where silylene–silicon centres matter in the activation of small molecules

Changkai Shan, Shenglai Yao and Matthias Driess

Chem. Soc. Rev., 2020, 49, 6733
DOI: 10.1039/D0CS00815J

Indium sulfide nanotubes with sulfur vacancies as an efficient photocatalyst for nitrogen fixation

Zhiyi He, Yu Wang, Xiaoli Dong, Nan Zheng, Hongchao Ma and Xiufang Zhang

RSC Adv., 2019, 9, 21646
DOI: 10.1039/C9RA03507A

Elongated heterometal double-sites promote nitrogen reduction on two-dimensional MM′B7 monolayers

Changyan Zhu, Chaoxia Wen, Cong Wang, Min Zhang, Yun Geng and Zhongmin Su

J. Mater. Chem. A, 2021, 9, 10855
DOI: 10.1039/D1TA01796A

PdP2 nanoparticles–reduced graphene oxide for electrocatalytic N2 conversion to NH3 under ambient conditions

Hongtao Xie, Qin Geng, Xiaojuan Zhu, Yonglan Luo, Le Chang, Xiaobin Niu, Xifeng Shi, Abdullah M. Asiri, Shuyan Gao, Zhiming Wang and Xuping Sun

J. Mater. Chem. A, 2019, 7, 24760
DOI: 10.1039/C9TA09910G

Photon localization effect and surface oxygen vacancy enhanced photocatalytic nitrogen fixation performance for nanocrystalline titanium dioxide films

Sheng Chen, Ying-Min Xu, Ji-Nan He, Sheng-Li Chen and Ai-Jun Wang

New J. Chem., 2023, 47, 14494
DOI: 10.1039/D3NJ02585C

Steric hindrance-induced selective growth of rhodium on gold nanobipyramids for plasmon-enhanced nitrogen fixation

Henglei Jia, Fan Li, Yuanyuan Yang, Mengxuan Zhao, Jingzhao Li and Chun-yang Zhang

Chem. Sci., 2023, 14, 5656
DOI: 10.1039/D3SC00081H

Efficient full-spectrum driven ammonia synthesis over heterostructured TiO2 nanosheet arrays

Xiaowei Mu, Shuang Cai, Rong Fu, Yumeng Qian, Ziye Pan and Lu Li

Chem. Commun., 2022, 58, 278
DOI: 10.1039/D1CC06489D

Metal-free electrocatalyst for reducing nitrogen to ammonia using a Lewis acid pair

Li Shi, Qiang Li, Chongyi Ling, Yehui Zhang, Yixin Ouyang, Xiaowan Bai and Jinlan Wang

J. Mater. Chem. A, 2019, 7, 4865
DOI: 10.1039/C8TA11025E

Dual-phase B-doped FeCoNiCuPd high-entropy alloys for nitrogen electroreduction to ammonia

Yankun Wen, Wenchao Zhang, Xiaofan Wang, Shuanglong Lu, Fang Duan, Han Zhu and Mingliang Du

Chem. Commun., 2023, 59, 13371
DOI: 10.1039/D3CC04581A

Graphdiyne coordinated transition metals as single-atom catalysts for nitrogen fixation

Zhen Feng, Yanan Tang, Weiguang Chen, Yi Li, Renyi Li, Yaqiang Ma and Xianqi Dai

Phys. Chem. Chem. Phys., 2020, 22, 9216
DOI: 10.1039/D0CP00722F

MXene-derived TiO2@C/g-C3N4 heterojunctions for highly efficient nitrogen photofixation

Qiuxia Liu, Lunhong Ai and Jing Jiang

J. Mater. Chem. A, 2018, 6, 4102
DOI: 10.1039/C7TA09350K

MXene─A New Paradigm Toward Artificial Nitrogen Fixation for Sustainable Ammonia Generation: Synthesis, Properties, and Future Outlook

Steven Hao Wan Kok, Jiale Lee, Lling-Lling Tan, Wee-Jun Ong and Siang-Piao Chai

ACS Materials Lett., 2022, 4, 212
DOI: 10.1021/acsmaterialslett.1c00673

Hydrides mediate nitrogen fixation

Qianru Wang, Yeqin Guan, Jianping Guo and Ping Chen

Cell Reports Physical Science, 2022, 3, 100779
DOI: 10.1016/j.xcrp.2022.100779

ZrO2/C Nanosphere Enables High‐Efficiency Nitrogen Reduction to Ammonia at Ambient Conditions

Shuyue Dong, Jiaojiao Xia, Hexin Zhu, Xiangning Du, Yang Gu, Qian Liu, Yonglan Luo, Qingquan Kong, Haoran Guo, Tingshuai Li and Enrico Traversa

ChemCatChem, 2022, 14
DOI: 10.1002/cctc.202200458

CuCo2S4 integrated multiwalled carbon nanotube as high-performance electrocatalyst for electroreduction of nitrogen to ammonia

Hongwei Li, Ting-Ting Li, Jinjie Qian, Yan Mei and Yue-Qing Zheng

International Journal of Hydrogen Energy, 2020, 45, 14640
DOI: 10.1016/j.ijhydene.2020.03.198

Sustainable Nitrogen Photofixation Promoted by Carbon Nitride Supported Bimetallic RuPd Nanoparticles under Mild Conditions

Iago F. de Sá, Pedro H. P. R. Carvalho, Higor A. Centurion, Renato V. Gonçalves and Jackson D. Scholten

ACS Sustainable Chem. Eng., 2021, 9, 8721
DOI: 10.1021/acssuschemeng.1c00977

Bimetallic MIL-68(InFe) MOF nanorods for biomimetic photocatalytic N2 fixation

Cheng Liu, Mengning Chen, Yueling Chen, Qi Chen, Jionghua Wu, Sen Lin, Ling Wu and Jimmy C. Yu

Chemical Engineering Journal, 2024, 498, 155646
DOI: 10.1016/j.cej.2024.155646

Reactivity of Dinitrogen Bound to Mid‐ and Late‐Transition‐Metal Centers

Nitesh Khoenkhoen, Bas de Bruin, Joost N. H. Reek and Wojciech I. Dzik

Eur J Inorg Chem, 2015, 2015, 567
DOI: 10.1002/ejic.201403041

Electrocatalytic Reduction of Nitrogen to Ammonia Using Tiara‐like Phenylethanethiolated Nickel Cluster

Manju P. Maman, Tamilselvi Gurusamy, Arun K. Pal, Rajkumar Jana, Kothandaraman Ramanujam, Ayan Datta and Sukhendu Mandal

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202305462

How thermal fluctuations influence the function of the FeMo cofactor in nitrogenase enzymes

Wan-Lu Li, Yong Li, Jun Li and Teresa Head-Gordon

Chem Catalysis, 2023, 3, 100662
DOI: 10.1016/j.checat.2023.100662

Fabrication of In2O3/In2S3 microsphere heterostructures for efficient and stable photocatalytic nitrogen fixation

Huichang Xu, Yu Wang, Xiaoli Dong, Nan Zheng, Hongchao Ma and Xiufang Zhang

Applied Catalysis B: Environmental, 2019, 257, 117932
DOI: 10.1016/j.apcatb.2019.117932

Analysis of nitrogen fixation by a catalyst capable of transforming N2, CO2 and CH4 into amino acids under mild reactions conditions

Guillermo Revilla-López, Jordi Sans, Jordi Casanovas, Oscar Bertran, Jordi Puiggalí, Pau Turon and Carlos Alemán

Applied Catalysis A: General, 2020, 596, 117526
DOI: 10.1016/j.apcata.2020.117526

Catalytic Formation of Ammonia from Molecular Dinitrogen by Use of Dinitrogen-Bridged Dimolybdenum–Dinitrogen Complexes Bearing PNP-Pincer Ligands: Remarkable Effect of Substituent at PNP-Pincer Ligand

Shogo Kuriyama, Kazuya Arashiba, Kazunari Nakajima, Hiromasa Tanaka, Nobuaki Kamaru, Kazunari Yoshizawa and Yoshiaki Nishibayashi

J. Am. Chem. Soc., 2014, 136, 9719
DOI: 10.1021/ja5044243

Coupling Ru single-atom and oxygen vacancy in Ru/SnO2−x for efficient nitrogen reduction to ammonia via electronic synergistic effect

Jiaqi Zheng, Kaiqiang Yu, Shisheng Yuan, Lijuan Xiang, Kaiwen Wang, Shubo Jing and Nan Li

Journal of Alloys and Compounds, 2023, 962, 171028
DOI: 10.1016/j.jallcom.2023.171028

Oxygen Vacancies in Ta2O5 Nanorods for Highly Efficient Electrocatalytic N2 Reduction to NH3 under Ambient Conditions

Wenzhi Fu, Peiyuan Zhuang, Mason OliverLam Chee, Pei Dong, Mingxin Ye and Jianfeng Shen

ACS Sustainable Chem. Eng., 2019, 7, 9622
DOI: 10.1021/acssuschemeng.9b01178

Emerging electrocatalysts for green ammonia production: Recent progress and future outlook

Sajid Mahmood, Shahid Iqbal, Zeping Wang, Muhammad Ammar, Muhammad Javed Iqbal, Ali Bahadur, Nasser S. Awwad and Hala A. Ibrahium

Arabian Journal of Chemistry, 2024, 17, 105950
DOI: 10.1016/j.arabjc.2024.105950

Recent Advances in Nonprecious Metal Oxide Electrocatalysts and Photocatalysts for N2 Reduction Reaction under Ambient Condition

Tong Xu, Jie Liang, Shaoxiong Li, Zhaoquan Xu, Luchao Yue, Tingshuai Li, Yonglan Luo, Qian Liu, Xifeng Shi, Abdullah M. Asiri, Chun Yang and Xuping Sun

Small Science, 2021, 1
DOI: 10.1002/smsc.202000069

High-throughput screening of single-atom catalysts confined in monolayer black phosphorus for efficient nitrogen reduction reaction

Xiao-Yan Li, Manyi Duan and Pengfei Ou

Nano Res., 2024, 17, 2360
DOI: 10.1007/s12274-023-6068-1

Amelioration of enteric dysbiosis by polyoxotungstates in mice gut

Kun Chen, Yuan Liu, Mu Li, Lu Liu, Qiang Yu and Long Wu

Journal of Inorganic Biochemistry, 2022, 226, 111654
DOI: 10.1016/j.jinorgbio.2021.111654

Molybdenum bound nitrogen‐doped graphene catalyst for reduction of N2 to NH3 and NH2NH2, using FLP as a co‐catalyst: A DFT study

Akhil K. Sivan, Jisha Mary Thomas, Thayalaraj Christopher Jeyakumar and Chinnappan Sivasankar

Applied Organom Chemis, 2022, 36
DOI: 10.1002/aoc.6644

Recent progress in Pd based electrocatalysts for electrochemical nitrogen reduction to ammonia

Shehman Assad, Tayyeba Tariq, Muhammad Zaeem Idrees, Abdul Mannan Butt, Khush Bakhat and Umair Shamraiz

Journal of Electroanalytical Chemistry, 2023, 931, 117174
DOI: 10.1016/j.jelechem.2023.117174

Coupled Cluster Study of the Interactions of AnO2, AnO2+, and AnO22+ (An = U, Np) with N2 and CO

Rulin Feng, Eric D. Glendening and Kirk A. Peterson

Inorg. Chem., 2020, 59, 4753
DOI: 10.1021/acs.inorgchem.9b03759

Investigation into the mechanism of electrochemical nitrogen reduction reaction to ammonia using niobium oxynitride thin-film catalysts

Fatemeh Hanifpour, Camila P. Canales, Emil G. Fridriksson, Arnar Sveinbjörnsson, Tryggvi K. Tryggvason, Erik Lewin, Fridrik Magnus, Árni S. Ingason, Egill Skúlason and Helga D. Flosadóttir

Electrochimica Acta, 2022, 403, 139551
DOI: 10.1016/j.electacta.2021.139551

Boron-Enriched Benzene Boronic Acid Based Hyper-Cross-Linked Polymer for Selective Electrocatalytic N2 Reduction to Ammonia

Sachin Balhara, Ruchi Sharma, Shubham Sharma and Paritosh Mohanty

ACS Appl. Polym. Mater., 2024, 6, 6393
DOI: 10.1021/acsapm.4c00594

Significant enhancement of nitrogen photofixation to ammonia and hydrogen storage by a MIL-53 (Fe) based novel plasmonic nanocatalysis at ambient condition

Soheila Sharafinia, Rouein Halladj and Alimorad Rashidi

Sci Rep, 2025, 15
DOI: 10.1038/s41598-025-96079-3

Effective N2 activation strategies for electrochemical ammonia synthesis

Minghang Jiang, Xi Chen, Fasheng Chen, Mengjun Wang, Xiaojun Luo, Yi He, Caijun Wu, Liyun Zhang, Xiao Li, Xuemei Liao, Zhenju Jiang and Zhong Jin

Chem, 2025, 11, 102441
DOI: 10.1016/j.chempr.2025.102441

Photo‐Assisted Li‐N2 Batteries with Enhanced Nitrogen Fixation and Energy Conversion

Jian‐You Li, Xing‐Yuan Du, Xiao‐Xue Wang, Xin‐Yuan Yuan, De‐Hui Guan and Ji‐Jing Xu

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202319211

Recent progress in research and design concepts for the characterization, testing, and photocatalysts for nitrogen reduction reaction

Benteng Sun, Shucao Lu, Yeye Qian, Xiaoli Zhang and Jian Tian

Carbon Energy, 2023, 5
DOI: 10.1002/cey2.305

Late Metal Scaffolds that Activate Both, Dinitrogen and Reduced Dinitrogen Species NxHy

Claudia Köthe and Christian Limberg

Zeitschrift anorg allge chemie, 2015, 641, 18
DOI: 10.1002/zaac.201400378

Graphene Derivatives and Graphene Composite Electrocatalysts for N2 Reduction Reaction

Fei Wang, Limin Mao, Hongtao Xie and Jian Mao

Small Structures, 2021, 2
DOI: 10.1002/sstr.202000075

Rational Design of Fe–N/C Hybrid for Enhanced Nitrogen Reduction Electrocatalysis under Ambient Conditions in Aqueous Solution

Ying Wang, Xiaoqiang Cui, Jingxiang Zhao, Guangri Jia, Lin Gu, Qinghua Zhang, Lingkun Meng, Zhan Shi, Lirong Zheng, Chunyu Wang, Ziwei Zhang and Weitao Zheng

ACS Catal., 2019, 9, 336
DOI: 10.1021/acscatal.8b03802

Photoexcited Electron Dynamics of Nitrogen Fixation Catalyzed by Ruthenium Single-Atom Catalysts

Xiaoyou Niu, Qing Zhu, Shenlong Jiang and Qun Zhang

J. Phys. Chem. Lett., 2020, 11, 9579
DOI: 10.1021/acs.jpclett.0c02833

Progress in design and application research of nitrogen carrier in chemical looping ammonia synthesis technology

Zhouting GONG, Tan ZHANG, Na LI, Yanyan YANG, Shoujun IU, Jie ZHENG, Zhongliang YU and Song ANG

Journal of Fuel Chemistry and Technology, 2024, 52, 512
DOI: 10.1016/S1872-5813(23)60397-4

Production of Liquid Solar Fuels and Their Use in Fuel Cells

Shunichi Fukuzumi

Joule, 2017, 1, 689
DOI: 10.1016/j.joule.2017.07.007

Experimental and Theoretical Study of N2 Adsorption on Hydrogenated Y2C4H− and Dehydrogenated Y2C4− Cluster Anions at Room Temperature

Min Gao, Yong-Qi Ding and Jia-Bi Ma

IJMS, 2022, 23, 6976
DOI: 10.3390/ijms23136976

Identification of M‐NH2‐NH2 Intermediate and Rate Determining Step for Nitrogen Reduction with Bioinspired Sulfur‐Bonded FeW Catalyst

Yilong Zhao, Fusheng Li, Wenlong Li, Yingzheng Li, Chang Liu, Ziqi Zhao, Yu Shan, Yongfei Ji and Licheng Sun

Angew Chem Int Ed, 2021, 60, 20331
DOI: 10.1002/anie.202104918

Triggering surface oxygen vacancies on atomic layered molybdenum dioxide for a low energy consumption path toward nitrogen fixation

Gong Zhang, Qinghua Ji, Kai Zhang, Yu Chen, Zhaohui Li, Huijuan Liu, Jinghong Li and Jiuhui Qu

Nano Energy, 2019, 59, 10
DOI: 10.1016/j.nanoen.2019.02.028

Fundamentals, Applications, and Future Directions of Bioelectrocatalysis

Hui Chen, Olja Simoska, Koun Lim, Matteo Grattieri, Mengwei Yuan, Fangyuan Dong, Yoo Seok Lee, Kevin Beaver, Samali Weliwatte, Erin M. Gaffney and Shelley D. Minteer

Chem. Rev., 2020, 120, 12903
DOI: 10.1021/acs.chemrev.0c00472

Metal-free electrocatalysts for nitrogen reduction reaction

Wenqing Zhang, Jingxiang Low, Ran Long and Yujie Xiong

EnergyChem, 2020, 2, 100040
DOI: 10.1016/j.enchem.2020.100040

Li-intercalation boosted oxygen vacancies enable efficient electrochemical nitrogen reduction on ultrathin TiO2 nanosheets

Renna Zhao, Guangbin Wang, Yuyin Mao, Xiaolei Bao, Zeyan Wang, Peng Wang, Yuanyuan Liu, Zhaoke Zheng, Ying Dai, Hefeng Cheng and Baibiao Huang

Chemical Engineering Journal, 2022, 430, 133085
DOI: 10.1016/j.cej.2021.133085

An Amorphous Noble‐Metal‐Free Electrocatalyst that Enables Nitrogen Fixation under Ambient Conditions

Chade Lv, Chunshuang Yan, Gang Chen, Yu Ding, Jingxue Sun, Yansong Zhou and Guihua Yu

Angewandte Chemie, 2018, 130, 6181
DOI: 10.1002/ange.201801538

Interplay of Alkali, Transition Metals, Nitrogen, and Hydrogen in Ammonia Synthesis and Decomposition Reactions

Jianping Guo and Ping Chen

Acc. Chem. Res., 2021, 54, 2434
DOI: 10.1021/acs.accounts.1c00076

ChemInform Abstract: Mechanistic Aspects of Dinitrogen Cleavage and Hydrogenation to Produce Ammonia in Catalysis and Organometallic Chemistry: Relevance of Metal Hydride Bonds and Dihydrogen

Hong‐Peng Jia and Elsje Alessandra Quadrelli

ChemInform, 2014, 45
DOI: 10.1002/chin.201417260

Heterogeneous electrocatalysts design for nitrogen reduction reaction under ambient conditions

Yuchi Wan, Jichu Xu and Ruitao Lv

Materials Today, 2019, 27, 69
DOI: 10.1016/j.mattod.2019.03.002

Establishing theoretical landscapes of identifying electrocatalysts for urea synthesis via dispersed dual-metals anchored on Ti2CO2 MXene

Jinyou Zhong, Dongyue Gao, Zhe Liu, Yadong Yu, Chao Yu, Yi Fang, Jing Lin, Chengchun Tang and Zhonglu Guo

Fuel, 2024, 366, 131280
DOI: 10.1016/j.fuel.2024.131280

Photocatalytic N2 Reduction: Uncertainties in the Determination of Ammonia Production

Qiong Liu, Jianglu Yuan, Zhiwen Gan, Cheng Liu, Jun Li, Ying Liang and Rong Chen

ACS Sustainable Chem. Eng., 2021, 9, 560
DOI: 10.1021/acssuschemeng.0c08064

Recent advances and challenges of nitrogen/nitrate electro catalytic reduction to ammonia synthesis

Junwen Cao, Yikun Hu, Yun Zheng, Wenqiang Zhang and Bo Yu

Front. Energy, 2024, 18, 128
DOI: 10.1007/s11708-023-0908-2

Access to Metal Centers and Fluxional Hydride Coordination Integral for CO2 Insertion into [Fe3(μ-H)3]3+ Clusters

Dae Ho Hong, Ricardo B. Ferreira, Vincent J. Catalano, Ricardo García-Serres, Jason Shearer and Leslie J. Murray

Inorg. Chem., 2021, 60, 7228
DOI: 10.1021/acs.inorgchem.1c00244

In Situ Characterization Techniques for Electrochemical Nitrogen Reduction Reaction

Jing Wu, Suxi Wang, Rong Ji, Dan Kai, Junhua Kong, Songlin Liu, Warintorn Thitsartarn, Beng Hoon Tan, Ming Hui Chua, Jianwei Xu, Xian Jun Loh, Qingyu Yan and Qiang Zhu

ACS Nano, 2024, 18, 20934
DOI: 10.1021/acsnano.4c05956

Molecular Engineering of Active Fe Center in Metalloporphyrin Coupled with Polyoxometalates for Efficient Photochemical Nitrogen Fixation: Synergistic Effect of Multiactive Sites Strengthening Metal‐N‐N* Interactions

Ximing Li, Qibing Dong, Junjun Wang, Xinxin Liang, Peter K. J. Robertson, Fei Li, Ming Guo, Wonyong Choi and Chuanyi Wang

Adv Funct Materials, 2025, 35
DOI: 10.1002/adfm.202424128

Single‐Site Molybdenum on Solid Support Materials for Catalytic Hydrogenation of N2‐into‐NH3

Luis Miguel Azofra, Natalia Morlanés, Albert Poater, Manoja K. Samantaray, Balamurugan Vidjayacoumar, Khalid Albahily, Luigi Cavallo and Jean‐Marie Basset

Angewandte Chemie, 2018, 130, 16038
DOI: 10.1002/ange.201810409

Oxygen vacancies in metal oxides: recent progress towards advanced catalyst design

Guoxin Zhuang, Yawen Chen, Zanyong Zhuang, Yan Yu and Jiaguo Yu

Sci. China Mater., 2020, 63, 2089
DOI: 10.1007/s40843-020-1305-6

Palladium-Modified MoS2 with Accelerated Water Hydrolysis for Highly Efficient Electrocatalytic Ammonia Production

Xiaoyue Chen, Guangmin Ren, Zhongrui Chen, Kelei Huang, Xiangchao Meng and Zizhen Li

ACS Sustainable Chem. Eng., 2025, 13, 8894
DOI: 10.1021/acssuschemeng.4c10443

Advanced cold plasma-assisted technology for green and sustainable ammonia synthesis

Deepak Panchal, Qiuyun Lu, Ken Sakaushi and Xuehua Zhang

Chemical Engineering Journal, 2024, 498, 154920
DOI: 10.1016/j.cej.2024.154920

N2 Reduction into Silylamine at Tridentate Phosphine/Mo Center: Catalysis and Mechanistic Study

Qian Liao, Nathalie Saffon-Merceron and Nicolas Mézailles

ACS Catal., 2015, 5, 6902
DOI: 10.1021/acscatal.5b01626

An Introduction to the Role of Molybdenum and Tungsten in Biology

Helder M. Marques

Inorganics, 2025, 13, 219
DOI: 10.3390/inorganics13070219

Review on photocatalytic and electrocatalytic artificial nitrogen fixation for ammonia synthesis at mild conditions: Advances, challenges and perspectives

Xiaolan Xue, Renpeng Chen, Changzeng Yan, Peiyang Zhao, Yi Hu, Wenjun Zhang, Songyuan Yang and Zhong Jin

Nano Res., 2019, 12, 1229
DOI: 10.1007/s12274-018-2268-5

Concurrent incorporation of Fe doping and construction of Pd-O-Fe interface for Pd/CeO2 photo-assisted thermocatalytic NO reduction into ammonia

Aoqiang Li, Jianfei Li, Chaowei Liang, Xiangyu Meng, Xianzhi Fu and Wenxin Dai

Chemical Engineering Journal, 2025, 522, 167773
DOI: 10.1016/j.cej.2025.167773

C–N Coupling in N2 Fixation by the Ditantalum Carbide Cluster Anions Ta2C4–

Zi-Yu Li, Li-Hui Mou, Gong-Ping Wei, Yi Ren, Mei-Qi Zhang, Qing-Yu Liu and Sheng-Gui He

Inorg. Chem., 2019, 58, 4701
DOI: 10.1021/acs.inorgchem.8b03502

Single-Metal Atom Anchored on Boron Monolayer (β12) as an Electrocatalyst for Nitrogen Reduction into Ammonia at Ambient Conditions: A First-Principles Study

Hao-Ran Zhu, Yan-Ling Hu, Shi-Hao Wei and Da-Yin Hua

J. Phys. Chem. C, 2019, 123, 4274
DOI: 10.1021/acs.jpcc.8b11696

Vacancy Engineering in Semiconductor Photocatalysts: Implications in Hydrogen Evolution and Nitrogen Fixation Applications

Ashish Kumar and Venkata Krishnan

Adv Funct Materials, 2021, 31
DOI: 10.1002/adfm.202009807

Molten salt assistant synthesis of three-dimensional cobalt doped graphitic carbon nitride for photocatalytic N2 fixation: Experiment and DFT simulation analysis

Keyun Wang, Guizhou Gu, Shaozheng Hu, Jian Zhang, Xiaolong Sun, Fei Wang, Ping Li, Yanfeng Zhao, Zhiping Fan and Xiong Zou

Chemical Engineering Journal, 2019, 368, 896
DOI: 10.1016/j.cej.2019.03.037

Supramolecular preorganization effect to access single cobalt sites for enhanced photocatalytic hydrogen evolution and nitrogen fixation

Wenyao Zhang, Yongsheng Fu, Qiong Peng, Qiushi Yao, Xin Wang, Aiping Yu and Zhongwei Chen

Chemical Engineering Journal, 2020, 394, 124822
DOI: 10.1016/j.cej.2020.124822

Electrostatics Generated by a Supramolecular Capsule Stabilizes the Transition State for Carbon–Carbon Reductive Elimination from Gold(III) Complex

Valerie Vaissier Welborn and Teresa Head-Gordon

J. Phys. Chem. Lett., 2018, 9, 3814
DOI: 10.1021/acs.jpclett.8b01710

Ce-Doped W18O49 Nanowires for Tuning N2 Activation toward Direct Nitrate Photosynthesis

Jingjing Yang, Zhoushilin Ruan, Shenlong Jiang, Pengfei Xia, Qinghua Yang, Qun Zhang, Chong Xiao and Yi Xie

J. Phys. Chem. Lett., 2021, 12, 11295
DOI: 10.1021/acs.jpclett.1c03207

Surface‐Engineered Molybdenum Oxide with Cucurbit[6]uril for Enhanced Nitrogen Reduction Electrocatalysis

Jian Dai, Yunxuan Ding, Yilong Zhao, Zeju Li, Shuai Liu, Peili Zhang, Fei Li, Shudong Zhang, Licheng Sun and Fusheng Li

Small, 2025
DOI: 10.1002/smll.202507453

Synthesis and Catalytic Reactivity of Bis(molybdenum-trihalide) Complexes Bridged by Ferrocene Skeleton toward Catalytic Nitrogen Fixation

Takayuki Itabashi, Kazuya Arashiba, Hiromasa Tanaka, Asuka Konomi, Aya Eizawa, Kazunari Nakajima, Kazunari Yoshizawa and Yoshiaki Nishibayashi

Organometallics, 2019, 38, 2863
DOI: 10.1021/acs.organomet.9b00263

Photolytic N2 Splitting: A Road to Sustainable NH3 Production?

Christophe Rebreyend and Bas de Bruin

Angew Chem Int Ed, 2015, 54, 42
DOI: 10.1002/anie.201409727

Photocatalytic oxygen reduction to hydrogen peroxide over copper doped graphitic carbon nitride hollow microsphere: The effect of Cu(I)-N active sites

Shaozheng Hu, Xiaoyu Qu, Ping Li, Fei Wang, Qiang Li, Lijuan Song, Yanfeng Zhao and Xiaoxue Kang

Chemical Engineering Journal, 2018, 334, 410
DOI: 10.1016/j.cej.2017.10.016

Enabling Unconventional “Alternating‐Distal” N2 Reduction Pathway for Efficient Ammonia Electrosynthesis

Chu Zhang, Qing Wang, Zeyu Li, Hengjie Liu, Lixiang Zhong, Jiawei Liu, Zheng Wang, Runjie Wu, Pin Song, Wen‐Jie Chen, Zeming Qi, Chunshuang Yan, Li Song, Qingyu Yan and Chade Lv

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202502957

A review on intermediate temperature electrochemical synthesis of ammonia

Gurpreet Kaur, Haijin Zhu, Dattatray S. Dhawale, HyungKuk Ju, Saheli Biswas, Jae Hyung Kim, Hyung Chul Yoon and Sarbjit Giddey

Applied Energy, 2025, 393, 126092
DOI: 10.1016/j.apenergy.2025.126092

EPR spectroscopy: A versatile tool for exploring transition metal complexes in organometallic and bioinorganic chemistry

Minyoung Ju, Jin Kim and Jeongcheol Shin

Bulletin Korean Chem Soc, 2024, 45, 835
DOI: 10.1002/bkcs.12899

Coupling ZnN4 Atomic Sites with Graphitic Nitrogen for Enhanced Ammonium Production via Electrocatalytic Nitrate Reduction

Qianghua Li, Yixuan Ma, Qingling Zeng, Wenjun Liu, Chunfeng Wang, Shun Han, Peijiang Cao, Deliang Zhu and Ming Fang

Small, 2025, 21
DOI: 10.1002/smll.202409925

Near ambient N2 fixation on solid electrodes versus enzymes and homogeneous catalysts

Olivia Westhead, Jesús Barrio, Alexander Bagger, James W. Murray, Jan Rossmeisl, Maria-Magdalena Titirici, Rhodri Jervis, Andrea Fantuzzi, Andrew Ashley and Ifan E. L. Stephens

Nat Rev Chem, 2023, 7, 184
DOI: 10.1038/s41570-023-00462-5

Nitrogen centered inverse coordination complexes. A survey of molecular topologies

Ionel Haiduc

Journal of Coordination Chemistry, 2018, 71, 3139
DOI: 10.1080/00958972.2018.1515429

Thiolate-Bridged Dicobalt Complexes Bearing Hydrazine, Hydrazido, and Diazenido Ligands: Synthesis, Structural Characterization, and Interconversion

Jianzhe Li, Dawei Yang, Peng Tong, Chunlong Wang, Baomin Wang and Jingping Qu

Inorg. Chem., 2020, 59, 8203
DOI: 10.1021/acs.inorgchem.0c00542

Photocatalysis and Photoelectrocatalysis Methods of Nitrogen Reduction for Sustainable Ammonia Synthesis

Kemakorn Ithisuphalap, Hanguang Zhang, Lin Guo, Qingui Yang, Haipeng Yang and Gang Wu

Small Methods, 2019, 3
DOI: 10.1002/smtd.201800352

Efficient Catalytic Conversion of Dinitrogen to N(SiMe3)3 Using a Homogeneous Mononuclear Cobalt Complex

Tatsuya Suzuki, Keisuke Fujimoto, Yoshiyuki Takemoto, Yuko Wasada-Tsutsui, Tomohiro Ozawa, Tomohiko Inomata, Michael D. Fryzuk and Hideki Masuda

ACS Catal., 2018, 8, 3011
DOI: 10.1021/acscatal.7b04351

Two‐dimensional conjugated polymer frameworks for solar fuel generation from water

Lei Wang and Hangxun Xu

Progress in Polymer Science, 2023, 145, 101734
DOI: 10.1016/j.progpolymsci.2023.101734

Prediction of Highly Selective Electrocatalytic Nitrogen Reduction at Low Overpotential on a Mo-Doped g-GaN Monolayer

Lesheng Li, J. Mark P. Martirez and Emily A. Carter

ACS Catal., 2020, 10, 12841
DOI: 10.1021/acscatal.0c03140

The Mechanism of N–N Double Bond Cleavage by an Iron(II) Hydride Complex

Sarina M. Bellows, Nicholas A. Arnet, Prabhuodeyara M. Gurubasavaraj, William W. Brennessel, Eckhard Bill, Thomas R. Cundari and Patrick L. Holland

J. Am. Chem. Soc., 2016, 138, 12112
DOI: 10.1021/jacs.6b04654

COFcap2, a recyclable tandem catalysis reactor for nitrogen fixation and conversion to chiral amines

Qianqian Zhu, Peijie Dong, Jiangyue Yu, Zhifang Wang, Ting Wang, Shan Qiao, Jinjin Liu, Shubo Geng, Yunlong Zheng, Peng Cheng, Michael J. Zaworotko, Zhenjie Zhang and Yao Chen

Nat Commun, 2025, 16
DOI: 10.1038/s41467-025-56214-0

Activation of N2, the Enzymatic Way

Ian Dance

Zeitschrift anorg allge chemie, 2015, 641, 91
DOI: 10.1002/zaac.201400120

Highly enhanced stability and efficiency for atmospheric ammonia photocatalysis by hot electrons from a graphene composite catalyst with Al2O3

Yang Yang, Tengfei Zhang, Zhen Ge, Yanhong Lu, Huicong Chang, Peishuang Xiao, Ruiqi Zhao, Yanfeng Ma and Yongsheng Chen

Carbon, 2017, 124, 72
DOI: 10.1016/j.carbon.2017.07.014

Surface chemical-functionalization of ultrathin two-dimensional nanomaterials for electrocatalysis

Dawei Chen, Yuqin Zou and Shuangyin Wang

Materials Today Energy, 2019, 12, 250
DOI: 10.1016/j.mtener.2019.01.006

Electro-reduction of N2 on nanostructured materials and the design strategies of advanced catalysts based on descriptors

Chenxu Zhao, Menghui Xi, Jinrong Huo, Chaozheng He and Ling Fu

Materials Today Physics, 2022, 22, 100609
DOI: 10.1016/j.mtphys.2022.100609

Double metals sites synergistically enhanced photocatalytic N2 fixation performance over Bi24O31Br10@Bi/Ti3C2Tx Ohm junctions

Ruqi Li, Hua Wen, Maomao Niu, Li Guo, Xin Huang, Chunming Yang and Danjun Wang

Journal of Colloid and Interface Science, 2024, 659, 139
DOI: 10.1016/j.jcis.2023.12.154

Highly ordered Nb2O5 nanochannel film with rich oxygen vacancies for electrocatalytic N2 reduction: Inactivation and regeneration of electrode

Jialu Wang, Shenghong Kang, Xiaoguang Zhu, Guozhong Wang and Haimin Zhang

Chinese Chemical Letters, 2021, 32, 2833
DOI: 10.1016/j.cclet.2021.01.020

Oxygen Vacancy‐Mediated Photocatalysis of BiOCl: Reactivity, Selectivity, and Perspectives

Hao Li, Jie Li, Zhihui Ai, Falong Jia and Lizhi Zhang

Angew Chem Int Ed, 2018, 57, 122
DOI: 10.1002/anie.201705628

Free Reaction Enthalpy Profile of the Schrock Cycle Derived from Density Functional Theory Calculations on the Full [MoHIPTN3N] Catalyst

Wulf Thimm, Christian Gradert, Henning Broda, Frank Wennmohs, Frank Neese and Felix Tuczek

Inorg. Chem., 2015, 54, 9248
DOI: 10.1021/acs.inorgchem.5b00787

Dinitrogen Splitting Coupled to Protonation

Gleb A. Silantyev, Moritz Förster, Bastian Schluschaß, Josh Abbenseth, Christian Würtele, Christian Volkmann, Max C. Holthausen and Sven Schneider

Angew Chem Int Ed, 2017, 56, 5872
DOI: 10.1002/anie.201701504

Recent progress of photocatalysts based on tungsten and related metals for nitrogen reduction to ammonia

Xiangchao Hui, Lijun Wang, Zhibo Yao, Leiduan Hao and Zhenyu Sun

Front. Chem., 2022, 10
DOI: 10.3389/fchem.2022.978078

Single-atom catalytic N2 fixation with integrated descriptors on a novel π-π conjugated graphitic carbon nitride (g-C13N15) platform obtained by self-doping design: Prediction of ultrahigh activity and desirable selectivity

Yali Lu, Chunyao Fang, Qiang Zhang, Zongjin Hu, Yanlei Wu, Chenglong Shi, Jingcheng Xu and Yuanrui Li

Journal of Power Sources, 2024, 595, 234030
DOI: 10.1016/j.jpowsour.2023.234030

Recent progress in two-dimensional nanomaterials: Synthesis, engineering, and applications

Fa Yang, Ping Song, Mingbo Ruan and Weilin Xu

FlatChem, 2019, 18, 100133
DOI: 10.1016/j.flatc.2019.100133

Advances in catalysts and reaction systems for electro/photocatalytic ammonia production

Shenshen Zheng, Fengying Zhang, Yuman Jiang, Tao Xu, Han Li, Heng Guo and Ying Zhou

Front. Chem. Sci. Eng., 2024, 18
DOI: 10.1007/s11705-024-2463-8

Plasmonic MoO3−x/Ag Photocatalyst for the Fixation of N2 from Air with the Solar Energy Conversion Efficiency Reaching over 0.28%

Jingtian Hu, Ke An, Yifei Ren, Feng Ryan Wang, Yanzhen Guo, Xiaopeng Bai, Degao Wang and Jianfang Wang

Advanced Materials, 2025
DOI: 10.1002/adma.202509652

Defect Engineering Metal‐Free Polymeric Carbon Nitride Electrocatalyst for Effective Nitrogen Fixation under Ambient Conditions

Chade Lv, Yumin Qian, Chunshuang Yan, Yu Ding, Yuanyue Liu, Gang Chen and Guihua Yu

Angew Chem Int Ed, 2018, 57, 10246
DOI: 10.1002/anie.201806386

Perovskite Oxide Based Materials for Energy and Environment-Oriented Photocatalysis

Ashish Kumar, Ajay Kumar and Venkata Krishnan

ACS Catal., 2020, 10, 10253
DOI: 10.1021/acscatal.0c02947

Alternative Strategies Toward Sustainable Ammonia Synthesis

Chengcheng Li, Tuo Wang and Jinlong Gong

Trans. Tianjin Univ., 2020, 26, 67
DOI: 10.1007/s12209-020-00243-x

Theoretical insights into the performance of single and double transition metal atoms doped on N-graphenes for N2 electroreduction

Mengnan Qu, Gangqiang Qin, Jianfen Fan, Aijun Du and Qiao Sun

Applied Surface Science, 2021, 537, 148012
DOI: 10.1016/j.apsusc.2020.148012

Defect Engineering Metal‐Free Polymeric Carbon Nitride Electrocatalyst for Effective Nitrogen Fixation under Ambient Conditions

Chade Lv, Yumin Qian, Chunshuang Yan, Yu Ding, Yuanyue Liu, Gang Chen and Guihua Yu

Angewandte Chemie, 2018, 130, 10403
DOI: 10.1002/ange.201806386

High-Efficiency “Working-in-Tandem” Nitrogen Photofixation Achieved by Assembling Plasmonic Gold Nanocrystals on Ultrathin Titania Nanosheets

Jianhua Yang, Yanzhen Guo, Ruibin Jiang, Feng Qin, Han Zhang, Wenzheng Lu, Jianfang Wang and Jimmy C. Yu

J. Am. Chem. Soc., 2018, 140, 8497
DOI: 10.1021/jacs.8b03537

Advances in Electrocatalytic Nitrate Reduction: Insights into Mechanisms and Reaction Optimization

Haotian Tan, Yunrui Tian, Wei Peng, Xiaoqing Liu, Liqun Wang, Yanjie Peng, Chao Wang, Ji Liang and Xiao Yan

Advanced Sustainable Systems, 2025
DOI: 10.1002/adsu.202400934

Durch Sauerstoff‐Leerstellen vermittelte Photokatalyse mit BiOCl: Reaktivität, Selektivität und Ausblick

Hao Li, Jie Li, Zhihui Ai, Falong Jia and Lizhi Zhang

Angewandte Chemie, 2018, 130, 128
DOI: 10.1002/ange.201705628

Photocatalytic ammonia synthesis: Recent progress and future

Shuai Zhang, Yunxuan Zhao, Run Shi, Geoffrey I.N. Waterhouse and Tierui Zhang

EnergyChem, 2019, 1, 100013
DOI: 10.1016/j.enchem.2019.100013

Hierarchical hollow nanotubes of NiFeV-layered double hydroxides@CoVP heterostructures towards efficient, pH-universal electrocatalytical nitrogen reduction reaction to ammonia

Muhammad Arif, Ghulam Yasin, Lan Luo, Wen Ye, Muhammad Asim Mushtaq, Xiaoyu Fang, Xu Xiang, Shengfu Ji and Dongpeng Yan

Applied Catalysis B: Environmental, 2020, 265, 118559
DOI: 10.1016/j.apcatb.2019.118559

High Efficiency Electrochemical Nitrogen Fixation Achieved with a Lower Pressure Reaction System by Changing the Chemical Equilibrium

Hui Cheng, Peixin Cui, Fangrui Wang, Liang‐Xin Ding and Haihui Wang

Angew Chem Int Ed, 2019, 58, 15541
DOI: 10.1002/anie.201910658

When nitrogen reduction meets single-atom catalysts

Yingping Pang, Chao Su, Liqiang Xu and Zongping Shao

Progress in Materials Science, 2023, 132, 101044
DOI: 10.1016/j.pmatsci.2022.101044

Different Atomic Terminations Affect the Photocatalytic Nitrogen Fixation of Bismuth Oxybromide: A First Principles Study

Hongxian Liu, Zhenxing Fang, Yongfei Su, Yuanli Suo, Shuping Huang, Yongfan Zhang and Kaining Ding

Chemistry An Asian Journal, 2018, 13, 799
DOI: 10.1002/asia.201701670

The Triple‐Bond Metathesis of Aryldiazonium Salts: A Prospect for Dinitrogen Cleavage

Aaron D. Lackner and Alois Fürstner

Angewandte Chemie, 2015, 127, 13005
DOI: 10.1002/ange.201506546

Review on Electrocatalytic Coreduction of Carbon Dioxide and Nitrogenous Species for Urea Synthesis

Minghang Jiang, Mengfei Zhu, Mengjun Wang, Yi He, Xiaojun Luo, Caijun Wu, Liyun Zhang and Zhong Jin

ACS Nano, 2023, 17, 3209
DOI: 10.1021/acsnano.2c11046

Regulating nitrogenous adsorption and desorption on Pd clusters by the acetylene linkages of hydrogen substituted graphdiyne for efficient electrocatalytic ammonia synthesis

Ying Guo, Jianwen Liu, Qi Yang, Pongtanawat Khemthong, Zhaodong Huang, Yuwei Zhao, Ze Chen, Binbin Dong, Xian-Zhu Fu, Jing-Li Luo and Chunyi Zhi

Nano Energy, 2021, 86, 106099
DOI: 10.1016/j.nanoen.2021.106099

Molecular Pnictogen Activation by Rare Earth and Actinide Complexes

Zoë Turner

Inorganics, 2015, 3, 597
DOI: 10.3390/inorganics3040597

Benzene Selectivity in Competitive Arene Hydrogenation: Effects of Single-Site Catalyst···Acidic Oxide Surface Binding Geometry

Weixing Gu, Madelyn Marie Stalzer, Christopher P. Nicholas, Alak Bhattacharyya, Alessandro Motta, James R. Gallagher, Guanghui Zhang, Jeffrey T. Miller, Takeshi Kobayashi, Marek Pruski, Massimiliano Delferro and Tobin J. Marks

J. Am. Chem. Soc., 2015, 137, 6770
DOI: 10.1021/jacs.5b03254

Recent Progress in Transition-Metal-Catalyzed Reduction of Molecular Dinitrogen under Ambient Reaction Conditions

Yoshiaki Nishibayashi

Inorg. Chem., 2015, 54, 9234
DOI: 10.1021/acs.inorgchem.5b00881

Optically and Electrocatalytically Decoupled Si Photocathodes with a Porous Carbon Nitride Catalyst for Nitrogen Reduction with Over 61.8% Faradaic Efficiency

Karthik Peramaiah, Vinoth Ramalingam, Hui‐Chun Fu, Merfat M. Alsabban, Rafia Ahmad, Luigi Cavallo, Vincent Tung, Kuo‐Wei Huang and Jr‐Hau He

Advanced Materials, 2021, 33
DOI: 10.1002/adma.202100812

Advancement of Bismuth‐Based Materials for Electrocatalytic and Photo(electro)catalytic Ammonia Synthesis

Wahyu Prasetyo Utomo, Michael K. H. Leung, Zongyou Yin, Hao Wu and Yun Hau Ng

Adv Funct Materials, 2022, 32
DOI: 10.1002/adfm.202106713

Mechanisms of electrochemical nitrogen gas reduction to ammonia under ambient conditions: a focused review

Anjali Kaiprathu, Parthiban Velayudham, Hanan Teller and Alex Schechter

J Solid State Electrochem, 2022, 26, 1897
DOI: 10.1007/s10008-022-05228-5

Multimetallic Rare Earth and Group 4 Transition Metal Hydrides for Novel Transformations of Small Molecules

Takanori Shima

J. Phys. Soc. Jpn., 2020, 89, 051014
DOI: 10.7566/JPSJ.89.051014

Reversible Dihydrogen Activation and Hydride Transfer by a Uranium Nitride Complex

Marta Falcone, Lok Nga Poon, Farzaneh Fadaei Tirani and Marinella Mazzanti

Angew Chem Int Ed, 2018, 57, 3697
DOI: 10.1002/anie.201800203

Recent advances of MXene as promising catalysts for electrochemical nitrogen reduction reaction

Jie Sun, Wenhan Kong, Zhaoyong Jin, Yaqian Han, Liangyu Ma, Xiaoteng Ding, Yusheng Niu and Yuanhong Xu

Chinese Chemical Letters, 2020, 31, 953
DOI: 10.1016/j.cclet.2020.01.035

Theoretical Evaluation of Electrochemical Nitrate Reduction Reaction on Graphdiyne-Supported Transition Metal Single-Atom Catalysts

Fei Ai and Jike Wang

ACS Omega, 2022, 7, 31309
DOI: 10.1021/acsomega.2c03588

Alkali Metal Salt Interference on the Salicylate Method for Quantifying Ammonia from Nitrogen Reduction

Juan José Giner-Sanz, Graham M. Leverick, Livia Giordano, Valentín Pérez-Herranz and Yang Shao-Horn

ECS Adv., 2022, 1, 024501
DOI: 10.1149/2754-2734/ac6a68

Direct synthesis of cyanate anion from dinitrogen catalysed by molybdenum complexes bearing pincer-type ligand

Takayuki Itabashi, Kazuya Arashiba, Akihito Egi, Hiromasa Tanaka, Keita Sugiyama, Shun Suginome, Shogo Kuriyama, Kazunari Yoshizawa and Yoshiaki Nishibayashi

Nat Commun, 2022, 13
DOI: 10.1038/s41467-022-33809-5

Experimental and Computational Studies of Dinitrogen Activation and Hydrogenation at a Tetranuclear Titanium Imide/Hydride Framework

Takanori Shima, Gen Luo, Shaowei Hu, Yi Luo and Zhaomin Hou

J. Am. Chem. Soc., 2019, 141, 2713
DOI: 10.1021/jacs.8b13341

Electro- and Photocatalytic Conversion of N2 to NH3 by Chemically Modified Transition Metal Dichalcogenides, MoS2, and WS2

Ashwin Ganesan, Samar Alhowity, Ajyal Z. Alsaleh, Manan Guragain, Olatomide Omolere, Thomas R. Cundari, Jeffry Kelber and Francis D’Souza

J. Electrochem. Soc., 2023, 170, 056501
DOI: 10.1149/1945-7111/acd02d

Dinitrogen Activation by a Heterometallic VFe Complex Derived from 1,1'‐Bis(arylamido)vanadocene

Tsubasa Hatanaka, Hinano Kusunose, Hiroyuki Kawaguchi and Yasuhiro Funahashi

Eur J Inorg Chem, 2020, 2020, 1449
DOI: 10.1002/ejic.201901120

Silylamido supported dinitrogen heterobimetallic complexes: syntheses and their catalytic ability

Dan-dan Zhai, Si-jun Xie, Yi Xia, Hua-yi Fang and Zhang-jie Shi

National Science Review, 2021, 8
DOI: 10.1093/nsr/nwaa290

Surface Single-Cluster Catalyst for N2-to-NH3 Thermal Conversion

Xue-Lu Ma, Jin-Cheng Liu, Hai Xiao and Jun Li

J. Am. Chem. Soc., 2018, 140, 46
DOI: 10.1021/jacs.7b10354

Role of Metal Centers in Metal–Organic Frameworks for Nitrogen Reduction Reaction: A First-Principles Study

Naoyuki Nagasako and Nobuhiro Ogihara

J. Phys. Chem. C, 2025, 129, 12836
DOI: 10.1021/acs.jpcc.5c02184

An iron-free nitrogenase? Computational estimation of the ability to bind/activate N 2 in manganese and cobalt complexes

Rami Doukeh, Daniela Craciun, Maria Lehene, Adrian M. V. Branzanic, Alexandru Lupan and Radu Silaghi-Dumitrescu

Journal of Coordination Chemistry, 2024, 77, 1597
DOI: 10.1080/00958972.2024.2372812

Surface electronic fine-perturbation driven by distal atom coupling at W-Se pair sites for enhanced ammonia synthesis

Chuanzhen Feng, Jin Wan, Huijuan Zhang, Xiaodong Wang, Yangjun Luo and Yu Wang

Applied Catalysis B: Environment and Energy, 2025, 362, 124728
DOI: 10.1016/j.apcatb.2024.124728

Cobalt‐Catalyzed Transformation of Molecular Dinitrogen into Silylamine under Ambient Reaction Conditions

Ryuji Imayoshi, Hiromasa Tanaka, Yuki Matsuo, Masahiro Yuki, Kazunari Nakajima, Kazunari Yoshizawa and Yoshiaki Nishibayashi

Chemistry A European J, 2015, 21, 8905
DOI: 10.1002/chem.201501088

Semiconductor photocatalysts and mechanisms of carbon dioxide reduction and nitrogen fixation under UV and visible light

Ekaterina A. Kozlova, Mikhail N. Lyulyukin, Denis V. Kozlov and Valentin N. Parmon

Russ. Chem. Rev., 2021, 90, 1520
DOI: 10.1070/RCR5004

Unveiling Electrochemical Urea Synthesis by Co‐Activation of CO2 and N2 with Mott–Schottky Heterostructure Catalysts

Menglei Yuan, Junwu Chen, Yiling Bai, Zhanjun Liu, Jingxian Zhang, Tongkun Zhao, Qin Wang, Shuwei Li, Hongyan He and Guangjin Zhang

Angewandte Chemie, 2021, 133, 11005
DOI: 10.1002/ange.202101275

Construction of Fe(III) Active Sites on Phenanthroline-Grafted g-C3N4: Reduced Work Function and Enhanced Intramolecular Charge Transfer for Efficient N2 Photofixation

Donghui Cui, Xue Yang, Tingting Zhang, Meixi Li and Fengyan Li

ACS Appl. Mater. Interfaces, 2024, 16, 30040
DOI: 10.1021/acsami.4c03370

A New Nitrogenase Mechanism Using a CFe8S9 Model: Does H2 Elimination Activate the Complex to N2 Addition to the Central Carbon Atom?

Michael L. McKee

J. Phys. Chem. A, 2016, 120, 754
DOI: 10.1021/acs.jpca.5b10384

Synthesis and Reactivity of Molybdenum‐Dinitrogen Complexes Bearing PNN‐Type Pincer Ligand

Kazuya Arashiba, Kazunari Nakajima and Yoshiaki Nishibayashi

Zeitschrift anorg allge chemie, 2015, 641, 100
DOI: 10.1002/zaac.201400117

Unveiling Electrochemical Urea Synthesis by Co‐Activation of CO2 and N2 with Mott–Schottky Heterostructure Catalysts

Menglei Yuan, Junwu Chen, Yiling Bai, Zhanjun Liu, Jingxian Zhang, Tongkun Zhao, Qin Wang, Shuwei Li, Hongyan He and Guangjin Zhang

Angew Chem Int Ed, 2021, 60, 10910
DOI: 10.1002/anie.202101275

Carbon-Based Catalysts for Selective Electrochemical Nitrogen-to-Ammonia Conversion

Lu-Hua Zhang, Fengshou Yu and N. Raveendran Shiju

ACS Sustainable Chem. Eng., 2021, 9, 7687
DOI: 10.1021/acssuschemeng.1c00575

Partial Hydrogenation of a Tetranuclear Titanium Nitrido Complex with Ammonia Borane

Jorge Caballo, Mariano González-Moreiras, Maider Greño, Miguel Mena, Adrián Pérez-Redondo and Carlos Yélamos

Inorg. Chem., 2014, 53, 8851
DOI: 10.1021/ic5015972

Highly Selective Electrochemical Reduction of Dinitrogen to Ammonia at Ambient Temperature and Pressure over Iron Oxide Catalysts

Xiaoyang Cui, Cheng Tang, Xiao‐Meng Liu, Chen Wang, Wenjun Ma and Qiang Zhang

Chemistry A European J, 2018, 24, 18494
DOI: 10.1002/chem.201800535

Photo‐Assisted Li‐N2 Batteries with Enhanced Nitrogen Fixation and Energy Conversion

Jian‐You Li, Xing‐Yuan Du, Xiao‐Xue Wang, Xin‐Yuan Yuan, De‐Hui Guan and Ji‐Jing Xu

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202319211

Hydrogenase as the basis for green hydrogen production and utilization

Haishuo Ji, Lei Wan, Yanxin Gao, Ping Du, Wenjin Li, Hang Luo, Jiarui Ning, Yingying Zhao, Huangwei Wang, Lixin Zhang and Liyun Zhang

Journal of Energy Chemistry, 2023, 85, 348
DOI: 10.1016/j.jechem.2023.06.018

Cascading of Thermocatalysis and Electrocatalysis for Enhanced Nitrogen Reduction on the Dual-Atom Cobalt Catalyst

Xing Fan, Jianhua Wang, Jiangdong Bo, Zhengda Chen, Guoxin Zhang, Xinying Yang, Jiangbo Lu, Yongfeng Wang and Haiping Lin

J. Phys. Chem. Lett., 2025, 16, 6447
DOI: 10.1021/acs.jpclett.5c01120

Synthesis, Characterization, and Interconversion of β‐Diketiminato Nickel NxHy Complexes

Claudia Köthe, Beatrice Braun, Christian Herwig and Christian Limberg

Eur J Inorg Chem, 2014, 2014, 5296
DOI: 10.1002/ejic.201402812

Systematic Design of a Frustrated Lewis Pair Containing Methyleneborane and Carbene for Dinitrogen Activation

Alvi Muhammad Rouf, Yuanyuan Huang, Shicheng Dong and Jun Zhu

Inorg. Chem., 2021, 60, 5598
DOI: 10.1021/acs.inorgchem.0c03520

Constructing boron-doped graphitic carbon nitride with 2D/1D porous hierarchical architecture and efficient N2 photofixation

Jing Yu, Shihao Xiong, Bichen Wang, Rui Wang, Beibei He, Jun Jin, Huanwen Wang and Yansheng Gong

Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2023, 656, 130481
DOI: 10.1016/j.colsurfa.2022.130481

C–H Bond Activation of Benzene, Toluene, 3,3‐Dimethyl‐1‐butene and Methane by Silica‐Supported TaV Imido Amido Surface Complex

Hong‐Peng Jia, Yasemin Kaya, Catherine Chow, Mostafa Taoufik and Elsje Alessandra Quadrelli

Zeitschrift anorg allge chemie, 2015, 641, 56
DOI: 10.1002/zaac.201400178

Strategy of constructing D-A structure and accurate active sites over graphitic carbon nitride nanowires for high efficient photocatalytic nitrogen fixation

Donghui Cui, Xue Yang, Yu Liu, Ting Ou, Xiangyi Kong, Yali Zhang, Jiangwei Zhang and Fengyan Li

Journal of Colloid and Interface Science, 2025, 678, 955
DOI: 10.1016/j.jcis.2024.09.052

Dinitrogen Binding at a Trititanium Chloride Complex and Its Conversion to Ammonia under Ambient Conditions

Estefanía del Horno, Jesús Jover, Miguel Mena, Adrián Pérez‐Redondo and Carlos Yélamos

Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202204544

Grenzen erweitern: Spaltung und Funktionalisierung von N2 jenseits von frühen Übergangsmetallen

Máté J. Bezdek and Paul J. Chirik

Angewandte Chemie, 2016, 128, 8022
DOI: 10.1002/ange.201603142

Theoretical study of transition metal doped α-borophene nanosheet as promising electrocatalyst for electrochemical reduction of N2

Chenyin Li, Xin Liu, Dandan Wu, Hong Xu and Guohong Fan

Computational and Theoretical Chemistry, 2022, 1213, 113732
DOI: 10.1016/j.comptc.2022.113732

Recent progress on catalyst design of nitrogen reduction reaction by density functional theory

Tian-Yi Dai, Chun-Cheng Yang and Qing Jiang

Sci. China Mater., 2024, 67, 1101
DOI: 10.1007/s40843-023-2847-1

Construction mechanisms, synthesis strategies, and photocatalytic applications of homojunction catalysts: A review

Hao-wen Zhu, Rui-tang Guo, Qing-shan Wang, Cong Liu, Heng-fei Cui, Ming-yang Liu and Wei-guo Pan

Journal of Environmental Chemical Engineering, 2024, 12, 114953
DOI: 10.1016/j.jece.2024.114953

Cleavage and Formation of Molecular Dinitrogen in a Single System Assisted by Molybdenum Complexes Bearing Ferrocenyldiphosphine

Takamasa Miyazaki, Hiromasa Tanaka, Yoshiaki Tanabe, Masahiro Yuki, Kazunari Nakajima, Kazunari Yoshizawa and Yoshiaki Nishibayashi

Angew Chem Int Ed, 2014, 53, 11488
DOI: 10.1002/anie.201405673

Examining the relationship between coordination mode and reactivity of dinitrogen

Richard J. Burford and Michael D. Fryzuk

Nat Rev Chem, 2017, 1
DOI: 10.1038/s41570-017-0026

N2 Electroreduction to NH3 by Selenium Vacancy‐Rich ReSe2 Catalysis at an Abrupt Interface

Feili Lai, Wei Zong, Guanjie He, Yang Xu, Haowei Huang, Bo Weng, Dewei Rao, Johan A. Martens, Johan Hofkens, Ivan P. Parkin and Tianxi Liu

Angew Chem Int Ed, 2020, 59, 13320
DOI: 10.1002/anie.202003129

Functionalization of N2 via Formal 1,3‐Haloboration of a Tungsten(0) σ‐Dinitrogen Complex

Anna Rempel, Soren K. Mellerup, Felipe Fantuzzi, Anselm Herzog, Andrea Deißenberger, Rüdiger Bertermann, Bernd Engels and Holger Braunschweig

Chemistry A European J, 2020, 26, 16019
DOI: 10.1002/chem.202002678

Is nitrogen fixation (once again) “vital to the progress of civilized humanity”?

Luis F. Razon

Clean Techn Environ Policy, 2015, 17, 301
DOI: 10.1007/s10098-014-0835-3

Metal-organic framework as a photocatalyst: Progress in modulation strategies and environmental/energy applications

Sherif A. Younis, Eilhann E. Kwon, Muhammad Qasim, Ki-Hyun Kim, Taejin Kim, Deepak Kukkar, Xiaomin Dou and Imran Ali

Progress in Energy and Combustion Science, 2020, 81, 100870
DOI: 10.1016/j.pecs.2020.100870

Dinitrogen Splitting and Functionalization in the Coordination Sphere of Rhenium

Isabel Klopsch, Markus Finger, Christian Würtele, Bastian Milde, Daniel B. Werz and Sven Schneider

J. Am. Chem. Soc., 2014, 136, 6881
DOI: 10.1021/ja502759d

Catalytic Reduction of Dinitrogen to Ammonia by Use of Molybdenum–Nitride Complexes Bearing a Tridentate Triphosphine as Catalysts

Kazuya Arashiba, Eriko Kinoshita, Shogo Kuriyama, Aya Eizawa, Kazunari Nakajima, Hiromasa Tanaka, Kazunari Yoshizawa and Yoshiaki Nishibayashi

J. Am. Chem. Soc., 2015, 137, 5666
DOI: 10.1021/jacs.5b02579

Conversion of Dinitrogen into Acetonitrile under Ambient Conditions

Isabel Klopsch, Markus Kinauer, Markus Finger, Christian Würtele and Sven Schneider

Angew Chem Int Ed, 2016, 55, 4786
DOI: 10.1002/anie.201600790

Synergy between metals for small molecule activation: Enzymes and bio-inspired complexes

Ashta C. Ghosh, Carole Duboc and Marcello Gennari

Coordination Chemistry Reviews, 2021, 428, 213606
DOI: 10.1016/j.ccr.2020.213606

Pitfalls and Limitations in Group 6 Triamidophosphane Chemistry: Cage‐Closure Restrictions in Square‐Pyramidal Nitrido Complexes and Degradation via Spiro‐[4.4]‐λ5‐Amidophosphorane Formation

Malte Sietzen, Sonja Batke, Lukas Merz, Hubert Wadepohl and Joachim Ballmann

Eur J Inorg Chem, 2017, 2017, 5442
DOI: 10.1002/ejic.201701023

Counterion Dependence of Dinitrogen Activation and Functionalization by a Diniobium Hydride Anion

Shoi Suzuki, Yutaka Ishida, Hajime Kameo, Shigeyoshi Sakaki and Hiroyuki Kawaguchi

Angewandte Chemie, 2020, 132, 13546
DOI: 10.1002/ange.202006039

Vacancy Defect-Assisted Enhanced Nitrogen Fixation in Metal-Free 2D Orthorhombic Boron Nitride: Insights from Nonadiabatic Molecular Dynamics Simulations

Subhash Kumar, Atish Ghosh, Biplab Goswami and Pranab Sarkar

J. Phys. Chem. Lett., 2025, 16, 8311
DOI: 10.1021/acs.jpclett.5c02032

Mechanistic Insights into Nitrogenase FeMo-Cofactor Catalysis through a Steady-State Kinetic Model

Derek F. Harris, Artavazd Badalyan and Lance C. Seefeldt

Biochemistry, 2022, 61, 2131
DOI: 10.1021/acs.biochem.2c00415

Efficient electrocatalytic reduction of N2 to ammonia at ambient conditions with municipal sludge-derived porous carbon codoped with multiple heteroatoms

Lifang Deng, Lufeng Wang, Guoqiang Wei, Haoran Yuan, Jun Xie and Yong Chen

Electrochimica Acta, 2022, 408, 139934
DOI: 10.1016/j.electacta.2022.139934

Efficient Visible Light Nitrogen Fixation with BiOBr Nanosheets of Oxygen Vacancies on the Exposed {001} Facets

Hao Li, Jian Shang, Zhihui Ai and Lizhi Zhang

J. Am. Chem. Soc., 2015, 137, 6393
DOI: 10.1021/jacs.5b03105

2D Electrocatalysts for Converting Earth‐Abundant Simple Molecules into Value‐Added Commodity Chemicals: Recent Progress and Perspectives

Huajie Yin, Yuhai Dou, Shan Chen, Zhengju Zhu, Porun Liu and Huijun Zhao

Advanced Materials, 2020, 32
DOI: 10.1002/adma.201904870

Fixation of Nitrogen to Ammonia with Photocatalytic on Petroleum Pitch-Based Graphene Oxide Supported Nickel/Nickel Oxide Composite Catalyst

Shi-Xin Wang, Halidan Maimaiti, Bo Xu, Yuan Guo, Pei-shuai Zhai and Hai-zhen Zhang

J. Phys. Chem. C, 2019, 123, 31119
DOI: 10.1021/acs.jpcc.9b10189

Current Progress of Electrocatalysts for Ammonia Synthesis Through Electrochemical Nitrogen Reduction Under Ambient Conditions

Anmin Liu, Yanan Yang, Xuefeng Ren, Qidong Zhao, Mengfan Gao, Weixin Guan, Fanning Meng, Liguo Gao, Qiyue Yang, Xingyou Liang and Tingli Ma

ChemSusChem, 2020, 13, 3766
DOI: 10.1002/cssc.202000487

Hydrogen Spillover to Oxygen Vacancy of TiO2–xHy/Fe: Breaking the Scaling Relationship of Ammonia Synthesis

Chengliang Mao, Jiaxian Wang, Yunjie Zou, Guodong Qi, Joel Yi Yang Loh, Tianhua Zhang, Meikun Xia, Jun Xu, Feng Deng, Mireille Ghoussoub, Nazir P. Kherani, Lu Wang, Huan Shang, Meiqi Li, Jie Li, Xiao Liu, Zhihui Ai, Geoffrey A. Ozin, Jincai Zhao and Lizhi Zhang

J. Am. Chem. Soc., 2020, 142, 17403
DOI: 10.1021/jacs.0c06118

Photocatalytic nitrogen fixation: Oxygen vacancy modified novel micro-nanosheet structure Bi2O2CO3 with band gap engineering

Yalan Feng, Zisheng Zhang, Kai Zhao, Shuanglong Lin, Hong Li and Xin Gao

Journal of Colloid and Interface Science, 2021, 583, 499
DOI: 10.1016/j.jcis.2020.09.089

Challenges and prospects in the catalysis of electroreduction of nitrogen to ammonia

Bryan H. R. Suryanto, Hoang-Long Du, Dabin Wang, Jun Chen, Alexandr N. Simonov and Douglas R. MacFarlane

Nat Catal, 2019, 2, 290
DOI: 10.1038/s41929-019-0252-4

Cr3C2 Nanoparticle-Embedded Carbon Nanofiber for Artificial Synthesis of NH3 through N2 Fixation under Ambient Conditions

Guangsen Yu, Haoran Guo, Shanhu Liu, Liang Chen, Abdulmohsen Ali Alshehri, Khalid Ahmad Alzahrani, Feng Hao and Tingshuai Li

ACS Appl. Mater. Interfaces, 2019, 11, 35764
DOI: 10.1021/acsami.9b12675

Photocatalytic Conversion of Nitrogen to Ammonia with Water on Surface Oxygen Vacancies of Titanium Dioxide

Hiroaki Hirakawa, Masaki Hashimoto, Yasuhiro Shiraishi and Takayuki Hirai

J. Am. Chem. Soc., 2017, 139, 10929
DOI: 10.1021/jacs.7b06634

First-principles study on Fe2B2 as efficient catalyst for nitrogen reduction reaction

Wei Song, Jia Wang, Ling Fu, Chaozheng He, Chenxu Zhao, Yongliang Guo, Jinrong Huo and Guohui Dong

Chinese Chemical Letters, 2021, 32, 3137
DOI: 10.1016/j.cclet.2021.02.043

Unique behaviour of dinitrogen-bridged dimolybdenum complexes bearing pincer ligand towards catalytic formation of ammonia

Hiromasa Tanaka, Kazuya Arashiba, Shogo Kuriyama, Akira Sasada, Kazunari Nakajima, Kazunari Yoshizawa and Yoshiaki Nishibayashi

Nat Commun, 2014, 5
DOI: 10.1038/ncomms4737

Plasmonic chemistry for sustainable ammonia production

Arsha Choudhary, Anubhab Halder, Pooja Aggarwal and Vishal Govind Rao

Commun Mater, 2024, 5
DOI: 10.1038/s43246-024-00510-7

Recent trends on perovskite materials and their applications in photocatalysis: a review

Sujubili Narzary, Kumutha Duraisamy, Nageswara Rao Medikondu, Kunal Chakraborty, Sudipta Das, Mahua Gupta Choudhury and Samrat Paul

Opt Quant Electron, 2024, 56
DOI: 10.1007/s11082-024-07418-z

Progress and Prospective of Nitrogen-Based Alternative Fuels

Oren Elishav, Bar Mosevitzky Lis, Elisa M. Miller, Douglas J. Arent, Agustin Valera-Medina, Alon Grinberg Dana, Gennady E. Shter and Gideon S. Grader

Chem. Rev., 2020, 120, 5352
DOI: 10.1021/acs.chemrev.9b00538

Photoelectrocatalytic nitrogen fixation with Vo-BiOBr/TiO2 heterostructured photoelectrode as photocatalyst

Sheng Lin, Yinhuan Chen, Jiangjian Fu, Lan Sun, Qiaorong Jiang, Jian-Feng Li, Jun Cheng, Changjian Lin and Zhong-Qun Tian

International Journal of Hydrogen Energy, 2022, 47, 41553
DOI: 10.1016/j.ijhydene.2022.02.026

Photocatalytic hydrogen production from alcohols to in-situ hydrogenation of nitrogen to ammonia by a dual-catalyst system

Rui-shuang Zhang, Wei Sun, Yue Zhang, Yan Feng, Bin Dai and Yulin Deng

Applied Catalysis B: Environment and Energy, 2024, 358, 124429
DOI: 10.1016/j.apcatb.2024.124429

Bis(dinitrogen)cobalt(−1) Complexes with NHC Ligation: Synthesis, Characterization, and Their Dinitrogen Functionalization Reactions Affording Side-on Bound Diazene Complexes

Yafei Gao, Guangyu Li and Liang Deng

J. Am. Chem. Soc., 2018, 140, 2239
DOI: 10.1021/jacs.7b11660

Photo‐ and Photoelectrocatalysis in Nitrogen Reduction Reactions to Ammonia: Interfaces, Mechanisms, and Modeling Simulations

Dimitrij Ješić, Brett Pomeroy, Khaja Mohaideen Kamal, Žan Kovačič, Matej Huš and Blaž Likozar

Adv Energy and Sustain Res, 2024
DOI: 10.1002/aesr.202400083

Elucidating the Mechanism of Uranium Mediated Diazene N═N Bond Cleavage

John J. Kiernicki, Robert F. Higgins, Steven J. Kraft, Matthias Zeller, Matthew P. Shores and Suzanne C. Bart

Inorg. Chem., 2016, 55, 11854
DOI: 10.1021/acs.inorgchem.6b01922

Reactions of iron(II) hydrides formed by selective C F/C H bond activation in fluoroaryl-imines

Lin Wang, Hongjian Sun, Zhenyu Zuo, Benjing Xue, Xiaoyan Li, Olaf Fuhr and Dieter Fenske

Inorganica Chimica Acta, 2017, 461, 64
DOI: 10.1016/j.ica.2017.02.009

<italic>In-situ</italic> characterization technique in electrocatalytic nitrogen reduction to ammonia

Peng Yang, Heng Guo, Fengying Zhang, Ying Zhou and Xiaobin Niu

Chin. Sci. Bull., 2022, 67, 2921
DOI: 10.1360/TB-2022-0139

Efficiently enhanced N2 photofixation performance of sea-urchin-like W18O49 microspheres with Mn-doping

Zihao Ying, Shengtao Chen, Shuai Zhang, Tianyou Peng and Renjie Li

Applied Catalysis B: Environmental, 2019, 254, 351
DOI: 10.1016/j.apcatb.2019.05.005

Advanced Non‐metallic Catalysts for Electrochemical Nitrogen Reduction under Ambient Conditions

Lili Zhang, Gao‐Feng Chen, Liang‐Xin Ding and Haihui Wang

Chemistry A European J, 2019, 25, 12464
DOI: 10.1002/chem.201901668

Orbital symmetry matching: Achieving superior nitrogen reduction reaction over single-atom catalysts anchored on Mxene substrates

Jiale Qu, Jiewen Xiao, Hetian Chen, Xiaopeng Liu, Tianshuai Wang and Qianfan Zhang

Chinese Journal of Catalysis, 2021, 42, 288
DOI: 10.1016/S1872-2067(20)63643-9

Design, modification and application of semiconductor photocatalysts

Lizhuo Wang, Jinhui Zhao, Huimin Liu and Jun Huang

Journal of the Taiwan Institute of Chemical Engineers, 2018, 93, 590
DOI: 10.1016/j.jtice.2018.09.004

High-Performance Gas-Liquid-Solid Optofluidic Microreactor with Tio2-X-Ag@Hkust-1/Carbon Paper for Efficient Photocatalytic Nitrogen Fixation to Ammonia

Hui Zhao, Jihai Duan, Zhengnan Ji, Zisheng Zhang and Weiwen Wang

SSRN Journal, 2022
DOI: 10.2139/ssrn.4141612

Amorphous Oxide Nanostructures for Advanced Electrocatalysis

Leigang Li, Qi Shao and Xiaoqing Huang

Chemistry A European J, 2020, 26, 3943
DOI: 10.1002/chem.201903206

The Crucial Role of Charge Accumulation and Spin Polarization in Activating Carbon‐Based Catalysts for Electrocatalytic Nitrogen Reduction

Yuanyuan Yang, Lifu Zhang, Zhenpeng Hu, Yao Zheng, Cheng Tang, Ping Chen, Ruguang Wang, Kangwen Qiu, Jing Mao, Tao Ling and Shi‐Zhang Qiao

Angewandte Chemie, 2020, 132, 4555
DOI: 10.1002/ange.201915001

Superlattice‐based Plasmonic Catalysis: Concentrating Light at the Nanoscale to Drive Efficient Nitrogen‐to‐Ammonia Fixation at Ambient Conditions

Siew Kheng Boong, Carice Chong, Jinn‐Kye Lee, Zhi Zhong Ang, Haitao Li and Hiang Kwee Lee

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202216562

Electrocatalytic nitrogen fixation performance of two-dimensional Metal-Organic Frameworks Cu3(C6O6) and TM/Cu3(C6O6) from first-principle study

Ya-Xin Liu, Hong Zhang and Xin-Lu Cheng

Chemical Physics, 2023, 568, 111837
DOI: 10.1016/j.chemphys.2023.111837

Electrochemical Ammonia Synthesis at p-Block Active Sites Using Various Nitrogen Sources: Theoretical Insights

Shuhua Wang, Baibiao Huang, Ying Dai and Wei Wei

J. Phys. Chem. Lett., 2025, 16, 889
DOI: 10.1021/acs.jpclett.4c03301

Electrosynthetic Route to Cyclopentadienyl Rhenium Hydride Complexes Enabled by Electrochemical Investigations of their Redox-Induced Formation

Tao Huang, Tayliz M. Rodriguez, Cole T. Gruninger, Daniel A. Kurtz, Aldo M. Jordan, Chun-Hsing Chen and Jillian L. Dempsey

Organometallics, 2020, 39, 1730
DOI: 10.1021/acs.organomet.0c00049

Mechanistic insights into nitrogen activation on atomic Ru clusters in self-pillared pentasil using operando atomistic models and experimental kinetics

Geet Gupta, Weiye Qu, Zihao Rei Gao, Wei-Ling Huang, Ryan Zhou, Lu Ma, Nayeon Kang, Paul Haghi Ashtiani, Fan Bu, Jeffrey T. Miller, Michael Tsapatsis, Chao Wang and Brandon C. Bukowski

Journal of Catalysis, 2025, 451, 116374
DOI: 10.1016/j.jcat.2025.116374

Effect of Different Rates of Bacteria (Rhizobium leguminosarum) Inoculated in Seed on Yield and Some Quality Parameters of Common Vetch (Vicia sativa L.)

İbrahim ERTEKİN and Sadık ÇAKMAKÇI

Kahramanmaraş Sütçü İmam Üniversitesi Tarım ve Doğa Dergisi, 2020, 23, 343
DOI: 10.18016/ksutarimdoga.vi.562310

Study of a Fe₂N₄@graphene catalyst for electrocatalytic nitrogen reduction

Xu Tang, Peng Qiu and Zhengbing Xia

International Journal of Electrochemical Science, 2025, 20, 100911
DOI: 10.1016/j.ijoes.2024.100911

Iron-group electrocatalysts for ambient nitrogen reduction reaction in aqueous media

Benyuan Ma, Haitao Zhao, Tingshuai Li, Qian Liu, Yongsong Luo, Chengbo Li, Siyu Lu, Abdullah M. Asiri, Dongwei Ma and Xuping Sun

Nano Res., 2021, 14, 555
DOI: 10.1007/s12274-020-3049-5

Recent Advances in MOF‐Based Materials for Photocatalytic Nitrogen Fixation

Kongqiu Hu, Zhiwei Huang, Liwen Zeng, Zhihui Zhang, Lei Mei, Zhifang Chai and Weiqun Shi

Eur J Inorg Chem, 2022, 2022
DOI: 10.1002/ejic.202100748

Conversion of dinitrogen to ammonia by rhenium doped graphyne

Chong Wang and Chen Guo

International Journal of Hydrogen Energy, 2021, 46, 33409
DOI: 10.1016/j.ijhydene.2021.07.184

Breaking-down the catalyst used for the electrophotosynthesis of amino acids by nitrogen and carbon fixation

Jordi Sans, Elaine Armelin, Vanesa Sanz, Jordi Puiggalí, Pau Turon and Carlos Alemán

Journal of Catalysis, 2020, 389, 646
DOI: 10.1016/j.jcat.2020.07.006

High‐Performance Electrochemical NO Reduction into NH3 by MoS2 Nanosheet

Longcheng Zhang, Jie Liang, Yuanyuan Wang, Ting Mou, Yiting Lin, Luchao Yue, Tingshuai Li, Qian Liu, Yonglan Luo, Na Li, Bo Tang, Yang Liu, Shuyan Gao, Abdulmohsen Ali Alshehri, Xiaodong Guo, Dongwei Ma and Xuping Sun

Angew Chem Int Ed, 2021, 60, 25263
DOI: 10.1002/anie.202110879

Advancements in Electrocatalytic Nitrogen Reduction Reaction: A Review on the Role of Catalyst Electronic Structure and Design Strategies

Wei Tan, Hongbo Zhao, Longhua Ding, Na Ren, Xin Yu, Aizhu Wang and Mingwen Zhao

ACS Appl. Nano Mater., 2025, 8, 2632
DOI: 10.1021/acsanm.4c05946

Catalytic Dinitrogen Fixation to Form Ammonia at Ambient Reaction Conditions Using Transition Metal-Dinitrogen Complexes

Yoshiaki Tanabe and Yoshiaki Nishibayashi

The Chemical Record, 2016, 16, 1549
DOI: 10.1002/tcr.201600025

Enhanced electrocatalytic nitrate reduction to ammonia using plasma‐induced oxygen vacancies in CoTiO3 − x nanofiber

Xiaoya Fan, Jie Liang, Longcheng Zhang, Donglin Zhao, Luchao Yue, Yongsong Luo, Qian Liu, Lisi Xie, Na Li, Bo Tang, Qingquan Kong and Xuping Sun

Carbon Neutralization, 2022, 1, 6
DOI: 10.1002/cnl2.8

CRISPR-Based Therapies: Revolutionizing Drug Development and Precision Medicine

Dilip Kumar Chanchal, Jitendra Singh Chaudhary, Pushpendra Kumar, Neha Agnihotri and Prateek Porwal

CGT, 2024, 24, 193
DOI: 10.2174/0115665232275754231204072320

MXene-based 2D/2D Ti3C2/TiO2 heterojunction with spatially separated redox sites for efficient photocatalytic N2 reduction towards NH3

Chi Cao, Jinshuo Li, Linfeng Zhang, Yang Hu, Lin Zhang and Wensheng Yang

Journal of Materials Science & Technology, 2025, 214, 180
DOI: 10.1016/j.jmst.2024.06.038

Recent advance in single-atom catalysis

Zeng-Xi Wei, Ya-Ting Zhu, Jin-Yuan Liu, Zhi-Cheng Zhang, Wen-Ping Hu, Hui Xu, Yue-Zhan Feng and Jian-Min Ma

Rare Met., 2021, 40, 767
DOI: 10.1007/s12598-020-01592-1

Photocatalytic and electrocatalytic approaches towards atmospheric nitrogen reduction to ammonia under ambient conditions

Jude John, Dong-Kyu Lee and Uk Sim

Nano Convergence, 2019, 6
DOI: 10.1186/s40580-019-0182-5

Photolytische N2‐Spaltung: ein Weg zur nachhaltigen NH3‐Produktion?

Christophe Rebreyend and Bas de Bruin

Angewandte Chemie, 2015, 127, 42
DOI: 10.1002/ange.201409727

Recent Progress on Computation‐Guided Catalyst Design for Highly Efficient Nitrogen Reduction Reaction

Tian‐Yi Dai, Tong‐Hui Wang, Zi Wen and Qing Jiang

Adv Funct Materials, 2024, 34
DOI: 10.1002/adfm.202400773

Edge-hosted CoFeB active sites with graphene nanosheets for highly selective nitrogen reduction reaction towards ambient ammonia synthesis

Muhammad Arif, Anuj Kumar, Muhammad Asim Mushtaq, Umair Azhar, Muhammad Sagir, Muhammad Bilal Tahir, Unaiza Talib, Saira Ajmal, Khalid M. Alotaibi and Ghulam Yasin

Chemical Engineering Journal, 2023, 473, 145368
DOI: 10.1016/j.cej.2023.145368

Electron‐rich, Nitrido‐bridged Ruthenium Complexes

Arne Glüer, Bjorn Askevold, Bastian Schluschaß, Frank W. Heinemann and Sven Schneider

Zeitschrift anorg allge chemie, 2015, 641, 49
DOI: 10.1002/zaac.201400166

Dinitrogen Activation by Heteronuclear Metal Carbide Cluster Anions Y1‐3CoC1,2−: An Experimental and DFT Study

Meng‐Meng Wang, Ming Wang, Zhi‐Wen Ji, Xiao‐Meng Huang, Han‐Bin He, Xun‐Lei Ding and Jia‐Bi Ma

ChemCatChem, 2024, 16
DOI: 10.1002/cctc.202300978

Boron-Doped g-C6N6 Layer as a Metal-Free Photoelectrocatalyst for N2 Reduction Reaction

Zhao-Qin Chu, Catherine Stampfl and Xiang-Mei Duan

J. Phys. Chem. C, 2019, 123, 28739
DOI: 10.1021/acs.jpcc.9b08169

Atomic dispersion of bulk/nano metals to atomic-sites catalysts and their application in thermal catalysis

Lingcong Li and Ningqiang Zhang

Nano Res., 2023, 16, 6380
DOI: 10.1007/s12274-022-5335-x

Dinitrogen Fixation and Reduction by Ta3N3H0,1– Cluster Anions at Room Temperature: Hydrogen-Assisted Enhancement of Reactivity

Yue Zhao, Jia-Tong Cui, Ming Wang, David Yubero Valdivielso, André Fielicke, Lian-Rui Hu, Xin Cheng, Qing-Yu Liu, Zi-Yu Li, Sheng-Gui He and Jia-Bi Ma

J. Am. Chem. Soc., 2019, 141, 12592
DOI: 10.1021/jacs.9b03168

Silylation of Dinitrogen Catalyzed by Hydridodinitrogentris(Triphenylphosphine)Cobalt(I)

Wojciech Dzik

Inorganics, 2016, 4, 21
DOI: 10.3390/inorganics4030021

Renewable N-cycle catalysis

Simson Wu and Shik Chi Edman Tsang

Trends in Chemistry, 2021, 3, 660
DOI: 10.1016/j.trechm.2021.04.010

Group 6 Transition‐Metal/Boron Frustrated Lewis Pair Templates Activate N2and Allow its Facile Borylation and Silylation

Antoine Simonneau, Raphaël Turrel, Laure Vendier and Michel Etienne

Angew Chem Int Ed, 2017, 56, 12268
DOI: 10.1002/anie.201706226

Construction of single-atom catalysts for electro-, photo- and photoelectro-catalytic applications: State-of-the-art, opportunities, and challenges

Jiexiang Xia, Bin Wang, Jun Di, Yingjie Li, Shi-Ze Yang, Huaming Li and Shaojun Guo

Materials Today, 2022, 53, 217
DOI: 10.1016/j.mattod.2021.11.022

Design Refinement of Catalytic System for Scale-Up Mild Nitrogen Photo-Fixation

Xiao Hu Wang, Bin Wu, Yongfa Zhu, Dingsheng Wang, Nian Bing Li, Zhichuan J. Xu and Hong Qun Luo

Nano-Micro Lett., 2025, 17
DOI: 10.1007/s40820-025-01695-3

High Nitrogen Gas Solubility and Physicochemical Properties of [C4mpyr][eFAP]–Fluorinated Solvent Mixtures

Colin S. M. Kang, Xinyi Zhang and Douglas R. MacFarlane

J. Phys. Chem. C, 2019, 123, 21376
DOI: 10.1021/acs.jpcc.9b06000

Ketjenblack-Supported and Unsupported ZrO2–ZrN Nanoparticle Systems for Enabling Efficient Electrochemical Nitrogen Reduction to Ammonia

Mitu Sharma, Kotaro Sasaki, Gary Halada, Krishnakumari Pamula, Taejin Kim and Stanislaus S. Wong

ACS Appl. Mater. Interfaces, 2025, 17, 1153
DOI: 10.1021/acsami.4c17137

Edge-Rich Black Phosphorus for Photocatalytic Nitrogen Fixation

Shi Bian, Min Wen, Jiahong Wang, Na Yang, Paul K. Chu and Xue-Feng Yu

J. Phys. Chem. Lett., 2020, 11, 1052
DOI: 10.1021/acs.jpclett.9b03507

Effect of Zn Vacancies in Zn3In2S6 Nanosheets on Boosting Photocatalytic N2 Fixation

Huijuan Han, Yang Yang, Jiafang Liu, Xiuzhen Zheng, Xulin Wang, Sugang Meng, Sujuan Zhang, Xianliang Fu and Shifu Chen

ACS Appl. Energy Mater., 2020, 3, 11275
DOI: 10.1021/acsaem.0c02202

In-situ monitoring of dynamic behavior of catalyst materials and reaction intermediates in semiconductor catalytic processes

Zhen Fang, Yao Liu, Chengyi Song, Peng Tao, Wen Shang, Tao Deng, Xiaoqin Zeng and Jianbo Wu

J. Semicond., 2022, 43, 041104
DOI: 10.1088/1674-4926/43/4/041104

Defect and Interface Engineering on Two‐Dimensional Nanosheets for the Photocatalytic Nitrogen Reduction Reaction

Wenjun Zhao, Baojun Liu, Jiangzhou Qin, Jun Ke, Lanlan Yu and Xia Hu

ChemPhotoChem, 2020, 4, 5322
DOI: 10.1002/cptc.202000114

Defect Regulating of Few-Layer Antimonene from Acid-Assisted Exfoliation for Enhanced Electrocatalytic Nitrogen Fixation

Shihai Cao, Yuntong Sun, Shiying Guo, Zichang Guo, Yanchao Feng, Sheng Chen, Huan Chen, Shengli Zhang and Fang Jiang

ACS Appl. Mater. Interfaces, 2021, 13, 40618
DOI: 10.1021/acsami.1c10967

Photocatalytic N 2 conversion to ammonia using efficient nanostructured solar-energy-materials in aqueous media: A novel hydrogenation strategy and basic understanding of the phenomenon

Mohsen Lashgari and Parisa Zeinalkhani

Applied Catalysis A: General, 2017, 529, 91
DOI: 10.1016/j.apcata.2016.10.017

DFT study of Al-doped In2O3 with surface frustrated Lewis pair sites for enhanced nitrogen reduction efficiency

Yuchen Sima, Ming Zheng and Xin Zhou

J Mater Sci, 2025, 60, 7374
DOI: 10.1007/s10853-025-10869-8

Modulation of photo-generated solvated electrons for ammonia synthesis via facet-dependent engineering of heterojunctions

Guanhua Zhang, Tiantian Dai, Ying Wang, Yue Meng, Bo Xie, Zheming Ni and Shengjie Xia

Applied Catalysis B: Environmental, 2021, 288, 119990
DOI: 10.1016/j.apcatb.2021.119990

Synthesis of pyrimidines from dinitrogen and carbon

Xianghui Shi, Qianru Wang, Chao Qin, Li-Jun Wu, Yuanjin Chen, Gao-Xiang Wang, Yongli Cai, Wenbo Gao, Teng He, Junnian Wei, Jianping Guo, Ping Chen and Zhenfeng Xi

National Science Review, 2022, 9
DOI: 10.1093/nsr/nwac168

Spectroscopic and Quantum Chemical Investigation of Benzene-1,2-dithiolate-Coordinated Diiron Complexes with Relevance to Dinitrogen Activation

Sabrina I. Kalläne, Anselm W. Hahn, Thomas Weyhermüller, Eckhard Bill, Frank Neese, Serena DeBeer and Maurice van Gastel

Inorg. Chem., 2019, 58, 5111
DOI: 10.1021/acs.inorgchem.9b00177

Plasmonic W18O49/attapulgite nanocomposite with enhanced photofixation of nitrogen under full-spectrum light

Yahui Liu, Xiazhang Li, Huan Su, Xiaofan Chen, Shixiang Zuo, Junchao Qian and Chao Yao

J Mater Sci: Mater Electron, 2019, 30, 20019
DOI: 10.1007/s10854-019-02370-1

Fe3+ doping promoted N2 photofixation ability of honeycombed graphitic carbon nitride: The experimental and density functional theory simulation analysis

Shaozheng Hu, Xin Chen, Qiang Li, Fayun Li, Zhiping Fan, Hui Wang, Yanjuan Wang, Binghui Zheng and Guang Wu

Applied Catalysis B: Environmental, 2017, 201, 58
DOI: 10.1016/j.apcatb.2016.08.002

Dinitrogen and Carbon Dioxide Activation to Form C–N Bonds at Room Temperature: A New Mechanism Revealed by Experimental and Theoretical Studies

Ming Wang, Lan-Ye Chu, Zi-Yu Li, Antonis M. Messinis, Yong-Qi Ding, Lianrui Hu and Jia-Bi Ma

J. Phys. Chem. Lett., 2021, 12, 3490
DOI: 10.1021/acs.jpclett.1c00183

Recent advances on MOFs for photocatalytic and electrocatalytic nitrogen reduction to produce ammonia

Jingdan Zhao, Guangmin Ren and Xiangchao Meng

Nano Energy, 2024, 130, 110109
DOI: 10.1016/j.nanoen.2024.110109

Reactivity of Polynuclear Niobium Oxynitride Cluster Anions Nb4N5‐xOx− (x=0–5) toward N2

Xiao‐Xiao Liu, Zi‐Yu Li, Qing‐Yu Liu, Xi‐Guan Zhao, Qian Li and Sheng‐Gui He

Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202402695

Photodriven Disproportionation of Nitrogen and Its Change to Reductive Nitrogen Photofixation

Jianhua Yang, Haoyuan Bai, Yanzhen Guo, Han Zhang, Ruibin Jiang, Baocheng Yang, Jianfang Wang and Jimmy C. Yu

Angewandte Chemie, 2021, 133, 940
DOI: 10.1002/ange.202010192

Atomically Dispersed Iron Metal Site in a Porphyrin-Based Metal–Organic Framework for Photocatalytic Nitrogen Fixation

Shanshan Shang, Wei Xiong, Chao Yang, Bernt Johannessen, Rugeng Liu, Hsien-Yi Hsu, Qinfen Gu, Michael K. H. Leung and Jin Shang

ACS Nano, 2021, 15, 9670
DOI: 10.1021/acsnano.0c10947

The sequential activation of H2 and N2 mediated by the gas-phase Sc3N+ clusters: Formation of amido unit

Ming Wang, Chong-Yang Zhao, Hai-Yan Zhou, Yue Zhao, Ya-Ke Li and Jia-Bi Ma

The Journal of Chemical Physics, 2021, 154
DOI: 10.1063/5.0029180

Observation of new band in stimulated luminescence of solid nitrogen

M. A. Bludov, I. V. Khyzhniy, S. A. Uyutnov, G. B. Gumenchuk and E. V. Savchenko

Low Temperature Physics, 2025, 51, 104
DOI: 10.1063/10.0034653

Recent Advances in Single‐Atom Catalyst for Solar Energy Conversion: A Comprehensive Review and Future Outlook

Saad Mehmood, Saddam Sk, B. Moses Abraham, Mohsen Ahmadipour, Ujjwal Pal and Joydeep Dutta

Adv Funct Materials, 2025, 35
DOI: 10.1002/adfm.202418602

Bi-Atom Electrocatalyst for Electrochemical Nitrogen Reduction Reactions

Wenchao Zhang and Bin-Wei Zhang

Nano-Micro Lett., 2021, 13
DOI: 10.1007/s40820-021-00638-y

Dinitrogen Binding at a Trititanium Chloride Complex and Its Conversion to Ammonia under Ambient Conditions

Estefanía del Horno, Jesús Jover, Miguel Mena, Adrián Pérez‐Redondo and Carlos Yélamos

Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202204544

Developing Pathways to the Synthesis of Low‐Valence Molybdenum Methoxides: Preparation, Characterization, and Redox Chemistry of Dimeric and Tetrameric Molybdenum Alkoxide Clusters

Denis A. Kuznetsov, Ivan V. Fedyanin, Natal'ya S. Komarova, Gennady V. Shilov, Vyacheslav M. Martynenko, Sergey G. Vasil'ev, Alexander G. Krivenko, Konstantin A. Lyssenko and Tamara A. Bazhenova

Eur J Inorg Chem, 2015, 2015, 715
DOI: 10.1002/ejic.201403032

Light‐Induced Ammonia Generation over Defective Carbon Nitride Modified with Pyrite

Judith Zander, Jana Timm, Morten Weiss and Roland Marschall

Advanced Energy Materials, 2022, 12
DOI: 10.1002/aenm.202202403

Modifying Enzymatic Substrate Binding within a Metal–Organic Capsule for Supramolecular Catalysis

Yang Yang, Xu Jing, Youpeng Shi, Yuchen Wu and Chunying Duan

J. Am. Chem. Soc., 2023, 145, 10136
DOI: 10.1021/jacs.3c00626

Reduction of dinitrogen to ammonia on doped three-atom clusters Nb2M (M = Sc to Cu & Y to Ag)

Ran Cheng, Chao-Nan Cui and Zhi-Xun Luo

Rare Met., 2024, 43, 3810
DOI: 10.1007/s12598-024-02680-2

The Crucial Role of Charge Accumulation and Spin Polarization in Activating Carbon‐Based Catalysts for Electrocatalytic Nitrogen Reduction

Yuanyuan Yang, Lifu Zhang, Zhenpeng Hu, Yao Zheng, Cheng Tang, Ping Chen, Ruguang Wang, Kangwen Qiu, Jing Mao, Tao Ling and Shi‐Zhang Qiao

Angew Chem Int Ed, 2020, 59, 4525
DOI: 10.1002/anie.201915001

Photochemical Ammonia Synthesis over Reduced Polyoxovanadate-Intercalated Defective ZnAl Layered Double Hydroxide Nanosheets

Fengrui Li, Tuo Ji, Weichao Chen, Wei Du, Yonghui Wang, Yinan Hou and Weilin Chen

Inorg. Chem., 2023, 62, 9528
DOI: 10.1021/acs.inorgchem.3c00891

Group 4 Half-Sandwich Tris(trimethylsilylmethyl) Complexes: Thermal Decomposition and Reactivity with N,N-Dimethylamine–Borane

Maider Greño, Estefanía del Horno, Miguel Mena, Adrián Pérez-Redondo, Víctor Varela-Izquierdo and Carlos Yélamos

Inorg. Chem., 2017, 56, 11220
DOI: 10.1021/acs.inorgchem.7b01607

Recent achievements in rare earth modified metal oxides for environmental and energy applications: A review

Yicheng Li, Qian Liu, Tianhao Li, Hao Bi and Zhurui Shen

Chinese Chemical Letters, 2025, 36, 110698
DOI: 10.1016/j.cclet.2024.110698

Rational Design of Graphene Derivatives for Electrochemical Reduction of Nitrogen to Ammonia

Mandira Majumder, Haneesh Saini, Ivan Dědek, Andreas Schneemann, Nilesh R. Chodankar, Viswanatha Ramarao, Mysore Sridhar Santosh, Ashok Kumar Nanjundan, Štěpán Kment, Deepak Dubal, Michal Otyepka, Radek Zbořil and Kolleboyina Jayaramulu

ACS Nano, 2021, 15, 17275
DOI: 10.1021/acsnano.1c08455

Reaction of Ta3– Clusters with Molecular Nitrogen: A Mechanism Investigation

Xiaoli Sun and Xuri Huang

ACS Omega, 2022, 7, 22682
DOI: 10.1021/acsomega.2c02138

Electrocatalytic Synthesis of Urea: An In‐depth Investigation from Material Modification to Mechanism Analysis

Jianghui Cao, Fang Zhao, Chengjie Li, Qidong Zhao, Liguo Gao, Tingli Ma, Hao Xu, Xuefeng Ren and Anmin Liu

Small, 2024, 20
DOI: 10.1002/smll.202403412

Newly designed photocatalyst of Fe4 single clusters on g-C6N6 for nitrogen reduction reaction

Min Wang, Yuhong Huang, Fei Ma, Xiumei Wei, Pengfei Hou, Gangqiang Zhu, Ruhai Du and Jianmin Zhang

Computational and Theoretical Chemistry, 2023, 1222, 114074
DOI: 10.1016/j.comptc.2023.114074

High throughput computational screening of tantalum based small metal clusters for nitrogen fixation

Venkata Surya Kumar Choutipalli, Sai Saravanan Ambi Venkataramanan and Venkatesan Subramanian

Inorganica Chimica Acta, 2022, 530, 120700
DOI: 10.1016/j.ica.2021.120700

Enhancing Electrocatalytic NO Reduction to NH3 by the CoS Nanosheet with Sulfur Vacancies

Longcheng Zhang, Qiang Zhou, Jie Liang, Luchao Yue, Tingshuai Li, Yongsong Luo, Qian Liu, Na Li, Bo Tang, Feng Gong, Xiaodong Guo and Xuping Sun

Inorg. Chem., 2022, 61, 8096
DOI: 10.1021/acs.inorgchem.2c01112

Highly active manganese nitride-europium nitride catalyst for ammonia synthesis

Jiemin Wang, Lin Liu, Ruili Li, Shangshang Wang, Xiaohua Ju, Teng He, Jianping Guo and Ping Chen

iScience, 2024, 27, 110858
DOI: 10.1016/j.isci.2024.110858

Simultaneously Enhancing Adsorbed Hydrogen and Dinitrogen to Enable Efficient Electrochemical NH3 Synthesis on Sm(OH)3

Zengxiang Lv, Zexu Li, Honghong Liu, Weixiang Li, Tai-Sing Wu, Song Hong, Yukun Ruan, Yun-Liang Soo, Leiduan Hao, Liang Xu, Alex W. Robertson, Pei Xiong, Molly Meng-Jung Li, Liang-Xin Ding and Zhenyu Sun

Small Structures, 2023, 4
DOI: 10.1002/sstr.202300158

Dinitrogen-Facilitated Reversible Formation of a Si–H Bond in a Pincer-Supported Ni Complex

David J. Charboneau, David Balcells, Nilay Hazari, Hannah M. C. Lant, James M. Mayer, Patrick R. Melvin, Brandon Q. Mercado, Wesley D. Morris, Michal Repisky and Hee-Won Suh

Organometallics, 2016, 35, 3154
DOI: 10.1021/acs.organomet.6b00514

Rational Catalyst Design for N2 Reduction under Ambient Conditions: Strategies toward Enhanced Conversion Efficiency

Lei Shi, Yu Yin, Shaobin Wang and Hongqi Sun

ACS Catal., 2020, 10, 6870
DOI: 10.1021/acscatal.0c01081

Recent advances in wireless photofixation of dinitrogen to ammonia under the ambient condition: A review

Sriram Mansingh, Kundan Kumar Das, Sabiha Sultana and Kulamani Parida

Journal of Photochemistry and Photobiology C: Photochemistry Reviews, 2021, 47, 100402
DOI: 10.1016/j.jphotochemrev.2021.100402

Effect on electrochemical reduction of nitrogen to ammonia under ambient conditions: Challenges and opportunities for chemical fuels

Lijuan Niu, Li An, Xiayan Wang and Zaicheng Sun

Journal of Energy Chemistry, 2021, 61, 304
DOI: 10.1016/j.jechem.2021.01.018

Electrochemical Nitrogen Reduction Reaction Performance of Single-Boron Catalysts Tuned by MXene Substrates

Shisheng Zheng, Shunning Li, Zongwei Mei, Zongxiang Hu, Mihai Chu, Jiahua Liu, Xin Chen and Feng Pan

J. Phys. Chem. Lett., 2019, 10, 6984
DOI: 10.1021/acs.jpclett.9b02741

Fe-Mg alloy nitrogen carrier for chemical looping ammonia synthesis process formed by mechanochemical nitrogen fixation and heating hydrogenation

Zhicheng Deng and Yan Cao

Fuel, 2025, 384, 133930
DOI: 10.1016/j.fuel.2024.133930

Light‐Switchable Oxygen Vacancies in Ultrafine Bi5O7Br Nanotubes for Boosting Solar‐Driven Nitrogen Fixation in Pure Water

Shengyao Wang, Xiao Hai, Xing Ding, Kun Chang, Yonggang Xiang, Xianguang Meng, Zixin Yang, Hao Chen and Jinhua Ye

Advanced Materials, 2017, 29
DOI: 10.1002/adma.201701774

Electrochemical Nitrate Production via Nitrogen Oxidation with Atomically Dispersed Fe on N-Doped Carbon Nanosheets

Ying Guo, Shaoce Zhang, Rong Zhang, Donghong Wang, Daming Zhu, Xuewan Wang, Diwen Xiao, Na Li, Yuwei Zhao, Zhaodong Huang, Wenjie Xu, Shuangming Chen, Li Song, Jun Fan, Qing Chen and Chunyi Zhi

ACS Nano, 2022, 16, 655
DOI: 10.1021/acsnano.1c08109

Ammonia Iron: An Epistemic Challenge with Practical Consequences

Robert Schlögl

J. Phys. Chem. C, 2024, 128, 19601
DOI: 10.1021/acs.jpcc.4c05161

Photocatalytic nitrogen reduction to ammonia: Insights into the role of defect engineering in photocatalysts

Huidong Shen, Mengmeng Yang, Leiduan Hao, Jinrui Wang, Jennifer Strunk and Zhenyu Sun

Nano Res., 2022, 15, 2773
DOI: 10.1007/s12274-021-3725-0

Possibility of reducing the coordinated dinitrogen into ammonia and hydrazine using [Ru-L] (L = triamidoamine) and FLP-H $$_{2}$$ 2 : A DFT study

Thayalaraj Christopher Jeyakumar, Sambath Baskaran and Chinnappan Sivasankar

J Chem Sci, 2018, 130
DOI: 10.1007/s12039-018-1460-1

Ultrathin MoS2 Nanosheets for Electrocatalytic N2-To-NH3 Fixation Under Ambient Conditions

Yanmei Liao, Weijun Ye, Yinghong Zhu and Lianbang Wang

International Journal of Electrochemical Science, 2020, 15, 11555
DOI: 10.20964/2020.11.71

Iron-Doped MoO3 Nanosheets for Boosting Nitrogen Fixation to Ammonia at Ambient Conditions

Haohong Xian, Haoran Guo, Jiaojiao Xia, Qiru Chen, Yonglan Luo, Rui Song, Tingshuai Li and Enrico Traversa

ACS Appl. Mater. Interfaces, 2021, 13, 7142
DOI: 10.1021/acsami.0c19644

Fe Enhanced Visible-Light-Driven Nitrogen Fixation on BiOBr Nanosheets

Yang Liu, Zhuofeng Hu and Jimmy C. Yu

Chem. Mater., 2020, 32, 1488
DOI: 10.1021/acs.chemmater.9b04448

Electrocatalysis of N2to NH3by HKUST‐1 with High NH3Yield

Yueming Cao, Peipei Li, Tengteng Wu, Meiling Liu and Youyu Zhang

Chemistry An Asian Journal, 2020, 15, 1272
DOI: 10.1002/asia.201901714

Transition Metal‐dinitrogen Complex Embedded Graphene for Nitrogen Reduction Reaction

Yulu Yang, Jiandong Liu, Zengxi Wei, Shuangyin Wang and Jianmin Ma

ChemCatChem, 2019, 11, 2821
DOI: 10.1002/cctc.201900536

Metal–Organic Framework‐Based Photocatalysis for Solar Fuel Production

Juan‐Ding Xiao, Rui Li and Hai‐Long Jiang

Small Methods, 2023, 7
DOI: 10.1002/smtd.202201258

Carbon‐Based Metal‐Free Catalysts for Electrocatalytic Reduction of Nitrogen for Synthesis of Ammonia at Ambient Conditions

Shenlong Zhao, Xunyu Lu, Lianzhou Wang, Julian Gale and Rose Amal

Advanced Materials, 2019, 31
DOI: 10.1002/adma.201805367

Advances in S-scheme heterojunction semiconductor photocatalysts for CO2 reduction, nitrogen fixation and NOx degradation

Amit Kumar, Sahil Rana, Tongtong Wang, Pooja Dhiman, Gaurav Sharma, Bing Du and Florian J. Stadler

Materials Science in Semiconductor Processing, 2023, 168, 107869
DOI: 10.1016/j.mssp.2023.107869

Electrochemical Reduction of N2 to Ammonia Promoted by Hydrated Cation Ions: Mechanistic Insights from a Combined Computational and Experimental Study

Xin Mao, Xiaowan Bai, Guanzheng Wu, Qing Qin, Anthony P. O’Mullane, Yan Jiao and Aijun Du

J. Am. Chem. Soc., 2024, 146, 18743
DOI: 10.1021/jacs.4c06629

Nitrogen Reduction to Ammonia on Atomic‐Scale Active Sites under Mild Conditions

Xiao Yan, Daolan Liu, Huanhuan Cao, Feng Hou, Ji Liang and Shi Xue Dou

Small Methods, 2019, 3
DOI: 10.1002/smtd.201800501

Atomic Modulation, Structural Design, and Systematic Optimization for Efficient Electrochemical Nitrogen Reduction

Yiyin Huang, Dickson D. Babu, Zhen Peng and Yaobing Wang

Advanced Science, 2020, 7
DOI: 10.1002/advs.201902390

Synergistic Promotion of the Electrochemical Reduction of Nitrogen to Ammonia by Phosphorus and Potassium

Qikun Zhang, Baoliang Liu, Liping Yu, Yiling Bei and Bo Tang

ChemCatChem, 2020, 12, 334
DOI: 10.1002/cctc.201901519

Emerging Materials and Methods toward Ammonia‐Based Energy Storage and Conversion

Fei Chang, Wenbo Gao, Jianping Guo and Ping Chen

Advanced Materials, 2021, 33
DOI: 10.1002/adma.202005721

Ni2P loading on Cd0.5Zn0.5S solid solution for exceptional photocatalytic nitrogen fixation under visible light

Liqun Ye, Chunqiu Han, Zhaoyu Ma, Yumin Leng, Jue Li, Xiaoxu Ji, Dongqin Bi, Haiquan Xie and Zixuan Huang

Chemical Engineering Journal, 2017, 307, 311
DOI: 10.1016/j.cej.2016.08.102

Active and stable Fe-based catalyst, mechanism, and key role of alkali promoters in ammonia synthesis

Walid Al Maksoud, Rohit K. Rai, Natalia Morlanés, Moussab Harb, Rafia Ahmad, Samy Ould-Chikh, Dalaver Anjum, Mohamed N. Hedhili, Bedour E. Al-Sabban, Khalid Albahily, Luigi Cavallo and Jean-Marie Basset

Journal of Catalysis, 2021, 394, 353
DOI: 10.1016/j.jcat.2020.10.031

Methods for nitrogen activation by reduction and oxidation

Haldrian Iriawan, Suzanne Z. Andersen, Xilun Zhang, Benjamin M. Comer, Jesús Barrio, Ping Chen, Andrew J. Medford, Ifan E. L. Stephens, Ib Chorkendorff and Yang Shao-Horn

Nat Rev Methods Primers, 2021, 1
DOI: 10.1038/s43586-021-00053-y

Aryldiazonium Salts as Nitrogen‐Based Lewis Acids: Facile Synthesis of Tuneable Azophosphonium Salts

Evi R. M. Habraken, Nicolaas P. van Leest, Pim Hooijschuur, Bas de Bruin, Andreas W. Ehlers, Martin Lutz and J. Chris Slootweg

Angewandte Chemie, 2018, 130, 12105
DOI: 10.1002/ange.201806913

Recent Progress on Electrocatalyst and Photocatalyst Design for Nitrogen Reduction

Mengqiao Li, Hao Huang, Jingxiang Low, Chao Gao, Ran Long and Yujie Xiong

Small Methods, 2019, 3
DOI: 10.1002/smtd.201800388

Single Mo Atom Supported on Defective Boron Nitride Monolayer as an Efficient Electrocatalyst for Nitrogen Fixation: A Computational Study

Jingxiang Zhao and Zhongfang Chen

J. Am. Chem. Soc., 2017, 139, 12480
DOI: 10.1021/jacs.7b05213

Boosting the photocatalytic nitrogen reduction to ammonia through adsorption-plasmonic synergistic effects

Yunni Liu, Xingyu Ye, Ruping Li, Ying Tao, Chi Zhang, Zichao Lian, Dieqing Zhang and Guisheng Li

Chinese Chemical Letters, 2022, 33, 5162
DOI: 10.1016/j.cclet.2022.01.076

Photocatalytic Synthesis of Ammonia from Pinecone Graphite-Phase Carbon Nitride Loaded with MoS2 Nanosheets as Co-catalysts

Fushan Wen, Xiaoli Huang, Yajie Li, Le Pang, Yuan Xu and Tao Zhang

Langmuir, 2023, 39, 8475
DOI: 10.1021/acs.langmuir.3c00763

Cleavage and Formation of Molecular Dinitrogen in a Single System Assisted by Molybdenum Complexes Bearing Ferrocenyldiphosphine

Takamasa Miyazaki, Hiromasa Tanaka, Yoshiaki Tanabe, Masahiro Yuki, Kazunari Nakajima, Kazunari Yoshizawa and Yoshiaki Nishibayashi

Angewandte Chemie, 2014, 126, 11672
DOI: 10.1002/ange.201405673

Iron group elements (Fe, Co, Ni) in Electrocatalytic applications: Evaluation, characterization and prospects

Jiwen Wu, Naiyan Liu, Fengshi Li, Binbin Jia and Jinlong Zheng

Coordination Chemistry Reviews, 2025, 525, 216343
DOI: 10.1016/j.ccr.2024.216343

Atomistic Description of Reaction Intermediates for Supported Metathesis Catalysts Enabled by DNP SENS

Ta‐Chung Ong, Wei‐Chih Liao, Victor Mougel, David Gajan, Anne Lesage, Lyndon Emsley and Christophe Copéret

Angewandte Chemie, 2016, 128, 4821
DOI: 10.1002/ange.201510821

Recent Advances and Challenges of Electrocatalytic N2Reduction to Ammonia

Geletu Qing, Reza Ghazfar, Shane T. Jackowski, Faezeh Habibzadeh, Mona Maleka Ashtiani, Chuan-Pin Chen, Milton R. Smith and Thomas W. Hamann

Chem. Rev., 2020, 120, 5437
DOI: 10.1021/acs.chemrev.9b00659

In situ modification of cobalt on MXene/TiO2 as composite photocatalyst for efficient nitrogen fixation

Wanguo Gao, Xiaoman Li, Shijian Luo, Zhenglong Luo, Xu Zhang, Rong Huang and Min Luo

Journal of Colloid and Interface Science, 2021, 585, 20
DOI: 10.1016/j.jcis.2020.11.064

Electrocatalytic and Photocatalytic N2 Fixation Using Carbon Catalysts

Changchun Xu, Hongli Su, Shuaifei Zhao, Azadeh Nilghaz, Kunning Tang, Luxiang Ma and Zhuo Zou

Nanomaterials, 2025, 15, 65
DOI: 10.3390/nano15010065

Sulfur‐Vacancy Defective MoS2 as a Promising Electrocatalyst for Nitrogen Reduction Reaction under Mild Conditions

Bingping Liu, Chaoqun Ma, Da Liu and Shihai Yan

ChemElectroChem, 2021, 8, 3030
DOI: 10.1002/celc.202100534

Beyond Ammonia: Nitrogen–Element Bond Forming Reactions with Coordinated Dinitrogen

Sangmin Kim, Florian Loose and Paul J. Chirik

Chem. Rev., 2020, 120, 5637
DOI: 10.1021/acs.chemrev.9b00705

Electrocatalytic Reduction of Nitrogen to Hydrazine Using a Trinuclear Nickel Complex

Paramita Saha, Sk Amanullah and Abhishek Dey

J. Am. Chem. Soc., 2020, 142, 17312
DOI: 10.1021/jacs.0c08785

Iron–Cobalt-Based Materials: An Efficient Bimetallic Catalyst for Ammonia Synthesis at Low Temperatures

Rohit K. Rai, Walid Al Maksoud, Natalia Morlanés, Moussab Harb, Rafia Ahmad, Alessandro Genovese, Mohamed N. Hedhili, Luigi Cavallo and Jean-Marie Basset

ACS Catal., 2022, 12, 587
DOI: 10.1021/acscatal.1c05078

Effect of Cu(I)–N Active Sites on the N2 Photofixation Ability over Flowerlike Copper-Doped g-C3N4 Prepared via a Novel Molten Salt-Assisted Microwave Process: The Experimental and Density Functional Theory Simulation Analysis

Shaozheng Hu, Xiaoyu Qu, Jin Bai, Ping Li, Qiang Li, Fei Wang and Lijuan Song

ACS Sustainable Chem. Eng., 2017, 5, 6863
DOI: 10.1021/acssuschemeng.7b01089

NH3 synthesis via photo-assisted thermalcatalytic NO and H2O reduction by CO over Pd/TiO2: Synergistic effects of Pd and oxygen vacancies

Gang Cheng, Junhua Zou, Xinjie Song, Hongmei Tang, Qing Gong, Hongxian Liu and Wenxin Dai

Molecular Catalysis, 2025, 578, 115008
DOI: 10.1016/j.mcat.2025.115008

Group 6 Transition‐Metal/Boron Frustrated Lewis Pair Templates Activate N2and Allow its Facile Borylation and Silylation

Antoine Simonneau, Raphaël Turrel, Laure Vendier and Michel Etienne

Angewandte Chemie, 2017, 129, 12436
DOI: 10.1002/ange.201706226

Engineering green ammonia photoproduction from nitrogen: advances, challenges and perspectives

Ying Tang, Yang Song, Juan Jia, Zhipeng Liu, Hui Zeng, Xue Yang and Zebao Rui

Journal of Energy Chemistry, 2025
DOI: 10.1016/j.jechem.2025.07.088

Molybdenum-Containing Metalloenzymes and Synthetic Catalysts for Conversion of Small Molecules

Donghyeon Kim, Jaeheon Lee and Junhyeok Seo

Catalysts, 2021, 11, 217
DOI: 10.3390/catal11020217

Heteronuclear transition metal decorated C2N monolayer: Promising catalysts for nitrogen reduction reactions

Bilal Aladerah and Nirpendra Singh

International Journal of Hydrogen Energy, 2025, 127, 750
DOI: 10.1016/j.ijhydene.2025.04.190

Room‐Temperature Functionalization of N2 to Borylamine at a Molybdenum Complex

Maria F. Espada, Soukaina Bennaamane, Qian Liao, Nathalie Saffon‐Merceron, Stéphane Massou, Eric Clot, Noel Nebra, Marie Fustier‐Boutignon and Nicolas Mézailles

Angewandte Chemie, 2018, 130, 13047
DOI: 10.1002/ange.201805915

Nitrogen–Carbon Bond Formation by Reactions of a Titanium–Potassium Dinitrogen Complex with Carbon Dioxide, tert‐Butyl Isocyanate, and Phenylallene

Yusuke Nakanishi, Yutaka Ishida and Hiroyuki Kawaguchi

Angew Chem Int Ed, 2017, 56, 9193
DOI: 10.1002/anie.201704286

0D/2D AgInS2/MXene Z-scheme heterojunction nanosheets for improved ammonia photosynthesis of N2

Jiangzhou Qin, Xia Hu, Xinyong Li, Zhifan Yin, Baojun Liu and Kwok-ho Lam

Nano Energy, 2019, 61, 27
DOI: 10.1016/j.nanoen.2019.04.028

Protonation Studies of a Tungsten Dinitrogen Complex Supported by a Diphosphine Ligand Containing a Pendant Amine

Charles J. Weiss, Jonathan D. Egbert, Shentan Chen, Monte L. Helm, R. Morris Bullock and Michael T. Mock

Organometallics, 2014, 33, 2189
DOI: 10.1021/om401127v

Oxygen Vacancies of CeO2 Nanospheres by Mn-Doping: An Efficient Electrocatalyst for N2 Reduction under Ambient Conditions

Yuyao Ji, Wendong Cheng, Chengbo Li and Xingquan Liu

Inorg. Chem., 2022, 61, 28
DOI: 10.1021/acs.inorgchem.1c02989

Rational catalyst design for N2 electro-reduction: Regulation strategies and quick screen towards enhanced conversion efficiency

Jinzhou Zheng, Chaozheng He and Chenxu Zhao

Chinese Chemical Letters, 2025, 36, 111056
DOI: 10.1016/j.cclet.2025.111056

Sandwich-Structured Metal–Organic Framework/Polyoxometalate Nanocomposites for Photocatalytic Nitrogen Reduction under Visible Light

Xiaodong Liu, Xingwang Li, Jing Zhang, Yao Di, Xiaoshu Qu and Weilin Chen

ACS Appl. Nano Mater., 2025, 8, 15673
DOI: 10.1021/acsanm.5c02737

Direct Raman Spectroscopic Measurements of Biological Nitrogen Fixation under Natural Conditions: An Analytical Approach for Studying Nitrogenase Activity

Tobias Jochum, Agnes Fastnacht, Susan E. Trumbore, Jürgen Popp and Torsten Frosch

Anal. Chem., 2017, 89, 1117
DOI: 10.1021/acs.analchem.6b03101

Efficient electrochemical nitrogen fixation at iron phosphide (Fe2P) catalyst in alkaline medium

Beata Rytelewska, Anna Chmielnicka, Takwa Chouki, Magdalena Skunik-Nuckowska, Shaghayegh Naghdi, Dominik Eder, Aleksandra Michalowska, Tomasz Ratajczyk, Egon Pavlica, Saim Emin, Yongsheng Fu, Iwona A. Rutkowska and Pawel J. Kulesza

Electrochimica Acta, 2023, 471, 143360
DOI: 10.1016/j.electacta.2023.143360

Recent advances of ammonia synthesis under ambient conditions over metal-organic framework based electrocatalysts

Yu Yu, Yuan Li, Yu Fang, Lili Wen, Binbin Tu and Yi Huang

Applied Catalysis B: Environmental, 2024, 340, 123161
DOI: 10.1016/j.apcatb.2023.123161

Non‐Dissociative Activation of Chemisorbed Dinitrogen on One or Two Vanadium Atoms Supported by a Mo6S8 Cluster

Ya‐Ya Wang, Xun‐Lei Ding, Joseph Israel Gurti, Yan Chen, Wei Li, Xin Wang, Wen‐Jie Wang and Jia‐Jun Deng

ChemPhysChem, 2021, 22, 1645
DOI: 10.1002/cphc.202100195

Dinitrogen activation and transformation by multimetallic polyhydride complexes

Takanori Shima, Qingde Zhuo and Zhaomin Hou

Coordination Chemistry Reviews, 2022, 472, 214766
DOI: 10.1016/j.ccr.2022.214766

N–H Bond Dissociation Enthalpies and Facile H Atom Transfers for Early Intermediates of Fe–N2 and Fe–CN Reductions

Jonathan Rittle and Jonas C. Peters

J. Am. Chem. Soc., 2017, 139, 3161
DOI: 10.1021/jacs.6b12861

Catalytic Conversion of Dinitrogen into Ammonia under Ambient Reaction Conditions by Using Proton Source from Water

Yoshiaki Tanabe, Kazuya Arashiba, Kazunari Nakajima and Yoshiaki Nishibayashi

Chemistry An Asian Journal, 2017, 12, 2544
DOI: 10.1002/asia.201701067

Oxygen Vacancy–Enhanced Electrocatalytic Performances of TiO2 Nanosheets toward N2 Reduction Reaction

Caihong Fang, Ting Bi, Xiaoxiao Xu, Nan Yu, Zhiqing Cui, Ruibin Jiang and Baoyou Geng

Adv Materials Inter, 2019, 6
DOI: 10.1002/admi.201901034

Defect and interface engineering for electrochemical nitrogen reduction reaction under ambient conditions

Dongxue Guo, Shuo Wang, Jun Xu, Wenjun Zheng and Danhong Wang

Journal of Energy Chemistry, 2022, 65, 448
DOI: 10.1016/j.jechem.2021.06.012

Photoprompted Hot Electrons from Bulk Cross-Linked Graphene Materials and Their Efficient Catalysis for Atmospheric Ammonia Synthesis

Yanhong Lu, Yang Yang, Tengfei Zhang, Zhen Ge, Huicong Chang, Peishuang Xiao, Yuanyuan Xie, Lei Hua, Qingyun Li, Haiyang Li, Bo Ma, Naijia Guan, Yanfeng Ma and Yongsheng Chen

ACS Nano, 2016, 10, 10507
DOI: 10.1021/acsnano.6b06472

Counterion Dependence of Dinitrogen Activation and Functionalization by a Diniobium Hydride Anion

Shoi Suzuki, Yutaka Ishida, Hajime Kameo, Shigeyoshi Sakaki and Hiroyuki Kawaguchi

Angew Chem Int Ed, 2020, 59, 13444
DOI: 10.1002/anie.202006039

Refining Defect States in W18O49 by Mo Doping: A Strategy for Tuning N2 Activation towards Solar-Driven Nitrogen Fixation

Ning Zhang, Abdul Jalil, Daoxiong Wu, Shuangming Chen, Yifei Liu, Chao Gao, Wei Ye, Zeming Qi, Huanxin Ju, Chengming Wang, Xiaojun Wu, Li Song, Junfa Zhu and Yujie Xiong

J. Am. Chem. Soc., 2018, 140, 9434
DOI: 10.1021/jacs.8b02076

Modern applications of low-valent early transition metals in synthesis and catalysis

Evan P. Beaumier, Adam J. Pearce, Xin Yi See and Ian A. Tonks

Nat Rev Chem, 2018, 3, 15
DOI: 10.1038/s41570-018-0059-x

Boosting charge-transfer in tuned Au nanoparticles on defect-rich TiO2 nanosheets for enhancing nitrogen electroreduction to ammonia production

Peng Yang, Heng Guo, Haoran Wu, Fengying Zhang, Jiaxin Liu, Mengyue Li, Yuantao Yang, Yuehan Cao, Guidong Yang and Ying Zhou

Journal of Colloid and Interface Science, 2023, 636, 184
DOI: 10.1016/j.jcis.2023.01.002

Single Molybdenum Atom Anchored on N-Doped Carbon as a Promising Electrocatalyst for Nitrogen Reduction into Ammonia at Ambient Conditions

Chongyi Ling, Xiaowan Bai, Yixin Ouyang, Aijun Du and Jinlan Wang

J. Phys. Chem. C, 2018, 122, 16842
DOI: 10.1021/acs.jpcc.8b05257

Visible-Light-Driven Nitrogen Fixation Catalyzed by Bi5O7Br Nanostructures: Enhanced Performance by Oxygen Vacancies

Peishen Li, Ziang Zhou, Qiang Wang, Ming Guo, Shaowei Chen, Jingxiang Low, Ran Long, Wen Liu, Peiren Ding, Yunyun Wu and Yujie Xiong

J. Am. Chem. Soc., 2020, 142, 12430
DOI: 10.1021/jacs.0c05097

Ti3+-mediated MIL-125(Ti) by metal substitution for boosting photocatalytic N2 fixation

Cheng Liu, Qi Chen, Yueling Chen, Jimmy C. Yu, Jionghua Wu and Ling Wu

Journal of Colloid and Interface Science, 2025, 678, 616
DOI: 10.1016/j.jcis.2024.08.218

Machine Learning Accelerated Screening Advanced Single-Atom Anchored MXenes Electrocatalyst for Nitrogen Fixation

Gaobo Lin, Teng Guo, Wenwen Lin, Haoan Fan, Lei Guo, Zhenyu Zhang, Bolong Li, Jianghao Wang, Huiping Ji, Weiyu Song and Jie Fu

ACS Catal., 2025, 15, 13534
DOI: 10.1021/acscatal.4c06914

Theoretical exploration of bare and oxygen-functionalized Ti3C2 clusters for catalytic NH3 production

Sougata Saha, Sourav Ghoshal and Pranab Sarkar

J Chem Sci, 2023, 135
DOI: 10.1007/s12039-023-02169-y

Research Progress on the Application of MOF and MOF‐Based Materials in Nitrogen Reduction

Ying Zhu, Houqiang Ji, Tianyu Huang, Yangyang Sun and Huan Pang

Advanced Sustainable Systems, 2024
DOI: 10.1002/adsu.202400225

Single-molecule imaging of dinitrogen molecule adsorption on individual iron phthalocyanine

Chengding Gu, Jia Lin Zhang, Jian Qiang Zhong, Qian Shen, Xiong Zhou, Kaidi Yuan, Shuo Sun, Xu Lian, Zhirui Ma and Wei Chen

Nano Res., 2020, 13, 2393
DOI: 10.1007/s12274-020-2863-0

Recent Developments in Polymeric Carbon Nitride-Derived Photocatalysts and Electrocatalysts for Nitrogen Fixation

Zhonghao Wang, Xun Hu, Zhenzhen Liu, Guojun Zou, Guannan Wang and Kan Zhang

ACS Catal., 2019, 9, 10260
DOI: 10.1021/acscatal.9b03015

Activation of dinitrogen by gas-phase species

Li-hui Mou, Gui-duo Jiang, Zi-yu Li and Sheng-gui He

Chinese Journal of Chemical Physics, 2020, 33, 507
DOI: 10.1063/1674-0068/cjcp2008141

Constructing FeS2/MoS2 interface with asymmetric electron distribution for efficient neutral electrocatalytic nitrogen reduction

Jiawei Shi, Jun Ma, Jing Li, Hansong Cheng and Weiwei Cai

Applied Surface Science, 2025, 691, 162635
DOI: 10.1016/j.apsusc.2025.162635

Scandium Reduced Arene Complex: Protonation and Reaction with Azobenzene

Priyabrata Ghana, Thomas P. Spaniol and Jun Okuda

Chemistry An Asian Journal, 2021, 16, 3170
DOI: 10.1002/asia.202100684

Hydrosilylation of an Iron(IV) Nitride Complex

Juan A. Valdez-Moreira, Sean P. Millikan, Xinfeng Gao, Veronica Carta, Chun-Hsing Chen and Jeremy M. Smith

Inorg. Chem., 2020, 59, 579
DOI: 10.1021/acs.inorgchem.9b02831

An Amorphous Noble‐Metal‐Free Electrocatalyst that Enables Nitrogen Fixation under Ambient Conditions

Chade Lv, Chunshuang Yan, Gang Chen, Yu Ding, Jingxue Sun, Yansong Zhou and Guihua Yu

Angew Chem Int Ed, 2018, 57, 6073
DOI: 10.1002/anie.201801538

Progress in Biomass Electro‐Valorization for Paired Electrosynthesis of Valuable Chemicals and Fuels

Amira Ben Abderrahmane, Sophie Tingry, David Cornu and Yaovi Holade

Adv Energy and Sustain Res, 2024, 5
DOI: 10.1002/aesr.202300302

Ambient electrosynthesis of ammonia with efficient denitration

Xianyun Peng, Yuying Mi, Haihong Bao, Yifan Liu, Defeng Qi, Yuan Qiu, Longchao Zhuo, Shunzheng Zhao, Jiaqiang Sun, Xiaolong Tang, Jun Luo and Xijun Liu

Nano Energy, 2020, 78, 105321
DOI: 10.1016/j.nanoen.2020.105321

Recent Advances in Application of Graphitic Carbon Nitride‐Based Catalysts for Photocatalytic Nitrogen Fixation

Lei Zhang, Shaoqi Hou, Tianyi Wang, Sixiao Liu, Xiaochun Gao, Chengyin Wang and Guoxiu Wang

Small, 2022, 18
DOI: 10.1002/smll.202202252

Bioinspired and Bioderived Aqueous Electrocatalysis

Jesús Barrio, Angus Pedersen, Silvia Favero, Hui Luo, Mengnan Wang, Saurav Ch. Sarma, Jingyu Feng, Linh Tran Thi Ngoc, Simon Kellner, Alain You Li, Ana Belén Jorge Sobrido and Maria-Magdalena Titirici

Chem. Rev., 2023, 123, 2311
DOI: 10.1021/acs.chemrev.2c00429

Monodisperse Cu Cluster-Loaded Defective ZrO2 Nanofibers for Ambient N2 Fixation to NH3

Tingshuai Li, Jiaojiao Xia, Qiru Chen, Ke Xu, Yang Gu, Qian Liu, Yonglan Luo, Haoran Guo and Enrico Traversa

ACS Appl. Mater. Interfaces, 2021, 13, 40724
DOI: 10.1021/acsami.1c12279

High-performance gas-liquid-solid optofluidic microreactor with TiO2−x-Ag@HKUST-1/carbon paper for efficient photocatalytic nitrogen fixation to ammonia

Hui Zhao, Jihai Duan, Zisheng Zhang and Weiwen Wang

Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2023, 660, 130874
DOI: 10.1016/j.colsurfa.2022.130874

High‐Performance Electrochemical NO Reduction into NH3 by MoS2 Nanosheet

Longcheng Zhang, Jie Liang, Yuanyuan Wang, Ting Mou, Yiting Lin, Luchao Yue, Tingshuai Li, Qian Liu, Yonglan Luo, Na Li, Bo Tang, Yang Liu, Shuyan Gao, Abdulmohsen Ali Alshehri, Xiaodong Guo, Dongwei Ma and Xuping Sun

Angewandte Chemie, 2021, 133, 25467
DOI: 10.1002/ange.202110879

Direct Transformation of Molecular Dinitrogen into Ammonia Catalyzed by Cobalt Dinitrogen Complexes Bearing Anionic PNP Pincer Ligands

Shogo Kuriyama, Kazuya Arashiba, Hiromasa Tanaka, Yuki Matsuo, Kazunari Nakajima, Kazunari Yoshizawa and Yoshiaki Nishibayashi

Angew Chem Int Ed, 2016, 55, 14291
DOI: 10.1002/anie.201606090

Acetylene in Organic Synthesis: Recent Progress and New Uses

Vladimir V. Voronin, Maria S. Ledovskaya, Alexander S. Bogachenkov, Konstantin S. Rodygin and Valentine P. Ananikov

Molecules, 2018, 23, 2442
DOI: 10.3390/molecules23102442

Comparing Molecular Mechanisms in Solar NH3 Production and Relations with CO2 Reduction

Domenico Mallamace, Georgia Papanikolaou, Siglinda Perathoner, Gabriele Centi and Paola Lanzafame

IJMS, 2020, 22, 139
DOI: 10.3390/ijms22010139

Dinitrogen Activation and Hydrogenation by C5Me4SiMe3-Ligated Di- and Trinuclear Chromium Hydride Complexes

Takanori Shima, Jimin Yang, Gen Luo, Yi Luo and Zhaomin Hou

J. Am. Chem. Soc., 2020, 142, 9007
DOI: 10.1021/jacs.0c02939

MoS2 nanosheets supported gold nanoparticles for electrochemical nitrogen fixation at various pH value

Yan Zhou, Xinping Yu, Xueyuan Wang, Chen Chen, Shutao Wang and Jun Zhang

Electrochimica Acta, 2019, 317, 34
DOI: 10.1016/j.electacta.2019.05.111

Enhancing *CO and *N≡N Orbital Coupling via Tuned Mn d‐p Hybridization at MnO/Mn7C3 Interfaces for Highly Selective Urea Electrosynthesis

Xin Ge, Jili Yuan, Hu Li, Liang Wang, Haibo Xie and Chengbin Liu

Advanced Energy Materials, 2025
DOI: 10.1002/aenm.202503375

Innovative progress of thermal ammonia synthesis under mild conditions

Feiyang Tian, Jinkun Li, Wenqian Chen, Liang Tang and Minghong Wu

International Journal of Hydrogen Energy, 2024, 78, 92
DOI: 10.1016/j.ijhydene.2024.06.206

In-situ precipitation enabled Bi/BiFeO3 Schottky junction with an electronic tunnel for promoting photocatalytic ammonia synthesis

Zhaowu Zeng, Yongchao Wang, Xiaoyi Liu, Bing He, Jian Ding, Zhen Li, Panxing Zhu, Huan Wang, Yanli Zhao and Yang Wang

Applied Catalysis B: Environment and Energy, 2025, 378, 125596
DOI: 10.1016/j.apcatb.2025.125596

Direct Synthesis of Silylamine from N2 and a Silane: Mediated by a Tridentate Phosphine Molybdenum Fragment

Qian Liao, Anthony Cavaillé, Nathalie Saffon‐Merceron and Nicolas Mézailles

Angew Chem Int Ed, 2016, 55, 11212
DOI: 10.1002/anie.201604812

High Efficiency Electrochemical Nitrogen Fixation Achieved with a Lower Pressure Reaction System by Changing the Chemical Equilibrium

Hui Cheng, Peixin Cui, Fangrui Wang, Liang‐Xin Ding and Haihui Wang

Angewandte Chemie, 2019, 131, 15687
DOI: 10.1002/ange.201910658

Co-Doped Fe3S4 Nanoflowers for Boosting Electrocatalytic Nitrogen Fixation to Ammonia under Mild Conditions

Xue Chen, Hongfei Yin, Xiaoyong Yang, Weining Zhang, Dongdong Xiao, Zhen Lu, Yongzheng Zhang and Ping Zhang

Inorg. Chem., 2022, 61, 20123
DOI: 10.1021/acs.inorgchem.2c03578

Recent advances in single- and dual-atom catalysts for efficient nitrogen electro-reduction and their perspectives

Joyjit Kundu, Toshali Bhoyar, Saehyun Park, Haneul Jin, Kwangyeol Lee and Sang-Il Choi

Advanced Powder Materials, 2025, 4, 100279
DOI: 10.1016/j.apmate.2025.100279

Fe-based MOFs for photocatalytic N2 reduction: Key role of transition metal iron in nitrogen activation

Guoqiang Li, Feifei Li, Jianxin Liu and Caimei Fan

Journal of Solid State Chemistry, 2020, 285, 121245
DOI: 10.1016/j.jssc.2020.121245

Assessing the Activity of Transition Metal Oxides for the Electrochemical N2 Oxidation to Nitrate

Haldrian Iriawan, Graham Leverick, Barış Alkan, Daniel Delgado, John Eom, Hongbin Xu, Sunmoon Yu, Livia Giordano, Annette Trunschke, Ifan E. L. Stephens and Yang Shao-Horn

ACS Catal., 2025, 15, 6315
DOI: 10.1021/acscatal.4c07924

Direct transformation of dinitrogen: synthesis of N-containing organic compounds via N−C bond formation

Ze-Jie Lv, Junnian Wei, Wen-Xiong Zhang, Ping Chen, Dehui Deng, Zhang-Jie Shi and Zhenfeng Xi

National Science Review, 2020, 7, 1564
DOI: 10.1093/nsr/nwaa142

Functional customization of two-dimensional materials for photocatalytic activation and conversion of inert small molecules in the air

Ming Cheng, Lan Yang, Huanhuan Zhang, Jingjing Yang, Chong Xiao and Yi Xie

NSO, 2023, 2, 20220028
DOI: 10.1360/nso/20220028

Comprehensive Understanding of the Thriving Ambient Electrochemical Nitrogen Reduction Reaction

Xue Zhao, Guangzhi Hu, Gao‐Feng Chen, Haibo Zhang, Shusheng Zhang and Haihui Wang

Advanced Materials, 2021, 33
DOI: 10.1002/adma.202007650

Mo- and W-molecular catalysts for the H2 evolution, CO2 reduction and N2 fixation

Dang B. Tran, Tung H. To and Phong D. Tran

Coordination Chemistry Reviews, 2022, 457, 214400
DOI: 10.1016/j.ccr.2021.214400

Hydrogen-assisted activation of N2 molecules on atomic steps of ZnSe nanorods

Kun Du, Xiuyao Lang, Yuanyuan Yang, Chuanqi Cheng, Ning Lan, Kangwen Qiu, Jing Mao, Weichao Wang and Tao Ling

Nano Res., 2023, 16, 6721
DOI: 10.1007/s12274-023-5508-2

Recent Progress in Electrocatalytic Urea Synthesis under Ambient Conditions

Zongwei Mei, Yulong Zhou, Weiqiang Lv, Shengfu Tong, Xiaoyang Yang, Longquan Chen and Ning Zhang

ACS Sustainable Chem. Eng., 2022, 10, 12477
DOI: 10.1021/acssuschemeng.2c03681

Successive Protonation and Methylation of Bridging Imido and Nitrido Ligands at Titanium Complexes

Paula Barriopedro, Jorge Caballo, Miguel Mena, Adrián Pérez-Redondo and Carlos Yélamos

Inorg. Chem., 2020, 59, 7631
DOI: 10.1021/acs.inorgchem.0c00550

Nitrogen–Carbon Bond Formation by Reactions of a Titanium–Potassium Dinitrogen Complex with Carbon Dioxide, tert‐Butyl Isocyanate, and Phenylallene

Yusuke Nakanishi, Yutaka Ishida and Hiroyuki Kawaguchi

Angewandte Chemie, 2017, 129, 9321
DOI: 10.1002/ange.201704286

Br doped porous bismuth oxychloride micro-sheets with rich oxygen vacancies and dominating {0 0 1} facets for enhanced nitrogen photo-fixation performances

Dapeng Wu, Rui Wang, Can Yang, Yipeng An, Hai Lu, Hongju Wang, Kun Cao, Zhiyong Gao, Wenchao Zhang, Fang Xu and Kai Jiang

Journal of Colloid and Interface Science, 2019, 556, 111
DOI: 10.1016/j.jcis.2019.08.048

Vacancy‐Mediated Control of Local Electronic Structure for High‐Efficiency Electrocatalytic Conversion of N2 to NH3

Heng Guo, Peng Yang, Yuantao Yang, Haoran Wu, Fengying Zhang, Zhen‐Feng Huang, Guidong Yang and Ying Zhou

Small, 2024, 20
DOI: 10.1002/smll.202309007

Revealing electrocatalytic C N coupling for urea synthesis with metal–free electrocatalyst

Yongyong Cao, Yuxiao Meng, Runzhi An, Xuhui Zou, Hongjie Huang, Weichan Zhong, Zhangfeng Shen, Qineng Xia, Xi Li and Yangang Wang

Journal of Colloid and Interface Science, 2023, 641, 990
DOI: 10.1016/j.jcis.2023.03.135

Emerging Applications of Plasmons in Driving CO2 Reduction and N2 Fixation

Jianhua Yang, Yanzhen Guo, Wenzheng Lu, Ruibin Jiang and Jianfang Wang

Advanced Materials, 2018, 30
DOI: 10.1002/adma.201802227

Cryo IR spectroscopy and cryo kinetics of dinitrogen activation and cleavage by small tantalum cluster cations

Daniela V. Fries, Matthias P. Klein, Annika Straßner, Maximilian E. Huber, Maximilian Luczak, Christopher Wiehn and Gereon Niedner-Schatteburg

The Journal of Chemical Physics, 2023, 159
DOI: 10.1063/5.0157217

Direct Synthesis of Silylamine from N2 and a Silane: Mediated by a Tridentate Phosphine Molybdenum Fragment

Qian Liao, Anthony Cavaillé, Nathalie Saffon‐Merceron and Nicolas Mézailles

Angewandte Chemie, 2016, 128, 11378
DOI: 10.1002/ange.201604812

Multiple reaction pathway on alkaline earth imide supported catalysts for efficient ammonia synthesis

Zichuang Li, Yangfan Lu, Jiang Li, Miao Xu, Yanpeng Qi, Sang-Won Park, Masaaki Kitano, Hideo Hosono, Jie-Sheng Chen and Tian-Nan Ye

Nat Commun, 2023, 14
DOI: 10.1038/s41467-023-42050-7

Advancements in Non‐Noble Metal Based Plasmonic Materials for Sustainable Nitrogen Photofixation

Dev Kumar Thapa and Soumava Biswas

Advanced Sustainable Systems, 2025, 9
DOI: 10.1002/adsu.202400954

Solar Water Splitting and Nitrogen Fixation with Layered Bismuth Oxyhalides

Jie Li, Hao Li, Guangming Zhan and Lizhi Zhang

Acc. Chem. Res., 2017, 50, 112
DOI: 10.1021/acs.accounts.6b00523

Recent Progress in Dinitrogen Activation by Gas-Phase Metal Species

Li-Hui Mou, Zi-Yu Li and Sheng-Gui He

J. Phys. Chem. Lett., 2022, 13, 4159
DOI: 10.1021/acs.jpclett.2c00850

Side-On Bound Beryllium Dinitrogen Complex: A Precursor for Complete Conversion of Dinitrogen to Ammonia Mediated by N-Heterocyclic Carbene

Siddhartha K. Purkayastha and Ankur K. Guha

J. Phys. Chem. A, 2025, 129, 705
DOI: 10.1021/acs.jpca.4c06738

Theoretical screening of double-atom metals anchored on defective boron nitride for N2 reduction

Xin Lian, Xinlin Tang, Haiyue Liao, Wenlong Guo, Yunhuai Zhang and Guangyong Gao

Reac Kinet Mech Cat, 2024, 137, 3241
DOI: 10.1007/s11144-024-02691-1

Enriched oxygen vacancies of Cu2O/SnS2/SnO2 heterostructure for enhanced photocatalytic reduction of CO2 by water and nitrogen fixation

Niwesh Ojha, Abhinav Bajpai and Sushant Kumar

Journal of Colloid and Interface Science, 2021, 585, 764
DOI: 10.1016/j.jcis.2020.10.056

Machine learning-assisted Ru-N bond regulation for ammonia synthesis

Zichuang Li, Mingxin Zhang, Xiaozhi Su, Yangfan Lu, Jiang Li, Qing Zhang, Wenqian Li, Kailong Qian, Xiaojun Lu, Bo Dai, Hideo Hosono, Yanpeng Qi, Miao Xu, Renzhong Tai, Jie-Sheng Chen and Tian-Nan Ye

Nat Commun, 2025, 16
DOI: 10.1038/s41467-025-63064-3

Oxygen vacancies engineering in electrocatalysts nitrogen reduction reaction

Haijiang Zhu, Chao Wang, Yuling He, Yi Pu, Peiwen Li, Liang He, Xianglan Huang, Wu Tang and Hui Tang

Front. Chem., 2022, 10
DOI: 10.3389/fchem.2022.1039738

Enhanced Nitrogen Photofixation over LaFeO3 via Acid Treatment

Xiang Sun, Dong Jiang, Ling Zhang, Songmei Sun and Wenzhong Wang

ACS Sustainable Chem. Eng., 2017, 5, 9965
DOI: 10.1021/acssuschemeng.7b01912

Molecular Crowding Effect in Aqueous Electrolytes to Suppress Hydrogen Reduction Reaction and Enhance Electrochemical Nitrogen Reduction

Ying Guo, Jinxing Gu, Rong Zhang, Shaoce Zhang, Zhen Li, Yuwei Zhao, Zhaodong Huang, Jun Fan, Zhongfang Chen and Chunyi Zhi

Advanced Energy Materials, 2021, 11
DOI: 10.1002/aenm.202101699

Fundamentals and Recent Progress of Photocatalytic Nitrogen‐Fixation Reaction over Semiconductors

Shengtao Chen, Dong Liu and Tianyou Peng

Solar RRL, 2021, 5
DOI: 10.1002/solr.202000487

Single-layer MoS2 with adjacent Mo sites for efficient electrocatalytic nitrogen fixation via spin-delocalized electrons effect

Guangming Zhan, Fengjiao Quan, Yancai Yao, Shengxi Zhao, Xiufan Liu, Huayu Gu, Yi Huang, Xiao Liu, Falong Jia and Lizhi Zhang

Applied Catalysis B: Environmental, 2023, 323, 122186
DOI: 10.1016/j.apcatb.2022.122186

Electrochemical N2 Reduction to Ammonia Using Single Au/Fe Atoms Supported on Nitrogen-Doped Porous Carbon

Sudhir K. Sahoo, Julian Heske, Markus Antonietti, Qing Qin, Martin Oschatz and Thomas D. Kühne

ACS Appl. Energy Mater., 2020, 3, 10061
DOI: 10.1021/acsaem.0c01740

Exploring trimetallic clusters containing alkali and alkaline earth metal atoms with high activity for nitrogen activation

Xue-Qian Huang, Xun-Lei Ding, Jian Wang, Ya-Ya Wang, Joseph Israel Gurti, Yan Chen, Meng-Meng Wang, Wei Li and Xin Wang

Struct Chem, 2023, 34, 87
DOI: 10.1007/s11224-022-01919-x

An Overview on Transition Metal Catalyzed Ammonia Generation Through N─N Bond Cleavage of Hydrazine

Aisa Mohanty and Prosenjit Daw

Chemistry An Asian Journal, 2025
DOI: 10.1002/asia.202500657

Recent Advanced Materials for Electrochemical and Photoelectrochemical Synthesis of Ammonia from Dinitrogen: One Step Closer to a Sustainable Energy Future

Zihao Yan, Mengxia Ji, Jiexiang Xia and Huiyuan Zhu

Advanced Energy Materials, 2020, 10
DOI: 10.1002/aenm.201902020

Site-Selective Growth of Crystalline Ceria with Oxygen Vacancies on Gold Nanocrystals for Near-Infrared Nitrogen Photofixation

Henglei Jia, Aoxuan Du, Han Zhang, Jianhua Yang, Ruibin Jiang, Jianfang Wang and Chun-yang Zhang

J. Am. Chem. Soc., 2019, 141, 5083
DOI: 10.1021/jacs.8b13062

Multi‐Site Electrocatalysts Boost pH‐Universal Nitrogen Reduction by High‐Entropy Alloys

Dan Zhang, Huan Zhao, Xueke Wu, Ying Deng, Zuochao Wang, Yi Han, Hongdong Li, Yue Shi, Xilei Chen, Shaoxiang Li, Jianping Lai, Bolong Huang and Lei Wang

Adv Funct Materials, 2021, 31
DOI: 10.1002/adfm.202006939

Looking for Options to Sustainably Fixate Nitrogen. Are Molecular Metal Oxides Catalysts a Viable Avenue?

Rebeca González-Cabaleiro, Jake A. Thompson and Laia Vilà-Nadal

Front. Chem., 2021, 9
DOI: 10.3389/fchem.2021.742565

Fe S bridged CdS/MIL-68(Fe) heterojunction for biomimetic photocatalytic N2 fixation

Qi Chen, Zewei Zhang, Yueling Chen, Jimmy C. Yu, Cheng Liu and Ling Wu

Applied Catalysis B: Environment and Energy, 2026, 380, 125823
DOI: 10.1016/j.apcatb.2025.125823

Functionalization of N 2 to NH 3 via direct N ≡ N bond cleavage using M(III)(NMe 2 ) 3 (M=W/Mo): A theoretical study

SAMBATH BASKARAN, PERUMAL BALU and CHINNAPPAN SIVASANKAR

J Chem Sci, 2015, 127, 83
DOI: 10.1007/s12039-014-0752-3

Recent Progress in Computational Design of Single-Atom/Cluster Catalysts for Electrochemical and Solar-Driven N2 Fixation

Sourav Ghoshal, Atish Ghosh, Prodyut Roy, Biswajit Ball, Anup Pramanik and Pranab Sarkar

ACS Catal., 2022, 12, 15541
DOI: 10.1021/acscatal.2c04527

Side‐on‐End‐on Coordination of Dinitrogen on a Polynuclear Vanadium Nitride Cluster Anion [V5N5]−

Xin Cheng, Zi‐Yu Li, Li‐Hui Mou, Yi Ren, Qing‐Yu Liu, Xun‐Lei Ding and Sheng‐Gui He

Chemistry A European J, 2019, 25, 16523
DOI: 10.1002/chem.201904362

Metal‐Nitrogen‐Doped Carbon Materials as Highly Efficient Catalysts: Progress and Rational Design

Zhangsheng Shi, Wenqing Yang, Yuantong Gu, Ting Liao and Ziqi Sun

Advanced Science, 2020, 7
DOI: 10.1002/advs.202001069

Facile and controllable preparation of carbon microsphere for electro-driven nitrogen reduction: Accommodating nitrogen doping with hierarchical porous structure

Da-Wei Liu, Lei Ji, Yan Nie, Yong Li, Long Xu, Ji-Quan Liu and Ganglin Xue

Journal of Colloid and Interface Science, 2023, 634, 995
DOI: 10.1016/j.jcis.2022.12.105

Strategic nitrogen defect engineering for optimizing the photocatalytic performance of polymerized carbon nitride: Identification, synthesis, and mechanism

Zhangkai Chen, Meifang Li, Xinjiang Hu, Yuan Yuan, Hui Wang, Jiaqin Deng, Xiaodong Ji, Guoyu Li, Yuan Ouyang and Ni Liu

Journal of Environmental Chemical Engineering, 2023, 11, 111121
DOI: 10.1016/j.jece.2023.111121

Mixed-Valent Cobalt-Modulated Tungsten Trioxide Nanorod Arrays for Improved Photocatalytic N2 Fixation

Huaiwei Zhang, Qingyu Liu, Yifan Chen, Lang Pei, Liang Bao and Yong-Jun Yuan

J. Phys. Chem. C, 2021, 125, 21997
DOI: 10.1021/acs.jpcc.1c06832

Molecular Catalysts for N2 Reduction: State of the Art, Mechanism, and Challenges

Yoann Roux, Carole Duboc and Marcello Gennari

ChemPhysChem, 2017, 18, 2606
DOI: 10.1002/cphc.201700665

Application of 93Nb NMR spectroscopy to (silox)3Nb(Xn/Lm) complexes (silox =tBu3SiO): Where does (silox)3Nb(NN)Nb(silox)3 appear?

Elliott B. Hulley, Valerie A. Williams, Kurt F. Hirsekorn, Peter T. Wolczanski, Kyle M. Lancaster and Emil B. Lobkovsky

Polyhedron, 2016, 103, 105
DOI: 10.1016/j.poly.2015.10.005

Progress in Single/Multi Atoms and 2D‐Nanomaterials for Electro/Photocatalytic Nitrogen Reduction: Experimental, Computational and Machine Leaning Developments

Aditya Narayan Singh, Rohit Anand, Mohammad Zafari, Miran Ha and Kwang S. Kim

Advanced Energy Materials, 2024, 14
DOI: 10.1002/aenm.202304106

Overview: Insight into NH3 permselective membranes and their application to a membrane reactor for efficient ammonia production

Wei-Wei Yan and Toshinori Tsuru

Separation and Purification Technology, 2025, 370, 133275
DOI: 10.1016/j.seppur.2025.133275

Fe-Pt nanoclusters modified Mott-Schottky photocatalysts for enhanced ammonia synthesis at ambient conditions

Zhen Li, Zhuoyang Gao, Bingwen Li, Lili Zhang, Rong Fu, Yan Li, Xiaoyue Mu and Lu Li

Applied Catalysis B: Environmental, 2020, 262, 118276
DOI: 10.1016/j.apcatb.2019.118276

Synthesis and Characterization of a Bridging Cerium(IV) Nitride Complex

Henry H. Wilson, Xiaojuan Yu, Thibault Cheisson, Patrick W. Smith, Pragati Pandey, Patrick J. Carroll, Stefan G. Minasian, Jochen Autschbach and Eric J. Schelter

J. Am. Chem. Soc., 2023, 145, 781
DOI: 10.1021/jacs.2c12145

Selective Catalytic Reduction of N2 to N2H4 by a Simple Fe Complex

Peter J. Hill, Laurence R. Doyle, Andrew D. Crawford, William K. Myers and Andrew E. Ashley

J. Am. Chem. Soc., 2016, 138, 13521
DOI: 10.1021/jacs.6b08802

Ammonia electrosynthesis on single-atom catalysts: Mechanistic understanding and recent progress

Panpan Li, Zhiwei Fang, Zhaoyu Jin and Guihua Yu

Chemical Physics Reviews, 2021, 2
DOI: 10.1063/5.0069736

Insight into the Iron–Molybdenum Cofactor of Nitrogenase from Synthetic Iron Complexes with Sulfur, Carbon, and Hydride Ligands

Ilija Čorić and Patrick L. Holland

J. Am. Chem. Soc., 2016, 138, 7200
DOI: 10.1021/jacs.6b00747

Synthesis and Catalytic Activity of Molybdenum–Nitride Complexes Bearing Pincer Ligands

Eriko Kinoshita, Kazuya Arashiba, Shogo Kuriyama, Aya Eizawa, Kazunari Nakajima and Yoshiaki Nishibayashi

Eur J Inorg Chem, 2015, 2015, 1789
DOI: 10.1002/ejic.201500017

Identification of M‐NH2‐NH2 Intermediate and Rate Determining Step for Nitrogen Reduction with Bioinspired Sulfur‐Bonded FeW Catalyst

Yilong Zhao, Fusheng Li, Wenlong Li, Yingzheng Li, Chang Liu, Ziqi Zhao, Yu Shan, Yongfei Ji and Licheng Sun

Angewandte Chemie, 2021, 133, 20494
DOI: 10.1002/ange.202104918

Ternary ruthenium complex hydrides for ammonia synthesis via the associative mechanism

Qianru Wang, Jaysree Pan, Jianping Guo, Heine Anton Hansen, Hua Xie, Ling Jiang, Lei Hua, Haiyang Li, Yeqin Guan, Peikun Wang, Wenbo Gao, Lin Liu, Hujun Cao, Zhitao Xiong, Tejs Vegge and Ping Chen

Nat Catal, 2021, 4, 959
DOI: 10.1038/s41929-021-00698-8

Fundamentals and Advances in Emerging Crystalline Porous Materials for Photocatalytic and Electrocatalytic Nitrogen Fixation

Jinheng Li, Xiaolei Guo, Li Gan, Zhen-Feng Huang, Lun Pan, Chengxiang Shi, Xiangwen Zhang, Guidong Yang and Ji-Jun Zou

ACS Appl. Energy Mater., 2022, 5, 9241
DOI: 10.1021/acsaem.2c01346

A Review of Electrocatalytic Reduction of Dinitrogen to Ammonia under Ambient Conditions

Xiaoyang Cui, Cheng Tang and Qiang Zhang

Advanced Energy Materials, 2018, 8
DOI: 10.1002/aenm.201800369

High‐Throughput Screening Technologies of Efficient Catalysts for the Ammonia Economy

Xu Quan, Ming Cheng, Ke Wang, Linlong Hu, Yao Shi, Mi Yan and Pengfei Xie

ChemCatChem, 2025, 17
DOI: 10.1002/cctc.202401001

Direct Transformation of Molecular Dinitrogen into Ammonia Catalyzed by Cobalt Dinitrogen Complexes Bearing Anionic PNP Pincer Ligands

Shogo Kuriyama, Kazuya Arashiba, Hiromasa Tanaka, Yuki Matsuo, Kazunari Nakajima, Kazunari Yoshizawa and Yoshiaki Nishibayashi

Angewandte Chemie, 2016, 128, 14503
DOI: 10.1002/ange.201606090

Recent advances in TiO2‐based catalysts for N2 reduction reaction

Jiayin Chen, Wei Zhang, Haoze Li, Wei Li and Dongyuan Zhao

SusMat, 2021, 1, 174
DOI: 10.1002/sus2.13

Dinitrogen Activation and Cyanide Release by the Gas-Phase Cluster Anions InNbC2–: Synergistic Effects of the p-Block Indium and the d-Block Niobium

Xiao-Wang Li, Feng-Xiang Zhang, Xi-Guan Zhao, Qing-Yu Liu, Sheng-Gui He and Jia-Bi Ma

J. Am. Chem. Soc., 2025, 147, 22185
DOI: 10.1021/jacs.5c06920

Activation and Functionalization of Dinitrogen in the Presence of Molecular Hydrogen Promoted by Transition Metal Complexes

Chinnappan Sivasankar, Packirisamy Kuzhalmozhi Madarasi and Masilamani Tamizmani

Eur J Inorg Chem, 2020, 2020, 1383
DOI: 10.1002/ejic.201901130

Enhanced Photofixation of Dinitrogen to Ammonia over a Biomimetic Metal (Fe,Mo)-Doped Mesoporous MCM-41 Zeolite Catalyst under Ambient Conditions

Suresh Thangudu, Chien-Hou Wu, Chih-Hao Lee and Kuo Chu Hwang

ACS Sustainable Chem. Eng., 2021, 9, 8748
DOI: 10.1021/acssuschemeng.1c01208

Spectroscopic Description of the E1 State of Mo Nitrogenase Based on Mo and Fe X-ray Absorption and Mössbauer Studies

Casey Van Stappen, Roman Davydov, Zhi-Yong Yang, Ruixi Fan, Yisong Guo, Eckhard Bill, Lance C. Seefeldt, Brian M. Hoffman and Serena DeBeer

Inorg. Chem., 2019, 58, 12365
DOI: 10.1021/acs.inorgchem.9b01951

Catalytic photo-redox of simulated air into ammonia over bimetallic MOFs nanosheets with oxygen vacancies

Wenjun Zhao, Jiangzhou Qin, Wei Teng, Jincheng Mu, Chang Chen, Jun Ke, Jacob C. Huang, Baojun Liu and Shaobin Wang

Applied Catalysis B: Environmental, 2022, 305, 121046
DOI: 10.1016/j.apcatb.2021.121046

Bi-based visible light-driven nano-photocatalyst: the design, synthesis, and its application in pollutant governance and energy development

Yanyan Cui, Mengke Li, Nali Zhu, Yan Cheng, Su Shiung Lam, Jun Chen, Yuxi Gao and Jiating Zhao

Nano Today, 2022, 43, 101432
DOI: 10.1016/j.nantod.2022.101432

Photocatalytic nitrogen fixation under an ambient atmosphere using a porous coordination polymer with bridging dinitrogen anions

Yan Xiong, Bang Li, Yuming Gu, Tong Yan, Zhigang Ni, Shuhua Li, Jing-Lin Zuo, Jing Ma and Zhong Jin

Nat. Chem., 2023, 15, 286
DOI: 10.1038/s41557-022-01088-8

C–H Bond Activation by an Isolated Dinuclear U(III)/U(IV) Nitride

Chad T. Palumbo, Rosario Scopelliti, Ivica Zivkovic and Marinella Mazzanti

J. Am. Chem. Soc., 2020, 142, 3149
DOI: 10.1021/jacs.9b12804

Recent progress in electrocatalytic nitrogen reduction to ammonia (NRR)

Zanling Huang, Madiha Rafiq, Abebe Reda Woldu, Qing-Xiao Tong, Didier Astruc and Liangsheng Hu

Coordination Chemistry Reviews, 2023, 478, 214981
DOI: 10.1016/j.ccr.2022.214981

Lighting the Path to Practical Applications of Single‐Atom Catalysts in Photocatalysis: The Role of Platinum Group Single Atoms in Enhancing Catalytic Activity

Zi Qi Chen, Aldrich Ngan, Christopher Chan, Jaeha Lee, David Dwi Sanjaya and Frank Gu

Solar RRL, 2025, 9
DOI: 10.1002/solr.202400804

Structural Enzymology of Nitrogenase Enzymes

Oliver Einsle and Douglas C. Rees

Chem. Rev., 2020, 120, 4969
DOI: 10.1021/acs.chemrev.0c00067

Dinitrogen Activation by Dihydrogen and Quaternary Cluster Anions AuNbBO–: Nb- and B-Mediated N2 Activation and Au-Assisted Nitrogen Transfer

Ying Li, Yong-Qi Ding, Shaodong Zhou and Jia-Bi Ma

J. Phys. Chem. Lett., 2022, 13, 4058
DOI: 10.1021/acs.jpclett.2c00945

Emerging Metal Single Atoms in Electrocatalysts and Batteries

Lianbo Ma, Guoyin Zhu, Dandan Wang, Huixian Chen, Yaohui Lv, Yizhou Zhang, Xiaojun He and Huan Pang

Adv Funct Materials, 2020, 30
DOI: 10.1002/adfm.202003870

Photo-derived fixation of dinitrogen into ammonia at ambient condition with water on ruthenium/coal-based carbon nanosheets

Abuduheiremu Awati, Halidan Maimaiti, Shixin Wang and Bo Xu

Science of The Total Environment, 2019, 695, 133865
DOI: 10.1016/j.scitotenv.2019.133865

Enabling Unconventional “Alternating‐Distal” N2 Reduction Pathway for Efficient Ammonia Electrosynthesis

Chu Zhang, Qing Wang, Zeyu Li, Hengjie Liu, Lixiang Zhong, Jiawei Liu, Zheng Wang, Runjie Wu, Pin Song, Wen‐Jie Chen, Zeming Qi, Chunshuang Yan, Li Song, Qingyu Yan and Chade Lv

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202502957

Multimetallic Catalysis Based on Heterometallic Complexes and Clusters

Paulin Buchwalter, Jacky Rosé and Pierre Braunstein

Chem. Rev., 2015, 115, 28
DOI: 10.1021/cr500208k

Electrocatalytic Reduction of Nitrogen to Ammonia Using Tiara‐like Phenylethanethiolated Nickel Cluster

Manju P. Maman, Tamilselvi Gurusamy, Arun K. Pal, Rajkumar Jana, Kothandaraman Ramanujam, Ayan Datta and Sukhendu Mandal

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202305462

Two-Dimensional Transition Metal Porphyrin Sheets as a Promising Single-Atom-Catalyst for Dinitrogen Electrochemical Reduction to Ammonia: A Theoretical Study

Shiqiang Liu, Yawei Liu, Xiaoping Gao, Yujia Tan, Zhiwen Cheng, Zhemin Shen and Maohong Fan

J. Phys. Chem. C, 2020, 124, 1492
DOI: 10.1021/acs.jpcc.9b10294

A recent review on photochemical and electrochemical nitrogen reduction to ammonia: Strategies to improve NRR selectivity and faradaic efficiency

Mohammed Ismael and Michael Wark

Applied Materials Today, 2024, 39, 102253
DOI: 10.1016/j.apmt.2024.102253

Study on the Regulation of Different Components at the Reaction Interface of the Electrocatalytic Nitrogen Reduction System and Its Synthetic Ammonia Performance

逢春周

JAPC, 2024, 13, 640
DOI: 10.12677/japc.2024.134067

Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage

Brian M. Hoffman, Dmitriy Lukoyanov, Zhi-Yong Yang, Dennis R. Dean and Lance C. Seefeldt

Chem. Rev., 2014, 114, 4041
DOI: 10.1021/cr400641x

Dinitrogen reduction using ruthenium coordinated by nitrogen‐doped graphene and cobalt complex coordinated by anionic PNP pincer ligand as catalysts and Frustrated Lewis Pair as a co‐catalyst: Density Functional Theory studies

Akhil K. Sivan, Jisha Mary Thomas and Chinnappan Sivasankar

Applied Organom Chemis, 2023, 37
DOI: 10.1002/aoc.7001

Expanding Boundaries: N2 Cleavage and Functionalization beyond Early Transition Metals

Máté J. Bezdek and Paul J. Chirik

Angew Chem Int Ed, 2016, 55, 7892
DOI: 10.1002/anie.201603142

Bioinspired Electrocatalyst for Electrochemical Reduction of N2 to NH3 in Ambient Conditions

Haohong Xian, Haoran Guo, Zhishu Chen, Guangsen Yu, Abdulmohsen Ali Alshehri, Khalid Ahmed Alzahrani, Feng Hao, Rui Song and Tingshuai Li

ACS Appl. Mater. Interfaces, 2020, 12, 2445
DOI: 10.1021/acsami.9b18027

Room‐Temperature Functionalization of N2 to Borylamine at a Molybdenum Complex

Maria F. Espada, Soukaina Bennaamane, Qian Liao, Nathalie Saffon‐Merceron, Stéphane Massou, Eric Clot, Noel Nebra, Marie Fustier‐Boutignon and Nicolas Mézailles

Angew Chem Int Ed, 2018, 57, 12865
DOI: 10.1002/anie.201805915

Advances in ammonia electrosynthesis from ambient nitrate/nitrite reduction

Jie Liang, Zixiao Li, Longcheng Zhang, Xun He, Yongsong Luo, Dongdong Zheng, Yan Wang, Tingshuai Li, Hong Yan, Binwu Ying, Shengjun Sun, Qian Liu, Mohamed S. Hamdy, Bo Tang and Xuping Sun

Chem, 2023, 9, 1768
DOI: 10.1016/j.chempr.2023.05.037

Layered‐Double‐Hydroxide Nanosheets as Efficient Visible‐Light‐Driven Photocatalysts for Dinitrogen Fixation

Yufei Zhao, Yunxuan Zhao, Geoffrey I. N. Waterhouse, Lirong Zheng, Xingzong Cao, Fei Teng, Li‐Zhu Wu, Chen‐Ho Tung, Dermot O'Hare and Tierui Zhang

Advanced Materials, 2017, 29
DOI: 10.1002/adma.201703828

Nitrogen Sorption in a Transition Metal Complex Solution for N2 Rejection from Methane

Zhikao Li, Gongkui Xiao, Brendan Graham, Gang Li and Eric F. May

Ind. Eng. Chem. Res., 2019, 58, 13284
DOI: 10.1021/acs.iecr.9b01356

NO hydrogenation to NH3 over FeCu/TiO2 catalyst with improved activity

Dan Cui, Yanqin Li, Keke Pan, Jinbao Liu, Qiang Wang, Minmin Liu, Peng Cao, Jianming Dan, Bin Dai and Feng Yu

Front. Chem. Sci. Eng., 2023, 17, 1973
DOI: 10.1007/s11705-023-2364-2

Ultrafine Cu nanoparticles decorated porous TiO2 for high-efficient electrocatalytic reduction of NO to synthesize NH3

Lei Chen, Wenting Sun, Zhiying Xu, Minghui Hao, Baojing Li, Xin Liu, Jingjing Ma, Liang Wang, Chunhu Li and Wentai Wang

Ceramics International, 2022, 48, 21151
DOI: 10.1016/j.ceramint.2022.04.006

Dinitrogen Splitting Coupled to Protonation

Gleb A. Silantyev, Moritz Förster, Bastian Schluschaß, Josh Abbenseth, Christian Würtele, Christian Volkmann, Max C. Holthausen and Sven Schneider

Angewandte Chemie, 2017, 129, 5966
DOI: 10.1002/ange.201701504

Cleavage of Dinitrogen from Forming Gas by a Titanium Molecular System under Ambient Conditions

Mariano González‐Moreiras, Miguel Mena, Adrián Pérez‐Redondo and Carlos Yélamos

Chemistry A European J, 2017, 23, 3558
DOI: 10.1002/chem.201700152

Machine learning-driven shortening the screening process towards high-performance nitrogen reduction reaction electrocatalysts with four-step screening strategy

C. He, D. Chen and W.X. Zhang

Journal of Colloid and Interface Science, 2024, 676, 22
DOI: 10.1016/j.jcis.2024.07.109

Transition Metal Diborides: A New Type of High‐performance Electrocatalysts for Nitrogen Reduction

Gangqiang Qin, Qianyi Cui, Aijun Du, Weihua Wang and Qiao Sun

ChemCatChem, 2019, 11, 2624
DOI: 10.1002/cctc.201900538

Exploration and Investigation of Periodic Elements for Electrocatalytic Nitrogen Reduction

Shivaraj B. Patil and Di‐Yan Wang

Small, 2020, 16
DOI: 10.1002/smll.202002885

Critical review on electrocatalytic reduction of nitrogen and nitrate to ammonia

Ali Ahsan, Murid Hussain, Moeen Ali Rashad, Parveen Akhter, Farrukh Jamil, Kanghee Cho and Young-Kwon Park

Journal of Industrial and Engineering Chemistry, 2025, 149, 313
DOI: 10.1016/j.jiec.2025.02.029

Electrochemical N2 splitting at well-defined metal complexes

Nils Ostermann and Inke Siewert

Current Opinion in Electrochemistry, 2019, 15, 97
DOI: 10.1016/j.coelec.2019.04.024

New emission band of solid nitrogen

E. V. Savchenko, I. V. Khyzhniy, S. A. Uyutnov and M. A. Bludov

Low Temperature Physics, 2024, 50, 89
DOI: 10.1063/10.0023897

Atomistic Description of Reaction Intermediates for Supported Metathesis Catalysts Enabled by DNP SENS

Ta‐Chung Ong, Wei‐Chih Liao, Victor Mougel, David Gajan, Anne Lesage, Lyndon Emsley and Christophe Copéret

Angew Chem Int Ed, 2016, 55, 4743
DOI: 10.1002/anie.201510821

Basal Plane‐Activated Boron‐Doped MoS2 Nanosheets for Efficient Electrochemical Ammonia Synthesis

Xiaoyue Chen, Shucao Lu, Yanjiao Wei, Mengjie Sun, Xu Wang, Min Ma and Jian Tian

ChemSusChem, 2023, 16
DOI: 10.1002/cssc.202202265

From Single Atom Photocatalysts to Synergistic Photocatalysts: Design Principles and Applications

Yaowu Luo, Xinqiang Wang, Fan Gao, Lin Jiang, Dingsheng Wang and Hongge Pan

Adv Funct Materials, 2025, 35
DOI: 10.1002/adfm.202418427

Reactivity of Tantalum Carbide Cluster Anions TaCn– (n = 1–4) with Dinitrogen

Li-Hui Mou, Qing-Yu Liu, Ting Zhang, Zi-Yu Li and Sheng-Gui He

J. Phys. Chem. A, 2018, 122, 3489
DOI: 10.1021/acs.jpca.8b01329

Nitrogen Fixation via Splitting into Nitrido Complexes

Sebastian J. K. Forrest, Bastian Schluschaß, Ekaterina Y. Yuzik-Klimova and Sven Schneider

Chem. Rev., 2021, 121, 6522
DOI: 10.1021/acs.chemrev.0c00958

An oxygen-vacancy-rich polyoxometalate-aided Ag-based heterojunction electrocatalyst for nitrogen fixation

Xinyu Chen, Cong-Cong Zhao, Jing Ren, Bo Li, Qianqian Liu, Wei Li, Fan Yang, Siqi Lu, YuFei Zhao, Li-Kai Yan and Hong-Ying Zang

Chinese Journal of Catalysis, 2024, 62, 209
DOI: 10.1016/S1872-2067(24)60046-X

Metal nitrides as electrocatalysts in green ammonia synthesis

A. Januszewska-Kubsik, S. Podsiadło, W. Pudełko and M. Siekierski

Appl. Phys. A, 2024, 130
DOI: 10.1007/s00339-024-07918-5

The Triple‐Bond Metathesis of Aryldiazonium Salts: A Prospect for Dinitrogen Cleavage

Aaron D. Lackner and Alois Fürstner

Angew Chem Int Ed, 2015, 54, 12814
DOI: 10.1002/anie.201506546

Terminal uranium(V)-nitride hydrogenations involving direct addition or Frustrated Lewis Pair mechanisms

Lucile Chatelain, Elisa Louyriac, Iskander Douair, Erli Lu, Floriana Tuna, Ashley J. Wooles, Benedict M. Gardner, Laurent Maron and Stephen T. Liddle

Nat Commun, 2020, 11
DOI: 10.1038/s41467-019-14221-y

Visible light sensitive bismuth vanadate for energy, environmental, and catalytic applications

Oshnik Maurya, Vaibhav Khapekar, Kanchan Pawar, Somnath Khaladkar, Girish Kamble, Harsh Mohane, Girish Gund, Bhavesh Sinha, Jin Hyeok Kim, Rajendra Deshmukh, Deepak Dubal and Archana Kalekar

Nano Research, 2024, 18, 94907364
DOI: 10.26599/NR.2025.94907364

Photocatalytic conversion of nitrogen to ammonia with water on triphase interfaces of hydrophilic-hydrophobic composite Bi4O5Br2/ZIF-8

Jianxin Liu, Rui Li, Xiang Zu, Xiaochao Zhang, Yunfang Wang, Yawen Wang and Caimei Fan

Chemical Engineering Journal, 2019, 371, 796
DOI: 10.1016/j.cej.2019.03.283

Advances in Theoretical Research on Synthesis of Urea by Electrocatalytic Co-Reduction of Nitric Oxide and Carbon Oxides

翔宇张

AAC, 2024, 14, 29
DOI: 10.12677/AAC.2024.141004

Efficient Nitrogen Fixation via a Redox-Flexible Single-Iron Site with Reverse-Dative Iron → Boron σ Bonding

Jun-Bo Lu, Xue-Lu Ma, Jia-Qi Wang, Jin-Cheng Liu, Hai Xiao and Jun Li

J. Phys. Chem. A, 2018, 122, 4530
DOI: 10.1021/acs.jpca.8b02089

High‐Performance Nitrogen Fixation over Mo Atom Modified Defective α‐MnO2 (001)

Linxia Wang, Minghui Wu, Xiuyao Lang, Shan Gao and Weichao Wang

ChemCatChem, 2020, 12, 3937
DOI: 10.1002/cctc.202000185

Superlattice‐based Plasmonic Catalysis: Concentrating Light at the Nanoscale to Drive Efficient Nitrogen‐to‐Ammonia Fixation at Ambient Conditions

Siew Kheng Boong, Carice Chong, Jinn‐Kye Lee, Zhi Zhong Ang, Haitao Li and Hiang Kwee Lee

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202216562

Photosynthetic System Based on a Polyoxometalate-Based Dehydrated Metal–Organic Framework for Nitrogen Fixation

Feng-Rui Li, Tuo Ji, Wei-Chao Chen, Wei Du, Yi-Jia Hao, Yan-Li Sun and Wei-Lin Chen

Inorg. Chem., 2024, 63, 593
DOI: 10.1021/acs.inorgchem.3c03472

Amorphizing of Au Nanoparticles by CeOx–RGO Hybrid Support towards Highly Efficient Electrocatalyst for N2 Reduction under Ambient Conditions

Si‐Jia Li, Di Bao, Miao‐Miao Shi, Ba‐Ri Wulan, Jun‐Min Yan and Qing Jiang

Advanced Materials, 2017, 29
DOI: 10.1002/adma.201700001

Electrochemical ammonia synthesis through N2 and H2O under ambient conditions: Theory, practices, and challenges for catalysts and electrolytes

Hui Xu, Kemakorn Ithisuphalap, Yi Li, Shreya Mukherjee, Judith Lattimer, Grigorii Soloveichik and Gang Wu

Nano Energy, 2020, 69, 104469
DOI: 10.1016/j.nanoen.2020.104469

FeP nanorod array: A high-efficiency catalyst for electroreduction of NO to NH3 under ambient conditions

Jie Liang, Qiang Zhou, Ting Mou, Hongyu Chen, Luchao Yue, Yongsong Luo, Qian Liu, Mohamed S. Hamdy, Abdulmohsen Ali Alshehri, Feng Gong and Xuping Sun

Nano Res., 2022, 15, 4008
DOI: 10.1007/s12274-022-4174-0

Electrochemical urea synthesis

Yannik Kohlhaas, Yannick S. Tschauder, Wenzel Plischka, Ulrich Simon, Rüdiger-A. Eichel, Matthias Wessling and Robert Keller

Joule, 2024, 8, 1579
DOI: 10.1016/j.joule.2024.04.004

Nitrogen Activation and Transformation on Monometallic Niobium Boron Oxide Cluster Anions at Room Temperature: A Dual-Site Mechanism

Ming Wang, Hai-Yan Zhou, Antonis M Messinis, Lan-Ye Chu, Ying Li and Jia-Bi Ma

J. Phys. Chem. Lett., 2021, 12, 6313
DOI: 10.1021/acs.jpclett.1c01633

Conversion of Dinitrogen to Ammonia by FeB‑Embedded Graphyne

Wei Song, Zhe Fu, Ling Fu and Chaozheng He

J. Electrochem. Soc., 2021, 168, 066503
DOI: 10.1149/1945-7111/ac030a

Constant-potential simulation of electrocatalytic N2 reduction over atomic metal-N-graphene catalysts

Sanmei Wang, Yong Zhou, Hengxin Fang, Chunyang Nie, Chang Q Sun and Biao Wang

Chinese Chemical Letters, 2025, 36, 110476
DOI: 10.1016/j.cclet.2024.110476

On the Nature of Three-Atom Metal Cluster Catalysis for N2 Reduction to Ammonia

Chaonan Cui, Hongchao Zhang, Ran Cheng, Benben Huang and Zhixun Luo

ACS Catal., 2022, 12, 14964
DOI: 10.1021/acscatal.2c04146

Possible Strong Promotional Effect of Al2O3 on Fe Catalysts for Ammonia Synthesis via Fe/γ-Al2O3

Jianfu Chen, Ye Chen, Huihui Liu and P. Hu

ACS Catal., 2025, 15, 13366
DOI: 10.1021/acscatal.5c03006

Photoelectrochemical nitrogen reduction: A step toward achieving sustainable ammonia synthesis

Liqun Wang, Xiao Yan, Wenping Si, Daolan Liu, Xinggang Hou, Dejun Li, Feng Hou, Shi Xue Dou and Ji Liang

Chinese Journal of Catalysis, 2022, 43, 1761
DOI: 10.1016/S1872-2067(21)64001-9

Plasma-etching enhanced titanium oxynitride active phase with high oxygen content for ambient electrosynthesis of ammonia

Shenghong Kang, Jialu Wang, Shengbo Zhang, Cuijiao Zhao, Guozhong Wang, Weiping Cai and Haimin Zhang

Electrochemistry Communications, 2019, 100, 90
DOI: 10.1016/j.elecom.2019.01.028

Nitrogen Electrocatalysis: Electrolyte Engineering Strategies to Boost Faradaic Efficiency

Loknath Thapa and C. Retna Raj

ChemSusChem, 2023, 16
DOI: 10.1002/cssc.202300465

Emerging Two-Dimensional Nanomaterials for Electrocatalysis

Huanyu Jin, Chunxian Guo, Xin Liu, Jinlong Liu, Anthony Vasileff, Yan Jiao, Yao Zheng and Shi-Zhang Qiao

Chem. Rev., 2018, 118, 6337
DOI: 10.1021/acs.chemrev.7b00689

Electrochemical Reduction of N2 to NH3 Using a Co‐Atom Stabilized on Defective N‐Doped Graphene: A Computational Study

Nasibeh Saeidi, Mehdi D. Esrafili and Jaber Jahanbin Sardroodi

ChemistrySelect, 2019, 4, 12216
DOI: 10.1002/slct.201903206

Reactivity of Neutral Tantalum Sulfide Clusters Ta3Sn (n = 0–4) with N2

Gui-Duo Jiang, Li-Hui Mou, Jiao-Jiao Chen, Zi-Yu Li and Sheng-Gui He

J. Phys. Chem. A, 2020, 124, 7749
DOI: 10.1021/acs.jpca.0c06462

Redox−Acid/Base Phase Diagrams as an Entry to Computational Redox Chemistry

Patrick M. Becker, Katja Heinze, Biprajit Sarkar and Johannes Kästner

ChemElectroChem, 2024, 11
DOI: 10.1002/celc.202400301

N2 Electroreduction to NH3 by Selenium Vacancy‐Rich ReSe2 Catalysis at an Abrupt Interface

Feili Lai, Wei Zong, Guanjie He, Yang Xu, Haowei Huang, Bo Weng, Dewei Rao, Johan A. Martens, Johan Hofkens, Ivan P. Parkin and Tianxi Liu

Angewandte Chemie, 2020, 132, 13422
DOI: 10.1002/ange.202003129

Photocatalytic Dinitrogen Reduction to Ammonia over Biomimetic FeMoSx Nanosheets

Suresh Thangudu, Chein Hou Wu and Kuo Chu Hwang

ACS Omega, 2024, 9, 20629
DOI: 10.1021/acsomega.4c03076

Biological nitrogen fixation in theory, practice, and reality: a perspective on the molybdenum nitrogenase system

Stephanie D. Threatt and Douglas C. Rees

FEBS Letters, 2023, 597, 45
DOI: 10.1002/1873-3468.14534

Boron-nitrogen fullerenes as electrocatalysts for nitrogen reduction: A computational study of affinity and reaction mechanism

Sasha Gazzari-Jara, Diego Cortés-Arriagada, Ernesto Chigo-Anota and Sebastián Miranda-Rojas

iScience, 2025, 28, 112326
DOI: 10.1016/j.isci.2025.112326

Aryldiazonium Salts as Nitrogen‐Based Lewis Acids: Facile Synthesis of Tuneable Azophosphonium Salts

Evi R. M. Habraken, Nicolaas P. van Leest, Pim Hooijschuur, Bas de Bruin, Andreas W. Ehlers, Martin Lutz and J. Chris Slootweg

Angew Chem Int Ed, 2018, 57, 11929
DOI: 10.1002/anie.201806913

K+-Intercalated carbon nitride with electron storage property for high-efficiency visible light driven nitrogen fixation

Gang Dong, Peng Qiu, Qingze Chen, Cong Huang, Feiyang Chen, Xueqin Liu, Zhen Li, Yang Wang and Yanli Zhao

Chemical Engineering Journal, 2022, 433, 133573
DOI: 10.1016/j.cej.2021.133573

Bimetallic Cooperative Cleavage of Dinitrogen to Nitride and Tandem Frustrated Lewis Pair Hydrogenation to Ammonia

Laurence R. Doyle, Ashley J. Wooles and Stephen T. Liddle

Angew Chem Int Ed, 2019, 58, 6674
DOI: 10.1002/anie.201902195

Recent Advances in Electrochemical Water Splitting and Reduction of CO2 into Green Fuels on 2D Phosphorene‐Based Catalyst

Rohit Srivastava, Shaista Nouseen, Jayeeta Chattopadhyay, Pei Meng Woi, Do Ngoc Son and Bishnu Prasad Bastakoti

Energy Tech, 2021, 9
DOI: 10.1002/ente.202000741

Hydrazine N–N Bond Cleavage over Silica-Supported Tantalum-Hydrides

Hong-Peng Jia, Eric Gouré, Xavier Solans-Monfort, Jessica Llop Castelbou, Catherine Chow, Mostafa Taoufik, Odile Eisenstein and Elsje Alessandra Quadrelli

Inorg. Chem., 2015, 54, 11648
DOI: 10.1021/acs.inorgchem.5b01541

Single‐Site Molybdenum on Solid Support Materials for Catalytic Hydrogenation of N2‐into‐NH3

Luis Miguel Azofra, Natalia Morlanés, Albert Poater, Manoja K. Samantaray, Balamurugan Vidjayacoumar, Khalid Albahily, Luigi Cavallo and Jean‐Marie Basset

Angew Chem Int Ed, 2018, 57, 15812
DOI: 10.1002/anie.201810409

Electrocatalytically Activating and Reducing N2 Molecule by Tuning Activity of Local Hydrogen Radical

Yuanyuan Yang, Cejun Hu, Jieqiong Shan, Chuanqi Cheng, Lili Han, Xinzhe Li, Ruguang Wang, Wei Xie, Yao Zheng and Tao Ling

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202300989

Density functional theory evaluation of cation-doped bismuth molybdenum oxide photocatalysts for nitrogen fixation

Alhassan S. Yasin, Botong Liu, Nianqiang Wu and Terence Musho

Computational Materials Science, 2019, 158, 65
DOI: 10.1016/j.commatsci.2018.08.039

Conversion of Dinitrogen into Acetonitrile under Ambient Conditions

Isabel Klopsch, Markus Kinauer, Markus Finger, Christian Würtele and Sven Schneider

Angewandte Chemie, 2016, 128, 4864
DOI: 10.1002/ange.201600790

Scandium-Promoted Direct Conversion of Dinitrogen into Hydrazine Derivatives via N–C Bond Formation

Ze-Jie Lv, Zhe Huang, Wen-Xiong Zhang and Zhenfeng Xi

J. Am. Chem. Soc., 2019, 141, 8773
DOI: 10.1021/jacs.9b04293

Photocatalytic Nitrogen Reduction Reaction over Two-Dimensional Cs3Bi2Br9–CdS Van der Waals Heterostructures by External Control Strategies

Bing-Hao Wang, Bo Sun, Lang Chen, Meng-Qiu Cai and Shuang-Feng Yin

J. Phys. Chem. C, 2021, 125, 13212
DOI: 10.1021/acs.jpcc.1c03521

Facile N≡N Bond Cleavage by Anionic Trimetallic Clusters V3−xTaxC4− (x=0–3): A DFT Study

Ya‐Ya Wang, Xun‐Lei Ding, Joseph Israel Gurti, Yan Chen, Xue‐Qian Huang, Wei Li and Xin Wang

ChemPhysChem, 2022, 23
DOI: 10.1002/cphc.202100771

Computational Study of Metal–Dinitrogen Keggin-Type Polyoxometalate Complexes [PW11O39MIIN2)]5– (M = Ru, Os, Re, Ir): Bonding Nature and Dinitrogen Splitting

Chun-Guang Liu, Shuang Liu and Ting Zheng

Inorg. Chem., 2015, 54, 7929
DOI: 10.1021/acs.inorgchem.5b01002

Trace to the Source: Self‐Tuning of MOF Photocatalysts

Zhiping Qian, Rui Zhang, Yan Xiao, Hongwei Huang, Ying Sun, Yang Chen, Tianyi Ma and Xiaodong Sun

Advanced Energy Materials, 2023, 13
DOI: 10.1002/aenm.202300086

Molybdenum-Catalyzed Ammonia Formation Using Simple Monodentate and Bidentate Phosphines as Auxiliary Ligands

Yuya Ashida, Kazuya Arashiba, Hiromasa Tanaka, Akihito Egi, Kazunari Nakajima, Kazunari Yoshizawa and Yoshiaki Nishibayashi

Inorg. Chem., 2019, 58, 8927
DOI: 10.1021/acs.inorgchem.9b01340

Co-doped graphene edge for enhanced N2-to-NH3 conversion

Zengxi Wei, Yuezhan Feng and Jianmin Ma

Journal of Energy Chemistry, 2020, 48, 322
DOI: 10.1016/j.jechem.2020.02.014

Bioelectrocatalytic Conversion from N2 to Chiral Amino Acids in a H2/α-Keto Acid Enzymatic Fuel Cell

Hui Chen, Matthew B. Prater, Rong Cai, Fangyuan Dong, Hsiaonung Chen and Shelley D. Minteer

J. Am. Chem. Soc., 2020, 142, 4028
DOI: 10.1021/jacs.9b13968

Homolytic or Heterolytic Dihydrogen Splitting with Ditantalum/Dizirconium Dinitrogen Complexes? A Computational Study

Xuelu Ma, Ming Lei and Shubin Liu

Organometallics, 2015, 34, 1255
DOI: 10.1021/om501316t

Synthesis, Characterization, and Comparative Theoretical Investigation of Dinitrogen-Bridged Group 6-Gold Heterobimetallic Complexes

David Specklin, Anaïs Coffinet, Laure Vendier, Iker del Rosal, Chiara Dinoi and Antoine Simonneau

Inorg. Chem., 2021, 60, 5545
DOI: 10.1021/acs.inorgchem.0c03271

Single-atomic site catalysts for electrochemical nitrogen fixation

Mingwei Chang, Jing Wu, Li Xu and Liming Zhang

Materials Research Letters, 2023, 11, 697
DOI: 10.1080/21663831.2023.2209156

Photodriven Disproportionation of Nitrogen and Its Change to Reductive Nitrogen Photofixation

Jianhua Yang, Haoyuan Bai, Yanzhen Guo, Han Zhang, Ruibin Jiang, Baocheng Yang, Jianfang Wang and Jimmy C. Yu

Angew Chem Int Ed, 2021, 60, 927
DOI: 10.1002/anie.202010192

Stepwise Reduction of Dinitrogen by a Uranium–Potassium Complex Yielding a U(VI)/U(IV) Tetranitride Cluster

Nadir Jori, Luciano Barluzzi, Iskander Douair, Laurent Maron, Farzaneh Fadaei-Tirani, Ivica Z̆ivković and Marinella Mazzanti

J. Am. Chem. Soc., 2021, 143, 11225
DOI: 10.1021/jacs.1c05389

Synthesis and Reactivity of Ruthenium Complexes Bearing Arsenic-Containing Arsenic-Nitrogen-Arsenic-Type Pincer Ligand

Yoshiaki Tanabe, Shogo Kuriyama, Kazuya Arashiba, Kazunari Nakajima and Yoshiaki Nishibayashi

Organometallics, 2014, 33, 5295
DOI: 10.1021/om5006116

Synthesis and crystal structure of the cluster (Et4N)[(Tp*)MoFe3S3(μ3-NSiMe3)(N3)3]

Yue Li, Jia Wei, Jie Han and Xu-Dong Chen

Acta Crystallogr E Cryst Commun, 2024, 80, 691
DOI: 10.1107/S2056989024004833

α-Hydroxy coordination of mononuclear vanadyl citrate, malate and S-citramalate with N-heterocycle ligand, implying a new protonation pathway of iron–vanadium cofactor in nitrogenase

Can-Yu Chen, Mao-Long Chen, Hong-Bin Chen, Hongxin Wang, Stephen P. Cramer and Zhao-Hui Zhou

Journal of Inorganic Biochemistry, 2014, 141, 114
DOI: 10.1016/j.jinorgbio.2014.08.003

Reversible Dihydrogen Activation and Hydride Transfer by a Uranium Nitride Complex

Marta Falcone, Lok Nga Poon, Farzaneh Fadaei Tirani and Marinella Mazzanti

Angewandte Chemie, 2018, 130, 3759
DOI: 10.1002/ange.201800203

Breaking Molecular Nitrogen under Mild Conditions with an Atomically Clean Lanthanide Surface

Felicia Ullstad, Gabriel Bioletti, Jay R. Chan, Audrey Proust, Charlotte Bodin, Ben J. Ruck, Joe Trodahl and Franck Natali

ACS Omega, 2019, 4, 5950
DOI: 10.1021/acsomega.9b00293

Enroute to the Carbon-Neutrality Goals via the Targeted Development of Ammonia as a Potential Nitrogen-Based Energy Carrier

Muhammad Asif Nawaz, Rubén Blay-Roger, Maria Saif, Fanhui Meng, J. González-Arias, Baoji Miao, Luis F. Bobadilla, Tomas Ramirez-Reina and J. A. Odriozola

ACS Catal., 2023, 13, 14415
DOI: 10.1021/acscatal.3c02410

Alkali Etching of Layered Double Hydroxide Nanosheets for Enhanced Photocatalytic N2 Reduction to NH3

Yunxuan Zhao, Lirong Zheng, Run Shi, Shuai Zhang, Xuanang Bian, Fan Wu, Xingzhong Cao, Geoffrey I. N. Waterhouse and Tierui Zhang

Advanced Energy Materials, 2020, 10
DOI: 10.1002/aenm.202002199

Bimetallic Cooperative Cleavage of Dinitrogen to Nitride and Tandem Frustrated Lewis Pair Hydrogenation to Ammonia

Laurence R. Doyle, Ashley J. Wooles and Stephen T. Liddle

Angewandte Chemie, 2019, 131, 6746
DOI: 10.1002/ange.201902195

Introduction of element Bi in the P-block promotes N2 activation for efficient electrocatalytic nitrogen reduction to produce ammonia

Xiaoyue Chen, Guangmin Ren, Yaru Wang, Zizhen Li, Zisheng Zhang and Xiangchao Meng

Applied Catalysis B: Environment and Energy, 2024, 355, 124173
DOI: 10.1016/j.apcatb.2024.124173

Applications of X-ray Absorption Fine Structure Spectroscopy in the Photocatalytic Conversion of Small Molecules

Peipei Du, Rui Si, Zhaosheng Li and Zhigang Zou

ACS Catal., 2023, 13, 6690
DOI: 10.1021/acscatal.2c06413

Manipulating Reactivity of Ir(CH2)0–2+ Cations toward Dinitrogen at Room Temperature: A Unique Dependence on the Organic Ligand Structures

Yong-Qi Ding, Feng-Xiang Zhang, Ying Li and Jia-Bi Ma

J. Phys. Chem. A, 2024, 128, 449
DOI: 10.1021/acs.jpca.3c07579

Activation of Dinitrogen by Polynuclear Metal Complexes

Devender Singh, William R. Buratto, Juan F. Torres and Leslie J. Murray

Chem. Rev., 2020, 120, 5517
DOI: 10.1021/acs.chemrev.0c00042

Electrocatalytically Activating and Reducing N2 Molecule by Tuning Activity of Local Hydrogen Radical

Yuanyuan Yang, Cejun Hu, Jieqiong Shan, Chuanqi Cheng, Lili Han, Xinzhe Li, Ruguang Wang, Wei Xie, Yao Zheng and Tao Ling

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202300989

Single atom catalysis perspective to reveal N2 and NRR intermediate adsorption properties on non-benzenoid carbon allotrope: A DFT study

A.E. Genç

Inorganic Chemistry Communications, 2025, 178, 114520
DOI: 10.1016/j.inoche.2025.114520

H–H and N–H Bond Cleavages of Dihydrogen and Ammonia by a Bifunctional Imido (NH)-Bridged Diiridium Complex: A DFT Study

Yang Yu, Hang Yu, Xiaohui Kang, Xingbao Wang, Jimin Yang, Jingping Qu and Yi Luo

Organometallics, 2017, 36, 4721
DOI: 10.1021/acs.organomet.7b00581

Toward Rational Design of the Two-Dimensional h-WO3/ZrGe2P4 Heterostructure for N2/CO2 Reduction: Incorporating Multiple Electronic Modulation Engineering

Haoran Guo, Pengfei Yuan, Min Xu, Yao Zhang and Rui Song

J. Phys. Chem. C, 2023, 127, 14784
DOI: 10.1021/acs.jpcc.3c03631

First principle study of feasibility of dinitrogen reduction to ammonia on two-dimensional transition metal phthalocyanine monolayer

Shiqiang Liu, Yawei Liu, Xiaoping Gao, Yujia Tan, Zhemin Shen and Maohong Fan

Applied Surface Science, 2020, 500, 144032
DOI: 10.1016/j.apsusc.2019.144032

Engineering electrocatalyst for low-temperature N2 reduction to ammonia

Faisal Rehman, Md Delowar Hossain, Abhishek Tyagi, Dong Lu, Bin Yuan and Zhengtang Luo

Materials Today, 2021, 44, 136
DOI: 10.1016/j.mattod.2020.09.006

From nitrogen to ammonia to ammoniating natural biomass: The applying of photocatalysis in preparation the temperature and salt-resistant filtrate reducer

Xiao Luo, Peipei Wang, Xin Zhang, Jian Luo, Guiyou Hua, Qiang Li and Yufan Lan

Chemical Engineering Journal, 2025, 522, 167497
DOI: 10.1016/j.cej.2025.167497

Recent Progress on 2D Transition Metal Compounds-based Electrocatalysts for Efficient Nitrogen Reduction

Wenfei Dong, Xiaoyu Chen, Juan Peng, Wanyi Liu, Xiaoyong Jin, Gang Ni and Zheng Liu

Chem. Res. Chin. Univ., 2020, 36, 648
DOI: 10.1007/s40242-020-0171-6

Rethinking the Nitrogenase Mechanism: Activating the Active Site

Trixia M. Buscagan and Douglas C. Rees

Joule, 2019, 3, 2662
DOI: 10.1016/j.joule.2019.09.004

A comparative study of the potential of [Os{(NHCH2CH2)3X}] catalysts (XN, P) for the reduction of dinitrogen to ammonia and hydrazine using FLP‐H2 as a co‐catalyst by density functional theory

Akhil K. Sivan and Chinnappan Sivasankar

Applied Organom Chemis, 2023, 37
DOI: 10.1002/aoc.7067

Three-Dimensional Tetrathiafulvalene-Based covalent organic frameworks for efficient photocatalytic nitrogen fixation

Yunchao Ma, Liaofang Shang, Jingyang Li, Yuanyuan Wu, Guangbo Che, Chunbo Liu and Qianrong Fang

Chemical Engineering Journal, 2024, 484, 149347
DOI: 10.1016/j.cej.2024.149347

Dinitrogen Activation in the Gas Phase: Spectroscopic Characterization of C−N Coupling in the V3C++N2Reaction

Zi‐Yu Li, Francine Horn, Yao Li, Li‐Hui Mou, Wieland Schöllkopf, Hui Chen, Sheng‐Gui He and Knut R. Asmis

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202203384

Transition Metal/Lanthanide-Nitrogen Double Bonds Co-stabilized in a Carbon Cage

Zhanxin Jiang, Ziqi Hu, Yang-Rong Yao, Wenhao Xiang, Xinyi Han, Jinpeng Xin, Huaimin Jin and Shangfeng Yang

Precision Chemistry, 2024, 2, 193
DOI: 10.1021/prechem.3c00123

Recent progress and prospects of electrolytes for electrocatalytic nitrogen reduction toward ammonia

Sajid Mahmood, Haiyan Wang, Fang Chen, Yijun Zhong and Yong Hu

Chinese Chemical Letters, 2024, 35, 108550
DOI: 10.1016/j.cclet.2023.108550

Structural engineering and operando characterization of advanced catalysts for electrochemical nitrogen reduction reaction

Muhammad Yasir, Zhiliang Zhao, Yongming Hu, Xinyi Zhang and Haunting Wang

Nano Energy, 2025, 135, 110693
DOI: 10.1016/j.nanoen.2025.110693

Rational Prediction of Single Metal Atom Supported on Two-Dimensional Metal Diborides for Electrocatalytic N2 Reduction Reaction with Integrated Descriptor

Lei Ge, Weiwei Xu, Chongyang Chen, Chao Tang, Lai Xu and Zhongfang Chen

J. Phys. Chem. Lett., 2020, 11, 5241
DOI: 10.1021/acs.jpclett.0c01582

A Brief Assessment on Recent Developments in Efficient Electrocatalytic Nitrogen Reduction with 2D Non-Metallic Nanomaterials

Muhammad Shahid, Hafiz Muhammad Asif Javed, Muhammad Irfan Ahmad, Akbar Ali Qureshi, Muhammad Ijaz Khan, Maha Abdallah Alnuwaiser, Arslan Ahmed, Muhammad Azhar Khan, El Sayed Mohamed Tag-ElDin, Arslan Shahid and Aiman Rafique

Nanomaterials, 2022, 12, 3413
DOI: 10.3390/nano12193413

Mechanistic Inquisition on the Reduction of C17Si(NH2)2 to NH3: A DFT Study

Sobitri Sen, Arijit Bag and Sourav Pal

ChemPhysChem, 2024, 25
DOI: 10.1002/cphc.202300723

Controlled etching to immobilize highly dispersed Fe in MXene for electrochemical ammonia production

Yu Wang, Ying Sun, Hui Li, Wei Zhang, Shuyao Wu, Chang Liu, Yue Gao, Baohua Jia, Jieshan Qiu and Tianyi Ma

Carbon Neutralization, 2022, 1, 117
DOI: 10.1002/cnl2.18

Stepwise Functionalization of N2 at Mo: Nitrido to Imido to Amido – Factors Favoring Amine Elimination from the Amido Complex

Soukaina Bennaamane, Maria F. Espada, Ikram Yagoub, Nathalie Saffon‐Merceron, Noel Nebra, Marie Fustier‐Boutignon, Eric Clot and Nicolas Mézailles

Eur J Inorg Chem, 2020, 2020, 1499
DOI: 10.1002/ejic.201901295

Recent Advances in Plasmonic Photocatalysis Based on TiO2 and Noble Metal Nanoparticles for Energy Conversion, Environmental Remediation, and Organic Synthesis

Ajay Kumar, Priyanka Choudhary, Ashish Kumar, Pedro H. C. Camargo and Venkata Krishnan

Small, 2022, 18
DOI: 10.1002/smll.202101638

Recent advances in nanostructured heterogeneous catalysts for N-cycle electrocatalysis

Jie Liang, Qian Liu, Abdulmohsen Ali Alshehri and Xuping Sun

Nano Research Energy, 2022, 1, e9120010
DOI: 10.26599/NRE.2022.9120010

Electronic Modulation of the Interaction between Fe Single Atoms and WO2.72–x for Photocatalytic N2 Reduction

Biao Hu, Bing-Hao Wang, Lang Chen, Zhang-Jun Bai, Wei Zhou, Jun-Kang Guo, Sheng Shen, Ting-Liang Xie, Chak-Tong Au, Li-Long Jiang and Shuang-Feng Yin

ACS Catal., 2022, 12, 11860
DOI: 10.1021/acscatal.2c03367

Advanced Electroanalysis for Electrosynthesis

Monica Brachi, Wassim El Housseini, Kevin Beaver, Rohit Jadhav, Ashwini Dantanarayana, Dylan G. Boucher and Shelley D. Minteer

ACS Org. Inorg. Au, 2024, 4, 141
DOI: 10.1021/acsorginorgau.3c00051

Low-valent molybdenum sites as active hydrogen traps in TiO2 for facilitating high-selectivity photocatalytic nitrate synthesis from NO

Ni Wang, Jianxin Liu, Lijun Guo, Yawen Wang, Yunfang Wang, Caimei Fan, Rui Li and Jiancheng Wang

Journal of Alloys and Compounds, 2025, 1025, 180314
DOI: 10.1016/j.jallcom.2025.180314

Non-Transition-Metal Catalytic System for N2 Reduction to NH3: A Density Functional Theory Study of Al-Doped Graphene

Yong-Hui Tian, Shuangli Hu, Xiaolan Sheng, Yixiang Duan, Jacek Jakowski, Bobby G. Sumpter and Jingsong Huang

J. Phys. Chem. Lett., 2018, 9, 570
DOI: 10.1021/acs.jpclett.7b03094

Urea Electrosynthesis Accelerated by Theoretical Simulations

Junxian Liu, Xiangyu Guo, Thomas Frauenheim, Yuantong Gu and Liangzhi Kou

Adv Funct Materials, 2024, 34
DOI: 10.1002/adfm.202313420

Titanium-Based Hydrides as Heterogeneous Catalysts for Ammonia Synthesis

Yoji Kobayashi, Ya Tang, Toki Kageyama, Hiroki Yamashita, Naoya Masuda, Saburo Hosokawa and Hiroshi Kageyama

J. Am. Chem. Soc., 2017, 139, 18240
DOI: 10.1021/jacs.7b08891

The New Equations for “Rate-Determining Chemisorption of Coal”

Cemil Koyunoğlu

Journal of Heat Transfer, 2018, 140
DOI: 10.1115/1.4040610

Two-Dimensional Single-Atom Catalyst TM3(HAB)2 Monolayers for Electrocatalytic Dinitrogen Reduction Using Hierarchical High-Throughput Screening

Man-Rong Zhao, Bingyi Song and Li-Ming Yang

ACS Appl. Mater. Interfaces, 2021, 13, 26109
DOI: 10.1021/acsami.1c06414

Recent Progress in Electrochemical Synthesis and Conversion of Nitrates in Aqueous Electrolyte

Fanghua Liu, Chizhong Wang, Lei Qiu and Huazhen Chang

Top Catal, 2024
DOI: 10.1007/s11244-024-01949-1

A General Strategy to Glassy M‐Te (M = Ru, Rh, Ir) Porous Nanorods for Efficient Electrochemical N2Fixation

Juan Wang, Bolong Huang, Yujin Ji, Mingzi Sun, Tong Wu, Rongguan Yin, Xing Zhu, Youyong Li, Qi Shao and Xiaoqing Huang

Advanced Materials, 2020, 32
DOI: 10.1002/adma.201907112

Main Group Lewis Acid-Mediated Transformations of Transition-Metal Hydride Complexes

Ayan Maity and Thomas S. Teets

Chem. Rev., 2016, 116, 8873
DOI: 10.1021/acs.chemrev.6b00034

Jahn–Teller Distorted Effects To Promote Nitrogen Reduction over Keggin-Type Phosphotungstic Acid Catalysts: Insight from Density Functional Theory Calculations

Yu Wang, Xue-Mei Chen, Li-Long Zhang and Chun-Guang Liu

Inorg. Chem., 2019, 58, 7852
DOI: 10.1021/acs.inorgchem.9b00537

Solar-Driven Ammonia Production through Engineering of the Electronic Structure of a Zr-Based MOF

Nasrin Shokouhfar, Sravan Kumar Kilaparthi, Alexandre Barras, B. Moses Abraham, Ahmed Addad, Pascal Roussel, Sakshi Bhatt, Suman Lata Jain, Sabine Szunerits, Ali Morsali and Rabah Boukherroub

Inorg. Chem., 2024, 63, 2327
DOI: 10.1021/acs.inorgchem.3c02583