Highly regio- and stereoselective (3 + 2) annulation reaction of allenoates with 3-methyleneindolin-2-ones catalyzed by a planar chiral [2.2]paracyclophane-based bifunctional phosphine–phenol catalyst

Shinji Kitagaki, Tomoki Nakayoshi, Sota Masunaka, Akane Uchida, Mai Inano, Emika Yoshida, Yusuke Washino, Hiroshi Aoyama and Keisuke Yoshida

Org. Biomol. Chem., 2024, 22, 7817
DOI: 10.1039/D4OB00831F

Quinine catalysed asymmetric Michael additions in a sustainable solvent

José A. Castro-Osma, James W. Comerford, Samantha Heath, Oliver Jones, Maria Morcillo and Michael North

RSC Adv., 2015, 5, 3678
DOI: 10.1039/C4RA12132E

Effect of metal complexation on the equilibrium between methylphosphepine and methylphosphanorcaradiene and their benzo analogues

Xiaohong Chen, Li Yuan, Xueqin Leng, Rong Jin, Quan Du, Hao Feng, Yaoming Xie, R. Bruce King and Henry F. Schaefer

New J. Chem., 2016, 40, 7804
DOI: 10.1039/C6NJ01481J

Ir/XuPhos-catalyzed direct asymmetric reductive amination of ketones with secondary amines

Zhou Luo, Tianxiang Fan, Jingyan Luo, Yuanyuan Liu and Junliang Zhang

Org. Chem. Front., 2024, 11, 6735
DOI: 10.1039/D4QO01495B

Stereospecific synthesis and catalytic activity of l-histidylidene metal complexes

Angèle Monney, Elisabetta Alberico, Yannick Ortin, Helge Müller-Bunz, Serafino Gladiali and Martin Albrecht

Dalton Trans., 2012, 41, 8813
DOI: 10.1039/c2dt30799e

Rhodium-catalysed asymmetric hydrogenation as a valuable synthetic tool for the preparation of chiral drugs

Pablo Etayo and Anton Vidal-Ferran

Chem. Soc. Rev., 2013, 42, 728
DOI: 10.1039/C2CS35410A

The diastereoselective synthesis of octahedral cationic iridium hydride complexes with a stereogenic metal centre

Nicolas Humbert and Clément Mazet

Chem. Commun., 2016, 52, 10629
DOI: 10.1039/C6CC06020J

Captured at last: a catalyst–substrate adduct and a Rh-dihydride solvate in the asymmetric hydrogenation by a Rh-monophosphine catalyst

Ilya D. Gridnev, Elisabetta Alberico and Serafino Gladiali

Chem. Commun., 2012, 48, 2186
DOI: 10.1039/c2cc17335b

Naphthyridine–2NO, a new C2-symmetric rigid tetradentate bimetallic ligand and its application in asymmetric Friedel–Crafts alkylation

Pan Hu, Ke-Lan Xu, Xi-Rui Wang, Zi-Yue Chen, Wen-Hui Zhang, Ying Zhou, Wen-Jing Zhang and Xiong-Li Liu

Org. Chem. Front., 2024, 11, 2600
DOI: 10.1039/D4QO00248B

Stereodivergent asymmetric synthesis of P-atropisomeric Si-stereogenic monohydrosilanes

Bo Yang, Xingfa Tan, Yicong Ge, Yingzi Li and Chuan He

Org. Chem. Front., 2023, 10, 4862
DOI: 10.1039/D3QO01084H

Ruthenium‐Containing Phosphinesulfonate Chelate for the Hydrogenation of Aryl Ketones

Fan Jiang, Kedong Yuan, Mathieu Achard and Christian Bruneau

Chemistry A European J, 2013, 19, 10343
DOI: 10.1002/chem.201301201

Leveraging Fluorescent Emission to Unitary Yield: Dimerization of Polycyclic Aromatic Hydrocarbons

Tanja Miletić, Nicolas Biot, Nicola Demitri, Giuseppe Brancato, Benson M. Kariuki and Davide Bonifazi

Helvetica Chimica Acta, 2019, 102
DOI: 10.1002/hlca.201900004

Ph‐tetraMe‐Bithienine, the First Member of the Class of Chiral Heterophosphepines: Synthesis, Electronic and Steric Properties, Metal Complexes and Catalytic Activity

Luca Vaghi, Tiziana Benincori, Roberto Cirilli, Elisabetta Alberico, Patrizia Romana Mussini, Marco Pierini, Tullio Pilati, Simona Rizzo and Francesco Sannicolò

Eur J Org Chem, 2013, 2013, 8174
DOI: 10.1002/ejoc.201301098

Phosphine-Catalyzed Enantioselective Intramolecular [3+2] Annulations To Generate Fused Ring Systems

Sarah Yunmi Lee, Yuji Fujiwara, Atsuko Nishiguchi, Marcin Kalek and Gregory C. Fu

J. Am. Chem. Soc., 2015, 137, 4587
DOI: 10.1021/jacs.5b01985

Electrochemical Dearomatization: Evolution from Chemicals to Traceless Electrons

Shide Lv, Guofeng Zhang, Jianbin Chen and Wei Gao

Adv Synth Catal, 2020, 362, 462
DOI: 10.1002/adsc.201900750

Aromatic Amide‐Derived Non‐Biaryl Atropisomers as Highly Efficient Ligands in Silver‐Catalyzed Asymmetric Cycloaddition Reactions

Xing‐Feng Bai, Tao Song, Zheng Xu, Chun‐Gu Xia, Wei‐Sheng Huang and Li‐Wen Xu

Angew Chem Int Ed, 2015, 54, 5255
DOI: 10.1002/anie.201501100

Palladium‐Catalyzed Asymmetric Hydrogenolysis of Aryl Triflates for Construction of Axially Chiral Biaryls

Xiang Li, Gao‐Wei Wang, Li‐Xia Liu, Chang‐Bin Yu and Yong‐Gui Zhou

Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202301337

The Discovery of Multifunctional Chiral P Ligands for the Catalytic Construction of Quaternary Carbon/Silicon and Multiple Stereogenic Centers

Fei Ye, Zheng Xu and Li-Wen Xu

Acc. Chem. Res., 2021, 54, 452
DOI: 10.1021/acs.accounts.0c00740

Palladium-Catalyzed Desymmetric Intermolecular C–N Coupling Enabled by a Chiral Monophosphine Ligand Derived from Anthracene Photodimer

Xin Wang, Wei-Gang Liu, Lan-Tao Liu, Xiao-Di Yang, Shu Niu, Chen-Ho Tung, Li-Zhu Wu and Huan Cong

Org. Lett., 2021, 23, 5485
DOI: 10.1021/acs.orglett.1c01839

Enantio‐ und Diastereoselektive Desymmetrisierung von 1,1’‐Biaryl‐2,6‐Dicarbaldehyden durch kupferkatalysierte 1,2‐Addition von Siliciumnukleophilen

Yao Xiao, Zhi‐Yuan Zhao, Elisabeth Irran and Martin Oestreich

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202414005

Highly Modular C1‐Symmetric Chiral (P,N) Ligands with a Stereolabile P Center: Experimental and Theoretical Studies

Nicolas Humbert, Evgeny Larionov, Luca Mantilli, Pradeep Nareddy, Céline Besnard, Laure Guénée and Clément Mazet

Chemistry A European J, 2014, 20, 745
DOI: 10.1002/chem.201303146

ChemInform Abstract: BINEPINES: Chiral Binaphthalene‐Core Monophosphepine Ligands for Multipurpose Asymmetric Catalysis

Serafino Gladiali, Elisabetta Alberico, Kathrin Junge and Matthias Beller

ChemInform, 2011, 42
DOI: 10.1002/chin.201149237

From Mechanistic Study to Chiral Catalyst Optimization: Theoretical Insight into Binaphthophosphepine-catalyzed Asymmetric Intramolecular [3 + 2] Cycloaddition

Meng Duan, Lei Zhu, Xiaotian Qi, Zhaoyuan Yu, Yingzi Li, Ruopeng Bai and Yu Lan

Sci Rep, 2017, 7
DOI: 10.1038/s41598-017-07863-9

Hidden Enantioselective Hydrogenation of N-Silyl Enamines and Silyl Enol Ethers in Net C═N and C═O Hydrosilylations Catalyzed by Ru–S Complexes with One Monodentate Chiral Phosphine Ligand

Susanne Bähr and Martin Oestreich

Organometallics, 2017, 36, 935
DOI: 10.1021/acs.organomet.7b00030

Biphenyl‐Derived Phosphepines as Chiral Nucleophilic Catalysts: Enantioselective [4+1] Annulations To Form Functionalized Cyclopentenes

Daniel T. Ziegler, Lorena Riesgo, Takuya Ikeda, Yuji Fujiwara and Gregory C. Fu

Angewandte Chemie, 2014, 126, 13399
DOI: 10.1002/ange.201405854

Diastereoselective Synthesis of Planar Chiral Phosphoramidites with a Ferrocenophane Scaffold

Mathilde Neel, Pascal Retailleau, Arnaud Voituriez and Angela Marinetti

Organometallics, 2018, 37, 797
DOI: 10.1021/acs.organomet.7b00700

Synthesis of Blue-Luminescent Seven-Membered Phosphorus Heterocycles

Elzbieta Regulska, Heiko Ruppert, Frank Rominger and Carlos Romero-Nieto

J. Org. Chem., 2020, 85, 1247
DOI: 10.1021/acs.joc.9b02723

Homochiral arsenic-/phosphorus-based ligands

Di Lu and Geoff Salem

Coordination Chemistry Reviews, 2013, 257, 1026
DOI: 10.1016/j.ccr.2012.06.033

Efficient Asymmetric Hydrogenation of α‐Acetamidocinnamates through a Simple, Readily Available Monodentate Chiral H‐Phosphinate

Xiang‐Bo Wang, Midori Goto and Li‐Biao Han

Chemistry A European J, 2014, 20, 3631
DOI: 10.1002/chem.201304675

Phosphine-Catalyzed (4 + 2) Cycloaddition of Conjugated Dienes with Enones and Its Asymmetric Variant

Ke Li, Zhenjie Gan, Er-Qing Li and Zheng Duan

Org. Lett., 2021, 23, 3094
DOI: 10.1021/acs.orglett.1c00780

Biphenyl‐Derived Phosphepines as Chiral Nucleophilic Catalysts: Enantioselective [4+1] Annulations To Form Functionalized Cyclopentenes

Daniel T. Ziegler, Lorena Riesgo, Takuya Ikeda, Yuji Fujiwara and Gregory C. Fu

Angew Chem Int Ed, 2014, 53, 13183
DOI: 10.1002/anie.201405854

HPLC Enantioseparation of Rigid Chiral Probes with Central, Axial, Helical, and Planar Stereogenicity on an Amylose (3,5-Dimethylphenylcarbamate) Chiral Stationary Phase

Simona Rizzo, Tiziana Benincori, Francesca Fontana, Dario Pasini and Roberto Cirilli

Molecules, 2022, 27, 8527
DOI: 10.3390/molecules27238527

Atropoisomeric (P,N) Ligands for the Highly Enantioselective Pd‐Catalyzed Intramolecular Asymmetric α‐Arylation of α‐Branched Aldehydes

Pradeep Nareddy, Luca Mantilli, Laure Guénée and Clément Mazet

Angewandte Chemie, 2012, 124, 3892
DOI: 10.1002/ange.201108061

Chiral monodentate phosphine ligands for the enantioselective α- and γ-arylation of aldehydes

Ivan Franzoni, Laure Guénée and Clément Mazet

Tetrahedron, 2014, 70, 4181
DOI: 10.1016/j.tet.2014.02.079

JoyaPhos: An Atropisomeric Teraryl Monophosphine Ligand

Alessandro Castrogiovanni, Dominik Lotter, Fabian R. Bissegger and Christof Sparr

Chemistry A European J, 2020, 26, 9864
DOI: 10.1002/chem.202001269

Enantioselective One‐Pot Synthesis of α‐Amino Esters by a Phosphine‐Catalyzed [3+2]‐Cycloaddition Reaction

Marianne Steurer, Kim L. Jensen, Dennis Worgull and Karl Anker Jørgensen

Chemistry A European J, 2012, 18, 76
DOI: 10.1002/chem.201103502

Enantio‐ and Diastereoselective Desymmetrization of 1,1’‐Biaryl‐2,6‐Dicarbaldehydes by Copper‐Catalyzed 1,2‐Addition of Silicon Nucleophiles

Yao Xiao, Zhi‐Yuan Zhao, Elisabeth Irran and Martin Oestreich

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202414005

Efficient Construction of Chiral Binaphthalene-Core Phosphepine Compounds Using Palladium-Catalyzed C—P Coupling Reactions

Cuiying Wang, Ying Zhang, Jia-Lian Zheng, Jia Yuan, Sixuan Meng, Jian Chen and Guang-Ao Yu

Chinese Journal of Organic Chemistry, 2024, 44, 3771
DOI: 10.6023/cjoc202404004

Chiral Monophosphorus Ligands for Asymmetric Catalytic Reactions

Wenzhen Fu and Wenjun Tang

ACS Catal., 2016, 6, 4814
DOI: 10.1021/acscatal.6b01001

Neutral η6-arene ruthenium complexes with monodentate P-donor ligands

Arnald Grabulosa, Alberto Mannu, Elisabetta Alberico, Stefania Denurra, Serafino Gladiali and Guillermo Muller

Journal of Molecular Catalysis A: Chemical, 2012, 363-364, 49
DOI: 10.1016/j.molcata.2012.05.015

Diastereo‐ and Enantioselective Intramolecular C(sp3)H Arylation for the Synthesis of Fused Cyclopentanes

Nicolas Martin, Cathleen Pierre, Michaël Davi, Rodolphe Jazzar and Olivier Baudoin

Chemistry A European J, 2012, 18, 4480
DOI: 10.1002/chem.201200018

Helical‐Chiral Small Molecules in Asymmetric Catalysis

Maurice J. Narcis and Norito Takenaka

Eur J Org Chem, 2014, 2014, 21
DOI: 10.1002/ejoc.201301045

Asymmetric Hydrophosphination of Heterobicyclic Alkenes: Facile Access to Phosphine Ligands for Asymmetric Catalysis

Zhiwu Lu, Haoyang Zhang, Zhiping Yang, Ning Ding, Ling Meng and Jun Wang

ACS Catal., 2019, 9, 1457
DOI: 10.1021/acscatal.8b04787

Chiral Catalysts for Pd0‐Catalyzed Enantioselective C−H Activation

Oleksandr Vyhivskyi, Anton Kudashev, Takeru Miyakoshi and Olivier Baudoin

Chemistry A European J, 2021, 27, 1231
DOI: 10.1002/chem.202003225

Synthesis and Hydrogenation Activity of Iron Dialkyl Complexes with Chiral Bidentate Phosphines

Jordan M. Hoyt, Michael Shevlin, Grant W. Margulieux, Shane W. Krska, Matthew T. Tudge and Paul J. Chirik

Organometallics, 2014, 33, 5781
DOI: 10.1021/om500329q

Efficient Pd0-Catalyzed Asymmetric Activation of Primary and Secondary C–H Bonds Enabled by Modular Binepine Ligands and Carbonate Bases

Philipp M. Holstein, Maria Vogler, Paolo Larini, Guillaume Pilet, Eric Clot and Olivier Baudoin

ACS Catal., 2015, 5, 4300
DOI: 10.1021/acscatal.5b00898

Brønsted‐Säure‐Aktivierung bei der übergangsmetallkatalysierten asymmetrischen Hydrierung N‐ungeschützter Imine, Enamine und N‐Heteroarene

Zhengkun Yu, Weiwei Jin and Quanbin Jiang

Angewandte Chemie, 2012, 124, 6164
DOI: 10.1002/ange.201200963

Organocatalytic Asymmetric Arylation of p-Quinone Phosphonates: A Green Access to Biaryl Monophosphorus Ligands

Guodong Sun, Zhuofei Deng, Zhonghua Luo, Zhongqing Wang and Jiancun Zhang

Org. Lett., 2021, 23, 7630
DOI: 10.1021/acs.orglett.1c02852

Modular POP Ligands in Rhodium‐Mediated Asymmetric Hydrogenation: A Comparative Catalysis Study

José L. Núñez‐Rico, Pablo Etayo, Héctor Fernández‐Pérez and Anton Vidal‐Ferran

Adv Synth Catal, 2012, 354, 3025
DOI: 10.1002/adsc.201200477

Chiral Rhodium Complexes Derived From Electron-Rich Phosphine-Phosphites as Asymmetric Hydrogenation Catalysts

Pablo Etayo, José L. Núñez-Rico and Anton Vidal-Ferran

Organometallics, 2011, 30, 6718
DOI: 10.1021/om200933b

Palladium‐Catalyzed Asymmetric Hydrogenolysis of Aryl Triflates for Construction of Axially Chiral Biaryls

Xiang Li, Gao‐Wei Wang, Li‐Xia Liu, Chang‐Bin Yu and Yong‐Gui Zhou

Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202301337

The α,α‐Dihalocarbonyl Building Blocks: An Avenue for New Reaction Development in Organic Synthesis

Santu Sadhukhan, Jampani Santhi and Beeraiah Baire

Chemistry A European J, 2020, 26, 7145
DOI: 10.1002/chem.201905475

Chiral microspheres constructed by helical substituted polyacetylene: A new class of organocatalyst toward asymmetric catalysis

Dongyue Zhang, Haiyang Zhang, Ci Song, Wantai Yang and Jianping Deng

Synthetic Metals, 2012, 162, 1858
DOI: 10.1016/j.synthmet.2012.08.019

Diphosphorus Ligands Containing a P‐Stereogenic Phosphane and a Chiral Phosphite or Phosphorodiamidite – Evaluation in Pd‐Catalysed Asymmetric Allylic Substitution Reactions

Pau Clavero, Arnald Grabulosa, Mercè Rocamora, Guillermo Muller and Mercè Font‐Bardia

Eur J Inorg Chem, 2016, 2016, 4054
DOI: 10.1002/ejic.201600550

Fine tuning of the structure of phosphine–phosphoramidites: application for rhodium-catalyzed asymmetric hydrogenations

Szabolcs Balogh, Gergely Farkas, Áron Szöllősy, Ferenc Darvas, László Ürge and József Bakos

Tetrahedron: Asymmetry, 2013, 24, 66
DOI: 10.1016/j.tetasy.2012.11.013

Brønsted Acid Activation Strategy in Transition‐Metal Catalyzed Asymmetric Hydrogenation of N‐Unprotected Imines, Enamines, and N‐Heteroaromatic Compounds

Zhengkun Yu, Weiwei Jin and Quanbin Jiang

Angew Chem Int Ed, 2012, 51, 6060
DOI: 10.1002/anie.201200963

Phenoxaphosphonium Mixed Ylides in Ring Expansion Reaction

Anton S. Nenashev, Dmitrii A. Dospekhov, Mikhail V. Zavaruev, Irina I. Levina, Vitaly A. Roznyatovsky, Andrey V. Mironov, Anna S. Pavlova and Tatyana A. Podrugina

J. Org. Chem., 2024, 89, 6533
DOI: 10.1021/acs.joc.4c00047

On the Theme of Amidiniophosphines: Synthesis and Reactivity of Benzo-, Diimidazolo-Tris-Annelated P-Aminodiazaphosphepines

Amelle Mankou Makaya, Yves Canac, Christian Bijani, Carine Duhayon and Remi Chauvin

Phosphorus, Sulfur, and Silicon and the Related Elements, 2015, 190, 789
DOI: 10.1080/10426507.2014.1002613

Atropoisomeric (P,N) Ligands for the Highly Enantioselective Pd‐Catalyzed Intramolecular Asymmetric α‐Arylation of α‐Branched Aldehydes

Pradeep Nareddy, Luca Mantilli, Laure Guénée and Clément Mazet

Angew Chem Int Ed, 2012, 51, 3826
DOI: 10.1002/anie.201108061

Aromatic Amide‐Derived Non‐Biaryl Atropisomers as Highly Efficient Ligands in Silver‐Catalyzed Asymmetric Cycloaddition Reactions

Xing‐Feng Bai, Tao Song, Zheng Xu, Chun‐Gu Xia, Wei‐Sheng Huang and Li‐Wen Xu

Angewandte Chemie, 2015, 127, 5344
DOI: 10.1002/ange.201501100

Phosphine-Catalyzed Doubly Stereoconvergent γ-Additions of Racemic Heterocycles to Racemic Allenoates: The Catalytic Enantioselective Synthesis of Protected α,α-Disubstituted α-Amino Acid Derivatives

Marcin Kalek and Gregory C. Fu

J. Am. Chem. Soc., 2015, 137, 9438
DOI: 10.1021/jacs.5b05528

RhIII‐Catalyzed Directed C−H Bromination and Iodination to Synthesize Atropisomeric Biaryls

Kiseong Kim, Jaeyong Hyun, Jin Kim and Hyunwoo Kim

Asian J Org Chem, 2016, 5, 1107
DOI: 10.1002/ajoc.201600259